Polystyrene doped with yttrium ethoxide was prepared. The coordination between yttrium atom and benzene ring in the polystyrene doped with yttrium ethoxide was confirmed by means of IR, XPS.
The polystyrene cation exchange resin was exchanged by La 3+ and then were carbonized to make resin carbon material. The electrochemical properties of the resin carbon material as the electrode of the lithium ion...The polystyrene cation exchange resin was exchanged by La 3+ and then were carbonized to make resin carbon material. The electrochemical properties of the resin carbon material as the electrode of the lithium ion cell were investigated. The test results show that comparing with the polystyrene cation exchange resin without adulterating, the contents of hydrogen, oxygen and sulfur are changed obviously for the resin carbon material derived from the La 3+ adulterating polystyrene cation exchange resin. The contents of hydrogen and oxygen are increased, and the one of sulfur is decreased. The test results also indicate that it is more easily to form the stratum graphite minicrystal structure with bigger diameter for the La 3+ adulterating resin. According to the electrochemical test results, the electrode derived from La 3+ adulterating polystyrene cation exchange resin has much better electrochemical property, and the capacity of charge and discharge of the electrode is increased about 30 mAh·g -1 in average.展开更多
文摘Polystyrene doped with yttrium ethoxide was prepared. The coordination between yttrium atom and benzene ring in the polystyrene doped with yttrium ethoxide was confirmed by means of IR, XPS.
文摘The polystyrene cation exchange resin was exchanged by La 3+ and then were carbonized to make resin carbon material. The electrochemical properties of the resin carbon material as the electrode of the lithium ion cell were investigated. The test results show that comparing with the polystyrene cation exchange resin without adulterating, the contents of hydrogen, oxygen and sulfur are changed obviously for the resin carbon material derived from the La 3+ adulterating polystyrene cation exchange resin. The contents of hydrogen and oxygen are increased, and the one of sulfur is decreased. The test results also indicate that it is more easily to form the stratum graphite minicrystal structure with bigger diameter for the La 3+ adulterating resin. According to the electrochemical test results, the electrode derived from La 3+ adulterating polystyrene cation exchange resin has much better electrochemical property, and the capacity of charge and discharge of the electrode is increased about 30 mAh·g -1 in average.
