The emeraldine base form of polyaniline (PANI) can be doped by a photo-induced doping method. In this method a. copolymer of vinylidene chloride and methyl acrylate (VCMAC) was used as photo acid generator which can r...The emeraldine base form of polyaniline (PANI) can be doped by a photo-induced doping method. In this method a. copolymer of vinylidene chloride and methyl acrylate (VCMAC) was used as photo acid generator which can release proton when it is exposed to ultraviolet light (lambda = 254 nm). The structure of PANI-VCMAC system before and after irradiation was characterized by elemental analysis, IR, XTP, anti SEM images. Results obtained indicate that the photo-induced doping characteristics, such as doping position and type of charge carriers, are similar to that of PANI doped with HCl. The poor room-temperature conductivity (similar to 10-S-5/cm) of PANI-VCMAC system after irradiation may be due to low doping degree (similar to pH=3) and the difference in morphology as compared with PANI-HCl film.展开更多
Phase partition of acrylonitrile in the vinylidene chloride/water system at different temperature and under pressure was studied. A calculation method for average VDC-AN copolymer composition with AN phase partition c...Phase partition of acrylonitrile in the vinylidene chloride/water system at different temperature and under pressure was studied. A calculation method for average VDC-AN copolymer composition with AN phase partition considered was proposed. The calculated results are in good agreement with the experimental data nearly the entire conversion range. VDC-AN copolymer with narrower composition distribution can be prepared in the suspension process and interpreted with dynamic equilibrium of AN between the oil and water phases continuously.展开更多
A series of vinylidene dichloride (VDC) copolymers with methyl acrylate (MA) as comonomer (3-12wt%), was prepared by free-radical suspension copolymerization. The permeability coefficients of the copolymers to oxygen ...A series of vinylidene dichloride (VDC) copolymers with methyl acrylate (MA) as comonomer (3-12wt%), was prepared by free-radical suspension copolymerization. The permeability coefficients of the copolymers to oxygen and carbon dioxide were measured at 1.0 MPa and at 30 degrees C, and those to water vapor were measured at 30 degrees C and 100% relative humidity. All the VDC/MA copolymers studied are semicrystalline. As the MA content increases, the permeability coefficients of the copolymers to oxygen, carbon dioxide, and water vapor are progressively increased, caused by decrease in crystalline fraction and increase in free volume of VDC/MA copolymers.展开更多
The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant difference...The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films, depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.展开更多
The roles of slightly crosslinked poly( dimethyldiallylammonium chloride) s( PDMDAACs) in fixing anionic dyes on cotton fabric were verified more precisely by optical analysis technologies,to achieve the new theoretic...The roles of slightly crosslinked poly( dimethyldiallylammonium chloride) s( PDMDAACs) in fixing anionic dyes on cotton fabric were verified more precisely by optical analysis technologies,to achieve the new theoretical guides for the widely applications. Firstly,one method of optical CIELAB color difference analysis was designed to exactly measure the values of dyefixing performances, so that the suitable molecular weights and structures of the slightly crosslinked PDMDAACs could be precisely confirmed to play a role in the development of their dye-fixing performances. Secondly,the FT-IR absorption shift of the dye on dyed cotton sample fixed by slightly crosslinked PDMDAACs was nearly in agreement with that of forming water-insoluble color lakes,indicating that the expected color lakes could be formed on dyed cotton fabric,and would play a role in further development of the fastness of dyes on cotton fabric. Thirdly,the FT-IR spectra of fixed undyed cotton samples and that of fixed dyed cotton samples both showed the absorptions of slightly crosslinked PDMDAACs,further revealing that the slightly crosslinked PDMDAACs could be penetrated into cotton fabric and be convenient to interact with dyes when fixing. However,those absorptions of the slightly crosslinked PDMDAACs fixed on cotton samples would be absent after being adequately washed to a constant weight,suggesting that the fixing interactions of the slightly crosslinked PDMDAAC and cotton fabric were very weak.展开更多
Three well-defined diblock copolymers ofpoly（methyl methacrylate-b-methacrylic acid） （P（MMA-b-MAA）） were synthesized using atom transfer radical polymerization method and varying poly（methacrylic acid） （PMAA...Three well-defined diblock copolymers ofpoly（methyl methacrylate-b-methacrylic acid） （P（MMA-b-MAA）） were synthesized using atom transfer radical polymerization method and varying poly（methacrylic acid） （PMAA） chain lengths. These copolymers were blended with PVC to fabricate porous membranes via phase inversion process. Membrane morphologies were observed by scanning electron microscopy （SEM）, and chemical composition changes of the membrane surfaces were measured by X-ray photoelectron spectroscopy （XPS）. Static and dynamic protein adsorption experiments were used to evaluate antifouling properties of the blend membranes. It was found that, the blend membranes containing longer PMAA arm length showed lower static protein adsorption, higher water permeation flux and better protein solution flux recovery.展开更多
基金The work was supported by the National Natural Science Foundation of China
文摘The emeraldine base form of polyaniline (PANI) can be doped by a photo-induced doping method. In this method a. copolymer of vinylidene chloride and methyl acrylate (VCMAC) was used as photo acid generator which can release proton when it is exposed to ultraviolet light (lambda = 254 nm). The structure of PANI-VCMAC system before and after irradiation was characterized by elemental analysis, IR, XTP, anti SEM images. Results obtained indicate that the photo-induced doping characteristics, such as doping position and type of charge carriers, are similar to that of PANI doped with HCl. The poor room-temperature conductivity (similar to 10-S-5/cm) of PANI-VCMAC system after irradiation may be due to low doping degree (similar to pH=3) and the difference in morphology as compared with PANI-HCl film.
文摘Phase partition of acrylonitrile in the vinylidene chloride/water system at different temperature and under pressure was studied. A calculation method for average VDC-AN copolymer composition with AN phase partition considered was proposed. The calculated results are in good agreement with the experimental data nearly the entire conversion range. VDC-AN copolymer with narrower composition distribution can be prepared in the suspension process and interpreted with dynamic equilibrium of AN between the oil and water phases continuously.
基金This project supported by the National Natural Science Foundation of China
文摘A series of vinylidene dichloride (VDC) copolymers with methyl acrylate (MA) as comonomer (3-12wt%), was prepared by free-radical suspension copolymerization. The permeability coefficients of the copolymers to oxygen and carbon dioxide were measured at 1.0 MPa and at 30 degrees C, and those to water vapor were measured at 30 degrees C and 100% relative humidity. All the VDC/MA copolymers studied are semicrystalline. As the MA content increases, the permeability coefficients of the copolymers to oxygen, carbon dioxide, and water vapor are progressively increased, caused by decrease in crystalline fraction and increase in free volume of VDC/MA copolymers.
基金The project is supported by Beijing Natural Science Fund.
文摘The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films, depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.
基金Science and Technology Project of Education Department of Jiangxi Province,China(No.GJJ13213)
文摘The roles of slightly crosslinked poly( dimethyldiallylammonium chloride) s( PDMDAACs) in fixing anionic dyes on cotton fabric were verified more precisely by optical analysis technologies,to achieve the new theoretical guides for the widely applications. Firstly,one method of optical CIELAB color difference analysis was designed to exactly measure the values of dyefixing performances, so that the suitable molecular weights and structures of the slightly crosslinked PDMDAACs could be precisely confirmed to play a role in the development of their dye-fixing performances. Secondly,the FT-IR absorption shift of the dye on dyed cotton sample fixed by slightly crosslinked PDMDAACs was nearly in agreement with that of forming water-insoluble color lakes,indicating that the expected color lakes could be formed on dyed cotton fabric,and would play a role in further development of the fastness of dyes on cotton fabric. Thirdly,the FT-IR spectra of fixed undyed cotton samples and that of fixed dyed cotton samples both showed the absorptions of slightly crosslinked PDMDAACs,further revealing that the slightly crosslinked PDMDAACs could be penetrated into cotton fabric and be convenient to interact with dyes when fixing. However,those absorptions of the slightly crosslinked PDMDAACs fixed on cotton samples would be absent after being adequately washed to a constant weight,suggesting that the fixing interactions of the slightly crosslinked PDMDAAC and cotton fabric were very weak.
基金supported by the National 973 Program(No.2009CB623402)the National Natural Science Foundation of China(No.20974094)
文摘Three well-defined diblock copolymers ofpoly（methyl methacrylate-b-methacrylic acid） （P（MMA-b-MAA）） were synthesized using atom transfer radical polymerization method and varying poly（methacrylic acid） （PMAA） chain lengths. These copolymers were blended with PVC to fabricate porous membranes via phase inversion process. Membrane morphologies were observed by scanning electron microscopy （SEM）, and chemical composition changes of the membrane surfaces were measured by X-ray photoelectron spectroscopy （XPS）. Static and dynamic protein adsorption experiments were used to evaluate antifouling properties of the blend membranes. It was found that, the blend membranes containing longer PMAA arm length showed lower static protein adsorption, higher water permeation flux and better protein solution flux recovery.
