In this paper, CiteSpace, a bibliometrics software, was adopted to collect research papers published on the Web of Science, which are relevant to biological model and effluent quality prediction in activated sludge pr...In this paper, CiteSpace, a bibliometrics software, was adopted to collect research papers published on the Web of Science, which are relevant to biological model and effluent quality prediction in activated sludge process in the wastewater treatment. By the way of trend map, keyword knowledge map, and co-cited knowledge map, specific visualization analysis and identification of the authors, institutions and regions were concluded. Furthermore, the topics and hotspots of water quality prediction in activated sludge process through the literature-co-citation-based cluster analysis and literature citation burst analysis were also determined, which not only reflected the historical evolution progress to a certain extent, but also provided the direction and insight of the knowledge structure of water quality prediction and activated sludge process for future research.展开更多
To develop technically feasible and economically favorable dynamic process control(DPC)strategies for an alternating activated sludge(AAS)system,a bench-scale continuous-flow alternating aerobic and anoxic reactor,per...To develop technically feasible and economically favorable dynamic process control(DPC)strategies for an alternating activated sludge(AAS)system,a bench-scale continuous-flow alternating aerobic and anoxic reactor,performing short-cut nitrogen removal from real domestic wastewater was operated under different control strategies for more than five months.A fixed-time control(FTC) study showed that bending-points on pH and oxidation-reduction potential(ORP)profiles accurately coincided with the major biologic...展开更多
The activated sludge process (ASP) is the most generally applied biological wastewater treatment method. The ASP for the removal of organic carbon and nitrogen can be looked as the combination of eight processes. In...The activated sludge process (ASP) is the most generally applied biological wastewater treatment method. The ASP for the removal of organic carbon and nitrogen can be looked as the combination of eight processes. In order to set up an ASP model, the stoichiometric coefficients should be deduced so that the stoichiometric matrix can be presented. The important assumptions and simplifications behind the model for ASP are enumerated. Using the matrix, mass balance equation and consistent units, the stoichiometric coefficients in the eight processes are exclusively deduced one by one.展开更多
As an important intermediate product, short-chain fatty acids(SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion...As an important intermediate product, short-chain fatty acids(SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS(6.8 times higher than the blank test) and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated.展开更多
These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the...These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the effect of untreated wastewaters or wastewaters that treat improperly. The aim of this present study was to evaluate performance of the wastewater treatment plant at Al-Diwaniyah City according to the national standards. Therefore, data of the most common parameters (PH, BOD<sub>5</sub>, COD, TSS, PO<sub>4</sub>, NO<sub>3</sub>, Cl, and Oil and Grease) were collected from the wastewater treatment plant. The study revealed that the wastewater treatment plant was receiving medium to strong influent with a BOD<sub>5</sub>/COD ratio of between (0.4 - 0.7). Regression analysis was achieved to approximate the influent of BOD<sub>5</sub> and TSS. While the effluent quality was exceeded the Iraq standards for disposing treated wastewater to the water bodies with a fluctuation in the ratio of BOD5to COD as a consequence of the operational problems. Therefore, these results would be of help to planners and policy makers in the City to combat such this problem and to take the necessary actions to reduce the impact of these pollutants.展开更多
Soluble microbial products(SMPs),dissolved organic matter excreted by activated sludge,can interact with antibiotics in wastewater and natural water bodies.Interactions between SMPs and antibiotics can influence antib...Soluble microbial products(SMPs),dissolved organic matter excreted by activated sludge,can interact with antibiotics in wastewater and natural water bodies.Interactions between SMPs and antibiotics can influence antibiotic migration,transformation,and toxicity but the mechanisms involved in such interactions are not fully understood.In this study,integrated spectroscopy approaches were used to investigate the mechanisms involved in interactions between SMPs and a representative antibiotic,trimethoprim(TMP),which has a low biodegradation rate and has been detected in wastewater.The results of liquid chromatography-organic carbon detection-organic nitrogen detection indicated that the SMPs used in the study contained 15% biopolymers and 28% humic-like substances(based on the total dissolved organic carbon concentration)so would have contained sites that could interact with TMP.A linear relationship of fluorescent intensities of tryptophan protein-like substances in SMP was observed(R^(2)>0.99),indicating that the fluorescence enhancement between SMP and TMP occurred.Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy indicated that carboxyl,carbonyl,and hydroxyl groups were the main functional groups involved in the interactions.The electrostatic andπ-πinteractions were discovered by the UV-vis spectra and 1H nuclear magnetic resonance spectra.Structural representations of the interactions between representative SMP subcomponents and TMP were calculated using density functional theory,and the results confirmed the conclusions drawn from the 1H nuclear magnetic resonance spectra.The results help characterize SMP–TMP complexes and will help understand antibiotic transformations in wastewater treatment plants and aquatic environments.展开更多
An oxic-anoxic-oxic(O-A-O)system followed by coagulation and ozonation processes was used to study the treatment of coking wastewater.In the O-A-O process,the removals of NH4+-N,total nitrogen and COD were 91.5-93.3%,...An oxic-anoxic-oxic(O-A-O)system followed by coagulation and ozonation processes was used to study the treatment of coking wastewater.In the O-A-O process,the removals of NH4+-N,total nitrogen and COD were 91.5-93.3%,91.3-92.6%and 89.1-93.8%,respectively when employing hydraulic residence times of 60 h for the biochemical system.High removal of NH4+-N was obtained due to the placement of an aerobic tank in front of A-O system which can mitigate the inhibitory effect of toxic compounds in coking wastewater on nitrifying bacteria.Addition of methanol into the anoxic reactor greatly increased the removal of total nitrogen,indicating that denitrifiers can hardly use organic compounds in coking wastewater as carbon source for denitrification.COD values of the effluent from the O-A-O system were still higher than 260 mg/L even with a prolonged time of 160 h mainly due to the high refractory properties of residual compounds in the effluent.The subsequent coagulation and ozonation processes resulted in the COD removal of 91.5%-93.3%and reduced the relative abundance of large molecular weight(MW)organics(>1 kDa)from 55.8%to 20.93%with the ozone,PAC and PAM dosages of 100,150 and 4 mg/L respectively.Under these conditions,the COD value and concentration of polycyclic aromatic hydrocarbons in the final effluent were less than 80 and 0.05 mg/L,respectively,which meet the requirement of the Chinese emission standard.These results indicate that the combined technology of O-A-O process,coagulation and ozonation is a reliable way for the treatment of coking wastewater.展开更多
Most of the monitoring data on the occurrence of antibiotics in sewage treatment plants(STPs)have been reported from Europe,North America and some countries in Northeast Asia,while very limited data can be found in So...Most of the monitoring data on the occurrence of antibiotics in sewage treatment plants(STPs)have been reported from Europe,North America and some countries in Northeast Asia,while very limited data can be found in Southeast Asian countries.As a pioneering research in Sri Lanka,we collected 24 h composite wastewater samples at the influent and effluent of two municipal STPs for consecutive 7 days to investigate occurrence,consumption and removal efficiency of seventeen antibiotics.The STP was located in Colombo and Hikkaduwa,respectively,representing two kinds of communities(i.e.local and tourists)in Sri Lanka.The targeted antibiotics were extracted by solid-phase extraction method and detected on an Agilent HPLCMSMS(1290/6470QQQ).Results illustrated that the majority of the antibiotics can be always detected from both STPs,except for chlorotetracycine(CTC),doxycycline(DOX)and florfenicol(FF).Fluoroquinolones(FQs)were detected at highest concentrations with ciprofloxacin(CIP)being the dominant compound.Concentrations of CIP in the influent samples were in the range of 433 e6010 ng/L.The consumption of antibiotics was estimated on the basis of influent mass load and catchment population data.We found difference in consumption patterns between the two served areas.Compared to local people in Colombo,tourists in Hikkaduwa appeared to take more antibiotics during the study period with the estimated daily dose of 0.25 g per 1000 persons.Moreover,macrolides accounted for a larger portion than FQs in Hikkaduwa,with azithromycin(AZM)being the most prevalent antibacterial agent.After comparison with an official report by Medical Supplies Division of Sri Lanka,we conjected that AZM was not commonly used among local people and it was mainly introduced by foreign arrivals.As for the removal efficiency,the activated sludge system of Colombo exhibited better elimination and more stable performance than the constructed wetland process of Hikkaduwa.展开更多
文摘In this paper, CiteSpace, a bibliometrics software, was adopted to collect research papers published on the Web of Science, which are relevant to biological model and effluent quality prediction in activated sludge process in the wastewater treatment. By the way of trend map, keyword knowledge map, and co-cited knowledge map, specific visualization analysis and identification of the authors, institutions and regions were concluded. Furthermore, the topics and hotspots of water quality prediction in activated sludge process through the literature-co-citation-based cluster analysis and literature citation burst analysis were also determined, which not only reflected the historical evolution progress to a certain extent, but also provided the direction and insight of the knowledge structure of water quality prediction and activated sludge process for future research.
文摘To develop technically feasible and economically favorable dynamic process control(DPC)strategies for an alternating activated sludge(AAS)system,a bench-scale continuous-flow alternating aerobic and anoxic reactor,performing short-cut nitrogen removal from real domestic wastewater was operated under different control strategies for more than five months.A fixed-time control(FTC) study showed that bending-points on pH and oxidation-reduction potential(ORP)profiles accurately coincided with the major biologic...
基金supported by the Special Foundation of Shanghai Municipal Education Commission (Grant No.06AZ057)
文摘The activated sludge process (ASP) is the most generally applied biological wastewater treatment method. The ASP for the removal of organic carbon and nitrogen can be looked as the combination of eight processes. In order to set up an ASP model, the stoichiometric coefficients should be deduced so that the stoichiometric matrix can be presented. The important assumptions and simplifications behind the model for ASP are enumerated. Using the matrix, mass balance equation and consistent units, the stoichiometric coefficients in the eight processes are exclusively deduced one by one.
基金supported by the National Science Foundation of China (Grant no. 51408419)the National Key Technology Research and Development Program of China (Grant nos. 2014BAL02B02-03 and 2014BAC29B01)the Key Program for International S&T Cooperation Projects of China (Grant no. 2012DFG91380)
文摘As an important intermediate product, short-chain fatty acids(SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS(6.8 times higher than the blank test) and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated.
文摘These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the effect of untreated wastewaters or wastewaters that treat improperly. The aim of this present study was to evaluate performance of the wastewater treatment plant at Al-Diwaniyah City according to the national standards. Therefore, data of the most common parameters (PH, BOD<sub>5</sub>, COD, TSS, PO<sub>4</sub>, NO<sub>3</sub>, Cl, and Oil and Grease) were collected from the wastewater treatment plant. The study revealed that the wastewater treatment plant was receiving medium to strong influent with a BOD<sub>5</sub>/COD ratio of between (0.4 - 0.7). Regression analysis was achieved to approximate the influent of BOD<sub>5</sub> and TSS. While the effluent quality was exceeded the Iraq standards for disposing treated wastewater to the water bodies with a fluctuation in the ratio of BOD5to COD as a consequence of the operational problems. Therefore, these results would be of help to planners and policy makers in the City to combat such this problem and to take the necessary actions to reduce the impact of these pollutants.
基金supported by the National Natural Science Foundation of China (Nos. 51878244 and 52170032)the the Fundamental Research Funds for the Central Universities (No. B200202101)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), China
文摘Soluble microbial products(SMPs),dissolved organic matter excreted by activated sludge,can interact with antibiotics in wastewater and natural water bodies.Interactions between SMPs and antibiotics can influence antibiotic migration,transformation,and toxicity but the mechanisms involved in such interactions are not fully understood.In this study,integrated spectroscopy approaches were used to investigate the mechanisms involved in interactions between SMPs and a representative antibiotic,trimethoprim(TMP),which has a low biodegradation rate and has been detected in wastewater.The results of liquid chromatography-organic carbon detection-organic nitrogen detection indicated that the SMPs used in the study contained 15% biopolymers and 28% humic-like substances(based on the total dissolved organic carbon concentration)so would have contained sites that could interact with TMP.A linear relationship of fluorescent intensities of tryptophan protein-like substances in SMP was observed(R^(2)>0.99),indicating that the fluorescence enhancement between SMP and TMP occurred.Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy indicated that carboxyl,carbonyl,and hydroxyl groups were the main functional groups involved in the interactions.The electrostatic andπ-πinteractions were discovered by the UV-vis spectra and 1H nuclear magnetic resonance spectra.Structural representations of the interactions between representative SMP subcomponents and TMP were calculated using density functional theory,and the results confirmed the conclusions drawn from the 1H nuclear magnetic resonance spectra.The results help characterize SMP–TMP complexes and will help understand antibiotic transformations in wastewater treatment plants and aquatic environments.
基金the National Natural Science Foundation of China(Project No.20907072)for the financial support of this work.
文摘An oxic-anoxic-oxic(O-A-O)system followed by coagulation and ozonation processes was used to study the treatment of coking wastewater.In the O-A-O process,the removals of NH4+-N,total nitrogen and COD were 91.5-93.3%,91.3-92.6%and 89.1-93.8%,respectively when employing hydraulic residence times of 60 h for the biochemical system.High removal of NH4+-N was obtained due to the placement of an aerobic tank in front of A-O system which can mitigate the inhibitory effect of toxic compounds in coking wastewater on nitrifying bacteria.Addition of methanol into the anoxic reactor greatly increased the removal of total nitrogen,indicating that denitrifiers can hardly use organic compounds in coking wastewater as carbon source for denitrification.COD values of the effluent from the O-A-O system were still higher than 260 mg/L even with a prolonged time of 160 h mainly due to the high refractory properties of residual compounds in the effluent.The subsequent coagulation and ozonation processes resulted in the COD removal of 91.5%-93.3%and reduced the relative abundance of large molecular weight(MW)organics(>1 kDa)from 55.8%to 20.93%with the ozone,PAC and PAM dosages of 100,150 and 4 mg/L respectively.Under these conditions,the COD value and concentration of polycyclic aromatic hydrocarbons in the final effluent were less than 80 and 0.05 mg/L,respectively,which meet the requirement of the Chinese emission standard.These results indicate that the combined technology of O-A-O process,coagulation and ozonation is a reliable way for the treatment of coking wastewater.
基金This work was funded by the International Partnership Program of the Chinese Academy of Sciences,(Grant No.132744KYSB20170002)UCAS scholarship for international students.The authors want to acknowledge the generous support from the National Water Supply and Drainage Board(Sewerage division),Sri Lanka and to Mr.S.M.Samaraweera for the assistance in wastewater sampling.
文摘Most of the monitoring data on the occurrence of antibiotics in sewage treatment plants(STPs)have been reported from Europe,North America and some countries in Northeast Asia,while very limited data can be found in Southeast Asian countries.As a pioneering research in Sri Lanka,we collected 24 h composite wastewater samples at the influent and effluent of two municipal STPs for consecutive 7 days to investigate occurrence,consumption and removal efficiency of seventeen antibiotics.The STP was located in Colombo and Hikkaduwa,respectively,representing two kinds of communities(i.e.local and tourists)in Sri Lanka.The targeted antibiotics were extracted by solid-phase extraction method and detected on an Agilent HPLCMSMS(1290/6470QQQ).Results illustrated that the majority of the antibiotics can be always detected from both STPs,except for chlorotetracycine(CTC),doxycycline(DOX)and florfenicol(FF).Fluoroquinolones(FQs)were detected at highest concentrations with ciprofloxacin(CIP)being the dominant compound.Concentrations of CIP in the influent samples were in the range of 433 e6010 ng/L.The consumption of antibiotics was estimated on the basis of influent mass load and catchment population data.We found difference in consumption patterns between the two served areas.Compared to local people in Colombo,tourists in Hikkaduwa appeared to take more antibiotics during the study period with the estimated daily dose of 0.25 g per 1000 persons.Moreover,macrolides accounted for a larger portion than FQs in Hikkaduwa,with azithromycin(AZM)being the most prevalent antibacterial agent.After comparison with an official report by Medical Supplies Division of Sri Lanka,we conjected that AZM was not commonly used among local people and it was mainly introduced by foreign arrivals.As for the removal efficiency,the activated sludge system of Colombo exhibited better elimination and more stable performance than the constructed wetland process of Hikkaduwa.