The air-flow’s states and ways acted on the technological process of chemical fiber are summed up, which includes chip drying, spinning quenching as well as airjet texturing (air texturing, tangling texturing and bul...The air-flow’s states and ways acted on the technological process of chemical fiber are summed up, which includes chip drying, spinning quenching as well as airjet texturing (air texturing, tangling texturing and bulked continuous filament (BCF)),and the effect of air-flow on the process and quality of chemical fiber is studied,and the action of mechanics and heat on the bulked continuous filament are calculated.展开更多
In this paper,the Reynolds number,velocity,pressureand kinetic energy of the BCF processing hot air-floware analyzed with the help of the aero-dynamic theory,and their distributions inside the texturing tube are ob-ta...In this paper,the Reynolds number,velocity,pressureand kinetic energy of the BCF processing hot air-floware analyzed with the help of the aero-dynamic theory,and their distributions inside the texturing tube are ob-tained by pressure measuring.展开更多
In the present study, the air quality is assessed for the year 2010 regarding to the Total Suspended Particles (TSP) for six cities of Sonora, Mexico, representing the first regional study in Sonora in air quality. Th...In the present study, the air quality is assessed for the year 2010 regarding to the Total Suspended Particles (TSP) for six cities of Sonora, Mexico, representing the first regional study in Sonora in air quality. The assessment used performance indicators and indicators of compliance with the regulations. It is established that in all the cities the maximum limit value of daily concentration of 210 μg/m3 is exceeded, being the percentage of days above the rule of 30%, 78%, 76%, 6%, 3% and 62% for Agua Prieta, Nogales, Puerto Penasco, Hermosillo, Guaymas and Obregón respectively, classifying these days with poor air quality. According to the annualized index used, the air quality was not satisfactory for the period of study in the six cities. Nogales and Puerto Penasco presented the most adverse conditions of air quality with annual average values of TSP of 363 and 345 μg/m3 and maximum daily of 1047 and 1239 μg/m3 (498% and 590% above the norm) respectively. The requirements of coverage that establishes the Mexican Official Standard NOM-025-SSA1-1993 (SSA, 2005) are questioned for its compliance, proposing in this paper a criterion of non-compliance by prioritizing the protection of health and the precautionary principle. It is recommended to implement air quality management programs (PROAIRE) in these cities.展开更多
Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar...Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar region.After the onset of a December WPV event,the dynamic processes influencing Eurasian temperature can be split into two separate periods.Period I(lag of 0-25 days)is referred to as the stratosphere-troposphere interactions period,as it is mainly characterized by stratospheric signals propagating downwards.In Period I,a stratospheric negative Northern Annular Mode(NAM)pattern associated with the WPV propagates downwards,inducing a negative NAM in the troposphere.The anomalous low centers over the Mediterranean and North Pacific bring cold advection to northern Eurasia,resulting in a north-cold-south-warm dipole pattern over Eurasia.The zero line between negative and positive temperature anomalies moves southwards during days 5-20.Stratospheric cold anomalies at midlatitudes propagate downwards to high latitudes in the troposphere and contribute to the dipole structure.During PeriodⅡ(lag of 25-40 days),as downward signals from the stratosphere have vanished,the dynamic processes mainly take place within the troposphere.Specifically,a wave train is initiated from the North Atlantic region to northern Europe.The propagation of wave activity flux intensifies a cyclonic anomaly over northern Europe,which brings cold advection to Scandinavia and warm advection to central Asia.Therefore,a northwest-cold-southeast-warm dipole structure occupies Eurasia and migrates southeastwards during this period.展开更多
In this paper, the factors to influence the dynamic heat - moisture comfort of summer clothing fabrics have been studied. It is pointed out that, when the wind speed outside is high, or the air permeability is very go...In this paper, the factors to influence the dynamic heat - moisture comfort of summer clothing fabrics have been studied. It is pointed out that, when the wind speed outside is high, or the air permeability is very good, the sweat of human body will evaporate mainly through turbulent diffusion. Because of the rapid sweat evaporation, human body will feel cold, and then, the difference in temperature and humidity of the micro - climatic section will be very slight. On the contrary, when the wind speed outside is slow or the air permeability is unsatisfactory, the sweat of human body will evaporate mainly through molecular diffusion, and in this case, the humidity of the micro - climatic section will be depended on the hygroscopicity of the fabric, that’ s to say, the better the hygroscopicity, the lower the humidity. It is difficult for pure wool fabric to loss heat because of its giving out much heat during the course of moisture - absorption in the initial stages of sweating. For pure polyester fabric,展开更多
The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between ...The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between 50-90℃.The optimum reaction conditions of the oxidative polycondensation and the main parameters of the process were established.At the optimum reaction conditions,yield of the products were found to be 67.72% and 61.49% for air O_2 and NaOCl oxidants respectively.The structures of the monomer ...展开更多
The oxidative polycondensation reaction conditions of 4-[（4-hydroxybenzylidene） amino] phenol （4-HBAP） were studied with H2O2, air oxygen and NaOCl in an aqueous alkaline medium between 50 and 90℃. The structures...The oxidative polycondensation reaction conditions of 4-[（4-hydroxybenzylidene） amino] phenol （4-HBAP） were studied with H2O2, air oxygen and NaOCl in an aqueous alkaline medium between 50 and 90℃. The structures of the obtained monomer and polymer were confirmed by FT-IR, UV-Vis, 1H- and 13C-NMR and elemental analysis. The characterization was made by TG-DTA, size exclusion chromatography （SEC） and solubility tests. At the optimum reaction conditions, the yield of poly[4-（4-hydroxybenzylidene amino） phenol] （P-4-HBAP） was found to be 48.3% （for H2O2 oxidant）, 80.5% （for air O2 oxidant） and 86.4% （for NaOCl oxidant）. According to the SEC analysis, the number-average molecular weight （Mn）, weight-average molecular weight （Mw） and polydispersity index （PDI） values of P-4-HBAP was found to be 8950, 10970 g tool^-1 and 1.225, respectively, using H202; and l l610, 15190 g tool^-1 and 1.308 respectively, using air 02 and 7900, 9610 g mol^-1 and 1.216, respectively, using NaOC1. According to TG-DTA analyses, P-4-HBAP was more stable than 4-HBAP against thermal decomposition. The weight loss of P-4-HBAP was found to be 49.27% at 1000℃. The highest occupied molecular orbital （HOMO） and the lowest unoccupied molecular orbital （LUMO） values calculated from electrochemical measurement. Electrochemical energy gaps （Eg＇） of 4-HBAP and P-4-HBAP were found to be -5.46, -5.28; -2.26, -2.67; 3.20 and 2.61 eV, respectively. According to UV-Vis measurements, optical band gap （Eg） of 4-HBAP and P-4-HBAP were found to be 3.34 and 3.01 eV, respectively. Also, antimicrobial activities of 4-HBAP and P-4-HBAP were examined against selected some bacteria. The electrical conductivity of the polymer was measured after doping with iodine.展开更多
The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between...The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...展开更多
Catalytic wet air oxidation(CWAO)coupled desalination technology provides a possibility for the effective and economic degradation of high salinity and high organic wastewater.Chloride widely occurs in natural and was...Catalytic wet air oxidation(CWAO)coupled desalination technology provides a possibility for the effective and economic degradation of high salinity and high organic wastewater.Chloride widely occurs in natural and wastewaters,and its high content jeopardizes the efficacy of Advanced oxidation process(AOPs).Thus,a novel chlorine ion resistant catalyst Bsite Ru doped LaFe_(1-x)Ru_(x)O_(3-)δin CWAO treatment of chlorine ion wastewater was examined.Especially,LaFe_(0.85)Ru_(0.15)O_(3-δ)was 45.5% better than that of the 6%RuO_(2)@TiO_(2)(commercial carrier)on total organic carbon(TOC)removal.Also,doped catalysts LaFe_(1-x)Ru_(x)O_(3-)δshowed better activity than supported catalysts RuO_(2)@LaFeO_(3) and RuO_(2)@TiO_(2) with the same Ru content.Moreover,LaFe_(0.85)Ru_(0.15)O_(3-)δhas novel chlorine ion resistance no matter the concentration of Cl^(−) and no Ru dissolves after the reaction.X-ray diffraction(XRD)refinement,X-ray photoelectron spectroscopy(XPS),transmission electron microscope(TEM),and X-ray absorption fine structure(XAFS)measurements verified the structure of LaFe_(0.85)Ru_(0.15)O_(3-)δ.Kinetic data and density functional theory(DFT)proved that Fe is the site of acetic acid oxidation and adsorption of chloride ions.The existence of Fe in LaFe_(0.85)Ru_(0.15)O_(3-)δcould adsorb chlorine ion(catalytic activity inhibitor),which can protect the Ru site and other active oxygen species to exert catalytic activity.This work is essential for the development of chloride-resistant catalyst in CWAO.展开更多
Temperature is one of the important loads for designing slab track. The characteristic of slab track tem- perature varies greatly with different regional climates. In this work, a bi-block slab track model was built u...Temperature is one of the important loads for designing slab track. The characteristic of slab track tem- perature varies greatly with different regional climates. In this work, a bi-block slab track model was built under outdoor conditions in Chengdu area; the statistical characteristic of temperature gradient in track slab and the relationship between temperature gradient and surface air temperature were tested and analyzed. The results show that the track slab temperature gradient will vary periodically according to the surface air temperature, and show a clear nonlinearity along the height direction. The temperature gradient distribution is extremely uneven： the temperature gradient in the top part of the track slab is larger than that in the bottom part; the most frequently occurring temperature gradient of the track slab is around -3.5 ℃/m and more than 75 % locates in the level -10 to 10 ℃/m; concrete with a relatively good heat exchange condition with the surrounding air has a narrower band distribution. In addition, the frequency distribution histogram should exclude the time zone from 00：00 to 06：00 because there is almost no traffic in this period. The amplitude of track slab temperature variation is obviously lower than that of the air temperature variation, and the former is approximately linear with the latter.展开更多
Cooling water provides the best protection for refractory in the blast furnace hearth. Stable and suitable water quality and abundant cooling water are the basis for long service life of the hearth. Some phenomena abo...Cooling water provides the best protection for refractory in the blast furnace hearth. Stable and suitable water quality and abundant cooling water are the basis for long service life of the hearth. Some phenomena about cooling system in the commercial blast furnaces were described, and reasonable explanations of these phenomena were analyzed. The results show that increasing the amount of cooling water and reducing the inlet temperature of cooling water can increase the cooling effect significantly in the case of water scaling. Heat flux in the blast furnace hearth is the average heat flux of cooling stave, and the erosion of carbon brick is uneven. There is no direct connection between the actual erosion condition and the heat flux in the hearth. The change trend of thermocouple temperature and heat flux in the hearth can reflect whether the gaps exist among the bricks or not, providing an effective guidance for industrial production and the evaluation of safety state in the hearth. And, the film boiling will not occur in the normal cooling system in the blast furnace hearth.展开更多
文摘The air-flow’s states and ways acted on the technological process of chemical fiber are summed up, which includes chip drying, spinning quenching as well as airjet texturing (air texturing, tangling texturing and bulked continuous filament (BCF)),and the effect of air-flow on the process and quality of chemical fiber is studied,and the action of mechanics and heat on the bulked continuous filament are calculated.
文摘In this paper,the Reynolds number,velocity,pressureand kinetic energy of the BCF processing hot air-floware analyzed with the help of the aero-dynamic theory,and their distributions inside the texturing tube are ob-tained by pressure measuring.
基金supported by the Institute of Engineering of the Autonomous University of Baja California,also by to the Industrial Environmental Engineering Program of the Sonora State University,and the Division of Engineering,Department of Chemical Engineering and Metallurgy of the University of Sonora.
文摘In the present study, the air quality is assessed for the year 2010 regarding to the Total Suspended Particles (TSP) for six cities of Sonora, Mexico, representing the first regional study in Sonora in air quality. The assessment used performance indicators and indicators of compliance with the regulations. It is established that in all the cities the maximum limit value of daily concentration of 210 μg/m3 is exceeded, being the percentage of days above the rule of 30%, 78%, 76%, 6%, 3% and 62% for Agua Prieta, Nogales, Puerto Penasco, Hermosillo, Guaymas and Obregón respectively, classifying these days with poor air quality. According to the annualized index used, the air quality was not satisfactory for the period of study in the six cities. Nogales and Puerto Penasco presented the most adverse conditions of air quality with annual average values of TSP of 363 and 345 μg/m3 and maximum daily of 1047 and 1239 μg/m3 (498% and 590% above the norm) respectively. The requirements of coverage that establishes the Mexican Official Standard NOM-025-SSA1-1993 (SSA, 2005) are questioned for its compliance, proposing in this paper a criterion of non-compliance by prioritizing the protection of health and the precautionary principle. It is recommended to implement air quality management programs (PROAIRE) in these cities.
基金supported by the National Natural Science Foundation of China [grant numbers 41730964,41575079,and 41421004]
文摘Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar region.After the onset of a December WPV event,the dynamic processes influencing Eurasian temperature can be split into two separate periods.Period I(lag of 0-25 days)is referred to as the stratosphere-troposphere interactions period,as it is mainly characterized by stratospheric signals propagating downwards.In Period I,a stratospheric negative Northern Annular Mode(NAM)pattern associated with the WPV propagates downwards,inducing a negative NAM in the troposphere.The anomalous low centers over the Mediterranean and North Pacific bring cold advection to northern Eurasia,resulting in a north-cold-south-warm dipole pattern over Eurasia.The zero line between negative and positive temperature anomalies moves southwards during days 5-20.Stratospheric cold anomalies at midlatitudes propagate downwards to high latitudes in the troposphere and contribute to the dipole structure.During PeriodⅡ(lag of 25-40 days),as downward signals from the stratosphere have vanished,the dynamic processes mainly take place within the troposphere.Specifically,a wave train is initiated from the North Atlantic region to northern Europe.The propagation of wave activity flux intensifies a cyclonic anomaly over northern Europe,which brings cold advection to Scandinavia and warm advection to central Asia.Therefore,a northwest-cold-southeast-warm dipole structure occupies Eurasia and migrates southeastwards during this period.
文摘In this paper, the factors to influence the dynamic heat - moisture comfort of summer clothing fabrics have been studied. It is pointed out that, when the wind speed outside is high, or the air permeability is very good, the sweat of human body will evaporate mainly through turbulent diffusion. Because of the rapid sweat evaporation, human body will feel cold, and then, the difference in temperature and humidity of the micro - climatic section will be very slight. On the contrary, when the wind speed outside is slow or the air permeability is unsatisfactory, the sweat of human body will evaporate mainly through molecular diffusion, and in this case, the humidity of the micro - climatic section will be depended on the hygroscopicity of the fabric, that’ s to say, the better the hygroscopicity, the lower the humidity. It is difficult for pure wool fabric to loss heat because of its giving out much heat during the course of moisture - absorption in the initial stages of sweating. For pure polyester fabric,
基金This work was supported by the Canakkale Onsekiz Mart University Scientific Research Projects Commission for financial support(No.2007/20).
文摘The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between 50-90℃.The optimum reaction conditions of the oxidative polycondensation and the main parameters of the process were established.At the optimum reaction conditions,yield of the products were found to be 67.72% and 61.49% for air O_2 and NaOCl oxidants respectively.The structures of the monomer ...
基金This work was financially supported by the TUBITAK Grants Commission for a research grant(No.TBAG-2451(104T062)).
文摘The oxidative polycondensation reaction conditions of 4-[（4-hydroxybenzylidene） amino] phenol （4-HBAP） were studied with H2O2, air oxygen and NaOCl in an aqueous alkaline medium between 50 and 90℃. The structures of the obtained monomer and polymer were confirmed by FT-IR, UV-Vis, 1H- and 13C-NMR and elemental analysis. The characterization was made by TG-DTA, size exclusion chromatography （SEC） and solubility tests. At the optimum reaction conditions, the yield of poly[4-（4-hydroxybenzylidene amino） phenol] （P-4-HBAP） was found to be 48.3% （for H2O2 oxidant）, 80.5% （for air O2 oxidant） and 86.4% （for NaOCl oxidant）. According to the SEC analysis, the number-average molecular weight （Mn）, weight-average molecular weight （Mw） and polydispersity index （PDI） values of P-4-HBAP was found to be 8950, 10970 g tool^-1 and 1.225, respectively, using H202; and l l610, 15190 g tool^-1 and 1.308 respectively, using air 02 and 7900, 9610 g mol^-1 and 1.216, respectively, using NaOC1. According to TG-DTA analyses, P-4-HBAP was more stable than 4-HBAP against thermal decomposition. The weight loss of P-4-HBAP was found to be 49.27% at 1000℃. The highest occupied molecular orbital （HOMO） and the lowest unoccupied molecular orbital （LUMO） values calculated from electrochemical measurement. Electrochemical energy gaps （Eg＇） of 4-HBAP and P-4-HBAP were found to be -5.46, -5.28; -2.26, -2.67; 3.20 and 2.61 eV, respectively. According to UV-Vis measurements, optical band gap （Eg） of 4-HBAP and P-4-HBAP were found to be 3.34 and 3.01 eV, respectively. Also, antimicrobial activities of 4-HBAP and P-4-HBAP were examined against selected some bacteria. The electrical conductivity of the polymer was measured after doping with iodine.
基金supported by the Government Planning Organization(GPO2002K120170-7)TUBITAK GrantsCommission for a research grant(No.TBAG-105T428).
文摘The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...
基金supported by the Natural Science Foundation of Liaoning Province (No. 2020-BS-012)the National Natural Science Foundation of China (No. 51878643)+2 种基金the Dalian Institute of Chemical Physics & Qingdao Institute of Bioenergy and Bioprocess Technology (DICP&QIBEBT) (No. UN201809)the Scientific Research Common Program of Beijing Municipal Commission of Education (No. KM202010017006)Talents Project of Beijing Organization Department (No. 2018000020124G091)。
文摘Catalytic wet air oxidation(CWAO)coupled desalination technology provides a possibility for the effective and economic degradation of high salinity and high organic wastewater.Chloride widely occurs in natural and wastewaters,and its high content jeopardizes the efficacy of Advanced oxidation process(AOPs).Thus,a novel chlorine ion resistant catalyst Bsite Ru doped LaFe_(1-x)Ru_(x)O_(3-)δin CWAO treatment of chlorine ion wastewater was examined.Especially,LaFe_(0.85)Ru_(0.15)O_(3-δ)was 45.5% better than that of the 6%RuO_(2)@TiO_(2)(commercial carrier)on total organic carbon(TOC)removal.Also,doped catalysts LaFe_(1-x)Ru_(x)O_(3-)δshowed better activity than supported catalysts RuO_(2)@LaFeO_(3) and RuO_(2)@TiO_(2) with the same Ru content.Moreover,LaFe_(0.85)Ru_(0.15)O_(3-)δhas novel chlorine ion resistance no matter the concentration of Cl^(−) and no Ru dissolves after the reaction.X-ray diffraction(XRD)refinement,X-ray photoelectron spectroscopy(XPS),transmission electron microscope(TEM),and X-ray absorption fine structure(XAFS)measurements verified the structure of LaFe_(0.85)Ru_(0.15)O_(3-)δ.Kinetic data and density functional theory(DFT)proved that Fe is the site of acetic acid oxidation and adsorption of chloride ions.The existence of Fe in LaFe_(0.85)Ru_(0.15)O_(3-)δcould adsorb chlorine ion(catalytic activity inhibitor),which can protect the Ru site and other active oxygen species to exert catalytic activity.This work is essential for the development of chloride-resistant catalyst in CWAO.
基金supported by the National Key Basic Research Program of China (973 Program) (2013CB036202)the National Natural Science Foundation of China (51008258)Fundamental Research Funds for the Central Universities (SWJTU12CX065)
文摘Temperature is one of the important loads for designing slab track. The characteristic of slab track tem- perature varies greatly with different regional climates. In this work, a bi-block slab track model was built under outdoor conditions in Chengdu area; the statistical characteristic of temperature gradient in track slab and the relationship between temperature gradient and surface air temperature were tested and analyzed. The results show that the track slab temperature gradient will vary periodically according to the surface air temperature, and show a clear nonlinearity along the height direction. The temperature gradient distribution is extremely uneven： the temperature gradient in the top part of the track slab is larger than that in the bottom part; the most frequently occurring temperature gradient of the track slab is around -3.5 ℃/m and more than 75 % locates in the level -10 to 10 ℃/m; concrete with a relatively good heat exchange condition with the surrounding air has a narrower band distribution. In addition, the frequency distribution histogram should exclude the time zone from 00：00 to 06：00 because there is almost no traffic in this period. The amplitude of track slab temperature variation is obviously lower than that of the air temperature variation, and the former is approximately linear with the latter.
基金This work National Science Foundation （51704019）. was financially supported by the for Young Scientists of China
文摘Cooling water provides the best protection for refractory in the blast furnace hearth. Stable and suitable water quality and abundant cooling water are the basis for long service life of the hearth. Some phenomena about cooling system in the commercial blast furnaces were described, and reasonable explanations of these phenomena were analyzed. The results show that increasing the amount of cooling water and reducing the inlet temperature of cooling water can increase the cooling effect significantly in the case of water scaling. Heat flux in the blast furnace hearth is the average heat flux of cooling stave, and the erosion of carbon brick is uneven. There is no direct connection between the actual erosion condition and the heat flux in the hearth. The change trend of thermocouple temperature and heat flux in the hearth can reflect whether the gaps exist among the bricks or not, providing an effective guidance for industrial production and the evaluation of safety state in the hearth. And, the film boiling will not occur in the normal cooling system in the blast furnace hearth.
