Agglomeration rate and action forces between atomized particles of agglomerator and inhaled-particles from coal combustion

In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the flue before precipitation devices of power station boiler in order to make inhaled-particles agglomerate into bigger particles, which can be easily removed but not change existing running conditions of boiler. According to this idea, a model is set up to study agglomeration rate and effect forces between fly ash inhaled-particles and atomized agglomerator particles. The developed agglomeration rate was expressed by relative particle number decreasing speed per unit volume. The result showed that viscosity force and flow resistance force give main influences on agglomeration effect of inhaled-particles, while springiness force and gravity have little effect on agglomeration effect of theirs. Factors influencing the agglomeration rate and effect forces are studied, including agglomerator concentration, agglomerator flux and agglomerator density, atomized-particles diameters and inhaled-particles diameter and so on.

Bipolar charged aerosol agglomeration and collection by a two-zone agglomerator

In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarly charged and coagulated in the same alternating electric field simultaneously. The silica flour with 2 fun mass median diameter and the smoke from burning wood powder were used as test aerosol. The comparison experimental results have shown that when the mean electric field is 4 kV/cm the collection efficiency of the new electrostatic agglomerator was 98.2% for silica flour and 67.4% for wood powder smoke, Under the same experimental condition. the collection efficiency of the electrostatic agglomerator with three zones was 97.4% for collecting silica flour and the collection efficiency of the electrostatic precipitator was 56.3% for wood powder smoke.

Particle Agglomeration in Bipolar Barb Agglomerator Under AC Electric Field

The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious.To improve agglomeration effectiveness of fine particles,a dual zone electric agglomeration device consisting of a charging chamber and an agglomeration chamber with bipolar barb electrodes was developed.The bipolar barb electric agglomerator with a polar distance of 200 mm demonstrates good agglomeration effectiveness for particles with a size less than 8.0μm under applied AC electric field.An optimal condition for achieving better agglomeration effectiveness was found to be as follows：flue gas flow velocity of3.00 m/s,particle concentration of 2.00 g/m^3,output voltage of 35 kV and length of the barb of16 ram.In addition,4.0-6.0μm particles haste the best effectiveness with the variation of particle volume occupancy of-3.2.

Effect of hafnium and molybdenum addition on inclusion characteristics in Co-based dual-phase high-entropy alloys

Specific grades of high-entropy alloys(HEAs)can provide opportunities for optimizing properties toward high-temperature applications.In this work,the Co-based HEA with a chemical composition of Co_(47.5)Cr_(30)Fe_(7.5)Mn_(7.5)Ni_(7.5)(at%)was chosen.The refractory metallic elements hafnium(Hf)and molybdenum(Mo)were added in small amounts(1.5at%)because of their well-known positive effects on high-temperature properties.Inclusion characteristics were comprehensively explored by using a two-dimensional cross-sectional method and extracted by using a three-dimensional electrolytic extraction method.The results revealed that the addition of Hf can reduce Al_(2)O_(3)inclusions and lead to the formation of more stable Hf-rich inclusions as the main phase.Mo addition cannot influence the inclusion type but could influence the inclusion characteristics by affecting the physical parameters of the HEA melt.The calculated coagulation coefficient and collision rate of Al_(2)O_(3)inclusions were higher than those of HfO_(2)inclusions,but the inclusion amount played a larger role in the agglomeration behavior of HfO_(2)and Al_(2)O_(3)inclusions.The impurity level and active elements in HEAs were the crucial factors affecting inclusion formation.

Evaluation and Influencing Factors on Particle Agglomeration in RAP

Asphalt extraction test and scanning electron microscopy(SEM) were used for analysis of agglomerations of reclaimed asphalt pavement(RAP) particles. In order to quantify the agglomeration degree of RAP, the fineness modulus ratio(FMR) and the percentage loss index(PLI) were proposed. In addition, grey correlation analysis was conducted to discuss the relationship between particle agglomerations and RAP size,asphalt content(AC), and surface area. Two indexes indicate that the agglomeration degree increases in general as the RAP size reduces. This can be attributed to that particles are prone to agglomeration in the case of higher AC. Based on the SEM images and the material composition of RAP, the particle agglomeration in RAP can be classified into weak agglomeration and strong agglomeration. Grey correlation analysis shows that AC is the crucial factor affecting the agglomeration degree and RAP variability. In order to produce consistent and stable reclaimed mixtures, disposal measures of RAP are suggested to lower the AC of RAP.

Particle agglomeration and inhibition method in the fluidized pyrolysis reaction of waste resin

This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglomeration and defluidization.Adding kaolin could effectively inhibit the particle agglomeration during the fluidized pyrolysis reaction through physical isolation and chemical reaction.On the one hand,kaolin could form a coating layer on the surface of ceramic particles to prevent the adhesion of organic ash generated by the pyrolysis of resin.On the other hand,when a sufficient amount of kaolin(-0.2%(mass))was added,the activated kaolin could fully contact with the Na+ ions generated by the pyrolysis of resin and react to form a high-melting aluminosilicate mineral(nepheline),which could reduce the formation of low-melting-point sodium sulfate and thereby avoid the agglomeration of ceramic particles.

Multi-scenario Simulation for 2060 and Driving Factors of the Eco-spatial Carbon Sink in the Beibu Gulf Urban Agglomeration, China

Since China announced its goal of becoming carbon-neutral by 2060, carbon neutrality has become a major target in the development of China's urban agglomerations. This study applied the Future Land Use Simulation(FLUS) model to predict the land use pattern of the ecological space of the Beibu Gulf urban agglomeration, in 2060 under ecological priority, agricultural priority and urbanized priority scenarios. The Integrated Valuation of Ecosystem Services and Trade-offs(In VEST) model was employed to analyse the spatial changes in ecological space carbon storage in each scenario from 2020 to 2060. Then, this study used a Geographically Weighted Regression(GWR) model to determine the main driving factors that influence the changes in land carbon sinking capacity. The results of the study can be summarised as follows: firstly, the agricultural and ecological priority scenarios will achieve balanced urban expansion and environmental protection of resources in an ecological space. The urbanized priority scenario will reduce the carbon sinking capacity. Among the simulation scenarios for 2060, carbon storage in the urbanized priority scenario will decrease by 112.26 × 10^(6) t compared with that for 2020 and the average carbon density will decrease by 0.96 kg/m^(2) compared with that for 2020. Carbon storage in the agricultural priority scenario will increase by 84.11 × 10^(6) t, and the average carbon density will decrease by 0.72 kg/m^(2). Carbon storage in the ecological priority scenario will increase by 3.03 × 10^(6) t, and the average carbon density will increase by 0.03 kg/m^(2). Under the premise that the population of the town will increases continuously, the ecological priority development approach may be a wise choice.Secondly, slope, distance to river and elevation are the most important factors that influence the carbon sink pattern of the ecological space in the Beibu Gulf urban agglomeration, followed by GDP, population density, slope direction and distance to traffic infrastructure.At the same time, urban space expansion is the main cause of the changes of this natural factors. Thirdly, the decreasing trend of ecological space is difficult to reverse, so reasonable land use policy to curb the spatial expansion of cities need to be made.

Experimental study of Al agglomeration on solid propellant burning surface and condensed combustion products

Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion surface may lower the combustion efficiency of propellants,resulting in a loss in twophase flow.Therefore,it is necessary to understand the agglomeration mechanism of aluminum particles on the combustion surface.In this paper,a high-pressure sealed combustion chamber is constructed,and high-speed camera is used to capture the whole process of aluminum accumulation,aggregation and agglomeration on the combustion surface,and the secondary agglomeration process near the combustion surface.The microscopic morphology and chemical composition of the condensed combustion products(CCPs) are then studied by using scanning electron microscopy coupled with energy dispersive(SEM-EDS) method.Results show that there are three main types of condensed combustion products:small smoke oxide particles oxidized by aluminum vapor,usually less than 1 μm;typical agglomerates formed by the combustion of aluminum agglomerates;carbonized agglomerates that are widely distributed,usually formed by irregular movements of aluminum agglomerates.The particle size of condensed combustion products is measured by laser particle size meter.As the pressure increases from 0.5 MPa to 1.0 MPa in nitrogen,the mass average particle size of aluminum agglomerates decreases by 49.7%.As the ambient gas is changed from 0.5 MPa nitrogen to 0.5 MPa air,the mass average particle size of aluminum agglomerates decreases by 67.3%.Results show that as the ambient pressure increases,the higher oxygen content can improve combustion efficiency and reduce the average agglomeration size of aluminum particles.

Spatially Heterogeneous Response of Carbon Storage to Land Use Changes in Pearl River Delta Urban Agglomeration, China

Carbon storage of terrestrial ecosystems plays a vital role in advancing carbon neutrality. Better understanding of how land use changes affect carbon storage in urban agglomeration will provide valuable guidance for policymakers in developing effective regional conservation policies. Taking the Pearl River Delta Urban Agglomeration(PRDUA) in China as an example, we examined the heterogeneous response of carbon storage to land use changes in 1990–2018 from a combined view of administrative units and physical entities. The results indicate that the primary change in land use was due to the expansion of construction land(5897.16 km2). The carbon storage in PRDUA decreased from 767.34 Tg C in 1990 to 725.42 Tg C in 2018 with a spatial pattern of high wings and the low middle. The carbon storage loss was largely attributed to construction land expansion(55.74%), followed by forest degradation(54.81%). Changes in carbon storage showed significant divergences in different sized cities and hierarchical boundaries. The coefficients of geographically weighted regression(GWR) reveal that the alteration in carbon storage in Guangzhou City was more responsive to changes in construction land(-0.11) compared to other cities, while that in Shenzhen was mainly affected by the dynamics of forest land(8.32). The change in carbon storage was primarily influenced by the conversion of farmland within urban extent(5.05) and the degradation of forest land in rural areas(5.82). Carbon storage changes were less sensitive to the expansion of construction land in the urban center, urban built-up area, and ex-urban built-up area, with the corresponding GWR coefficients of 0.19, 0.04, and 0.02. This study necessitates the differentiated protection strategies of carbon storage in urban agglomerations.

Measurement of Digital Economy Development Level in Yangtze River Delta and Its Influence on Ecological Efficiency

Based on the panel data of 41 cities in the Yangtze River Delta from 2007 to 2018,this paper empirically tests the impact of digital economy development on urban ecological efficiency in the Yangtze River Delta.The results show that the development level of digital economy in Yangtze River Delta urban agglomeration is fluctuating and rising;the development of digital economy has a significant positive role in promoting the improvement of urban ecological efficiency;there is significant regional heterogeneity in the promotion of ecological efficiency by digital economy,especially in central cities.

Urban Agglomerations in China: Characteristics and Influencing Factors of Population Agglomeration

Urban agglomeration(UA)is an advanced spatial economic form formed and developed in the process of rapid industrialization and urbanization,and an important carrier of urbanization and economic development.The economy has developed rapidly in the recent decades of China,and the UAs have also developed rapidly.However,as a large population country,the population distribution and changes of UAs in China has unique characteristics.Using the fifth,sixth and seventh population census data,spatial auto-correlation and spatial econometric models,we analyzed the spatial-temporal evolution characteristics and influencing factors of population agglomeration in China’s UAs.Results revealed that:1)from 2000 to 2020,the population gradually converged into UAs,and the characteristics of population agglomeration in different development degree of UAs differ.The higher the development degree of UA,the higher the population agglomeration degree.Besides,UAs are the main area with the most significant population agglomeration degree,and the spatial autocorrelation show that the cities with similar degree tend to be concentrated in space.The urban population gathering in UAs has a certain positive spillover effect on population size of neighboring cities.2)Economic development and social conditions factors are important factors affecting population agglomeration degree in UAs.The main factors of population gather into UAs are similar with the outside UAs,but the positive promotion of urbanization rate and proportion of tertiary industry in GDP on population agglomeration of UAs in China are enhancing from 2000 to 2020.Meanwhile,the other factors,such as high-quality public services,good urban living environment conditions,high-quality medical and educational resources,are also important factors to promote urban population gather into UAs.This study provides a basis for formulating the development planning of UAs in China,and enriches the relevant theoretical research of population evolution and influencing factors of UAs.

Interaction of water droplets with pyrolyzing coal particles and tablets

The paper presents the experimental research findings for the patterns of collisions of water droplets with pressed tableted samples used as substrates and with small particles of a pyrolyzing solid fuel.Brown coal samples were used.Droplet-substrate interactions were studied when varying the droplet diameter in the range from 1 to 4 mm and velocity from 0.5 to 4 m/s.That corresponded to the Weber number range of 7-830.The coal tablet surface temperature was varied from 20 to 700℃.In the interactions of water droplets(0.7-1.5 mm in diameter,pre-collision velocity from 1 to 3 m/s)with coal particles(with a size of 0.2-1 mm,pre-collision velocity 0.7-2 m/s),the temperature of the latter was varied in the range of 330-480℃.The following regimes of the interaction of droplets with solid particles during chemical reactions and phase transformations were distinguished:spreading/agglomeration and break-up/separation.Differences in the characteristics of the interaction of water droplets with coal particles at varying temperatures were identified.Droplet-particle interaction regime maps for B(We),We(Oh)and We(Ca)were constructed.The collision regime boundaries were described using fitted curves that can be utilized to develop the existing mathematical models of droplet-particle collisions in gas.It was established that the gaseous volatile production in coal pyrolysis has a modest effect on the regimes and characteristics of the droplet destruction in the temperature range under consideration(20-700℃).

Nano-enabled agglomerates and compact:Design aspects of challenges

Nanoscale medicine confers passive and active targeting potential.The development of nanomedicine is however met with processing,handling and administration hurdles.Excessive solid nanoparticle aggregation and caking result in lowproduct yield,poor particle flowability and inefficient drug administration.These are overcome by converting the nanoparticles into a microscale dosage form via agglomeration or compaction techniques.Agglomeration and compaction nonetheless predispose the nanoparticles to risks of losing their nanogeometry,surface composition or chemistry being altered and negating biological performance.This study reviews risk factors faced during agglomeration and compaction that could result in these changes to nanoparticles.The potential risk factors pertain to materials choice in nanoparticle and microscale dosage form development,and their interplay effects with process temperature,physical forces and environmental stresses.To render the physicochemical and biological behaviour of the nanoparticles unaffected by agglomeration or compaction,modes to modulate the interplay effects of material and formulation with processing and environment variables are discussed.

The Effect of Urban Agglomeration Expansion on PM_(2.5) Concentrations: Evidence from a Quasi-natural Experiment

This study constructs a quasi-natural experiment based on the expansion of the Yangtze River Delta urban agglomeration(YRDUA) of China in 2010 to investigate the impact and inner mechanism of urban agglomeration expansion on fine particulate matter(PM_(2.5)) concentrations through propensity scores in difference-in-differences models(PSM-DID) using panel data from 286 prefecturelevel cities in China from 2003 to 2016. The results show that 1) urban agglomeration expansion contributes to an overall decrease in PM_(2.5)concentration, which is mainly achieved from the original cities. For the new cities, on the other hand, the expansion significantly increases the local PM_(2.5)concentration. 2) In the long term, the significant influence of urban agglomeration expansion on PM_(2.5)concentration lasts for three years and gradually decreases. A series of robustness tests confirm the applicability of the PSM-DID model.3) Cities with weaker government regulation, a better educated population and higher per capita income present stronger PM_(2.5)reduction effects. 4) Urban agglomeration expansion affects the PM_(2.5)concentration mainly through industrial transfer and population migration, which cause a decrease in the PM_(2.5)concentration in the original cities and an increase in the PM_(2.5)concentration in the new cities.Corresponding policy suggestions are proposed based on the conclusions.

Urban Impact on Landfalling Tropical Cyclone Precipitation:A Numerical Study of Typhoon Rumbia(2018)

Coastal urban areas are prone to serious disasters caused by landfalling tropical cyclones(TCs). Despite the crucial role of urban forcing in precipitation, how fine-scale urban features impact landfalling TC precipitation remains poorly understood. In this study, high-resolution ensemble simulations of Typhoon Rumbia(2018), which crossed the Yangtze River Delta urban agglomeration, were conducted to analyze the potential urban impact on TC precipitation. Results show that the inner-core rainfall of Rumbia is strengthened by approximately 10% due to the urban impact near the landfall,whereas minor differences in outer-core rainfall are found when the urban impact is excluded. Further diagnostic analyses indicate that low-level upward motion is crucial for precipitation evolution, as both co-vary during landfall. Moreover, the frictionally induced upward motion plays a decisive role in enhancing the rainfall when the urban impacts are included.Urban surface friction can decelerate the tangential wind and therefore destroy the gradient balance and strengthen the radial wind within the boundary layer and thus can enhance upward motion. This study demonstrates that urban surface friction and related physical processes make the most significant contribution to landfalling TC rainfall enhancement.

Fast design of catalyst layer with optimal electrical-thermal-water performance for proton exchange membrane fuel cells

The catalyst layer(CL)is the core component in determining the electrical-thermal-water performance and cost of proton exchange membrane fuel cell(PEMFC).Systemic analysis and rapid prediction tools are required to improve the design efficiency of CL.In this study,a 3D multi-phase model integrated with the multi-level agglomerate model for CL is developed to describe the heat and mass transfer processes inside PEMFC.Moreover,a research framework combining the response surface method(RSM)and artificial neural network(ANN)model is proposed to conduct a quantitative analysis,and further a rapid and accurate prediction.With the help of this research framework,the effects of CL composition on the electrical-thermal-water performance of PEMFC are investigated.The results show that the mass of platinum,the mass of carbon,and the volume fraction of dry ionomer has a significant impact on the electrical-thermal-water performance.At the selected points,the sensitivity of the decision variables is ranked:volume fraction of dry ionomer>mass of platinum>mass of carbon>agglomerate radius.In particular,the sensitivity of the volume fraction of dry ionomer is over 50%at these points.Besides,the comparison results show that the ANN model could implement a more rapid and accurate prediction than the RSM model based on the same sample set.This in-depth study is beneficial to provide feasible guidance for high-performance CL design.

Surface Regional Heat(Cool) Island Effect and Its Diurnal Differences in Arid and Semiarid Resource-based Urban Agglomerations

With the rapid development of urban agglomerations in northwest arid and semiarid regions of China, the scope of the urban heat island(UHI) effect has gradually expanded and gradually connected, and has formed a regional heat island(RHI) with a larger range of impact to the regional environment. However, there are few studies on the heat island effect of urban agglomerations in arid and semiarid regions, so this paper selects the urban agglomeration of Hohhot, Baotou and Ordos(HBO) of Inner Mongolia, China as the study area. Based on the 8-day composite Moderate-resolution Imaging Spectroradiometer(MODIS) surface temperature data(156scenes in all) and land use maps for 2005, 2010, and 2015, we analyze the spatiotemporal distributions of regional heat(cool) islands(RH(C)I) and the responses of surface temperatures to land-use changes in the diurnal and interannual surface cities. The results showed that: 1) from 2005 to 2015, urban areas showed the cold island effect during the day, with the area of the cold island showing a shrinking feature;at night, they showed the heat island effect, with the area of the heat island showing a first decrease and then an increase.2) From 2005 to 2015, the land development(unutilized land to building land) brings the greatest temperature increase(ΔT = 1.36°C)during the day, while the greatest temperature change at night corresponds to the conversion of cultivated land to building land(ΔT =0.78°C) exhibited the largest changes at night. From 2010 to 2015, the land development(grassland to building land) bring the greatest temperature increase(ΔT = 0.85°C) during the day, while the great temperature change at night corresponds to the conversion of water areas to building land(ΔT = 1.38°C) exhibited the largest changes at night. Exploring the spatial and temporal evolution of surface urban heat(cool) islands in urban agglomerations in arid and semiarid regions will help to understand the urbanization characteristics of urban agglomerations and provide a reference for the formulation of policies for the coordinated and healthy development of the region and co-governance of regional environmental problems.

Does innovative city pilot policy promote urban green growth in China?An analysis of green total factor productivity,2005-2020

The innovative city pilot policy(ICPP)is an essential manifestation of China’s construction of an innovative and green-driven development country.We incorporated urban green total factor productivity(GTFP)growth into the evaluation of ICPP.Based on the panel data of 223 cities in China from 2005 to 2020,we used the difference-in-differences model to empirically assess the influence and mechanism of the ICPP on urban GTFP growth.The main results show that(i)The ICPP has maintained an effectively fluctuating promotion on urban GTFP growth,mainly manifested in the urban green technological progress improvement.(ii)The ICPP has urban heterogeneity in promoting GTFP growth in pilot cities,mainly affecting key cities such as provincial capitals.(iii)The interaction between the agglomeration of producer services and the ICPP inhibits GTFP growth in pilot cities.

Investment Promotion for Development Zones in China:Underlying Rationale and Policy Options

Development zones(DZs)have emerged as a significant policy initiative for promoting regional coordination and facilitating resources allocation.They serve as an organizational framework for fostering industrial agglomeration and driving high-quality development.DZs attract and accommodate resource factors,firms,and projects,thereby functioning as a central catalyst for economic growth.This study utilizes data collected at the“DZ,City and Countrycountry”levels through manual compilation,textual analysis,and innovation measurement.It aims to empirically examine the theoretical rationale and practical preferences for promoting business and investment in China’s DZs.This study considers several factors such as industry attribute,firm attribute,agglomeration theory,and industrial chain layout.Based on our research findings,DZs exhibit distinct preferences.First,industry attribute:DZs align with both national and regional strategic planning and adhere to the industrial endowments of the respective areas.Second,firm attribute:DZs prioritize attracting firms that are productive and innovative,and have an international presence,rather than those that primarily contribute to taxes and job creation.Third,DZs are guided by the agglomeration theory,which suggests that they prefer firms that generate strong agglomeration externalities.Lastly,DZs also consider the industrial chain layout,aiming to attract firms that not only align with their existing industrial strengths but also extend to the upstream and downstream supply chain links.These conclusions are substantiated by the performance of robustness test.The success of DZs in China can be attributed to the five key principles:Adherence to national and regional strategic planning,prioritizing the actual industrial foundation,incorporating the theory of agglomeration externalities,strengthening corporate competitiveness,and expanding industrial chains.

Spatio-temporal Evolution of Urban Expansion Based on a Novel Adjusted Index and GEE: A Case Study of Central Plains Urban Agglomeration, China

It is crucial to investigate the urban agglomerations spatio-temporal evolution patterns and driving factors for analyzing the urban spatial structure-functional division and promoting the coordinated development of urban agglomerations.In this study,a novel vegetation-building-nighttime light-adjusted index(VBNAI)was established for rapid and effective mapping of urban construction land(UCL)in Central Plains Urban Agglomeration(CPUA),China during 2000–2020 based on Google Earth Engine(GEE)platform.Compared with traditional indices,VBNAI can significantly decrease the blooming effect,Normalized Difference Vegetation Index(NDVI)saturation,and soil background of nighttime light data.In addition,the urban expansion indices and standard deviation ellipse model were synthetically adopted to analyze the spatio-temporal evolution pattern of urban expansion.The gravity model and the geographically weighted regression model were employed to determine the spatial interaction forces and drivers of urban expansion,respectively.The results showed that the VBNAI index has obvious advantages in efficiency and accuracy to extract UCL with the overall accuracy of more than 91%.The UCL of CPUA had increased by 4489.84 km2 during 2000–2020 with the gravity center moving towards southeast continuously.From 2000 to 2010,the urban expansion was in a‘center-hinterland’pattern which had benefit from the favorable effect of the traffic shaft belt.During 2010–2020,the urban network structure had basically established.Urban expansion had been influenced by a variety of socio-economic and demographic factors,and the impact degree varied from region to region.This study could provide scientific references for facilitating the intensive utilization of urban resources and optimizing the spatial development pattern of urban agglomeration.