This paper deals with the application of Acousto-ultrasonics,in con- junction with Pattern Recognition and Classification techniques,to the identification of residual impact properties of a class of polymeric material...This paper deals with the application of Acousto-ultrasonics,in con- junction with Pattern Recognition and Classification techniques,to the identification of residual impact properties of a class of polymeric material,namely,Polyvinylchlo- ride(PVC).PVC specimens of different low-energy repeated impact damage states are processed by Acousto-ultrasonics(AU)to retrieve AU signals in the form of dig- italized records.These AU signals are grouped as distinct classes,each pertaining to a known level of repeated impact damage.Describing features of these AU signals are used to build Pattern Recognition(PR)Classifiers.These classifiers are used to identify unknown damage states in other PVC specimens by classifying the re- trieved AU signals as belonging to one of the classes.The obtained results indicate that Acousto-ultrasonics in combination with Pattern Recognition and Classification techniques can be used for the quantitative non-destructive identification of damage states in PVC specimens of unknown low-energy repeated impact conditions.展开更多
气氛环境下原位研究催化剂的烧结行为,能够为理解催化剂在预处理以及反应条件下的烧结机理和高稳定催化剂的设计提供重要的实验依据。本文以Au/CeO_(2)模型纳米催化剂为研究对象,利用环境透射电子显微镜原位观察其在O_(2)与CO气氛下的...气氛环境下原位研究催化剂的烧结行为,能够为理解催化剂在预处理以及反应条件下的烧结机理和高稳定催化剂的设计提供重要的实验依据。本文以Au/CeO_(2)模型纳米催化剂为研究对象,利用环境透射电子显微镜原位观察其在O_(2)与CO气氛下的高温动态烧结过程。实验发现,负载在CeO_(2)上的Au纳米颗粒在O_(2)与CO气氛环境中表现出不同的烧结行为,其在O_(2)气氛下具有较高的烧结速度,同时存在颗粒迁移与聚集长大(particle migration and coalescence,PMC)和奥斯特瓦尔德熟化(Ostwald ripening,OR)两种烧结过程;在CO气氛下烧结速度较慢,烧结过程以OR为主。对比不同气氛环境下烧结后催化剂的表面结构可知,CO增加了CeO_(2)表面台阶的数量以及表面氧空位浓度,增强了载体对Au颗粒的锚定作用,从而提升Au/CeO_(2)催化剂的稳定性。展开更多
文摘This paper deals with the application of Acousto-ultrasonics,in con- junction with Pattern Recognition and Classification techniques,to the identification of residual impact properties of a class of polymeric material,namely,Polyvinylchlo- ride(PVC).PVC specimens of different low-energy repeated impact damage states are processed by Acousto-ultrasonics(AU)to retrieve AU signals in the form of dig- italized records.These AU signals are grouped as distinct classes,each pertaining to a known level of repeated impact damage.Describing features of these AU signals are used to build Pattern Recognition(PR)Classifiers.These classifiers are used to identify unknown damage states in other PVC specimens by classifying the re- trieved AU signals as belonging to one of the classes.The obtained results indicate that Acousto-ultrasonics in combination with Pattern Recognition and Classification techniques can be used for the quantitative non-destructive identification of damage states in PVC specimens of unknown low-energy repeated impact conditions.
文摘气氛环境下原位研究催化剂的烧结行为,能够为理解催化剂在预处理以及反应条件下的烧结机理和高稳定催化剂的设计提供重要的实验依据。本文以Au/CeO_(2)模型纳米催化剂为研究对象,利用环境透射电子显微镜原位观察其在O_(2)与CO气氛下的高温动态烧结过程。实验发现,负载在CeO_(2)上的Au纳米颗粒在O_(2)与CO气氛环境中表现出不同的烧结行为,其在O_(2)气氛下具有较高的烧结速度,同时存在颗粒迁移与聚集长大(particle migration and coalescence,PMC)和奥斯特瓦尔德熟化(Ostwald ripening,OR)两种烧结过程;在CO气氛下烧结速度较慢,烧结过程以OR为主。对比不同气氛环境下烧结后催化剂的表面结构可知,CO增加了CeO_(2)表面台阶的数量以及表面氧空位浓度,增强了载体对Au颗粒的锚定作用,从而提升Au/CeO_(2)催化剂的稳定性。
