We present the thermal expansion coefficient (TEC) measurement technology of compensating for the effect of variations in the refractive index based on a Nd: YA G laser feedback system, the beam frequency is shifte...We present the thermal expansion coefficient (TEC) measurement technology of compensating for the effect of variations in the refractive index based on a Nd: YA G laser feedback system, the beam frequency is shifted by a pair of aeousto-optic modulators and then the heterodyne phase measurement technique is used. The sample measured is placed in a muffle furnace with two coaxial holes opened on the opposite furnace walls. The measurement beams hit perpendicularly and coaxially on each surface of the sample. The reference beams hit on the reference mirror and the high-refiectivity mirror, respectively. By the heterodyne configuration and computing, the influences of the vibration, distortion of the sample supporter and the effect of variations in the refractive index are measured and largely minimized. For validation, the TECs of aluminum samples are determined in the temperature range of 29-748K, confirming not only the precision within 5 × 10-7 K-1 and the accuracy within 0.4% from 298K to 448K but also the high sensitivity non-contact measurement of the lower reflectivity surface induced by the sample oxidization from 448 K to 748 K.展开更多
Air pollution has considerable impact on human health and the wellbeing. Thus many regions of the world have established air pollution standards to ensure a minimum level of air quality. Precise assessment of the heal...Air pollution has considerable impact on human health and the wellbeing. Thus many regions of the world have established air pollution standards to ensure a minimum level of air quality. Precise assessment of the health and socio-economic impacts of air pollution is, however, a complex task;indeed, methods based within an epidemiological tradition generally underestimate human risk of exposure to polluted air. In this study, we introduce an agent-based modeling approach to ascertaining the impact of changes in particulate matter (PM10) on mortality and frequency of hospital visits in the greater metropolitan region of Sydney, Australia. Our modeling approach simulates human movement and behavioral patterns in order to obtain an accurate estimate of individual exposure to a pollutant. Results of our analysis indicate that a 50% reduction in PM10 levels (relative to the baseline) could considerably lower mortality, respiratory hospital admissions and emergency room visits leading to reduced pressure on health care sector costs and placing lower stress on emergency medical facilities. Our analysis also highlights the continued need to avoid significant increases in air pollution in Sydney so that associated health impacts, including health care costs, do not increase.展开更多
In 5G systems, massive multiple-input multiple-output (MIMO) has been adopted in base stations (BSs) to improve spectral efficiency and coverage. The traditional conductive performance test techniques are challenging ...In 5G systems, massive multiple-input multiple-output (MIMO) has been adopted in base stations (BSs) to improve spectral efficiency and coverage. The traditional conductive performance test techniques are challenging due to the unaffordable cost and high complexity when testing a large number of antennas. To solve this problem, the over-the-air (OTA) test has been presented, in which probe selection is the key to reduce the number of channel emulators and probes. In this paper, a novel artificial bee colony (ABC) algorithm is introduced to enhance the efficiency and accuracy of probe selection procedure. A sectoring- based multi-probe anechoic chamber (MPAC) is built to evaluate the throughput performance of massive MIMO equipped in 5G BS. In addition, link level simulation is carried out to evaluate the proposal’s performance gain under the commercial network assumptions, where the average throughput of three velocity is given with different SNR region. The results suggest that OTA chamber and multi-probe wall are available not only for 5G BSs, but also for user equipments (UEs) with end-to-end communication.展开更多
In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in ...In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in nitrogen environment,the spectrum result of Grignard-type reaction~[6] is verified by the decomposition characteristics of MT and MTV pyrolants.8.71% of Mg is consumed in the intermediate reaction of MT at 500-596 ℃ and the heat release of reaction is 31.93 k J/g.The endothermic decomposition of the intermediate product is at 684-740 ℃.In MTV,the intermediate reaction is at 435-595 ℃ and the heat release of reaction are increased by the addition of fluororubber.The intermediate product degrades at 677-745 ℃.In air environment,the decomposition of MT and MTV show the different reaction mechanism from the nitrogen environment.The presence of oxygen is involved in the reaction of Mg,and inhibits the intermediate reaction process of Mg and PTFE.展开更多
The influence of air-cooled blast furnace slag aggregates as replacement of natural aggregates on the water absorption of concrete and mortar was studied, and the mechanism was analyzed. The interface between aggregat...The influence of air-cooled blast furnace slag aggregates as replacement of natural aggregates on the water absorption of concrete and mortar was studied, and the mechanism was analyzed. The interface between aggregate and matrix in concrete was analyzed by using a micro-hardness tester, a laser confocal microscope and a scanning electron microscope with backscattered electron image mode. The pore structure of mortar matrixes under different curing conditions was investigated by mercury intrusion porosimetry. The results showed that when natural aggregates were replaced with air-cooled blast furnace slag aggregates in mortar or concrete, the content of the capillary pore in the mortar matrix was reduced and the interfacial structure between aggregate and matrix was improved, resulting in the lower water absorption of mortar or concrete. Compared to the concrete made with crushed limestone and natural river sand, the initial absorption coefficient, the secondary absorption coefficient and the water absorption capacity through the surface for 7 d of the concrete made from crushed air-cooled blast furnace slag and air-cooled blast furnace slag sand were reduced by 48.9%, 52.8%, and 46.5%, respectively.展开更多
The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flappi...The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flapping wing wasdeveloped.A control scheme inspired by human memory and learning concept was constructed for wing motion control ofMAVs.The salient feature of the proposed control lies in its capabilities to improve the control performance by learning fromexperience and observation on its current and past behaviors, without the need for system dynamic information.Furthermore,the overall control scheme has a fairly simple structure and demands little online computations, making it attractive for real-timeimplementation on MAVs.Both theoretical analysis and computer simulation confirms its effectiveness.展开更多
To investigate the durability, especially the long-term stability of cement-based materials with very low w/b, the air permeability test, carbonation test, capillary absorption rate test and dilation potential test we...To investigate the durability, especially the long-term stability of cement-based materials with very low w/b, the air permeability test, carbonation test, capillary absorption rate test and dilation potential test were adopted under long-term heat treatment condition. Microstructure of these materials is also analyzed by scanning electronic microscopy (SEM) and mercury intrusion porosimeter (MIP) in order to further unveil its mechanism and interrelation between microstructure and its properties. The results indicate that in the area investigated, cement-based material with w/b 0.17, like RPC, possesses low porosity and excellent durability. Moreover, its porosity will further decrease under long-term heat treatment compared with normal heat treatment. Its long-term durability is much superior to that of other cement-based materials with w/b 0.25 or 0.35 as high strength concrete(HSC).展开更多
In this paper, we present the development of flexible zinc–air battery. Multiwalled carbon nanotubes(MWCNTs) were added into electrodes to improve their performance. It was found that MWCNTs were effective conductive...In this paper, we present the development of flexible zinc–air battery. Multiwalled carbon nanotubes(MWCNTs) were added into electrodes to improve their performance. It was found that MWCNTs were effective conductive additive in anode as they bridged the zinc particles. Poly(3,4-ethylenedioxythiophene)polystyrene sulfonate(PEDOT:PSS) was applied as a co-binder to enhance both the conductivity and flexibility. A poly(acrylic acid)(PAA) and polyvinyl alcohol(PVA) coated paper separator was used to enhance the battery performance where the PVP–PAA layer facilitated electrolyte storage. The batteries remained functional under bending conditions and after bending. Multiple design optimizations were also carried out for storage and performance purposes.展开更多
Vanadium-catalyzed oxidative kinetic resolution(OKR) of methyl o-chloromandelate 2a,key intermediate of the well-known oral antiplatelet agent(S)-clopidogrel,was achieved by ambient air for the first time.The air ...Vanadium-catalyzed oxidative kinetic resolution(OKR) of methyl o-chloromandelate 2a,key intermediate of the well-known oral antiplatelet agent(S)-clopidogrel,was achieved by ambient air for the first time.The air oxidation system,which was composed of vanadium and tridentate Schiff base ligands derived from amino alcohols and salicylaldehyde derivatives,afforded an efficient and economic approach to the target intermediate with high enantioselectivities(99%ee).展开更多
The Global Geopotential Models (GGMs) of GOCE (Gravity Recovery and steady- state Ocean Circulation Explorer) differ globally as well as regionally in their accuracy and resolution based on the maximum degree and orde...The Global Geopotential Models (GGMs) of GOCE (Gravity Recovery and steady- state Ocean Circulation Explorer) differ globally as well as regionally in their accuracy and resolution based on the maximum degree and order (d/o) of the fully normalized spherical harmonic (SH) coefficients, which express each GGM. The main idea of this study is to compare the free-air gravity anomalies and quasi geoid heights determined from several recent GOCE-based GGMs with the corresponding ones from the Earth Gravitational Model 2008 (EGM2008) over Egypt on the one hand and with ground-based measurements on the other hand. The results regarding to the comparison of GOCE-based GGMs with terrestrial gravity and GPS/levelling data provide better improvement with respect to EGM2008. The 4th release GOCE-based GGM developed with the use of space-wise solution strategy (SPW_R4) approximates the gravity field well over the Egyptian region. The SPW_R4 model is accordingly suggested as a reference model for recovering the long wavelength (up to SH d/o 200) components of quasi geoid heights when modelling the gravimetric quasi-geoid over the Egypt. Finally, three types of transformation models: Four-, Five- and Seven-parameter transformations have been applied to reduce the data biases and to provide a better fitting of quasi geoid heights obtained from the studied GOCE-based GGMs to those from GPS/levelling data. These models reveal that the standard deviation of vertical datum over Egypt is at the level of about 32 cm.展开更多
It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting th...It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction (GLII) and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing (TVD) scheme, while in the base part, it is predicted by a characteristic line method (CLM). The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter (VAP), the branch pipe air entrainment, and the conditions on the stack bottom.展开更多
A systematic investigation of oxidation on a superconductive Fe Te_(0.5)Se_(0.5)thin film,which was grown on Nb-doped SrTiO_3(001) by pulsed laser deposition,has been carried out.The sample was exposed to ambien...A systematic investigation of oxidation on a superconductive Fe Te_(0.5)Se_(0.5)thin film,which was grown on Nb-doped SrTiO_3(001) by pulsed laser deposition,has been carried out.The sample was exposed to ambient air for one month for oxidation.Macroscopically,the exposed specimen lost its superconductivity due to oxidation.The specimen was subjected to in situ synchrotron radiation photoelectron spectroscopy(PES) and x-ray absorption spectroscopy(XAS) measurements following cycles of annealing and argon ion etching treatments to unravel what happened in the electronic structure and composition after exposure to air.By the spectroscopic measurements,we found that the as-grown FeTe_(0.5)Se_(0.5)superconductive thin film experienced an element selective substitution reaction.The oxidation preferentially proceeds through pumping out the Te and forming Fe–O bonds by O substitution of Te.In addition,our results certify that in situ vacuum annealing and low-energy argon ion etching methods combined with spectroscopy are suitable for depth element and valence analysis of layered structure superconductor materials.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No F050306
文摘We present the thermal expansion coefficient (TEC) measurement technology of compensating for the effect of variations in the refractive index based on a Nd: YA G laser feedback system, the beam frequency is shifted by a pair of aeousto-optic modulators and then the heterodyne phase measurement technique is used. The sample measured is placed in a muffle furnace with two coaxial holes opened on the opposite furnace walls. The measurement beams hit perpendicularly and coaxially on each surface of the sample. The reference beams hit on the reference mirror and the high-refiectivity mirror, respectively. By the heterodyne configuration and computing, the influences of the vibration, distortion of the sample supporter and the effect of variations in the refractive index are measured and largely minimized. For validation, the TECs of aluminum samples are determined in the temperature range of 29-748K, confirming not only the precision within 5 × 10-7 K-1 and the accuracy within 0.4% from 298K to 448K but also the high sensitivity non-contact measurement of the lower reflectivity surface induced by the sample oxidization from 448 K to 748 K.
文摘Air pollution has considerable impact on human health and the wellbeing. Thus many regions of the world have established air pollution standards to ensure a minimum level of air quality. Precise assessment of the health and socio-economic impacts of air pollution is, however, a complex task;indeed, methods based within an epidemiological tradition generally underestimate human risk of exposure to polluted air. In this study, we introduce an agent-based modeling approach to ascertaining the impact of changes in particulate matter (PM10) on mortality and frequency of hospital visits in the greater metropolitan region of Sydney, Australia. Our modeling approach simulates human movement and behavioral patterns in order to obtain an accurate estimate of individual exposure to a pollutant. Results of our analysis indicate that a 50% reduction in PM10 levels (relative to the baseline) could considerably lower mortality, respiratory hospital admissions and emergency room visits leading to reduced pressure on health care sector costs and placing lower stress on emergency medical facilities. Our analysis also highlights the continued need to avoid significant increases in air pollution in Sydney so that associated health impacts, including health care costs, do not increase.
基金supported by the State Major Science and Technology Special Projects under Grant No. 2018ZX03001028-003
文摘In 5G systems, massive multiple-input multiple-output (MIMO) has been adopted in base stations (BSs) to improve spectral efficiency and coverage. The traditional conductive performance test techniques are challenging due to the unaffordable cost and high complexity when testing a large number of antennas. To solve this problem, the over-the-air (OTA) test has been presented, in which probe selection is the key to reduce the number of channel emulators and probes. In this paper, a novel artificial bee colony (ABC) algorithm is introduced to enhance the efficiency and accuracy of probe selection procedure. A sectoring- based multi-probe anechoic chamber (MPAC) is built to evaluate the throughput performance of massive MIMO equipped in 5G BS. In addition, link level simulation is carried out to evaluate the proposal’s performance gain under the commercial network assumptions, where the average throughput of three velocity is given with different SNR region. The results suggest that OTA chamber and multi-probe wall are available not only for 5G BSs, but also for user equipments (UEs) with end-to-end communication.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51076066)
文摘In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in nitrogen environment,the spectrum result of Grignard-type reaction~[6] is verified by the decomposition characteristics of MT and MTV pyrolants.8.71% of Mg is consumed in the intermediate reaction of MT at 500-596 ℃ and the heat release of reaction is 31.93 k J/g.The endothermic decomposition of the intermediate product is at 684-740 ℃.In MTV,the intermediate reaction is at 435-595 ℃ and the heat release of reaction are increased by the addition of fluororubber.The intermediate product degrades at 677-745 ℃.In air environment,the decomposition of MT and MTV show the different reaction mechanism from the nitrogen environment.The presence of oxygen is involved in the reaction of Mg,and inhibits the intermediate reaction process of Mg and PTFE.
基金Funded by the National Natural Science Foundation of China(Nos.51778003 and 51308004)the Project of Anhui Provincial Education Department for Sending Visiting Scholars to Research Abroad(No.gxfx ZD2016134)+1 种基金the Anhui Province Higher Education Revitalization Program Talent Project([2014]No.11)the National Key Research and Development Plan(No.2017YFB0310001)
文摘The influence of air-cooled blast furnace slag aggregates as replacement of natural aggregates on the water absorption of concrete and mortar was studied, and the mechanism was analyzed. The interface between aggregate and matrix in concrete was analyzed by using a micro-hardness tester, a laser confocal microscope and a scanning electron microscope with backscattered electron image mode. The pore structure of mortar matrixes under different curing conditions was investigated by mercury intrusion porosimetry. The results showed that when natural aggregates were replaced with air-cooled blast furnace slag aggregates in mortar or concrete, the content of the capillary pore in the mortar matrix was reduced and the interfacial structure between aggregate and matrix was improved, resulting in the lower water absorption of mortar or concrete. Compared to the concrete made with crushed limestone and natural river sand, the initial absorption coefficient, the secondary absorption coefficient and the water absorption capacity through the surface for 7 d of the concrete made from crushed air-cooled blast furnace slag and air-cooled blast furnace slag sand were reduced by 48.9%, 52.8%, and 46.5%, respectively.
文摘The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flapping wing wasdeveloped.A control scheme inspired by human memory and learning concept was constructed for wing motion control ofMAVs.The salient feature of the proposed control lies in its capabilities to improve the control performance by learning fromexperience and observation on its current and past behaviors, without the need for system dynamic information.Furthermore,the overall control scheme has a fairly simple structure and demands little online computations, making it attractive for real-timeimplementation on MAVs.Both theoretical analysis and computer simulation confirms its effectiveness.
基金Funded by the National Natural Science Foundation of China(No.50708114)the Postgraduate Science Foundation of China(No.20060400883)
文摘To investigate the durability, especially the long-term stability of cement-based materials with very low w/b, the air permeability test, carbonation test, capillary absorption rate test and dilation potential test were adopted under long-term heat treatment condition. Microstructure of these materials is also analyzed by scanning electronic microscopy (SEM) and mercury intrusion porosimeter (MIP) in order to further unveil its mechanism and interrelation between microstructure and its properties. The results indicate that in the area investigated, cement-based material with w/b 0.17, like RPC, possesses low porosity and excellent durability. Moreover, its porosity will further decrease under long-term heat treatment compared with normal heat treatment. Its long-term durability is much superior to that of other cement-based materials with w/b 0.25 or 0.35 as high strength concrete(HSC).
文摘In this paper, we present the development of flexible zinc–air battery. Multiwalled carbon nanotubes(MWCNTs) were added into electrodes to improve their performance. It was found that MWCNTs were effective conductive additive in anode as they bridged the zinc particles. Poly(3,4-ethylenedioxythiophene)polystyrene sulfonate(PEDOT:PSS) was applied as a co-binder to enhance both the conductivity and flexibility. A poly(acrylic acid)(PAA) and polyvinyl alcohol(PVA) coated paper separator was used to enhance the battery performance where the PVP–PAA layer facilitated electrolyte storage. The batteries remained functional under bending conditions and after bending. Multiple design optimizations were also carried out for storage and performance purposes.
基金supported by National Natural Science Foundation of China(No.20472116) and 2009 intranational visiting doctoral student project of Ministry of Education.
文摘Vanadium-catalyzed oxidative kinetic resolution(OKR) of methyl o-chloromandelate 2a,key intermediate of the well-known oral antiplatelet agent(S)-clopidogrel,was achieved by ambient air for the first time.The air oxidation system,which was composed of vanadium and tridentate Schiff base ligands derived from amino alcohols and salicylaldehyde derivatives,afforded an efficient and economic approach to the target intermediate with high enantioselectivities(99%ee).
文摘The Global Geopotential Models (GGMs) of GOCE (Gravity Recovery and steady- state Ocean Circulation Explorer) differ globally as well as regionally in their accuracy and resolution based on the maximum degree and order (d/o) of the fully normalized spherical harmonic (SH) coefficients, which express each GGM. The main idea of this study is to compare the free-air gravity anomalies and quasi geoid heights determined from several recent GOCE-based GGMs with the corresponding ones from the Earth Gravitational Model 2008 (EGM2008) over Egypt on the one hand and with ground-based measurements on the other hand. The results regarding to the comparison of GOCE-based GGMs with terrestrial gravity and GPS/levelling data provide better improvement with respect to EGM2008. The 4th release GOCE-based GGM developed with the use of space-wise solution strategy (SPW_R4) approximates the gravity field well over the Egyptian region. The SPW_R4 model is accordingly suggested as a reference model for recovering the long wavelength (up to SH d/o 200) components of quasi geoid heights when modelling the gravimetric quasi-geoid over the Egypt. Finally, three types of transformation models: Four-, Five- and Seven-parameter transformations have been applied to reduce the data biases and to provide a better fitting of quasi geoid heights obtained from the studied GOCE-based GGMs to those from GPS/levelling data. These models reveal that the standard deviation of vertical datum over Egypt is at the level of about 32 cm.
基金Project supported by the National Natural Science Foundation of China (No. 10972212)
文摘It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction (GLII) and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing (TVD) scheme, while in the base part, it is predicted by a characteristic line method (CLM). The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter (VAP), the branch pipe air entrainment, and the conditions on the stack bottom.
基金Project supported by the Chinese Academy of Sciences(Grant No.1G2009312311750101)the National Natural Science Foundation of China(Grant Nos.11375228,11204303,and U1332105)
文摘A systematic investigation of oxidation on a superconductive Fe Te_(0.5)Se_(0.5)thin film,which was grown on Nb-doped SrTiO_3(001) by pulsed laser deposition,has been carried out.The sample was exposed to ambient air for one month for oxidation.Macroscopically,the exposed specimen lost its superconductivity due to oxidation.The specimen was subjected to in situ synchrotron radiation photoelectron spectroscopy(PES) and x-ray absorption spectroscopy(XAS) measurements following cycles of annealing and argon ion etching treatments to unravel what happened in the electronic structure and composition after exposure to air.By the spectroscopic measurements,we found that the as-grown FeTe_(0.5)Se_(0.5)superconductive thin film experienced an element selective substitution reaction.The oxidation preferentially proceeds through pumping out the Te and forming Fe–O bonds by O substitution of Te.In addition,our results certify that in situ vacuum annealing and low-energy argon ion etching methods combined with spectroscopy are suitable for depth element and valence analysis of layered structure superconductor materials.