Effects of Spherical Aggregates Addition on Properties of Al2O3-SiO2 System Castables

Compared with traditional aggregates,spherical aggregates with high flowability,easy control of particle size distribution and favor of dense packing and so on,are expected to replace traditional aggregates as important raw materials for future high performance refractories. Therefore,investigation of effects of spherical aggregates addition on properties of refractories becomes very meaningful. Using A70 mullite traditional aggregates and A70 mullite spherical aggregates, bauxite homogenization powder,microsilica,and calcium aluminate cement as raw materials,different AlO-SiOsystem low cement castables were prepared by replacing conventional aggregates with spherical aggregates. The effect of spherical aggregates addition on workability and mechanical properties of castables after heated at different temperatures was researched,and microstructure of the specimen was analyzed by SEM. Compared with traditional irregularly shaped aggregates,spherical aggregates endow castables with better flowability and easy pump ability. By introduction of spherical aggregates into the castables,flowability and pumpability are significantly improved,and water addition and ball completely sunk time are reduced. The introduction of spherical aggregates is favorable to density and cold crushing strength of castables,but unfavorable to CMOR. The effect of spherical aggregates addition on HMOR at1 400 ℃ can be negligible. Microstructure analysis showsthat the boundary bonding between spherical aggregates and matrix is strong,similar to the traditional aggregates.

Synthesis of Lightweight Spherical Forsterite Aggregates and Research on Their Application in Mgo Based Castables

Magnesite fine powder, natural silica powder,light-burned magnesia fine powder, silica fume and middle grade magnesia fine powder were used as the starting materials,and silica sol as binder to get high purity lightweight spherical forsterite aggregates. The mixture was granulated on a disc pelletizer and then calcined at 1 400 ℃ for 3h. The synthesized spherical forsterite aggregates were added in Mg O based castables with MgO-SiO2-H2O binding system to replace equaldensity high purity common forsterite aggregates. Effect of spherical forsterite aggregates addition on properties of MgO based castables was investigated. The results show that: compared with common aggregates,lightweight spherical forsterite aggregates can improve castables ’flow ability and decrease water addition; addition of spherical aggregates has little effect on cold strength of castables; with the increase of spherical aggregate addition,shrinkage of specimens after drying and heating at intermediate temperatures decreases,but the expansion of specimens after heating at high temperatures increases,bulk density decreases and apparent porosity increases,and thermal conductivity declines.

Effects of Spherical Light-weight Aggregates Additions on Workability and Mechanical Properties of Al_2O_3-SiO_2 System Castables

In order to clarify the effect of spherical light-weight aggregates addition on properties of A12 07 - Si02 system castables, adopting ATO mullite traditional light-weight aggregates and ATO mullite spherical light-weight aggre- gates, bauxite homogenization powder, microsilica , cal- cium aluminate cement as main raw materials, light- weight Al2 03 - SiO2 system castables were prepared by replacing conventional light-weight aggregate with spherical light-weight aggregates. The effects of spheri- cal light-weight aggregates addition on workability, me- chanical properties of castables after heated at different temperatures were researched; the microstructure of the aggregates was analyzed by SEM. The result shows that the introduction of spherical light-weight aggregates can significantly improve the flowability and reduce the water addition of the castables. Water demand of the castable is reduced from 18% with the conventional light-weight aggregates to 14% with spherical light-weight aggre- gates. In addition, light-weight castables prepared by spherical aggregates can keep the same workability with- in a wider range of water addition. Therefore, spherical aggregates are user-friendly. The introduction of spheri- cal light-weight aggregates is favorable to packing densi- ty and mechanical properties of castables, such as cold crushing strength, cold modulus of rupture, hot modulus of rupture at 1 200℃.

Influence of Kyanite Content on Microstructures and Properties of Castables Containing Spherical Lightweight Mullite Aggregates

Five lightweight mullite castables were prepared using the lightweight mullite aggregate（M45A） with narrow particle size distribution and spherical shape,mullite powder（M45P）,kyanite powder,microsilica and Secar 71 cement as raw materials. After the specimens fired at 1100 ℃,1200 ℃ and 1300 ℃ for 3h,respectively,the effects of kyanite contents（ 8%,10%,12%,14%,16% by mass） on the physical properties,phase composition and microstructures were investigated through an X-ray diffractometer（ XRD）,a scanning election microscopy（ SEM） and a microscopy measurement method,etc. The results show that,for the specimens fired at 1300 ℃ with the kyanite content from 8%to16%, the bulk densities and apparent porosities change little,but the cold modulus of rupture and the crushing strengths decrease significantly,and the linear change rates increase from-0.87% to 0.64%. The most apposite mode is the specimen containing 12% kyanite fired at 1300 ℃, which has a high crushing strength of 29.3 MPa,a low linear change of 0.18%,an apparent porosity of 36.8% and a bulk density of 1.73 g/cm^3.

Properties of Castables Made of Spherical Lightweight Mullite Aggregates

The castables were prepared from spherical lightweight mullite aggregates,bauxite,SiO2 fine powder,α-Al2O3 fine powder and calcium aluminate cement.The performance changes of the castables were studied after heat treatment at 110℃for 24 h,1100℃for 3 h,1200℃for 3 h and 1300℃for 3 h.The results illustrate that the cold modulus of rupture and hot modulus of rupture of the castable increase with the rising heat treatment temperature.The cold crushing strength shows a“V”change trend when the heat treatment temperature rises from 1100 to 1300℃.After the specimen is heat treated at 1300℃,the thermal conductivity is 0.500 W·m-1·K-1,0.586 W·m-1·K-1,0.595 W·m-1·K-1 at 300,600 and 900℃,respectively.The SEM analysis explains the change trends of these properties.The prepared lightweight mullite castables can be applied as the working lining of hot-blast furnaces.

Spherical Linear Diophantine Fuzzy Sets with Modeling Uncertainties in MCDM

The existing concepts of picture fuzzy sets(PFS),spherical fuzzy sets(SFSs),T-spherical fuzzy sets(T-SFSs)and neutrosophic sets(NSs)have numerous applications in decision-making problems,but they have various strict limitations for their satisfaction,dissatisfaction,abstain or refusal grades.To relax these strict constraints,we introduce the concept of spherical linearDiophantine fuzzy sets(SLDFSs)with the inclusion of reference or control parameters.A SLDFSwith parameterizations process is very helpful formodeling uncertainties in themulti-criteria decisionmaking(MCDM)process.SLDFSs can classify a physical systemwith the help of reference parameters.We discuss various real-life applications of SLDFSs towards digital image processing,network systems,vote casting,electrical engineering,medication,and selection of optimal choice.We show some drawbacks of operations of picture fuzzy sets and their corresponding aggregation operators.Some new operations on picture fuzzy sets are also introduced.Some fundamental operations on SLDFSs and different types of score functions of spherical linear Diophantine fuzzy numbers(SLDFNs)are proposed.New aggregation operators named spherical linear Diophantine fuzzy weighted geometric aggregation(SLDFWGA)and spherical linear Diophantine fuzzy weighted average aggregation(SLDFWAA)operators are developed for a robust MCDM approach.An application of the proposed methodology with SLDF information is illustrated.The comparison analysis of the final ranking is also given to demonstrate the validity,feasibility,and efficiency of the proposed MCDM approach.