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A-USC锅炉关键部件用候选合金金属间相特征 被引量:10
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作者 党莹樱 赵新宝 +5 位作者 尹宏飞 鲁金涛 严靖博 袁勇 杨珍 谷月峰 《中国电机工程学报》 EI CSCD 北大核心 2014年第23期3983-3989,共7页
文中总结了目前国内外先进超超临界(A-USC)锅炉关键部件用候选合金(Inconel 740/740H、CCA 617、Nomonic263、Haynes 230及GH 2984等)经标准热处理、无应力时效及持久实验后的组织特征和演化规律。结果表明:这类材料为了满足部件服役条... 文中总结了目前国内外先进超超临界(A-USC)锅炉关键部件用候选合金(Inconel 740/740H、CCA 617、Nomonic263、Haynes 230及GH 2984等)经标准热处理、无应力时效及持久实验后的组织特征和演化规律。结果表明:这类材料为了满足部件服役条件下对高温强度的要求,多采用析出强化设计,析出相种类繁多(如γ'、η、σ、μ及G相等);这些析出相的形貌、数量、尺寸及相间元素的分布等在高温长期时效或服役条件下均会发生明显变化,从而对合金的性能和服役行为产生重要影响。提出有必要进一步分析上述各相的演变规律及其作用,通过调整合金成分或热处理制度来优化组织结构,抑制或消除有害相的析出,提高合金的高温性能。 展开更多
关键词 先进超超临界(a-usc) 高温合金 析出相 演变规律 性能
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两种A-USC电站用候选合金的微观组织及演变规律 被引量:4
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作者 党莹樱 赵新宝 +2 位作者 杨征 张醒兴 尹宏飞 《中国电机工程学报》 EI CSCD 北大核心 2019年第17期5137-5143,共7页
实现700℃超超临界技术的关键是开发能够在高参数条件下长期安全运行的材料。以候选合金中的典型代表Inconel740H及自主研发合金HT1为对象,通过热力学模拟、长期时效试验,结合显微组织表征、显微硬度测定等方法对合金组织及其演变规律... 实现700℃超超临界技术的关键是开发能够在高参数条件下长期安全运行的材料。以候选合金中的典型代表Inconel740H及自主研发合金HT1为对象,通过热力学模拟、长期时效试验,结合显微组织表征、显微硬度测定等方法对合金组织及其演变规律进行了研究。结果表明:2种合金标准热处理后的组织均由奥氏体基体γ及γ’,M23C6、MC等析出相组成,其中γ’为合金的主要强化相。随着时效时间的延长,γ’粒子的粗化规律符合LSW熟化理论;在现时效过程中,无η、σ等有害相析出。随着时间的增加,合金的显微硬度呈现先上升后下降的变化趋势,但整体波动值较小,体现出较好的组织稳定性。 展开更多
关键词 先进超超临界(a-usc) Ni/Ni-Fe基高温合金 组织演变 显微硬度
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700℃ A-USC电站锅炉材料专利分析与研究 被引量:1
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作者 李阳 王岩 《材料导报(纳米与新材料专辑)》 EI CAS 2013年第2期148-152,共5页
以中国专利局、美国专利商标局、欧洲专利局世界专利等数据库中检索到的已公开发布的相关专利为研究样本,对专利的特征进行了统计和分析。结果表明:目前检索到700℃先进超超临界(A-USC)电站锅炉主要候选材料的核心发明专利为13项,主要包... 以中国专利局、美国专利商标局、欧洲专利局世界专利等数据库中检索到的已公开发布的相关专利为研究样本,对专利的特征进行了统计和分析。结果表明:目前检索到700℃先进超超临界(A-USC)电站锅炉主要候选材料的核心发明专利为13项,主要包括Inconel 740/740H、Inconel 617/617B、HR6W、Sanicro 25、GH2984等牌号合金;其中Inconel 617/617B和GH2984的专利已过期,且未检索到最新专利;有关Inconel 740/740H、HR6W和Sanicro 25等合金的专利分别在近年申请并获得授权,专利的保护范围主要针对合金的成分、组织、用途、制备方法等方面,且这些专利保护的范围很广,有效地保护了合金的知识产权。 展开更多
关键词 700℃ a-usc 锅炉材料 专利
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C-HRA-2合金在700 ℃先进超超临界(A-USC)锅炉煤灰/烟气环境中的高温腐蚀行为 被引量:1
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作者 罗坤杰 吴祥锋 +1 位作者 李成涛 赵彦芬 《腐蚀与防护》 CAS 北大核心 2022年第9期1-5,16,共6页
采用扫描电镜、能谱仪和X射线衍射仪,分析了C-HRA-2合金在700℃的模拟先进超超临界(A-USC)锅炉煤灰/烟气环境中腐蚀48 h和120 h后表面氧化膜的微观形貌、物相组成和元素分布,并分析了C-HRA-2合金的高温腐蚀行为。结果表明:C-HRA-2合金... 采用扫描电镜、能谱仪和X射线衍射仪,分析了C-HRA-2合金在700℃的模拟先进超超临界(A-USC)锅炉煤灰/烟气环境中腐蚀48 h和120 h后表面氧化膜的微观形貌、物相组成和元素分布,并分析了C-HRA-2合金的高温腐蚀行为。结果表明:C-HRA-2合金表面氧化膜主要由外层氧化层、中间混合层和内层硫化物组成;最外层氧化层主要为低熔点的共晶硫酸盐,其下方存在尺寸不一的堎块状NiO层;中间层主要由铬的氧化物、硫酸盐和Mo_(2)S_(3)组成;内层硫化物主要为不连续分布的Mo_(2)S_(3),深入合金基体内部;煤灰与C-HRA-2合金中的钼元素反应,在合金表面生成钼酸盐,随着腐蚀时间的延长,镍不断被氧化,NiO层增厚,硫元素不断向内扩散,Mo_(2)S_(3)硫化物层厚度增加,腐蚀不断加剧。 展开更多
关键词 C-HRA-2合金 先进超超临界(a-usc)锅炉 煤灰/烟气环境 腐蚀行为
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一种先进超超临界火电机组用Ni-Fe-Cr基高温合金的热变形行为 被引量:1
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作者 韩丽青 吴云胜 +5 位作者 刘状 秦学智 王常帅 周兰章 于宏 陈亚军 《材料导报》 EI CAS CSCD 北大核心 2020年第6期109-113,共5页
通过不同变形参数下的等温压缩实验,研究了一种Ni-Fe-Cr基高温合金的热变形行为及动态再结晶机理。结果表明,合金的流变应力随着变形温度的降低或应变速率的升高而增大,而动态再结晶比例随着变形温度的降低或应变速率的升高而降低,但受... 通过不同变形参数下的等温压缩实验,研究了一种Ni-Fe-Cr基高温合金的热变形行为及动态再结晶机理。结果表明,合金的流变应力随着变形温度的降低或应变速率的升高而增大,而动态再结晶比例随着变形温度的降低或应变速率的升高而降低,但受温升效应影响,应变速率高于1 s-1时,动态再结晶比例随着应变速率的升高而升高。合金合理的热变形温度为1100~1200℃,应变速率为0.01~0.3 s-1。热变形参数对合金的动态再结晶机理产生影响,高温低应变速率变形时,合金的主要再结晶机理为以晶界弓弯为主要特点的非连续动态再结晶,而低温高应变速率变形时,以晶内亚晶发展为主要特点的连续动态再结晶也发挥重要的作用。 展开更多
关键词 Ni-Fe-Cr基合金 热变形 动态再结晶 先进超超临界(a-usc)
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汽轮机先进超超临界和二次再热技术(英文) 被引量:1
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作者 Ivan McBean 《风机技术》 2018年第6期59-63,共5页
Environmental pressures and economic requirements have led to a drive to ever increasing steam parameters to further increase steam turbine cycle efficiencies. This poses a number of challenges: plant architecture,ste... Environmental pressures and economic requirements have led to a drive to ever increasing steam parameters to further increase steam turbine cycle efficiencies. This poses a number of challenges: plant architecture,steam turbine design and turbine material requirements. GE has been developing USC technology for more than 18 years and has many reference plants. The limits on inlet pressure and temperatures have been challenged as the technology and product development has proceeded. This paper discusses some of the options on how plant efficiency can be increased and some of the related challenges. The performance difference between a single reheat and double reheat is quantified based on a simplified thermodynamic model. 展开更多
关键词 STEAM Turbines High TEMPERATURE EFFICIENCY a-usc DOUBLE REHEAT
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The Effect of Cold Working on Creep Rupture Strength and Microstructure of Ni-23Cr-7W Alloy
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作者 Yoshiki Shioda Keiji Kubushiro +2 位作者 Youhei Sakakibara Kyohei Nomura Yoshinori Murata 《World Journal of Mechanics》 2017年第10期283-295,共13页
In order to clarify the reason why the creep rupture time of pre-strained Ni-23Cr-7W Alloy (HR6W) is longer than that of the non-pre-strained HR6W, microstructures of HR6W after a series of creep tests were investigat... In order to clarify the reason why the creep rupture time of pre-strained Ni-23Cr-7W Alloy (HR6W) is longer than that of the non-pre-strained HR6W, microstructures of HR6W after a series of creep tests were investigated. The creep tests were conducted at 750&deg;C, 90 and 100 MPa. In the pre-strained samples, the grain boundary shielding ratio by precipitates was larger than that of the non-pre-strained sample. In addition, in the pre-strained samples the size of the M23C6 carbide in the grains was finer than in the non-pre-strained sample. The W content in the M23C6 carbide in the pre-strained samples tended to be larger than in the non-pre-strained sample. Therefore, the Ostwald ripening of the carbide was delayed and the size of M23C6 carbide was thought to be fine for a long time. These observations show that creep strength in the pre-strained samples is higher than that of the non-pre-strained sample because of both precipitation strengthening inside of the grains and grain boundaries. 展开更多
关键词 a-usc HR6W COLD Working CREEP Strength GRAIN Boundary SHIELDING Ratio M23C6 CARBIDE
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Sensitivity Analysis of a 50+ Coal-Fired Power Unit Efficiency
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作者 Katarzyna Stepczyńska-Drygas Slawomir Dykas Krystian Smolka 《Journal of Power and Energy Engineering》 2015年第12期19-31,共13页
The coal-fired power unit integration with a CO2 capture and compression installation involves a considerable rise in the costs of electricity generation. Therefore, there is a need for a continuous search for methods... The coal-fired power unit integration with a CO2 capture and compression installation involves a considerable rise in the costs of electricity generation. Therefore, there is a need for a continuous search for methods of improving the electricity generation efficiency in steam power plants. One technology which is especially promising is the advanced ultra-supercritical (A-USC) power unit. Apart from steam parameters upstream the turbine, the overall efficiency also depends on the efficiency values of individual elements of the plant and the size of energy consumption of the process of CO2 sequestration from the boiler flue gases. These problems are considered herein to emphasize that without specifying the efficiency values of the power plant main elements the information concerning its electricity generation efficiency is incomplete. This paper presents the influence of the efficiency of individual elements of the power plant on its electricity generation efficiency. The lack of information of the efficiencies of the power plant individual elements, by presenting its overall efficiency, may lead to the false conclusions. 展开更多
关键词 Sensitivity Analysis a-usc Power Unit Efficiency CO_(2) Capture
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700℃先进超超临界燃煤电站汽轮机高位布置方案可行性研究
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作者 覃建果 《电力系统装备》 2020年第11期45-46,共2页
通过对塔式炉主蒸汽系统管道和高温再热蒸汽管道的应力计算,论证了700℃先进超超临界燃煤电站(A-USC)汽轮机高位布置方案的可行性,表明高位布置方案是实现700℃A-USC电站商业化运行的有效途径。
关键词 先进超超临界燃煤电站 a-usc 700℃ 紧凑设计 汽轮机高位布置
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Energy-Saving Optimization Study on 700℃ Double Reheat Advanced Ultra-Supercritical Coal-Fired Power Generation System
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作者 WANG Jing DUAN Liqiang +3 位作者 YANG Jinfu YANG Ming JING Yutian TIAN Liguo 《Journal of Thermal Science》 SCIE EI CAS CSCD 2023年第1期30-43,共14页
700°C double reheat advanced ultra-supercritical power generation technology is one of the most important development directions for the efficient and clean utilization of coal.To solve the great exergy loss prob... 700°C double reheat advanced ultra-supercritical power generation technology is one of the most important development directions for the efficient and clean utilization of coal.To solve the great exergy loss problem caused by the high superheat degrees of regenerative steam extractions in 700°C double reheat advanced ultra-supercritical power generation system,two optimization systems are proposed in this paper.System 1 is integrated with the back pressure extraction steam turbine,and system 2 is simultaneously integrated with both the outside steam cooler and back pressure extraction steam turbine.The system performance models are built by the Ebsilon Professional software.The performances of optimized systems are analyzed by the unit consumption method.The off-design performances of optimization systems are analyzed.The results show that:the standard power generation coal consumption rates of optimization systems 1 and 2 are decreased by 1.88 g·(kW·h)^(–1),2.97 g·(kW·h)^(–1)compared with that of the 700°C reference system;the average superheat degrees of regenerative steam extractions of optimized systems 1 and 2 are decreased by 122.2°C,140.7°C(100%turbine heat acceptance condition),respectively.The comparison results also show that the performance of the optimized system 2 is better than those of the optimized system 1 and the 700°C reference system.The power generation standard coal consumption rate and the power generation efficiency of the optimized system 2 are about 232.08 g·(kW·h)^(–1)and 52.96%(100%turbine heat acceptance condition),respectively. 展开更多
关键词 700℃ advanced ultra-supercritical(a-usc) double reheat cycle extraction steam superheat degree unit consumption method system optimization
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650℃一次再热超超临界燃煤发电机组设计优化 被引量:2
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作者 王婧 段立强 杨名 《机械工程学报》 EI CAS CSCD 北大核心 2022年第22期416-425,共10页
针对650℃一次再热超超临界燃煤发电机组热力系统抽汽过热度较高、空气预热器换热温差较大的问题,在650℃基准机组基础上提出加装2级前置式蒸汽冷却器(Outside steam coolers, OSCs)(方案1)和采用前置式空气预热器+OSCs(方案2)进行性能... 针对650℃一次再热超超临界燃煤发电机组热力系统抽汽过热度较高、空气预热器换热温差较大的问题,在650℃基准机组基础上提出加装2级前置式蒸汽冷却器(Outside steam coolers, OSCs)(方案1)和采用前置式空气预热器+OSCs(方案2)进行性能对比研究。通过Ebsilon建模,采用单耗分析法对比了650℃一次再热机组在变工况下的能耗分布情况。结果表明:650℃一次再热机组发电煤耗比600℃二次再热机组降低10.67g·(kW·h)^(-1),比700℃一次再热机组高9.77 g·(kW·h)^(-1)(100%THA),节煤效果显著。650℃一次再热不同优化方案中,方案2在各工况下性能均优于方案1和基准机组,方案2发电煤耗246.71 g·(kW·h)^(-1)(100%THA),比方案1降低1.99 g·(kW·h)^(-1),比基准机组降低3.32 g·(kW·h)^(-1),在低负荷下仍具有良好的节煤效果。 展开更多
关键词 650℃ 先进超超临界(a-usc) 一次再热 抽汽过热度 外置式蒸汽冷却器(OSC) 单耗分析
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Creep-fatigue interaction properties of nickel-based superalloy 617 被引量:4
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作者 Kazuo KOBAYASHI Masao HAYAKAWA Megumi KIMURA 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2011年第2期125-131,共7页
High-temperature fatigue properties were investigated for a nickel-based superalloy 617 as a typical candidate material for high-temperature components using an advanced ultra super critical (A-USC) power plant. Cre... High-temperature fatigue properties were investigated for a nickel-based superalloy 617 as a typical candidate material for high-temperature components using an advanced ultra super critical (A-USC) power plant. Creep-fatigue data obtained by strain-controlled tests at 700 ? C was analyzed for the superalloy 617 focused on position of hold at peak strain in comparison with continuously cycled tests. The fatigue life was the shortest with the hold tensile strain wave, which showed mainly intergranular fracture appearance. The life was the longest with symmetrical triangular wave which fractured from the specimen surface, while the wave with the hold compressive strain showed partially intergranular fracture appearance and the life was middle in the both waves. In this study, it is discussed with the creep-fatigue interaction for the superalloy 617. 展开更多
关键词 a-usc power plant Nickel-based superalloy Creep-fatigue interaction FRACTOGRAPHY
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Thermal Stability of a New Ni-Fe-Cr Base Alloy with Different Ti/Al Ratios 被引量:1
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作者 Changshuai Wang Tingting Wang +3 位作者 Meilin Tan Yongan Guo Jianting Guo Lanzhang Zhou 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2015年第2期135-142,共8页
Influence of Ti/Al ratios on the thermal stability of a new low cost Ni-Fe-Cr base wrought alloy,designed for application at 700℃ in advanced ultra-supercritical coal-fired power plants(700℃A-USC),was investigated b... Influence of Ti/Al ratios on the thermal stability of a new low cost Ni-Fe-Cr base wrought alloy,designed for application at 700℃ in advanced ultra-supercritical coal-fired power plants(700℃A-USC),was investigated both experimentally and thermodynamically. After standard heat treatment,the alloys with different Ti/Al ratios had the same microstructural characteristics. However,compared with the alloys with high Ti/Al ratio,the low Ti/Al ratio can increase the γ’-solvus temperature,decrease γ’ coarsening rate and reduce the temperature range of η phase precipitation. For the alloys with low Ti/Al ratio,the yield strength has no obvious decrease during long-term thermal exposure at 700 and 750℃,but after thermal exposure at 750℃ for 5000 h,the yield strength of the alloys with high Ti/Al ratio obviously decreases due to the η phase precipitation. The influence of h phase on mechanical properties is related with its size. When the h phase is small,it has no obvious influence on mechanical properties,but h phase becomes the crack initiation site with the further growth of η phase. It can be concluded that the decrease in Ti/Al ratio can improve the thermal stability to meet the requirement of 700℃ A-USC coal-fired power plants. 展开更多
关键词 700℃ a-usc Ni-Fe-Cr base alloy Thermal stability η
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