Deep structure and properties and features of the geophysical fields of the Panxi region, in the middle of the Kang-Dian (Kangding-Yunnan) tectonic belt, are studied as a whole. The study is based on the detection of ...Deep structure and properties and features of the geophysical fields of the Panxi region, in the middle of the Kang-Dian (Kangding-Yunnan) tectonic belt, are studied as a whole. The study is based on the detection of magnetic field (including paleomagnetic dating, aeromagnetics), geothermal field, natural earthquake, plate motion, explosion seismology and magneto-electrotelluric sounding.The results show that the Panxi tectonic zone is neither a completely withered ancient rift nor a modern rift system in the heyday having come into being since the Mesozoic or the Cenozoic era, but it is an active tectonic zone (i. e. a "resuscitating" ancient rift zone) formed and reformed by magma activity and tectonic movements in adjacent regions.展开更多
Pentamethylcyclopentadienyl-trimethylphosphine-metal compounds play an important role in the activation studies of saturated hydrocarbons. A method to synthesize ethyltetramethylruthenium compounds was established, wh...Pentamethylcyclopentadienyl-trimethylphosphine-metal compounds play an important role in the activation studies of saturated hydrocarbons. A method to synthesize ethyltetramethylruthenium compounds was established, which started from the reaction of RuCl_3. H_2O with ethyltetramethylcyclopentadiene to give a dimer compound of 2. When 2 was reacted with different amounts of trimethylphosphine, compounds 3 [C_5Me_4EtRu(PMe_3)Cl_2] and 4 [(C_5Me_4Et)Ru(PMe_3)_2Cl] were obtained. Compound 3 is a 17-electron species which is in formula similar to Bergman's Ir compound used in hydrocarbon activation reaction, but might be more reactive because of its unsaturated electron structure. The crystal structure analysis of compounds 2, 3 and 4, showed that the ruthenium atom was coordinated in a 'threeleg-piano-stool' geometry in all the three compounds. The Ru—Cl bond in 3 and 4 was lengthened, making it labile to other substitution reactions.展开更多
In this paper we report the synthesis and activation of OS-6 raft-llke planar clusters. The activated OS-66 raft-like clusters [OS-66(CO)_(20)(MeCN)] and [OS-66(CO)_(19) (MeCN)_2] have been prepared by involving PdCl_...In this paper we report the synthesis and activation of OS-6 raft-llke planar clusters. The activated OS-66 raft-like clusters [OS-66(CO)_(20)(MeCN)] and [OS-66(CO)_(19) (MeCN)_2] have been prepared by involving PdCl_2 as catalyst. Trimethylamine oxide (Me_3NO) has been used as an activation reagent to oxidize several carbonyl ligands coordinated in the activated clusters and to get a series of activated OS-66 raft-like clusters [OS-66(CO)_(21-x)(MeCN)_x] (n = 1--5) and corresponding substituted clusters [OS-66(CO)_(21-x)(P(OMe)_3)_x] (n=1--5). The structures of these OS-66 raft-like clusters have been characterized by the infrared spectra (IR), nuclear magnetic resonance spectra (NMR) and mass spectra (MS), and the characters of the raft-like planar structure and reactivity above have also been discussed in this paper.展开更多
文摘Deep structure and properties and features of the geophysical fields of the Panxi region, in the middle of the Kang-Dian (Kangding-Yunnan) tectonic belt, are studied as a whole. The study is based on the detection of magnetic field (including paleomagnetic dating, aeromagnetics), geothermal field, natural earthquake, plate motion, explosion seismology and magneto-electrotelluric sounding.The results show that the Panxi tectonic zone is neither a completely withered ancient rift nor a modern rift system in the heyday having come into being since the Mesozoic or the Cenozoic era, but it is an active tectonic zone (i. e. a "resuscitating" ancient rift zone) formed and reformed by magma activity and tectonic movements in adjacent regions.
基金Project supported by the National Natural Science Foundation of China.
文摘Pentamethylcyclopentadienyl-trimethylphosphine-metal compounds play an important role in the activation studies of saturated hydrocarbons. A method to synthesize ethyltetramethylruthenium compounds was established, which started from the reaction of RuCl_3. H_2O with ethyltetramethylcyclopentadiene to give a dimer compound of 2. When 2 was reacted with different amounts of trimethylphosphine, compounds 3 [C_5Me_4EtRu(PMe_3)Cl_2] and 4 [(C_5Me_4Et)Ru(PMe_3)_2Cl] were obtained. Compound 3 is a 17-electron species which is in formula similar to Bergman's Ir compound used in hydrocarbon activation reaction, but might be more reactive because of its unsaturated electron structure. The crystal structure analysis of compounds 2, 3 and 4, showed that the ruthenium atom was coordinated in a 'threeleg-piano-stool' geometry in all the three compounds. The Ru—Cl bond in 3 and 4 was lengthened, making it labile to other substitution reactions.
文摘In this paper we report the synthesis and activation of OS-6 raft-llke planar clusters. The activated OS-66 raft-like clusters [OS-66(CO)_(20)(MeCN)] and [OS-66(CO)_(19) (MeCN)_2] have been prepared by involving PdCl_2 as catalyst. Trimethylamine oxide (Me_3NO) has been used as an activation reagent to oxidize several carbonyl ligands coordinated in the activated clusters and to get a series of activated OS-66 raft-like clusters [OS-66(CO)_(21-x)(MeCN)_x] (n = 1--5) and corresponding substituted clusters [OS-66(CO)_(21-x)(P(OMe)_3)_x] (n=1--5). The structures of these OS-66 raft-like clusters have been characterized by the infrared spectra (IR), nuclear magnetic resonance spectra (NMR) and mass spectra (MS), and the characters of the raft-like planar structure and reactivity above have also been discussed in this paper.
