Polycarboxylate water-reducing admixture possesses the capability which could meet with the comprehensive performance of high performance concrete used in passenger dedicated line engineering.The problems of polycarbo...Polycarboxylate water-reducing admixture possesses the capability which could meet with the comprehensive performance of high performance concrete used in passenger dedicated line engineering.The problems of polycarboxylates water-reducing admixtures existed in the engineering application of were analyzed.At present the key for polycarboxylates application was to settle the compatibility between the water-reducing admixture and the cement and to keep the quality retention of this admixture.展开更多
The performance of concrete with a new admi xt ure MX was studied by using the freeze-thaw cycle, permeability and chemical at tack test. The experimental results show that MX improves the durability of conc re te. Wi...The performance of concrete with a new admi xt ure MX was studied by using the freeze-thaw cycle, permeability and chemical at tack test. The experimental results show that MX improves the durability of conc re te. Within the optimum proportion ranges from 0.1%to 1%,the compressive strength of concrete after freeze-thaw is increased by 20%-50%,and Young's modulus can be increased by 3.76-5.64 times.The strength and weight loss of concrete with 0.4%MX are respectively decreased by 28% and 60% after hydrochloric acid attack. The strength and weight loss of concrete with 0.4% MX are decreased by 5%-20% a fter sulfuric acid and sodium sulfate attack.The permeability of concrete with 1 % MX at 28 days can be decreased by more than 30%. The investigation of the nega tive temperature property of MX and analysis on concrete composition and microst ructure by MIP reveal that the heat conduction is resisted and the freezing proc edure of solution in concrete pore is retarded due to the adding of MX. Moreover ,the pore structure of concrete with MX is improved, thus improving the durabili ty. Based on this study, a resistance model of MX to block the heat and mass tra nsference was proposed, and the mechanism of durability improvement of concrete with MX was explained.展开更多
Despite the large variations in the behaviors of water-reducing admixtures upon changes in their structures,most previous reports on the cement-admixture compatibility did not provide suficient information on the stru...Despite the large variations in the behaviors of water-reducing admixtures upon changes in their structures,most previous reports on the cement-admixture compatibility did not provide suficient information on the structure of the admixture.Hence,the evaluation and generalization of the reports on the cement-admixture compatibility are challenging.In this study,three different polycarboxylate-ether-based water-reducing admixtures with the same free nonionic content,anionic/nonionic molar ratio,and main chain length and different side chain lengths were produced.The compatibility of these admixtures with a CEM I 42.5R-type cement was investigated.In addition,an analysis of variance was performed on the experiment results to evaluate the contributions of the admixture type,admixture/cement ratio,and elapsing time to the Marsh funnel flow time,mini-slump,slump flow,and compressive strength.The water-reducing admixtures having long or short side chains reduced the initial flow characteristics of the cementitious systems.However,the admixture having the shortest side chain was better with regard to flow retention.The side chain length of the admixture did not have significant effects on the compressive strength and water absorption capacity of the mortar mixtures and mini-slump performances of the cement paste mixtures.Regarding the behaviors of the admixtures in the cementitious systems,an optimal admixture side chain molecular weight is proposed.展开更多
文摘Polycarboxylate water-reducing admixture possesses the capability which could meet with the comprehensive performance of high performance concrete used in passenger dedicated line engineering.The problems of polycarboxylates water-reducing admixtures existed in the engineering application of were analyzed.At present the key for polycarboxylates application was to settle the compatibility between the water-reducing admixture and the cement and to keep the quality retention of this admixture.
基金Funded by the National"973"Project(2001CB610704 3)
文摘The performance of concrete with a new admi xt ure MX was studied by using the freeze-thaw cycle, permeability and chemical at tack test. The experimental results show that MX improves the durability of conc re te. Within the optimum proportion ranges from 0.1%to 1%,the compressive strength of concrete after freeze-thaw is increased by 20%-50%,and Young's modulus can be increased by 3.76-5.64 times.The strength and weight loss of concrete with 0.4%MX are respectively decreased by 28% and 60% after hydrochloric acid attack. The strength and weight loss of concrete with 0.4% MX are decreased by 5%-20% a fter sulfuric acid and sodium sulfate attack.The permeability of concrete with 1 % MX at 28 days can be decreased by more than 30%. The investigation of the nega tive temperature property of MX and analysis on concrete composition and microst ructure by MIP reveal that the heat conduction is resisted and the freezing proc edure of solution in concrete pore is retarded due to the adding of MX. Moreover ,the pore structure of concrete with MX is improved, thus improving the durabili ty. Based on this study, a resistance model of MX to block the heat and mass tra nsference was proposed, and the mechanism of durability improvement of concrete with MX was explained.
基金The authors express their sincere gratitude to the Scientific and Technological Research Council of Turkey(Grant No.219M425)Bursa Uludag University Science and Technology Center(Grant Nos.AYP(MH)-2016/16,DDP(MH)-2018/9,and DDP(MH)-2019/15).The first author thanks TUBITAK for the scholarship provided by Grant No.217M408 during his PhD study.The authors would like to acknowledge Polisan Construction Chemicals Company and Bursa Ready Mixed Concrete for the provision of the materials and information on their properties.
文摘Despite the large variations in the behaviors of water-reducing admixtures upon changes in their structures,most previous reports on the cement-admixture compatibility did not provide suficient information on the structure of the admixture.Hence,the evaluation and generalization of the reports on the cement-admixture compatibility are challenging.In this study,three different polycarboxylate-ether-based water-reducing admixtures with the same free nonionic content,anionic/nonionic molar ratio,and main chain length and different side chain lengths were produced.The compatibility of these admixtures with a CEM I 42.5R-type cement was investigated.In addition,an analysis of variance was performed on the experiment results to evaluate the contributions of the admixture type,admixture/cement ratio,and elapsing time to the Marsh funnel flow time,mini-slump,slump flow,and compressive strength.The water-reducing admixtures having long or short side chains reduced the initial flow characteristics of the cementitious systems.However,the admixture having the shortest side chain was better with regard to flow retention.The side chain length of the admixture did not have significant effects on the compressive strength and water absorption capacity of the mortar mixtures and mini-slump performances of the cement paste mixtures.Regarding the behaviors of the admixtures in the cementitious systems,an optimal admixture side chain molecular weight is proposed.
