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HPR1000: Advanced Pressurized Water Reactor with Active and Passive Safety 被引量:24
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作者 Ji xing Daiyong Song Yuxiang Wu 《Engineering》 SCIE EI 2016年第1期79-87,共9页
HPR1000 is an advanced nuclear power plant(NPP)with the significant feature of an active and passive safety design philosophy,developed by the China National Nuclear Corporation.On one hand,it is an evolutionary desig... HPR1000 is an advanced nuclear power plant(NPP)with the significant feature of an active and passive safety design philosophy,developed by the China National Nuclear Corporation.On one hand,it is an evolutionary design based on proven technology of the existing pressurized water reactor NPP;on the other hand,it incorporates advanced design features including a 177-fuel-assembly core loaded with CF3 fuel assemblies,active and passive safety systems,comprehensive severe accident prevention and mitigation measures,enhanced protection against external events,and improved emergency response capability.Extensive verification experiments and tests have been performed for critical innovative improvements on passive systems,the reactor core,and the main equipment.The design of HPR1000fulfills the international utility requirements for advanced light water reactors and the latest nuclear safety requirements,and addresses the safety issues relevant to the Fukushima accident.Along with its outstanding safety and economy,HPR1000 provides an excellent and practicable solution for both domestic and international nuclear power markets. 展开更多
关键词 被动安全系统 先进压水堆 中国核工业集团公司 压水堆核电站 设计哲学 燃料组件 轻水反应堆 进化设计
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Performance of Catalytically Active Membrane Reactors with Different A/V Ratios 被引量:1
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作者 Yang Chen Wei Jia +1 位作者 Jiayu Hu Weidong Zhang 《Transactions of Tianjin University》 EI CAS 2017年第6期521-529,共9页
Although the performance of membrane reactors(MR) is highly affected by the ratio of membrane area-toreaction volume, there are few studies on this effect owing to the difficulties associated with reactor manufacture.... Although the performance of membrane reactors(MR) is highly affected by the ratio of membrane area-toreaction volume, there are few studies on this effect owing to the difficulties associated with reactor manufacture. In this study, an MR with high A/V ratio, a diameter of 35 m,and a height of 0.8 mm was fabricated. Separation performance of this MR was investigated in an n-butanol/water system. Esterification of acetic acid and n-butanol was used as the model reaction to investigate the performance of catalytically active membrane reactors(CAMR)with different A/V ratios. The reaction conversion was 38.59% in the CAMR with the high A/V ratio of 12,497/m,which was much higher than that in other CAMRs, for reaction time of 60 min and W/Vfratio of 0.093 g/mL.Excellent catalytic stability of the CAMR was confirmed by performing long-term stability experiments. 展开更多
关键词 Catalytically active MEMBRANE reactor A/V ratios Separation–reaction coupling PERVAPORATION
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Removal of Pharmaceutically Active Compounds in Sequencing Batch Reactor
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作者 Beata Kamifiska Koleta Majewska Anna Skwierawska Natalia Lukasik Katarzyna Koztowska-Tylingo , 《Journal of Environmental Science and Engineering(A)》 2015年第9期484-489,共6页
关键词 序批式反应器 活性化合物 高效液相色谱-质谱 高效液相色谱法 化学需氧量 药学 生物降解过程 乙酰唑胺
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Activation characteristics of candidate structural materials for a near-term Indian fusion reactor and the impact of their impurities on design considerations 被引量:2
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作者 H L SWAMI C DANANI A K SHAW 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第6期186-193,共8页
Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help... Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help in the selection of materials for a nuclear reactor,by providing the radioactivity and dose rate levels after irradiation.This information is important to help define maintenance activity for different parts of the reactor,and to plan decommissioning and radioactive waste disposal strategies.The study of activation analyses of candidate structural materials for near-term fusion reactors or ITER is equally essential,due to the presence of a highenergy neutron environment which makes decisive demands on material selection.This study comprises two parts; in the first part the activation characteristics,in a fusion radiation environment,of several elements which are widely present in structural materials,are studied.It reveals that the presence of a few specific elements in a material can diminish its feasibility for use in the nuclear environment.The second part of the study concentrates on activation analyses of candidate structural materials for near-term fusion reactors and their comparison in fusion radiation conditions.The structural materials selected for this study,i.e.India-specific Reduced Activation Ferritic-Martensitic steel(IN-RAFMS),P91-grade steel,stainless steel 316 LN ITER-grade(SS-316 LN-IG),stainless steel 316 L and stainless steel 304,are candidates for use in ITER either in vessel components or test blanket systems.Tungsten is also included in this study because of its use for ITER plasma-facing components.The study is carried out using the reference parameters of the ITER fusion reactor.The activation characteristics of the materials are assessed considering the irradiation at an ITER equatorial port.The presence of elements like Nb,Mo,Co and Ta in a structural material enhance the activity level as well as the dose level,which has an impact on design considerations.IN-RAFMS was shown to be a more effective low-activation material than SS-316 LN-IG. 展开更多
关键词 activATION EASY nuclear safety fusion reactor structural materials
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ATP content and biomass activity in sequential anaerobic/aerobic reactors 被引量:1
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作者 陈红 《Journal of Zhejiang University Science》 EI CSCD 2004年第6期727-732,共6页
Specific ATP content of volatile solids was measured to characterize the sludge activity in a sequential anaerobic/aerobic wastewater treatment system, with an upflow anaerobic sludge blanket (UASB) reactor and a thre... Specific ATP content of volatile solids was measured to characterize the sludge activity in a sequential anaerobic/aerobic wastewater treatment system, with an upflow anaerobic sludge blanket (UASB) reactor and a three-phase aerobic fluidized bed (AFB) reactor. The wastewater COD level was 2000-3000 mg/L in simulation of real textile wastewater. The ATP content and the specific ATP contents of volatile solids at different heights of the UASB reactor and those of the suspended and immobilized biomass in the AFB reactor were measured. In the UASB reactor, the maximum value of specific ATP (0.85 mg ATP/g VS) was obtained at a hydraulic retention time (HRT) 7.14 h in the blanket solution. In the AFB reactor, the specific ATP content of suspended biomass was higher than that of immobilized biomass and increased with hydraulic retention time reaching a maximum value of 1.6 mg ATP/g VS at hydraulic retention time 4.35 h. The ATP content of anaerobes in the UASB effluent declined rapidly under aerobic conditions following a 2nd-order kinetic model. 展开更多
关键词 生物量活性 ATP 三磷酸腺苷 连续厌氧因子 连续需氧因子 废水处理 需氧流化床
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Measurement of Natural and Artificial Radioactivity in Soil at Some Selected Thanas around the TRIGA Mark-II Research Reactor at AERE, Savar, Dhaka
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作者 Shawpan C. Sarkar Idris Ali +2 位作者 Debasish Paul Mahbubur R. Bhuiyan Sheikh M. A. Islam 《Journal of Environmental Protection》 2011年第10期1353-1359,共7页
The activity concentration of natural and fallout radionuclides in the soil at some selected Thanas around the TRIGA Mark-II Research Reactor at Atomic Energy Research Establishment (AERE), Savar, Dhaka were measured ... The activity concentration of natural and fallout radionuclides in the soil at some selected Thanas around the TRIGA Mark-II Research Reactor at Atomic Energy Research Establishment (AERE), Savar, Dhaka were measured by using a high purity germanium detector (HPGe). The study revealed that only natural radionuclides were present in the samples and no trace of any artificial radionuclide was found. The average activity concentration of 238U, 232Th and 40K were found to be 37.8 ± 5.6 Bq.kg-1, 58.2 ± 11.0 Bq.kg-1 and 790.8 ± 153.4 Bq.kg-1 respectively. The radium equivalent activity (Req), absorbed dose rate (D), external radiation hazard index (Hex) and internal radiation hazard index (Hin) were also calculated to find out the probable radiological hazard of the natural radioactivity. 展开更多
关键词 NATURAL RADIONUCLIDE Artificial RADIONUCLIDE HPGE Detector TRIGA Mark-II Research reactor activity Concentration
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Production of Poly-b-hydroxybutyrate by Activated Sludge in Sequencing Batch Reactor under Aerobic Conditions
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作者 李晓岩 JIN Zijing +3 位作者 QIAN Yongyu CUI Daizong CHEN Xiguang 赵敏 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第3期733-738,共6页
In order to improve poly-β-hydroxybutyrate(PHB) production in activated sludge, the anaerobic/aerobic alternative operating sequencing batch reactor(SBR) process was applied in this paper to accumulate PHB. Effec... In order to improve poly-β-hydroxybutyrate(PHB) production in activated sludge, the anaerobic/aerobic alternative operating sequencing batch reactor(SBR) process was applied in this paper to accumulate PHB. Effects of nutritional conditions and carbon concentration on PHB accumulation were studied. Results indicated that PHB accumulation reached the highest level and accounted for 11.2 % under anaerobic condition for phosphate limitation and 20.84 % under aerobic condition for nitrogen and phosphate limitation of mixed liquor suspended solid(MLSS), respectively. In addition, 4 g/L was proved to be the optimum carbon concentration in both anaerobic and aerobic experiments, and the PHB accumulation reached 17.1 %(anaerobic, phosphorus limitation) and 60.4 %(aerobic, nitrogen and phosphorus limitation) of MLSS, respectively. PHB could be successfully extracted with sodium hypochlorite and chloroform method from the activated sludge. In addition, the infrared spectrum showed that the PHB sample extracted was of high purity. 展开更多
关键词 poly-β-hydroxybutyrate(PHB) activated sludge sequencing batch reactor(SBR)
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Combined process of sequencing batch reactor activated sludge process and constructed wetland for domestic wastewater treatment
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作者 魏武强 Wisaam S. Al-Rekabi 《Journal of Chongqing University》 CAS 2010年第4期201-207,共7页
By combining sequencing batch reactor (SBR) activated sludge process and constructed wetland (CW), this study is to achieve the domestic wastewater treatment. Our purpose was to determine the optimum operating paramet... By combining sequencing batch reactor (SBR) activated sludge process and constructed wetland (CW), this study is to achieve the domestic wastewater treatment. Our purpose was to determine the optimum operating parameters of the combined process. The process involved advantages and shortages of SBR and CW. Under normal temperature, the 3rd cycle (SBR’s operation cycle is 8 h: inflow for 1 h, limited aeration for 3 h, sediment for 1 h, outflow for 1 h, and idling for 2 h; CW’s hydraulic retention time (HRT) is 24.8 h and hydraulic loading is 24.5 m3/m2 d) was the best cyclic mode. The effluents can meet the standard GB/T18921-2002: "The reuse of urban recycling water: water quality standard for scenic environment use". In the 3rd cycle, the efficiency of CW was the maximum, and energy consumption of SBR was the minimum. Under the condition of low dissolved oxygen, the removing efficiency of chemical oxygen demand (COD) and ammonia was not affected obviously. Simultaneously, nitrification and denitrification phenomena occured and phosphorus was absorbed obviously. 展开更多
关键词 定序批反应堆激活污泥过程 构造沼泽地 精力消费 低溶解的氧
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反应堆瞬发γ活化成像技术研究进展
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作者 王唯 姚永刚 +5 位作者 肖才锦 赵梁 许小雨 李玉庆 李天富 陈东风 《中国无机分析化学》 CAS 北大核心 2024年第6期685-697,共13页
瞬发γ活化成像技术(Prompt Gamma Activation Imaging,PGAI)是基于瞬发γ中子活化分析技术(Prompt Gamma Neutron Activation Analysis,PGAA)的一种新型元素成像技术,具有PGAA非破坏性、高灵敏度的多元素分析特点,同时可研究大体积样... 瞬发γ活化成像技术(Prompt Gamma Activation Imaging,PGAI)是基于瞬发γ中子活化分析技术(Prompt Gamma Neutron Activation Analysis,PGAA)的一种新型元素成像技术,具有PGAA非破坏性、高灵敏度的多元素分析特点,同时可研究大体积样品内元素含量的三维分布情况。与移动中子源(如同位素中子源、加速器中子源)相比,反应堆中子源具有高通量的冷/热中子,因此,基于反应堆中子源的PGAI装置具有更加广阔的应用前景。鉴于PGAI技术的重要性,主要介绍了PGAI技术原理和测量方法、列举了国内外具有代表性的PGAI装置及特点,并指出当前PGAI技术研究现状与应用进展。其中,与中子层析成像(Neutron Tomography,NT)结合的PGAI是目前研究的重点。随着国内高通量中子反应堆的持续稳定运行以及PGAI装置的建立和技术发展,相信未来PGAI技术能在我国更多领域得到广泛和深入应用。 展开更多
关键词 瞬发γ活化成像 瞬发γ中子活化分析 中子层析成像 图像重建 反应堆中子源
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一回路管道活化腐蚀产物放射性活度计算方法
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作者 李垚 许非 +2 位作者 李莉 左伟 吴耀 《腐蚀与防护》 CAS CSCD 北大核心 2024年第3期75-79,共5页
对不同理论模型、模型方程及其优缺点等方面进行了综述,结合一回路活化腐蚀产物的迁移特性,推导出一种计算方法,对压水堆一回路管道活化腐蚀产物60Co、58Co的放射性活度进行了评估,通过Pactole计算结果对比论证了该方法的可靠性。
关键词 活化腐蚀产物 压水堆 一回路管道
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基于cosRMC的聚变堆输运-活化内耦合方法研究
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作者 王胜哲 刘仕倡 陈义学 《核技术》 EI CAS CSCD 北大核心 2024年第5期55-70,共16页
在聚变反应堆运行过程中,中子活化会导致大量放射性核素的产生,因此活化计算在反应堆的屏蔽设计和辐射安全分析中具有重要作用。本文基于蒙特卡罗粒子输运程序cosRMC的内置燃耗求解器Depth,开发了固定源模式下的内耦合输运-活化耦合计... 在聚变反应堆运行过程中,中子活化会导致大量放射性核素的产生,因此活化计算在反应堆的屏蔽设计和辐射安全分析中具有重要作用。本文基于蒙特卡罗粒子输运程序cosRMC的内置燃耗求解器Depth,开发了固定源模式下的内耦合输运-活化耦合计算功能。将该程序应用于中国聚变工程试验堆(Chinese Fusion EngineeringTestingReactor,CFETR)的第一壁(First-wall,FW)材料钢和面向等离子体部件(Plasma-facing Component,PFC)材料钨,分别使用连续能量截面和多群截面进行活化计算,并与活化程序ALARA进行对比验证,发现cosRMC的计算结果与ALARA计算的结果符合良好,初步验证了开发的cosRMC程序输运-活化内耦合计算功能的正确性。与传统蒙特卡罗-活化计算程序的外耦合方式相比,内耦合方式蒙特卡罗不需要把中子能谱传给外部活化程序,而是在蒙特卡罗中子输运过程中嵌入计算活化相关的核素单群反应截面,动态更新中子能谱和材料信息,同时可以使用连续能量截面进行反应率计算,得到与实际问题的几何、能谱相关的反应截面,从而精确地考虑了共振区核截面的影响。 展开更多
关键词 活化计算 聚变堆 固定源 ALARA cosRMC
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持续负荷冲击下AnSBBR运行性能及群落结构响应
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作者 王泽 于莉芳 +3 位作者 马芷萱 郑兰香 刘然 刘甜 《中国环境科学》 EI CAS CSCD 北大核心 2024年第1期140-149,共10页
以厌氧序批式生物膜反应器(AnSBBR)处理葡萄酒生产废水,考察反应器在持续负荷冲击下的运行特性及群落结构响应.结果显示,持续负荷冲击的前13d(29~41d),反应器运行稳定;因逐渐增加的氢分压和挥发性脂肪酸(VFAs),到56d时系统稳定性降低(VF... 以厌氧序批式生物膜反应器(AnSBBR)处理葡萄酒生产废水,考察反应器在持续负荷冲击下的运行特性及群落结构响应.结果显示,持续负荷冲击的前13d(29~41d),反应器运行稳定;因逐渐增加的氢分压和挥发性脂肪酸(VFAs),到56d时系统稳定性降低(VFA/TA=0.72),乙酸比产甲烷活性(SMA)降低46.2%,但氢利用速率(HUR)增加69.2%,辅酶F420浓度增加11.9%.在42d时仅外层的Slime-EPS浓度明显增加(34.1%);在56d时TB-EPS和LB-EPS浓度增加61.3%和62.8%,其PN/PS比值增加197.8%和126.0%,负荷冲击诱导EPS分泌大量的应急性蛋白类产物,其电活性物质提高了系统的电子传递活性(35.5%).Illumina MiSeq显示,负荷冲击下Desulfovibrio、Ruminococcus和Geobacter等产酸菌丰度降低,而Methanobacterium丰度由32.2%增至50.9%.生物膜系统通过逐级EPS分泌和强化还原CO_(2)产甲烷来响应持续负荷冲击的影响. 展开更多
关键词 厌氧序批式生物膜反应器 负荷冲击 胞外聚合物 代谢活性 群落结构
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Spherizone工艺多区反应器内聚丙烯结块的问题 被引量:1
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作者 李金扬 《广东化工》 CAS 2024年第2期60-62,共3页
介绍了Spherizone工艺的原理,指出了采用该工艺生产的主要聚丙烯(PP)产品与采用传统工艺生产的主要PP相比的优势和生产控制过程中的技术难点。分析了反应器内物料结块的主要原因是高活性细粉黏结、静电结块和反应器内PP物料循环不充分... 介绍了Spherizone工艺的原理,指出了采用该工艺生产的主要聚丙烯(PP)产品与采用传统工艺生产的主要PP相比的优势和生产控制过程中的技术难点。分析了反应器内物料结块的主要原因是高活性细粉黏结、静电结块和反应器内PP物料循环不充分造成的。重点提出了开工前清理反应器,合理控制反应器下降段柱塞流,优化出料阀振荡程序,控制物料循环速率、Atmer163型抗静电剂以及反应器制造质量等是避免反应器内物料结块的关键。 展开更多
关键词 聚丙烯 多区反应器 结块 催化剂活性 循环
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MnO_(2)促进厌氧氨氧化工艺启动的试验研究
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作者 耿诗雯 李军 +1 位作者 李光蕾 李俊鹏 《工业用水与废水》 CAS 2024年第2期25-30,共6页
为了考察投加MnO_(2)对ANAMMOX工艺启动效果和脱氮性能的促进作用,通过改变水力负荷以及采用逐级驯化手段,向反应器中投加MnO_(2)(0~50 mg/L),逐步提高厌氧氨氧化污泥对MnO_(2)耐受性,运行90 d成功启动ANAMMOX反应器。反应器对NH_(4)^(+... 为了考察投加MnO_(2)对ANAMMOX工艺启动效果和脱氮性能的促进作用,通过改变水力负荷以及采用逐级驯化手段,向反应器中投加MnO_(2)(0~50 mg/L),逐步提高厌氧氨氧化污泥对MnO_(2)耐受性,运行90 d成功启动ANAMMOX反应器。反应器对NH_(4)^(+)-N、NO_(2)--N去除率分别稳定在78%、98%,NLR可提升至0.855 kg/(m^(3)·d),NRR稳定在0.718 kg/(m^(3)·d)左右,NO_(2)^(-)-N与NH_(4)^(+)-N物质的量比以及NO_(3)^(-)-N与NH_(4)^(+)-N物质的量比分别稳定在1.32和0.20,SAA数值最大为269.86 mg[N]/(g[VSS]·d),利用高通量测序技术进行微生物群落结构分析,AnAOB属占比8.92%,成为优势菌属。相较于传统ANAMMOX工艺,投加MnO_(2)可促进AnAOB的富集、强化AnAOB的活性,为ANAMMOX工艺广泛应用于实际工程提供参考。 展开更多
关键词 MnO_(2) 厌氧氨氧化 生物脱氮 UASB反应器 微生物群落结构 AnAOB活性
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干式空心并联电抗器绕组绝缘状态在线监测方法
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作者 李增悦 咸日常 +2 位作者 赵如杰 耿凯 张伟 《科学技术与工程》 北大核心 2024年第14期5812-5821,共10页
干式空心并联电抗器用于无功补偿与抑制工频过电压,在电网中的数量和容量日益增加,事故率却高居不下,其中,绕组匝间绝缘故障占比高居首位,亟需有效的绕组绝缘状态在线监测手段。利用有限元软件对干式空心并联电抗器进行“场-路”耦合仿... 干式空心并联电抗器用于无功补偿与抑制工频过电压,在电网中的数量和容量日益增加,事故率却高居不下,其中,绕组匝间绝缘故障占比高居首位,亟需有效的绕组绝缘状态在线监测手段。利用有限元软件对干式空心并联电抗器进行“场-路”耦合仿真,通过分析其绕组异匝和同匝股间短路的电、磁、力变化特征,研究绕组匝间短路故障的发展过程、形成机理,探求便于故障监测的敏感状态量,提出了基于有功功率损耗变化率的绕组绝缘状态在线监测方法。研究结果表明:绕组异匝股间短路对电抗器电、磁、力等物理参量的影响大于相同位置同匝股间短路工况,且异匝股间短路发生在电抗器绕组端部的影响最大。有功功率损耗对电抗器绕组绝缘故障发展的过程反应敏感、易于监测,可通过选择合适的绝缘故障预警值和绝缘失效值,基于有功功率损耗变化率进行状态判断,能够实时发现电抗器绕组绝缘故障,便于及时采取措施,阻止故障蔓延。 展开更多
关键词 干式空心并联电抗器 绕组绝缘 异匝股间短路 有功功率损耗变化率 在线监测
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三维电极反应器电吸附深度处理含砷废水
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作者 罗永健 王云燕 +2 位作者 何紫彤 许欢 孙竹梅 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第2期443-459,共17页
水环境中砷的深度处理对减少环境污染和确保人类健康至关重要。自制了三维电极反应器,以活性炭颗粒为粒子电极材料,采用电吸附和物理/化学吸附联合模式实现As(Ⅴ)的深度处理。经优化后,As(Ⅴ)浓度可从0.5 mg/L降至0.032 mg/L,且均以H_(2... 水环境中砷的深度处理对减少环境污染和确保人类健康至关重要。自制了三维电极反应器,以活性炭颗粒为粒子电极材料,采用电吸附和物理/化学吸附联合模式实现As(Ⅴ)的深度处理。经优化后,As(Ⅴ)浓度可从0.5 mg/L降至0.032 mg/L,且均以H_(2)AsO_(4)-形式存在,无As(Ⅲ),表明不存在氧化还原反应。动力学研究发现,电吸附过程可分为三步:从溶液到电极材料表面的液膜扩散过程、从电极材料表面到内部孔隙的内扩散过程和电吸附接近平衡状态。为验证该工艺的循环性能,开展了电吸附-电脱附工艺研究,发现经过8次循环后,出水浓度仍仅为0.098 mg/L(低于0.1 mg/L的标准限值),实现了含砷废水的高效深度处理,但去除效率需提升、吸附后材料的处理仍需改进。 展开更多
关键词 电吸附 活性炭颗粒 三维电极反应器 砷的去除
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硫化态THFS-2催化剂在重整预加氢装置的工业应用
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作者 杨纪 《炼油技术与工程》 CAS 2024年第4期39-43,共5页
介绍了硫化态THFS-2催化剂在重整预加氢装置的应用情况,包括催化剂的装填、活化以及性能标定,并对预加氢装置运行过程中存在的反应器压力降高的问题提出了优化建议。与非硫化态催化剂相比,THFS-2催化剂具有开工简单、开工时间短、开工... 介绍了硫化态THFS-2催化剂在重整预加氢装置的应用情况,包括催化剂的装填、活化以及性能标定,并对预加氢装置运行过程中存在的反应器压力降高的问题提出了优化建议。与非硫化态催化剂相比,THFS-2催化剂具有开工简单、开工时间短、开工风险小的特点。标定结果表明:在反应器入口温度289℃、压力2.94 MPa的条件下,精制油中硫、氮、氯的质量分数均小于0.5μg/g并且砷、铜、铅的质量分数均小于1.0 ng/g,满足重整进料的要求,说明THFS-2催化剂在较低的温度、压力下具有较好的活性。 展开更多
关键词 硫化态 THFS-2 预加氢催化剂 湿法活化 活化油 反应器压力降
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微反应器制备过氧化新癸酸异丙苯酯
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作者 王淑娜 王鑫龙 +2 位作者 赵长森 刘波 牛强 《聚氯乙烯》 CAS 2024年第2期25-27,共3页
基于微反应器的发展及其固有的安全特性,探讨了用微通道反应器制备对过氧化新癸酸异丙苯酯工艺。研究了反应温度、物料配比、停留时间等对反应固含量和收率的影响,以及合成的最佳条件。结果表明,最佳反应条件为氢氧化钾∶异丙苯∶新癸酰... 基于微反应器的发展及其固有的安全特性,探讨了用微通道反应器制备对过氧化新癸酸异丙苯酯工艺。研究了反应温度、物料配比、停留时间等对反应固含量和收率的影响,以及合成的最佳条件。结果表明,最佳反应条件为氢氧化钾∶异丙苯∶新癸酰氯(摩尔比)=1.30∶1.05∶1.00,玻璃模块反应温度50℃,碳化硅模块反应温度60℃,反应停留时间57 s,收率和固含量最佳,含固质量分数为86.14%,收率为92.46%。 展开更多
关键词 微通道反应器 过氧化新癸酸异丙苯酯 超高活性引发剂 反应温度 物料配比 停留时间
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Anaerobic tapered fluidized bed reactor for starch wastewater treatment and modeling using multilayer perceptron neural network 被引量:8
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作者 RANGASAMY Parthiban PVR Iyer GANESAN Sekaran 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第12期1416-1423,共8页
treatability of synthetic sago wastewater was investigated in a laboratory anaerobic tapered fluidized bed reactor (ATFBR) with a mesoporous granular activated carbon (GAC) as a support material. The experimental ... treatability of synthetic sago wastewater was investigated in a laboratory anaerobic tapered fluidized bed reactor (ATFBR) with a mesoporous granular activated carbon (GAC) as a support material. The experimental protocol was defined to examine the effect of the maximum organic loading rate (OLR), hydraulic retention time (HRT), the efficiency of the reactor and to report on its steady- state performance. The reactor was subjected to a steady-state operation over a range of OLR up to 85.44 kg COD/(m^3·d). The COD removal efficiency was found to be 92% in the reactor while the biogas produced in the digester reached 25.38 m^3/(m^3·d) of the reactor. With the increase of OLR from 83.7 kg COD/(m^3·d), the COD removal efficiency decreased. Also an artificial neural network (ANN) model using multilayer perceptron (MLP) has been developed for a system of two input variable and five output dependent variables. For the training of the input-output data, the experimental values obtained have been used. The output parameters predicted have been found to be much closer to the corresponding experimental ones and the model was validated for 30% of the untrained data. The mean square error (MSE) was found to be only 0.0146. 展开更多
关键词 anaerobic digestion tapered fluidized bed reactor organic loading rate BIOGAS mesoporous granular activated carbon modeling artificial neural network
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Anaerobic hydrogen production of molasses from mixed microbial communities immobilized by activated granular carbon 被引量:2
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作者 李永峰 赵倩 《化工进展》 EI CAS CSCD 北大核心 2012年第S1期384-392,共9页
Molasses wastewater was evaluated as substrate for biohydrogen production by anaerobic fermentation in a novel continuous mixed attached growth reactor ( CMAGR ) with aeration pretreated sludge attached onto granular ... Molasses wastewater was evaluated as substrate for biohydrogen production by anaerobic fermentation in a novel continuous mixed attached growth reactor ( CMAGR ) with aeration pretreated sludge attached onto granular activated carbon under continuous flow condition.It was indicated that the CMAGR system was operated at the conditions of influent COD of 2000~6000mg / L , hydraulic retention time ( HRT ) of 6hand temperature of 35 ℃ , when the pH value and oxidation-reduction potential ( ORP ) ranged from 4.16and-434 mV respectively , stable ethanol-type fermentation was formed with the sum of ethanol and acetate concentration ratio of 89.3%to the total liquid products after 40days operation.The H 2 content in biogas and chemical oxygen demand ( COD ) removal were estimated to be 46.6% and 13% , respectively.It was also investigated that the effects of organic loading rates ( OLRs ) on CMAGR hydrogen production system.It was found that hydrogen production yield increased from 3.72 mmol / hL to 12.51 mmol / hL as OLRs increased from 8 kg / m 3 d to 32 kg / m 3 d.The maximum hydrogen production rate of 12.51mmol / hL at a OLR of 32kg / m 3 d and the maximum hydrogen yield by substrate consumed was 130.57 mmol / mol happened at OLR of 16 kg / m 3 d.Greater pHs appeared to be favour to butyrate production and the maximum of 0.51mol / mol was obtained at pH of 4.14.However , ethanol / acetate ratio was greater than 1.1at pH fluctuated between 3.4 - 3.6and 4.1 - 4.4which indicated that these pHs were favour to ethanol type fermentation.Therefore , the continuous mixed attached growth reactor ( CMAGR ) could be a promising attached growth system for biohydrogen fermentation. 展开更多
关键词 BIOHYDROGEN production continuous MIXED ATTACHED growth reactor molasess WASTEWATER activATED granular carbon WASTEWATER treatment
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