The key problem in physical model tests with highly reflective structures is to prevent the multiple reflections between the reflective structures and the wave maker. An active absorption wave maker system is describe...The key problem in physical model tests with highly reflective structures is to prevent the multiple reflections between the reflective structures and the wave maker. An active absorption wave maker system is described and the representative frequency method for irregular waves is proposed in this paper. Physical model tests are conducted to verify the effectiveness of the proposed method.展开更多
A numerical irregular wave flume with active absorption of re-reflected waves is simulated by use of volume of fluid (VOF) method. An active 'absorbing wave-maker based on linear wave theory is set on the left boun...A numerical irregular wave flume with active absorption of re-reflected waves is simulated by use of volume of fluid (VOF) method. An active 'absorbing wave-maker based on linear wave theory is set on the left boundary of the wave flume. The progressive waves and the absorbing waves are generated simultaneously at the active wave generating-absorbing boundary. The absorbing waves are generated to eliminate the waves coming back to the generating boundary due to reflection from the outflow boundary and the structures. SIRW method proposed by Frigaard and Brorsen (1995) is used to separate the incident waves and reflected waves. The digital filters are designed based on the surface elevation signals of the two wave gauges. The corrected velocity of the wave-maker paddle is the output from the digital filter in real time. The numerical results of regular and irregular waves by the active absorbing-generating boundary are compared with the numerical results by the ordinary generating boundary to verify the performance of the active absorbing-generator boundary. The differences between the initial incident waves and the estimated incident waves are analyzed.展开更多
The theory of active absorption of the perforated plate is proposed in this paper.The perforated plate is used as the material of active absorption and the depth of the cavity behind the perforated plate is changed ac...The theory of active absorption of the perforated plate is proposed in this paper.The perforated plate is used as the material of active absorption and the depth of the cavity behind the perforated plate is changed according to the resonant frequency of the perforated plate.The rigid wall is moved to produce resonance so that the absorption coefficient can reach the maximal level.It is shown from the numerical calculation that when the perforated plate resonates,the moving distance is large at low frequencies,and the absorption coefficient is low under certain conditions.Perforated plate resonance is effective for single frequency of incident sound wave,which is difficult for the wide frequency,so active absorption based on airflow is posed,and the numerical calculation and experiment are carried out.The results denote that this method of active absorption is practical.展开更多
The sound characteristic of the piezoelectric ceramics is posed for the excellent mechanic and electric coupling performance of piezoelectric material.Two pieces of piezoelectric ceramic are used as materials of activ...The sound characteristic of the piezoelectric ceramics is posed for the excellent mechanic and electric coupling performance of piezoelectric material.Two pieces of piezoelectric ceramic are used as materials of active absorption and active isolation,two pieces of PVDF with equal distance are placed in the front of the material in order to measure the incidence plane wave and the reflected wave,the voltages are applied on the surface of the material in order to make the reflected wave and transmission wave be zero using the adaptive controlling.At last,emulation is carried out with plane wave,and good absorption and isolation effect is achieved.展开更多
While we process observational data of the Flares 22, two rare phenomena of microwave ultra fast absorption (MUFA) are found for the first time. They occurred at 3 67 GHz and 4 00 GHz in the atmospheric layers above b...While we process observational data of the Flares 22, two rare phenomena of microwave ultra fast absorption (MUFA) are found for the first time. They occurred at 3 67 GHz and 4 00 GHz in the atmospheric layers above both active regions of NOAA/USAF 4808 and 5060 in the interval 05 h50 m17 s~05 h50 m25 s UT on May 19, 1987 and 07 h38 m50 s~07 h38 m58 s UT on June 29, 1988, respectively. These absorption phenomena were observed with Phoenix Ⅱ Micowave Spectrometer at three frequencies (1 42, 2 84 and 3 67 GHz) and (1 42, 2 84 and 4 00 GHz) at Yunnan observatory. Spike emissions appeared at both 2 84 GHz and 1 42 GHz. The notable observational characteristics of both absorption phenomena are given. A possible absorption mechanism of MUFA is discussed.展开更多
The enhancement of chemical absorption of CO2 by K2CO3/H2O absorbents in the presence of activated carbon (AC) particles was investigated. The results show that the gas absorption rates can be enhanced significantly...The enhancement of chemical absorption of CO2 by K2CO3/H2O absorbents in the presence of activated carbon (AC) particles was investigated. The results show that the gas absorption rates can be enhanced significantly in the presence of AC particles, and the maximum enhancement factor 3.7 was observed at low stirring intensities. The enhancement factor increased rapidly with the solid loading during the initial period of absorption and then be- came mild gradually to a maximum value. Both the liquid-solid contact area and the probability of solid particles residing at the gas-liquid interface decreased with the increase of the particle size, leading to a negative effect on the enhancement of mass transfer. The influence of the particles on gas absorption decreased with the reaction rate. The stirring speed changed the interfacial coverage and mass transfer rate on the liquid side and consequently affected the mass transfer between the gas and liquid phases; the enhancement factor decreased with the stirring intensity. A heterogeneous two-zone model was proposed for predicting the enhancement factor and the calculated results agreed well with the experimental data.展开更多
The online flow injection preconcentration and electrothermal atomic absorption spectrometry method were used for the determination of trace nickel in electrolytic manganese samples by sorption on a conical minicolumn...The online flow injection preconcentration and electrothermal atomic absorption spectrometry method were used for the determination of trace nickel in electrolytic manganese samples by sorption on a conical minicolumn packed with activated carbon at pH 9.0. The nickel was eluted from the minicolumn with 10%(v/v) nitric acid. An enrichment factor of 190-fold for a sample volume of 10mL was obtained. The detection limit (DL) of nickel with the use of the preconcentration method was 13ng·g -1in the original solid sample. The precision for 10 replicate determinations at 150ng·g -1 nickel concentration was 5.2% relative standard deviation (RSD). The calibration graph was linear with a correlation coefficient of r=0.9996 up to concentration of 660ng·g -1 nickel.展开更多
This experiment was conducted to determine the influences of adding organic selenium (Se) on growth properties, Se absorption and utilization, immunity and antioxidant activity in diets of Duroc weaning piglets. This ...This experiment was conducted to determine the influences of adding organic selenium (Se) on growth properties, Se absorption and utilization, immunity and antioxidant activity in diets of Duroc weaning piglets. This study was performed on 36 (average weight 7.6 kg) weaning piglets. The weaning piglets were randomly allocated to 1 of 4 homogeneous treatments (A, control treatment, no added Se;B, Sodium selenite, 0.3 mg Se/kg feed;C, yeast Se, 0.3 mg Se/kg;D, DL-methionine Se 0.3 mg Se/kg). Every treatment had 3 replicates, every replicate had 3 piglets. The experiment lasted for 35 d, with the first 7 d for adaptation. Feed intake, residual and contaminated feed were recorded every day. Every piglet weight was weighted respectively at beginning and end of experiment. Daily intake, gain weight and feed conversion rates of every replicate were calculated finally. Se concentrations of serum, blood antioxidant and immunity index were analyzed in the 36th d of experiment. The results showed average daily gain of treatment C was significant higher (P 0.05) and D had higher trend than that of treatment A and B (P = 0.06) respectively. And feed and gain ratio of C and D had trends to lower than them of A and B (P = 0.14). However, all the intake of every week and whole period had no significant differences among treatments (P > 0.05). At same time, except for the Immunoglobulin M of treatment D and C was higher than that of treatment A and B significantly (P < 0.05), all the other Se contents of serum, immunity indexes, blood cell parameters and enzymatic activities had no significant differences among treatments (P > 0.05). But they took on some obvious trends. For example, the Se contents and glutathione peroxidase activities increased successively in order of treatment A, B, C and D;the blood urea nitrogen and total bilirubin of treatment A had higher trend than that of other treatments (P = 0.06). All in all, adding to organic Se in basal diets could improve the animal’s healthy levels, growth properties and Se utilization to some extent. Relatively speaking, the DL-methionine Se had more advantages compared to yeast Se.展开更多
The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)...The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)and phenol(PhOH)were used to prepare a novel class of deep eutectic solvents(DESs)with multiple active sites and low viscosities.The NH_(3) separation performance of EtOHACl+PhOH DESs was analyzed completely.It is figured out that the NH_(3) absorption rates in EtOHACl+PhOH DESs are very fast.The NH_(3) absorption capacities are very high and reach up to 5.52 and 10.74 mol·kg1 at 11.2 and 100.4 kPa under 298.2 K,respectively.In addition,the EtOHACl+PhOH DESs present highly selective absorption of NH_(3) over N_(2) and H_(2) and good regenerative properties after seven cycles of absorption/desorption.The intrinsic separation mechanism of NH_(3) by EtOHACl+PhOH DESs was further revealed by spectroscopic analysis and quantum chemistry calculations.展开更多
This paper explores the correlation between the fractional variation of the ionizing continuum and CⅣbroad absorption lines(BALs)with different ionization levels.Our results reveal anti-correlations between fractiona...This paper explores the correlation between the fractional variation of the ionizing continuum and CⅣbroad absorption lines(BALs)with different ionization levels.Our results reveal anti-correlations between fractional variation of the continuum and fractional equivalency width(EW)variation of the CⅣB ALs without AlⅢB AL/mini-BALs at corresponding velocities,providing evidence for the widespread influence of the ionizing continuum variability on the variation of HiBALs.Conversely,for CⅣBALs accompanied by AlⅢBAL/mini-BALs(LoBAL groups),no significant correction is detected.The absence of such a correlation does not rule out the possibility that variations in these low-ionization lines are caused by ionizing continuum variability,but rather suggests the influence of B AL saturation to some extent.This saturation effect is reflected in the distribution of the fractional EW variation,where the CⅣBAL group accompanied by AlⅢBAL has a smaller standard deviation for the best-fitting Gaussian component than the two BAL groups without AlⅢB AL.However,the distribution of fractional variation of their continuum does not show any significant difference.Besides the saturation influence,another potential explanation for the lack of correlations in the LoBAL groups may be the effects of other variability mechanisms besides the ionization change,such as clouds transiting across the line of sight.展开更多
We investigate the relationship between the variability of broad absorption lines(BALs)or narrow absorption lines(NALs)and that of continuum using a data set of two-epoch SDSS spectra containing 134 C IV NAL-BAL pairs...We investigate the relationship between the variability of broad absorption lines(BALs)or narrow absorption lines(NALs)and that of continuum using a data set of two-epoch SDSS spectra containing 134 C IV NAL-BAL pairs.Our analysis reveals an anti-correlation between the fractional equivalent width(EW)variations in NALs(or BALs)and the fractional flux variations of the continuum,with Spearman rank correlation coefficients of r=-0.47(p=1E-08)and r=-0.58(p=1E-13),respectively.In addition,we find a positive correlation between the fractional EW variations in NALs and BALs(r=0.72,p=1E-22),and derive a regression equation ΔEW_(NAL)/<EW_(NAL)>=0.803ΔEW_(BAL)/<EW_(BAL)>+0.008,with an intrinsic scatter of 0.14.These results suggest that the variability in the ionizing continuum may play a significant role in the observed changes in C IV NALs and BALs,supporting the idea of photoionization-driven variability.The co-variability between C IV NALs and BALs may imply that they originate from outflows with similar physical conditions.展开更多
Zeolite A/CS xerogel hybrid films were prepared by in-situ crystallization method with uniform structure and good strength.The hybrid films prepared from the precursor films dried at 50℃showed zeolite A was well crys...Zeolite A/CS xerogel hybrid films were prepared by in-situ crystallization method with uniform structure and good strength.The hybrid films prepared from the precursor films dried at 50℃showed zeolite A was well crystallized.The hybrid films show high water absorption,good elastic strength and Young modulus.The antimicrobial ability of the hybrid films was investigated after Ag^(+)-ion exchanged.The Ag^(+)-exchanged hybrid films with 35%(mass)content of zeolite A showed the highest antimicrobial activity,which could reduce the concentration of the microbial to zero after 7 h.展开更多
The effects of polyaspartate protease fertilizer enhancer, made from oyster shell proteins, on the absorption of soil nutrition and the enzymatic activities of crops were studied. It has been found that the enhancer c...The effects of polyaspartate protease fertilizer enhancer, made from oyster shell proteins, on the absorption of soil nutrition and the enzymatic activities of crops were studied. It has been found that the enhancer contributes 30%, 50% and 50% augmentation of nitrogen (N), phosphate (P) and potassium (K) absorption respectively and about 20% of nitrate reductase and peroxide enzyme activities of crops. These results show that polyaspartate protease fertilizer enhancer could improve significantly the absorption and utilization efficiencies of soil nutrition and the activities of nitrate reductase and peroxide enzyme of crops, thus elevating the utilization rates of chemical fertilizers to a certain extent.展开更多
Physical model tests with highly reflective structures often encounter a problem of multiple reflections between the structures and the wavemaker. This paper presents a piston-type active absorbing wavemaker system wh...Physical model tests with highly reflective structures often encounter a problem of multiple reflections between the structures and the wavemaker. This paper presents a piston-type active absorbing wavemaker system which can absorb most of the reflections. Based on the first-order wavemaker theory, a frequency domain absorption transfer function is modeled. Its time realization can be achieved by designing an IIR digital filter, which is used to control the absorbing wavemaker system. In a real system, time delays often exist in the wave making process. Thus a delay compensation term to the transfer function is proposed. Experimental results show that the system performs well for both regular and irregular waves with periods from 0.6 s to 2.0 s, and the absorption capability is larger than 96.5% at target wave fields.展开更多
We report the discovery of a broad absorption line (BAL) of - 10^4 km s^-1 in width in the previously known BL Lac object PKS 0138-097, which we tentatively identified as an Mg II BAL. This is the first detection of...We report the discovery of a broad absorption line (BAL) of - 10^4 km s^-1 in width in the previously known BL Lac object PKS 0138-097, which we tentatively identified as an Mg II BAL. This is the first detection of a BAL, which is sometimes seen in powerful quasars with high accretion rates, in a BL Lac object. The BAL was clearly detected in its spectra spanning two epochs at a high luminosity state taken in the Sloan Digital Sky Survey (SDSS), while it disappeared in three SDSS spectra taken at a low luminosity state. The BAL and its variability pattern were also found in its historical multi-epoch spectra in the literature, but have been overlooked previously. In its high resolution radio maps, PKS 0138-097 shows a core plus a one- sided parsec-scale jet. The BAL variability can be interpreted as follows: The optical emission is dominated by the core in a high state and by the jet in a low state and the BAL material is located between the core and jet so that the BAL appears only when the core is shining. Our discovery suggests that outflows may also be produced in active galactic nuclei at a low accreting state.展开更多
The study is focused on the phenomenon of diffusion of water through the shells of two coconut species (coconut nucifera) of Cameroun. The kinetics absorption of water was studied experimentally by the gravimetric met...The study is focused on the phenomenon of diffusion of water through the shells of two coconut species (coconut nucifera) of Cameroun. The kinetics absorption of water was studied experimentally by the gravimetric method with discontinuous control of the mass of the samples at the temperature of 23℃. The mature coconut shells were cleaned mechanically, cut in a spherical shape and placed in a drying oven with 105℃ for 4 hours before being plunged in distilled water at 23℃. This study made it possible not only to determine the rate of water absorbed, but also to model the water kinetic absorption of the shells. Of the two models tested (Peleg and Page), the Page model predicted very well the experimental data. The Fick law made it possible to evaluate the effective diffusivity coefficients at the initial and final phases of absorption. The effective diffusivity coefficient was given from the Arrhenius equation.展开更多
We report the discovery of Balmer broad absorption lines (BALs) in the quasar LBQS 1206+1052 and present a detailed analysis of the peculiar absorption line spectrum. Besides the Mg II λλ2796, 2803 doublet, BALs ...We report the discovery of Balmer broad absorption lines (BALs) in the quasar LBQS 1206+1052 and present a detailed analysis of the peculiar absorption line spectrum. Besides the Mg II λλ2796, 2803 doublet, BALs are also detected in the He I* multiplet at λλ2946, 3189, 3889 A arising from the metastable helium 2 3 S level, and in Hα and Hβ from the excited hydrogen H I* n = 2 level, which are rarely seen in quasar spectra. We identify two components in the BAL troughs of v ~ 2000 km s 1 width: One component shows an identical profile in H I*, He I* and Mg II with its centroid blueshifted by v c ≈ 726 km s-1 . The other component is detected in He I* and Mg II with v c ≈ 1412 km s-1 . We estimate the column densities of H I*, He I*, and Mg II, and compare them with possible level population mechanisms. Our results favor the scenario that the Balmer BALs originate in a partially ionized region with a column density of N H ~ 10 21 10 22 cm-2 for an electron density of n e ~ 10 6 10 8 cm-3 via Lyα resonant scattering pumping. The harsh conditions needed may help to explain the rarity of Balmer absorption line systems in quasar spectra. With an i-band PSF magnitude of 16.50, LBQS 1206+1052 is the brightest Balmer-BAL quasar ever reported. Its high brightness and unique spectral properties make LBQS 1206+1052 a promising candidate for followup high-resolution spectroscopy, multi-band observations, and long-term monitoring.展开更多
Metamaterials have attracted increasing attention in recent years due to their powerful abilities in manipulating electromagnetic (EM) waves. However, most previously reported metamaterials are unable to actively cont...Metamaterials have attracted increasing attention in recent years due to their powerful abilities in manipulating electromagnetic (EM) waves. However, most previously reported metamaterials are unable to actively control full-band EM waves. In this paper, we propose a thermo-tunable broadband metamaterial (T-TBM) using paraffin-based composites (PD-Cs) with different phase transition temperatures. Active control of the T-TBM reflection loss peaks from low to high frequency is realized by manipulating the solid–liquid state of the PD-Cs at different phase transition temperatures. The absorption peak bandwidth (where the reflection loss value is less than −30 dB) can be changed, while the broad bandwidth absorption (where the reflection loss value is less than −10 dB) is satisfied by adjusting the temperature of the T-TBM. It is shown that the stagnation of the phase transition temperature of the PD-Cs in the T-TBM provides a time window for actively controlling the EM wave absorption response under different thermal conditions. The device has a broad application prospect in the fields of EM absorption, intelligent metamaterials, multifunctional structural devices, and more.展开更多
Multiple reflections of the waves between structure and wavemaker in hydraulic flumes could change the frequency content of the desired incident wave or result in resonance. A prominent approach to avoid multiple refl...Multiple reflections of the waves between structure and wavemaker in hydraulic flumes could change the frequency content of the desired incident wave or result in resonance. A prominent approach to avoid multiple reflections is active control of the wavemaker. This paper proposes a simple and practical active control algorithm for piston-type wavemaker. The block diagram of the control system is presented in real time domain. It is shown that there is no need to use any transfer function or filter in the feedback and feed forward loops and the use of constant gains can yield acceptable results. In the operating frequency range(0.25-2 Hz), it is revealed that the proposed system is very effective at suppressing the excitation of resonant sloshing for regular wave. In the case of irregular waves, it is depicted that the experimental waves agree quite well with the desired wave elevation in frequency domain. In addition, comparison of the results obtained both with and without absorption discloses the good characteristics in time domain.展开更多
In order to meet the requirements of the marine environment for microwave absorption(MA)materials,we put forward the strategy of constructing multi-functional composite materials,which integrate microwave absorption,a...In order to meet the requirements of the marine environment for microwave absorption(MA)materials,we put forward the strategy of constructing multi-functional composite materials,which integrate microwave absorption,anti-corrosion,and antibacterial properties.Herein,graphene oxide(GO)was used as a template to induce the growth of zeolitic imidazolate framework-8(ZIF-8),simultaneously as a two-dimensional(2D)nanocontainers to load corrosion inhibitors to achieve pH-responsive and self-healing properties.Finally,quaternary ammonium salt(dimethyl octadecyl(3-trimethoxylsilyl propyl)ammonium chloride(DMAOP))and sodium ascorbate(VCNa)were introduced to achieve synergistic antibacterial activity and the reduction of GO.The 2D strip-like structure of ZIF-8 was due to the confined growth induced by the electrostatic attraction between ZIF-8 and GO sheets.The as-obtained reduced GO(RGO)/ZIF-8/DMAOP5 exhibited excellent microwave absorption(MA)properties,with a minimum reflection loss(RL)value of-47.08 dB at 12.73 GHz when the thickness was 2.8 mm.Moreover,the effective absorption bandwidth reached 6.84 GHz.After soaking in 3.5%NaCl solution for 35 days,the RGO/ZIF-8/DMAOP5-0.7%coating still achieved an impedance value of 4.585×107Ω·cm^(2) and a protective efficiency of 99.994%,providing superior anti-corrosion properties.In addition,fantastic antibacterial activity was obtained,with the antibacterial rates of RGO/ZIF-8/DMAOP_(10) reaching 99.39%and 100%against Escherichia coli and Staphylococcus aureus.This work could open new avenues towards the development of a new generation of multifunctional MA materials.展开更多
基金TheworkwasfinanciallysupportedbytheNationalNaturalScienceFoundationofChina(GrantNo .5 990 90 0 1)andFokYingTungEducationFoundation (No .810 68)
文摘The key problem in physical model tests with highly reflective structures is to prevent the multiple reflections between the reflective structures and the wave maker. An active absorption wave maker system is described and the representative frequency method for irregular waves is proposed in this paper. Physical model tests are conducted to verify the effectiveness of the proposed method.
基金supported by the‘New Century Outstanding Talent’Scheme of the Ministry of Education of China(Grant No.NCET-07-0135)
文摘A numerical irregular wave flume with active absorption of re-reflected waves is simulated by use of volume of fluid (VOF) method. An active 'absorbing wave-maker based on linear wave theory is set on the left boundary of the wave flume. The progressive waves and the absorbing waves are generated simultaneously at the active wave generating-absorbing boundary. The absorbing waves are generated to eliminate the waves coming back to the generating boundary due to reflection from the outflow boundary and the structures. SIRW method proposed by Frigaard and Brorsen (1995) is used to separate the incident waves and reflected waves. The digital filters are designed based on the surface elevation signals of the two wave gauges. The corrected velocity of the wave-maker paddle is the output from the digital filter in real time. The numerical results of regular and irregular waves by the active absorbing-generating boundary are compared with the numerical results by the ordinary generating boundary to verify the performance of the active absorbing-generator boundary. The differences between the initial incident waves and the estimated incident waves are analyzed.
基金National Natural Science Foundation of China(No.51705545)。
文摘The theory of active absorption of the perforated plate is proposed in this paper.The perforated plate is used as the material of active absorption and the depth of the cavity behind the perforated plate is changed according to the resonant frequency of the perforated plate.The rigid wall is moved to produce resonance so that the absorption coefficient can reach the maximal level.It is shown from the numerical calculation that when the perforated plate resonates,the moving distance is large at low frequencies,and the absorption coefficient is low under certain conditions.Perforated plate resonance is effective for single frequency of incident sound wave,which is difficult for the wide frequency,so active absorption based on airflow is posed,and the numerical calculation and experiment are carried out.The results denote that this method of active absorption is practical.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51175195,15A460041)
文摘The sound characteristic of the piezoelectric ceramics is posed for the excellent mechanic and electric coupling performance of piezoelectric material.Two pieces of piezoelectric ceramic are used as materials of active absorption and active isolation,two pieces of PVDF with equal distance are placed in the front of the material in order to measure the incidence plane wave and the reflected wave,the voltages are applied on the surface of the material in order to make the reflected wave and transmission wave be zero using the adaptive controlling.At last,emulation is carried out with plane wave,and good absorption and isolation effect is achieved.
文摘While we process observational data of the Flares 22, two rare phenomena of microwave ultra fast absorption (MUFA) are found for the first time. They occurred at 3 67 GHz and 4 00 GHz in the atmospheric layers above both active regions of NOAA/USAF 4808 and 5060 in the interval 05 h50 m17 s~05 h50 m25 s UT on May 19, 1987 and 07 h38 m50 s~07 h38 m58 s UT on June 29, 1988, respectively. These absorption phenomena were observed with Phoenix Ⅱ Micowave Spectrometer at three frequencies (1 42, 2 84 and 3 67 GHz) and (1 42, 2 84 and 4 00 GHz) at Yunnan observatory. Spike emissions appeared at both 2 84 GHz and 1 42 GHz. The notable observational characteristics of both absorption phenomena are given. A possible absorption mechanism of MUFA is discussed.
基金Supported by the National Natural Science Foundation of China (No.20176036).
文摘The enhancement of chemical absorption of CO2 by K2CO3/H2O absorbents in the presence of activated carbon (AC) particles was investigated. The results show that the gas absorption rates can be enhanced significantly in the presence of AC particles, and the maximum enhancement factor 3.7 was observed at low stirring intensities. The enhancement factor increased rapidly with the solid loading during the initial period of absorption and then be- came mild gradually to a maximum value. Both the liquid-solid contact area and the probability of solid particles residing at the gas-liquid interface decreased with the increase of the particle size, leading to a negative effect on the enhancement of mass transfer. The influence of the particles on gas absorption decreased with the reaction rate. The stirring speed changed the interfacial coverage and mass transfer rate on the liquid side and consequently affected the mass transfer between the gas and liquid phases; the enhancement factor decreased with the stirring intensity. A heterogeneous two-zone model was proposed for predicting the enhancement factor and the calculated results agreed well with the experimental data.
文摘The online flow injection preconcentration and electrothermal atomic absorption spectrometry method were used for the determination of trace nickel in electrolytic manganese samples by sorption on a conical minicolumn packed with activated carbon at pH 9.0. The nickel was eluted from the minicolumn with 10%(v/v) nitric acid. An enrichment factor of 190-fold for a sample volume of 10mL was obtained. The detection limit (DL) of nickel with the use of the preconcentration method was 13ng·g -1in the original solid sample. The precision for 10 replicate determinations at 150ng·g -1 nickel concentration was 5.2% relative standard deviation (RSD). The calibration graph was linear with a correlation coefficient of r=0.9996 up to concentration of 660ng·g -1 nickel.
文摘This experiment was conducted to determine the influences of adding organic selenium (Se) on growth properties, Se absorption and utilization, immunity and antioxidant activity in diets of Duroc weaning piglets. This study was performed on 36 (average weight 7.6 kg) weaning piglets. The weaning piglets were randomly allocated to 1 of 4 homogeneous treatments (A, control treatment, no added Se;B, Sodium selenite, 0.3 mg Se/kg feed;C, yeast Se, 0.3 mg Se/kg;D, DL-methionine Se 0.3 mg Se/kg). Every treatment had 3 replicates, every replicate had 3 piglets. The experiment lasted for 35 d, with the first 7 d for adaptation. Feed intake, residual and contaminated feed were recorded every day. Every piglet weight was weighted respectively at beginning and end of experiment. Daily intake, gain weight and feed conversion rates of every replicate were calculated finally. Se concentrations of serum, blood antioxidant and immunity index were analyzed in the 36th d of experiment. The results showed average daily gain of treatment C was significant higher (P 0.05) and D had higher trend than that of treatment A and B (P = 0.06) respectively. And feed and gain ratio of C and D had trends to lower than them of A and B (P = 0.14). However, all the intake of every week and whole period had no significant differences among treatments (P > 0.05). At same time, except for the Immunoglobulin M of treatment D and C was higher than that of treatment A and B significantly (P < 0.05), all the other Se contents of serum, immunity indexes, blood cell parameters and enzymatic activities had no significant differences among treatments (P > 0.05). But they took on some obvious trends. For example, the Se contents and glutathione peroxidase activities increased successively in order of treatment A, B, C and D;the blood urea nitrogen and total bilirubin of treatment A had higher trend than that of other treatments (P = 0.06). All in all, adding to organic Se in basal diets could improve the animal’s healthy levels, growth properties and Se utilization to some extent. Relatively speaking, the DL-methionine Se had more advantages compared to yeast Se.
基金supported by the National Natural Science Foundation of China(22221005 and 22008033).
文摘The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)and phenol(PhOH)were used to prepare a novel class of deep eutectic solvents(DESs)with multiple active sites and low viscosities.The NH_(3) separation performance of EtOHACl+PhOH DESs was analyzed completely.It is figured out that the NH_(3) absorption rates in EtOHACl+PhOH DESs are very fast.The NH_(3) absorption capacities are very high and reach up to 5.52 and 10.74 mol·kg1 at 11.2 and 100.4 kPa under 298.2 K,respectively.In addition,the EtOHACl+PhOH DESs present highly selective absorption of NH_(3) over N_(2) and H_(2) and good regenerative properties after seven cycles of absorption/desorption.The intrinsic separation mechanism of NH_(3) by EtOHACl+PhOH DESs was further revealed by spectroscopic analysis and quantum chemistry calculations.
基金supported by the Guangxi Natural Science Foundation(No.2021GXNSFBA220044)the National Natural Science Foundation of China(No.11903002)the Research Project of Baise University(No.2019KN04)。
文摘This paper explores the correlation between the fractional variation of the ionizing continuum and CⅣbroad absorption lines(BALs)with different ionization levels.Our results reveal anti-correlations between fractional variation of the continuum and fractional equivalency width(EW)variation of the CⅣB ALs without AlⅢB AL/mini-BALs at corresponding velocities,providing evidence for the widespread influence of the ionizing continuum variability on the variation of HiBALs.Conversely,for CⅣBALs accompanied by AlⅢBAL/mini-BALs(LoBAL groups),no significant correction is detected.The absence of such a correlation does not rule out the possibility that variations in these low-ionization lines are caused by ionizing continuum variability,but rather suggests the influence of B AL saturation to some extent.This saturation effect is reflected in the distribution of the fractional EW variation,where the CⅣBAL group accompanied by AlⅢBAL has a smaller standard deviation for the best-fitting Gaussian component than the two BAL groups without AlⅢB AL.However,the distribution of fractional variation of their continuum does not show any significant difference.Besides the saturation influence,another potential explanation for the lack of correlations in the LoBAL groups may be the effects of other variability mechanisms besides the ionization change,such as clouds transiting across the line of sight.
基金supported by the Guangxi Natural Science Foundation(No.2021GXNSFBA220044)the National Natural Science Foundation of China(No.11903002)the Research Project of Baise University(No.2019KN04)。
文摘We investigate the relationship between the variability of broad absorption lines(BALs)or narrow absorption lines(NALs)and that of continuum using a data set of two-epoch SDSS spectra containing 134 C IV NAL-BAL pairs.Our analysis reveals an anti-correlation between the fractional equivalent width(EW)variations in NALs(or BALs)and the fractional flux variations of the continuum,with Spearman rank correlation coefficients of r=-0.47(p=1E-08)and r=-0.58(p=1E-13),respectively.In addition,we find a positive correlation between the fractional EW variations in NALs and BALs(r=0.72,p=1E-22),and derive a regression equation ΔEW_(NAL)/<EW_(NAL)>=0.803ΔEW_(BAL)/<EW_(BAL)>+0.008,with an intrinsic scatter of 0.14.These results suggest that the variability in the ionizing continuum may play a significant role in the observed changes in C IV NALs and BALs,supporting the idea of photoionization-driven variability.The co-variability between C IV NALs and BALs may imply that they originate from outflows with similar physical conditions.
基金We are grateful for financial support from the National&Local Joint Engineering Research Center for Deep Utilization Technology of Rock-salt Resource(SF201804)Opening Topic of Key Laboratory of Attapulgite Resources Utilization in Jiangsu Province(HPK201804)Jiangsu Province Industry University Research Project(BY2019133).
文摘Zeolite A/CS xerogel hybrid films were prepared by in-situ crystallization method with uniform structure and good strength.The hybrid films prepared from the precursor films dried at 50℃showed zeolite A was well crystallized.The hybrid films show high water absorption,good elastic strength and Young modulus.The antimicrobial ability of the hybrid films was investigated after Ag^(+)-ion exchanged.The Ag^(+)-exchanged hybrid films with 35%(mass)content of zeolite A showed the highest antimicrobial activity,which could reduce the concentration of the microbial to zero after 7 h.
文摘The effects of polyaspartate protease fertilizer enhancer, made from oyster shell proteins, on the absorption of soil nutrition and the enzymatic activities of crops were studied. It has been found that the enhancer contributes 30%, 50% and 50% augmentation of nitrogen (N), phosphate (P) and potassium (K) absorption respectively and about 20% of nitrate reductase and peroxide enzyme activities of crops. These results show that polyaspartate protease fertilizer enhancer could improve significantly the absorption and utilization efficiencies of soil nutrition and the activities of nitrate reductase and peroxide enzyme of crops, thus elevating the utilization rates of chemical fertilizers to a certain extent.
基金financially supported by the National Basic Research Program of China(973 ProgramGrant No.2013CB036101)+1 种基金the National Natural Science Foundation of China(Grant Nos.50879098 and 51221961)Science and Technology Research Projects of Liaoning Provincial Education Department(Grant No.LS2010032)
文摘Physical model tests with highly reflective structures often encounter a problem of multiple reflections between the structures and the wavemaker. This paper presents a piston-type active absorbing wavemaker system which can absorb most of the reflections. Based on the first-order wavemaker theory, a frequency domain absorption transfer function is modeled. Its time realization can be achieved by designing an IIR digital filter, which is used to control the absorbing wavemaker system. In a real system, time delays often exist in the wave making process. Thus a delay compensation term to the transfer function is proposed. Experimental results show that the system performs well for both regular and irregular waves with periods from 0.6 s to 2.0 s, and the absorption capability is larger than 96.5% at target wave fields.
基金Supported by the National Natural Science Foundation of China(Grant Nos. 10973012 and 11033007)the National Basic Research Program of China (973 program Grant Nos.2007CB815405 and 2009CB824800)
文摘We report the discovery of a broad absorption line (BAL) of - 10^4 km s^-1 in width in the previously known BL Lac object PKS 0138-097, which we tentatively identified as an Mg II BAL. This is the first detection of a BAL, which is sometimes seen in powerful quasars with high accretion rates, in a BL Lac object. The BAL was clearly detected in its spectra spanning two epochs at a high luminosity state taken in the Sloan Digital Sky Survey (SDSS), while it disappeared in three SDSS spectra taken at a low luminosity state. The BAL and its variability pattern were also found in its historical multi-epoch spectra in the literature, but have been overlooked previously. In its high resolution radio maps, PKS 0138-097 shows a core plus a one- sided parsec-scale jet. The BAL variability can be interpreted as follows: The optical emission is dominated by the core in a high state and by the jet in a low state and the BAL material is located between the core and jet so that the BAL appears only when the core is shining. Our discovery suggests that outflows may also be produced in active galactic nuclei at a low accreting state.
文摘The study is focused on the phenomenon of diffusion of water through the shells of two coconut species (coconut nucifera) of Cameroun. The kinetics absorption of water was studied experimentally by the gravimetric method with discontinuous control of the mass of the samples at the temperature of 23℃. The mature coconut shells were cleaned mechanically, cut in a spherical shape and placed in a drying oven with 105℃ for 4 hours before being plunged in distilled water at 23℃. This study made it possible not only to determine the rate of water absorbed, but also to model the water kinetic absorption of the shells. Of the two models tested (Peleg and Page), the Page model predicted very well the experimental data. The Fick law made it possible to evaluate the effective diffusivity coefficients at the initial and final phases of absorption. The effective diffusivity coefficient was given from the Arrhenius equation.
基金supported by the National Natural Science Foundation of China(Grants Nos.10973013 and 11033007)the Fundamental Research Funds for the Central Universities through grant WK 2030220006+8 种基金the SOA project CHINARE2012-02-03Funding for the SDSS and SDSS-Ⅱ has been provided by the Alfred P.Sloan Foundationthe Participating Institutionsthe National Science Foundationthe U.S. Department of Energythe National Aeronautics and Space Administrationthe Japanese Monbukagakushothe Max Planck Societythe Higher Education Funding Council for England
文摘We report the discovery of Balmer broad absorption lines (BALs) in the quasar LBQS 1206+1052 and present a detailed analysis of the peculiar absorption line spectrum. Besides the Mg II λλ2796, 2803 doublet, BALs are also detected in the He I* multiplet at λλ2946, 3189, 3889 A arising from the metastable helium 2 3 S level, and in Hα and Hβ from the excited hydrogen H I* n = 2 level, which are rarely seen in quasar spectra. We identify two components in the BAL troughs of v ~ 2000 km s 1 width: One component shows an identical profile in H I*, He I* and Mg II with its centroid blueshifted by v c ≈ 726 km s-1 . The other component is detected in He I* and Mg II with v c ≈ 1412 km s-1 . We estimate the column densities of H I*, He I*, and Mg II, and compare them with possible level population mechanisms. Our results favor the scenario that the Balmer BALs originate in a partially ionized region with a column density of N H ~ 10 21 10 22 cm-2 for an electron density of n e ~ 10 6 10 8 cm-3 via Lyα resonant scattering pumping. The harsh conditions needed may help to explain the rarity of Balmer absorption line systems in quasar spectra. With an i-band PSF magnitude of 16.50, LBQS 1206+1052 is the brightest Balmer-BAL quasar ever reported. Its high brightness and unique spectral properties make LBQS 1206+1052 a promising candidate for followup high-resolution spectroscopy, multi-band observations, and long-term monitoring.
基金supported by the National Natural Science Foundation of China(52003203 and 52075422)the Rapid Manufacturing Engineering Technology Research Center of Shaanxi Province(2017HBGC-06)the Youth Innovation Team of Shaanxi Universities,and the K.C.Wong Education Foundation.
文摘Metamaterials have attracted increasing attention in recent years due to their powerful abilities in manipulating electromagnetic (EM) waves. However, most previously reported metamaterials are unable to actively control full-band EM waves. In this paper, we propose a thermo-tunable broadband metamaterial (T-TBM) using paraffin-based composites (PD-Cs) with different phase transition temperatures. Active control of the T-TBM reflection loss peaks from low to high frequency is realized by manipulating the solid–liquid state of the PD-Cs at different phase transition temperatures. The absorption peak bandwidth (where the reflection loss value is less than −30 dB) can be changed, while the broad bandwidth absorption (where the reflection loss value is less than −10 dB) is satisfied by adjusting the temperature of the T-TBM. It is shown that the stagnation of the phase transition temperature of the PD-Cs in the T-TBM provides a time window for actively controlling the EM wave absorption response under different thermal conditions. The device has a broad application prospect in the fields of EM absorption, intelligent metamaterials, multifunctional structural devices, and more.
文摘Multiple reflections of the waves between structure and wavemaker in hydraulic flumes could change the frequency content of the desired incident wave or result in resonance. A prominent approach to avoid multiple reflections is active control of the wavemaker. This paper proposes a simple and practical active control algorithm for piston-type wavemaker. The block diagram of the control system is presented in real time domain. It is shown that there is no need to use any transfer function or filter in the feedback and feed forward loops and the use of constant gains can yield acceptable results. In the operating frequency range(0.25-2 Hz), it is revealed that the proposed system is very effective at suppressing the excitation of resonant sloshing for regular wave. In the case of irregular waves, it is depicted that the experimental waves agree quite well with the desired wave elevation in frequency domain. In addition, comparison of the results obtained both with and without absorption discloses the good characteristics in time domain.
基金supported by the National Natural Science Foundation of China(Nos.51903213 and 5217130190)the Science and Technology Planning Project of Sichuan Province(Nos.2023NSFSC1952 and 2022ZYD0028)+1 种基金the Central Government Guides Local Science and Technology Development Special Funds to freely explore basic research projects(No.2021Szvup124)the Fundamental Research Funds for the Central Universities(No.2682021GF004).
文摘In order to meet the requirements of the marine environment for microwave absorption(MA)materials,we put forward the strategy of constructing multi-functional composite materials,which integrate microwave absorption,anti-corrosion,and antibacterial properties.Herein,graphene oxide(GO)was used as a template to induce the growth of zeolitic imidazolate framework-8(ZIF-8),simultaneously as a two-dimensional(2D)nanocontainers to load corrosion inhibitors to achieve pH-responsive and self-healing properties.Finally,quaternary ammonium salt(dimethyl octadecyl(3-trimethoxylsilyl propyl)ammonium chloride(DMAOP))and sodium ascorbate(VCNa)were introduced to achieve synergistic antibacterial activity and the reduction of GO.The 2D strip-like structure of ZIF-8 was due to the confined growth induced by the electrostatic attraction between ZIF-8 and GO sheets.The as-obtained reduced GO(RGO)/ZIF-8/DMAOP5 exhibited excellent microwave absorption(MA)properties,with a minimum reflection loss(RL)value of-47.08 dB at 12.73 GHz when the thickness was 2.8 mm.Moreover,the effective absorption bandwidth reached 6.84 GHz.After soaking in 3.5%NaCl solution for 35 days,the RGO/ZIF-8/DMAOP5-0.7%coating still achieved an impedance value of 4.585×107Ω·cm^(2) and a protective efficiency of 99.994%,providing superior anti-corrosion properties.In addition,fantastic antibacterial activity was obtained,with the antibacterial rates of RGO/ZIF-8/DMAOP_(10) reaching 99.39%and 100%against Escherichia coli and Staphylococcus aureus.This work could open new avenues towards the development of a new generation of multifunctional MA materials.