The manufacturing of composite structures is a highly complex task with inevitable risks, particularly associated with aleatoric and epistemic uncertainty of both the materials and processes, as well as the need for &...The manufacturing of composite structures is a highly complex task with inevitable risks, particularly associated with aleatoric and epistemic uncertainty of both the materials and processes, as well as the need for <i>in-situ</i> decision-making to mitigate defects during manufacturing. In the context of aerospace composites production in particular, there is a heightened impetus to address and reduce this risk. Current qualification and substantiation frameworks within the aerospace industry define tractable methods for risk reduction. In parallel, Industry 4.0 is an emerging set of technologies and tools that can enable better decision-making towards risk reduction, supported by data-driven models. It offers new paradigms for manufacturers, by virtue of enabling <i>in-situ</i> decisions for optimizing the process as a dynamic system. However, the static nature of current (pre-Industry 4.0) best-practice frameworks may be viewed as at odds with this emerging novel approach. In addition, many of the predictive tools leveraged in an Industry 4.0 system are black-box in nature, which presents other concerns of tractability, interpretability and ultimately risk. This article presents a perspective on the current state-of-the-art in the aerospace composites industry focusing on risk reduction in the autoclave processing, as an example system, while reviewing current trends and needs towards a Composites 4.0 future.展开更多
Europium and terbium coordination polymers of pyridine-3-carboxylic acid were in-situ composed with ethyt methacrylate （ EMA ）. With the polymerization of EMA monomer and the formation of europium and terbium coordi...Europium and terbium coordination polymers of pyridine-3-carboxylic acid were in-situ composed with ethyt methacrylate （ EMA ）. With the polymerization of EMA monomer and the formation of europium and terbium coordination polymers of pyridiae- 3-carboxylic acid, the transparent hybrid thick fihns composed of [ Eu（ NIC ）3 ]n （ [ Tb（ NIC）3 ]n ） and poly ethyl mettuwrylate （ PEMA ） have been prepared. The luminescence properties and energy transfer of these polymeric composites were studied with absorption spectra, fluorescent excitation trod emission spectra in detail. All the hybrid thick films composed of terbium coordination polymer show the characteristic strong green emission of terbium ions, which implies the same energy transfer mechanism as the pure complex and the hybrid composite film is a suitable sabstrate for the luminescence of terbium ions. In the range of camposing concentration of luminescent species （0.01,0.025,0.05,0.1 mmol /15 mL EMA ）, emission intensities increase with the increasing of corresponding composing concentration and the concentration quenching effect does not take place.展开更多
文摘The manufacturing of composite structures is a highly complex task with inevitable risks, particularly associated with aleatoric and epistemic uncertainty of both the materials and processes, as well as the need for <i>in-situ</i> decision-making to mitigate defects during manufacturing. In the context of aerospace composites production in particular, there is a heightened impetus to address and reduce this risk. Current qualification and substantiation frameworks within the aerospace industry define tractable methods for risk reduction. In parallel, Industry 4.0 is an emerging set of technologies and tools that can enable better decision-making towards risk reduction, supported by data-driven models. It offers new paradigms for manufacturers, by virtue of enabling <i>in-situ</i> decisions for optimizing the process as a dynamic system. However, the static nature of current (pre-Industry 4.0) best-practice frameworks may be viewed as at odds with this emerging novel approach. In addition, many of the predictive tools leveraged in an Industry 4.0 system are black-box in nature, which presents other concerns of tractability, interpretability and ultimately risk. This article presents a perspective on the current state-of-the-art in the aerospace composites industry focusing on risk reduction in the autoclave processing, as an example system, while reviewing current trends and needs towards a Composites 4.0 future.
文摘Europium and terbium coordination polymers of pyridine-3-carboxylic acid were in-situ composed with ethyt methacrylate （ EMA ）. With the polymerization of EMA monomer and the formation of europium and terbium coordination polymers of pyridiae- 3-carboxylic acid, the transparent hybrid thick fihns composed of [ Eu（ NIC ）3 ]n （ [ Tb（ NIC）3 ]n ） and poly ethyl mettuwrylate （ PEMA ） have been prepared. The luminescence properties and energy transfer of these polymeric composites were studied with absorption spectra, fluorescent excitation trod emission spectra in detail. All the hybrid thick films composed of terbium coordination polymer show the characteristic strong green emission of terbium ions, which implies the same energy transfer mechanism as the pure complex and the hybrid composite film is a suitable sabstrate for the luminescence of terbium ions. In the range of camposing concentration of luminescent species （0.01,0.025,0.05,0.1 mmol /15 mL EMA ）, emission intensities increase with the increasing of corresponding composing concentration and the concentration quenching effect does not take place.
