Negative air ions are natural components of the air we breathe Forests are the main continuous natural source of negative air ions (NAI). The spatio-temporal patterns of negative air ions were explored in Shanghai, ...Negative air ions are natural components of the air we breathe Forests are the main continuous natural source of negative air ions (NAI). The spatio-temporal patterns of negative air ions were explored in Shanghai, based on monthly monitoring in 15 parks from March 2009 to February 2010. In each park, sampling sites were selected in forests and open spaces. The annual variation in negative air ion concentrations (NAIC) showed peak values from June to October and minimum values from December to January. NAIC were highest in summer and autumn, intermediate in spring, and lowest in winter. During spring and summer, NAIC in open spaces were significantly higher in rural areas than those in suburban areas. However, there were no significant differences in NAIC at forest sites among seasons. For open spaces, total suspended particles (TSP) were the dominant determining factor of NAIC in sum- mer, and air temperature and air humidity were the dominant determining factors of NAIC in spring, which were tightly correlated with Shanghai's ongoing urbanization and its impacts on the environment. R is suggested that urbanization could induce variation in NAIC along the urban-rural gradient, but that may not change the temporal variation pattern. Fur- thermore, the effects of urbanization on NAIC were limited in non-vegetated or less-vegetated sites, such as open spaces, but not in well-vegetated areas, such as urban forests. Therefore, we suggest that urban greening, especially urban forest, has significant resistance to theeffect of urbanization on NAIC.展开更多
Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors t...Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors that infl uence the concentration during urbanization is thus essential.In the present study of a typical developing urban district in southern China,negative air ion concentrations(NAICs)in 60 forests sites and 30 urban green spaces were quantifi ed on seven consecutive days in each of the four seasons.Large seasonal variations in NAIC were revealed in forests and urban green spaces with trough values in summer.NAIC progressively decreased from forests to urban green spaces and was infl uenced by local land morphology,vegetation characteristics,and climatic factors.The vast,heavily vegetated northeastern region was the richest area for NAIs,whereas the narrow central region(urbanized area)was the poorest,implying dramatic impacts of urbanization on the spatial distribution of NAIs.The relationship between air temperature and NAIC was better fi tted with a quadratic equation than a linear equation.Moreover,the NAIC was more sensitive to local morphology in urban green spaces than in urban forests,indicating the vulnerability of NAIs in urbanized areas.Therefore,the appropriate design of local urban morphology is critical.展开更多
[Objective] The study aimed to discuss the spatial changes of negative air ion concentration in Hefei City. [Method] Based on the observation of air ions, temperature, relative humidity, the spatial changes of negativ...[Objective] The study aimed to discuss the spatial changes of negative air ion concentration in Hefei City. [Method] Based on the observation of air ions, temperature, relative humidity, the spatial changes of negative air ion concentration in different districts of Hefei City were ana- lyzed firstly, then the correlation between negative air ion concentration and meteorological factors was discussed. [ Result] Air cleanliness index (CI) of the parks, residential areas, industrial regions, transport stations and prosperous commercial districts was 0.86, 0.53, 0.37, 0.26 and 0.17 respectively, and the latter two regions suffered mild and moderate pollution separately. Daily variations of negative air ion concentration in the residential areas and parks of Hefei City were obvious, showing U shape, that is, the maximum values appeared in the morning and evening, while the minimum values could be found around 14 :(30. There was no distinctly regular variation of negative air ion concentration in the prosperous com- mercial districts, transport stations and industrial areas. In Hefei City, the concentration of negative air ions showed an increasing trend from the ur- ban districts to the suburban districts; it was obviously higher in the residential areas and parks with numerous plants and waters compared with the prosperous commercial districts and transport stations. Negative air ion concentration correlated with relative humidity positively and temperature negatively, so the main meteorological factors influencing the negative air ion concentration in Hefei City were temperature and relative humidity. [ Coedusloa] The research could provide scientific references for city planning and greenbelt construction in future.展开更多
2,4,6-trichlorophenol (TCP) was firstly treated with air ions generated by electric discharge, and high dechlorination (53%) was observed after 60 min treatment, indicating that air ions are an efficient dechlorinatio...2,4,6-trichlorophenol (TCP) was firstly treated with air ions generated by electric discharge, and high dechlorination (53%) was observed after 60 min treatment, indicating that air ions are an efficient dechlorination means and might have a future in the oxidative removal of chlorinated phenols. In addition, a stepwise degradation of TCP, beginning with the formation of a major product 2,6-dichloro-1,4-benzenediol via substitution, is proposed through a detailed analysis of gas chromatography/mass spectrometry.展开更多
Objective:To investigate the short and long tenn efficacy of a commercial air ionizer in killing Dermatophagoides pteronyssinus(D.pteronyssinus)and Dermalophagoides farinae(D.farinae)mites.Methods:The effect of a comm...Objective:To investigate the short and long tenn efficacy of a commercial air ionizer in killing Dermatophagoides pteronyssinus(D.pteronyssinus)and Dermalophagoides farinae(D.farinae)mites.Methods:The effect of a commercial ionizer on D.pteronyssinus and D.farinae was evaluated in the laboratory,using a specially designed test.Mortality was assessed after 6,16and 24 hours for direct exposure and after 24,36,48,60 and 72 hours for exposure in simulated mattress.New batches of mites were used for each exposure time.Results:LT_(50)for direct exposure of ionizer was 10 hours for D.pteronyssinus and 18 hours for D.farinae.The LT_(50)for exposure in simulated mattress was 132 hours or 5.5 days for D.pteronyssinus and 72 hours or 3days for D.farinae.LT_(95)for direct exposure of ionizer was 36 hours for D.pteronyssinus and D.farinae.Meanwhile,the LT_(95)for exposure in simulated mattress was 956 hours or 39.8 days for D.pteronyssinus and 403 hours or 16.8 days for D.farinae.Conclusions:This study demonstrates the increasing mite mortalities with increasing exposure time of a commercial ionizer and suggests that negative ions produced by an ionizer kill dust mites and can be used to reduce natural mile populations on exposed surfaces such as floors,clothes,curtains,etc.However,there is reduced efficacy on mites inside stuffed materials as in mattresses and furniture.展开更多
This review intends to cover a range of brief description of the generation mechanisms,the determination of the concentration,and the identification of negative air ions(NAI).This is divided into two parts:(i)it pays ...This review intends to cover a range of brief description of the generation mechanisms,the determination of the concentration,and the identification of negative air ions(NAI).This is divided into two parts:(i)it pays attention to the generation of NAI,which contains natural and artificial methods.According to the variation of energy in the environment,different methods based on natural generation are introduced in detail.As for artificial generation of NAI,corona discharge is dominantly elaborated due to its preponderance in convenient to control of the concentration of ions.(ii)it tends to introduce the determination of NAI,containing quantitative and qualitative detection,by using ion counting device and mass spectrometer,respectively.展开更多
In recent years, air ions, especially of negative air ion has received a universal attention for its health function. The density of negative air ion has become one of the important indexes that measure the air qualit...In recent years, air ions, especially of negative air ion has received a universal attention for its health function. The density of negative air ion has become one of the important indexes that measure the air quality grade. With the air ions counter made in Japan, the spatial distribution characteristics of negative air concentrations at specific time in Danqinghe Experimental Forest were measured and studied, Harbin City, and the air quality was assessed by using ion polarity ration (q) and air ion assessment index (CI). The results showed that at a given time, the average concentrations of negative air ions were different for different forest types, stand origins, tree species and different parts of Balan River. There was a clear difference in ion polarity ration and air ion assessment index, and the air quality in different environments were also quite different.展开更多
Qinhuangdao is a provincial municipality under the jurisdiction of Hebei Province and a coastal city in China. Beidaihe is a district under the jurisdiction of Qinhuangdao and is a famous seaside scenic area. Alliance...Qinhuangdao is a provincial municipality under the jurisdiction of Hebei Province and a coastal city in China. Beidaihe is a district under the jurisdiction of Qinhuangdao and is a famous seaside scenic area. Alliance Peak, located in Beidaihe seashore scenic West. Jinshan mouth is the peak of the Union Peak, located in the easternmost Beidaihe waterfront. In this paper, we use the observed data of air negative ions in the Beidaihe, Qinhuangdao, Jinshanzui and Lianfeng Mountains for seven years to study the distribution characteristics of negative air ions in different ecological environments through meteorological observation. Research shows that the annual mean of air anion concentration fluctuates less. The annual mean is 1730 ind·cm-3, and the difference between the highest and lowest concentrations is 535 ind·cm-3. The average air anion concentration was the highest in August at 7785 ind·cm-3 and the lowest in January at 365 ind·cm-3. Negative air ions have obvious spatial characteristics, and negative ion concentrations of the sea and forest air are significantly high. The average annual mean of the sea is 3902 ind·cm-3, and that of the forest is 5403 ind·cm-3. The concentration of air anion changes daily, and daytime concentration is significantly lower than nighttime concentration. The highest peak appears at night or in the morning, while the lowest value appears between noon and afternoon. Inter-annual features and concentration of negative air ions, as well as annual rain days, total rainfall, thunderstorm days, and average relative humidity, are negatively related to the annual average temperature and sunshine hours. However, in the average concentration of negative air ions, the average correlation test of meteorological elements was insignificant. The air anion concentration is negatively correlated with the PM2.5 concentration of fine particulate matter. The concentrations of nitrogen dioxide, sulfur dioxide, and carbon monoxide in the fine particulate matter are negatively correlated with the ozone concentration, which is positively correlated with ozone concentration and is tested by significance. Atmospheric discharge (thunderstorm) can produce a considerable amount of air anion. Air negative ions are an important indicator of air quality, which is of great significance to the living environment. The distribution of negative ions in the study space and its influencing factors in order to provide a basis for air quality assessment in the region and provide references for the long-term research on air anion in different urban areas.展开更多
Single cell temperature difference of lithium-ion battery(LIB) module will significantly affect the safety and cycle life of the battery. The reciprocating air-flow module created by a periodic reversal of the air flo...Single cell temperature difference of lithium-ion battery(LIB) module will significantly affect the safety and cycle life of the battery. The reciprocating air-flow module created by a periodic reversal of the air flow was investigated in an effort to mitigate the inherent temperature gradient problem of the conventional battery system with a unidirectional coolant flow with computational fluid dynamics(CFD). Orthogonal experiment and optimization design method based on computational fluid dynamics virtual experiments were developed. A set of optimized design factors for the cooling of reciprocating air flow of LIB thermal management was determined. The simulation experiments show that the reciprocating flow can achieve good heat dissipation, reduce the temperature difference, improve the temperature homogeneity and effectively lower the maximal temperature of the modular battery. The reciprocating flow improves the safety, long-term performance and life span of LIB.展开更多
The application of non-suppressed ion chromatography for monitoring of trace elements in air particulate matter was studied in the present investigation. The results indicate that the use of microwave acid digestion m...The application of non-suppressed ion chromatography for monitoring of trace elements in air particulate matter was studied in the present investigation. The results indicate that the use of microwave acid digestion method is superior in comparison with the conventional thermal acid digestion method as it leads to higher recovery, better reproducibility, lower volatility loss, better protection against environmental contamination and much less digestion time (5 minutes vs. 24 hours). The use of eluent as extractant is shown to reduce the water dip problem in the chro-matogram. The addition of chelating agent in the eluent coupled with UV detection is shown to provide satisfactory chromatographic separation and good sensitivity for the analysis of transition metals present in the air particulate matter. Using the U.S. National Bureau of Standards Reference Material 1648 Urban Particulate Matter as standard for checking, the analytical procedure is shown to give good recovery and reproducibility for the detection of the following cations and anions in air particulate matter: Fe2 Cu, Mn, Pb, Zn, Mg, Na, HN4+, Cl-, NO3- and SO42-. Field test was also performed to check the applicability of the method and the results obtained were discussed in the present paper.展开更多
空气负离子(Negative air ion, NAI)是衡量空气质量的重要指标之一,受到植被和环境的共同影响。然而,森林生态系统作为NAI产生的重要来源,森林中的植被和环境之间的相互作用以及对NAI的影响机制和贡献潜力仍难以捉摸。以暖温带森林生态...空气负离子(Negative air ion, NAI)是衡量空气质量的重要指标之一,受到植被和环境的共同影响。然而,森林生态系统作为NAI产生的重要来源,森林中的植被和环境之间的相互作用以及对NAI的影响机制和贡献潜力仍难以捉摸。以暖温带森林生态系统中广泛分布的栓皮栎(Quercus variabilis BI.)为对象,基于自动观测设备长期定位观测获取了气象、土壤性质、空气洁净度以及植被光合等数据,利用皮尔逊相关系数分析和偏最小二乘结构方程模型分析了森林植被和环境要素对NAI的影响机制和贡献潜力。结果表明,环境要素和植被光合对NAI的贡献差异显著,植被光合对NAI的贡献潜力为62.65%,环境要素对NAI的贡献率为37.35%。环境要素中太阳辐射和饱和水汽压差的影响程度最大,分别为68.94%和16.55%。植被光合和PM2.5主要通过直接效应影响NAI,而光合有效辐射、紫外辐射、土壤温湿度和饱和水汽压差主要通过间接效应影响NAI。因此,利用结构方程模型可以阐明植被光合与环境要素的变化对NAI的影响趋势,从而全面揭示了森林生态系统中植被产生NAI的作用机制以及环境对NAI的影响趋势,并为评估森林生态系统对NAI的贡献潜力提供理论基础。展开更多
基金supported by the National Natural Science Foundation of China(No.40971041)
文摘Negative air ions are natural components of the air we breathe Forests are the main continuous natural source of negative air ions (NAI). The spatio-temporal patterns of negative air ions were explored in Shanghai, based on monthly monitoring in 15 parks from March 2009 to February 2010. In each park, sampling sites were selected in forests and open spaces. The annual variation in negative air ion concentrations (NAIC) showed peak values from June to October and minimum values from December to January. NAIC were highest in summer and autumn, intermediate in spring, and lowest in winter. During spring and summer, NAIC in open spaces were significantly higher in rural areas than those in suburban areas. However, there were no significant differences in NAIC at forest sites among seasons. For open spaces, total suspended particles (TSP) were the dominant determining factor of NAIC in sum- mer, and air temperature and air humidity were the dominant determining factors of NAIC in spring, which were tightly correlated with Shanghai's ongoing urbanization and its impacts on the environment. R is suggested that urbanization could induce variation in NAIC along the urban-rural gradient, but that may not change the temporal variation pattern. Fur- thermore, the effects of urbanization on NAIC were limited in non-vegetated or less-vegetated sites, such as open spaces, but not in well-vegetated areas, such as urban forests. Therefore, we suggest that urban greening, especially urban forest, has significant resistance to theeffect of urbanization on NAIC.
基金The authors acknowledge the volunteers who helped with the fi eld investigations.
文摘Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors that infl uence the concentration during urbanization is thus essential.In the present study of a typical developing urban district in southern China,negative air ion concentrations(NAICs)in 60 forests sites and 30 urban green spaces were quantifi ed on seven consecutive days in each of the four seasons.Large seasonal variations in NAIC were revealed in forests and urban green spaces with trough values in summer.NAIC progressively decreased from forests to urban green spaces and was infl uenced by local land morphology,vegetation characteristics,and climatic factors.The vast,heavily vegetated northeastern region was the richest area for NAIs,whereas the narrow central region(urbanized area)was the poorest,implying dramatic impacts of urbanization on the spatial distribution of NAIs.The relationship between air temperature and NAIC was better fi tted with a quadratic equation than a linear equation.Moreover,the NAIC was more sensitive to local morphology in urban green spaces than in urban forests,indicating the vulnerability of NAIs in urbanized areas.Therefore,the appropriate design of local urban morphology is critical.
基金Supported by Key Scientific and Technological Program of Anhui Province (10010302001)
文摘[Objective] The study aimed to discuss the spatial changes of negative air ion concentration in Hefei City. [Method] Based on the observation of air ions, temperature, relative humidity, the spatial changes of negative air ion concentration in different districts of Hefei City were ana- lyzed firstly, then the correlation between negative air ion concentration and meteorological factors was discussed. [ Result] Air cleanliness index (CI) of the parks, residential areas, industrial regions, transport stations and prosperous commercial districts was 0.86, 0.53, 0.37, 0.26 and 0.17 respectively, and the latter two regions suffered mild and moderate pollution separately. Daily variations of negative air ion concentration in the residential areas and parks of Hefei City were obvious, showing U shape, that is, the maximum values appeared in the morning and evening, while the minimum values could be found around 14 :(30. There was no distinctly regular variation of negative air ion concentration in the prosperous com- mercial districts, transport stations and industrial areas. In Hefei City, the concentration of negative air ions showed an increasing trend from the ur- ban districts to the suburban districts; it was obviously higher in the residential areas and parks with numerous plants and waters compared with the prosperous commercial districts and transport stations. Negative air ion concentration correlated with relative humidity positively and temperature negatively, so the main meteorological factors influencing the negative air ion concentration in Hefei City were temperature and relative humidity. [ Coedusloa] The research could provide scientific references for city planning and greenbelt construction in future.
基金the Alexander von Humboldt Foundation of Germany, and partly by the CAS and the NNSF of China.
文摘2,4,6-trichlorophenol (TCP) was firstly treated with air ions generated by electric discharge, and high dechlorination (53%) was observed after 60 min treatment, indicating that air ions are an efficient dechlorination means and might have a future in the oxidative removal of chlorinated phenols. In addition, a stepwise degradation of TCP, beginning with the formation of a major product 2,6-dichloro-1,4-benzenediol via substitution, is proposed through a detailed analysis of gas chromatography/mass spectrometry.
文摘Objective:To investigate the short and long tenn efficacy of a commercial air ionizer in killing Dermatophagoides pteronyssinus(D.pteronyssinus)and Dermalophagoides farinae(D.farinae)mites.Methods:The effect of a commercial ionizer on D.pteronyssinus and D.farinae was evaluated in the laboratory,using a specially designed test.Mortality was assessed after 6,16and 24 hours for direct exposure and after 24,36,48,60 and 72 hours for exposure in simulated mattress.New batches of mites were used for each exposure time.Results:LT_(50)for direct exposure of ionizer was 10 hours for D.pteronyssinus and 18 hours for D.farinae.The LT_(50)for exposure in simulated mattress was 132 hours or 5.5 days for D.pteronyssinus and 72 hours or 3days for D.farinae.LT_(95)for direct exposure of ionizer was 36 hours for D.pteronyssinus and D.farinae.Meanwhile,the LT_(95)for exposure in simulated mattress was 956 hours or 39.8 days for D.pteronyssinus and 403 hours or 16.8 days for D.farinae.Conclusions:This study demonstrates the increasing mite mortalities with increasing exposure time of a commercial ionizer and suggests that negative ions produced by an ionizer kill dust mites and can be used to reduce natural mile populations on exposed surfaces such as floors,clothes,curtains,etc.However,there is reduced efficacy on mites inside stuffed materials as in mattresses and furniture.
基金This work was financially supported by the National Natural Science Foundation of China(No.21621003)CERS-China Equipment and Education Resources System(No.CERS-1-75).
文摘This review intends to cover a range of brief description of the generation mechanisms,the determination of the concentration,and the identification of negative air ions(NAI).This is divided into two parts:(i)it pays attention to the generation of NAI,which contains natural and artificial methods.According to the variation of energy in the environment,different methods based on natural generation are introduced in detail.As for artificial generation of NAI,corona discharge is dominantly elaborated due to its preponderance in convenient to control of the concentration of ions.(ii)it tends to introduce the determination of NAI,containing quantitative and qualitative detection,by using ion counting device and mass spectrometer,respectively.
文摘In recent years, air ions, especially of negative air ion has received a universal attention for its health function. The density of negative air ion has become one of the important indexes that measure the air quality grade. With the air ions counter made in Japan, the spatial distribution characteristics of negative air concentrations at specific time in Danqinghe Experimental Forest were measured and studied, Harbin City, and the air quality was assessed by using ion polarity ration (q) and air ion assessment index (CI). The results showed that at a given time, the average concentrations of negative air ions were different for different forest types, stand origins, tree species and different parts of Balan River. There was a clear difference in ion polarity ration and air ion assessment index, and the air quality in different environments were also quite different.
文摘Qinhuangdao is a provincial municipality under the jurisdiction of Hebei Province and a coastal city in China. Beidaihe is a district under the jurisdiction of Qinhuangdao and is a famous seaside scenic area. Alliance Peak, located in Beidaihe seashore scenic West. Jinshan mouth is the peak of the Union Peak, located in the easternmost Beidaihe waterfront. In this paper, we use the observed data of air negative ions in the Beidaihe, Qinhuangdao, Jinshanzui and Lianfeng Mountains for seven years to study the distribution characteristics of negative air ions in different ecological environments through meteorological observation. Research shows that the annual mean of air anion concentration fluctuates less. The annual mean is 1730 ind·cm-3, and the difference between the highest and lowest concentrations is 535 ind·cm-3. The average air anion concentration was the highest in August at 7785 ind·cm-3 and the lowest in January at 365 ind·cm-3. Negative air ions have obvious spatial characteristics, and negative ion concentrations of the sea and forest air are significantly high. The average annual mean of the sea is 3902 ind·cm-3, and that of the forest is 5403 ind·cm-3. The concentration of air anion changes daily, and daytime concentration is significantly lower than nighttime concentration. The highest peak appears at night or in the morning, while the lowest value appears between noon and afternoon. Inter-annual features and concentration of negative air ions, as well as annual rain days, total rainfall, thunderstorm days, and average relative humidity, are negatively related to the annual average temperature and sunshine hours. However, in the average concentration of negative air ions, the average correlation test of meteorological elements was insignificant. The air anion concentration is negatively correlated with the PM2.5 concentration of fine particulate matter. The concentrations of nitrogen dioxide, sulfur dioxide, and carbon monoxide in the fine particulate matter are negatively correlated with the ozone concentration, which is positively correlated with ozone concentration and is tested by significance. Atmospheric discharge (thunderstorm) can produce a considerable amount of air anion. Air negative ions are an important indicator of air quality, which is of great significance to the living environment. The distribution of negative ions in the study space and its influencing factors in order to provide a basis for air quality assessment in the region and provide references for the long-term research on air anion in different urban areas.
基金Project(50803008)supported by the National Natural Science Foundation of ChinaProjects(14JJ4035,2011RS4067)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(2013-sdllmd-08)supported by the State Key Laboratory of Luminescent Materials and Devices(South China University of Technology),ChinaProjects(20100480946,201104508)supported by the China Postdoctoral Science Foundation,China
文摘Single cell temperature difference of lithium-ion battery(LIB) module will significantly affect the safety and cycle life of the battery. The reciprocating air-flow module created by a periodic reversal of the air flow was investigated in an effort to mitigate the inherent temperature gradient problem of the conventional battery system with a unidirectional coolant flow with computational fluid dynamics(CFD). Orthogonal experiment and optimization design method based on computational fluid dynamics virtual experiments were developed. A set of optimized design factors for the cooling of reciprocating air flow of LIB thermal management was determined. The simulation experiments show that the reciprocating flow can achieve good heat dissipation, reduce the temperature difference, improve the temperature homogeneity and effectively lower the maximal temperature of the modular battery. The reciprocating flow improves the safety, long-term performance and life span of LIB.
文摘The application of non-suppressed ion chromatography for monitoring of trace elements in air particulate matter was studied in the present investigation. The results indicate that the use of microwave acid digestion method is superior in comparison with the conventional thermal acid digestion method as it leads to higher recovery, better reproducibility, lower volatility loss, better protection against environmental contamination and much less digestion time (5 minutes vs. 24 hours). The use of eluent as extractant is shown to reduce the water dip problem in the chro-matogram. The addition of chelating agent in the eluent coupled with UV detection is shown to provide satisfactory chromatographic separation and good sensitivity for the analysis of transition metals present in the air particulate matter. Using the U.S. National Bureau of Standards Reference Material 1648 Urban Particulate Matter as standard for checking, the analytical procedure is shown to give good recovery and reproducibility for the detection of the following cations and anions in air particulate matter: Fe2 Cu, Mn, Pb, Zn, Mg, Na, HN4+, Cl-, NO3- and SO42-. Field test was also performed to check the applicability of the method and the results obtained were discussed in the present paper.