Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediate...Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.展开更多
Alachlor is used widely as a herbicide,but is an environmental endocrine disruptor. O 3/H 2O 2 system is used as catalyst to delve on the degradation efficiency of alachlor. The amount of the catalyst H 2O 2,the pH va...Alachlor is used widely as a herbicide,but is an environmental endocrine disruptor. O 3/H 2O 2 system is used as catalyst to delve on the degradation efficiency of alachlor. The amount of the catalyst H 2O 2,the pH value of the soluble, the temperature and quality of water sample are changed to investigate the effect of these factors on the degradation of alachlor. The degradation of alachlor is qualitatively analyzed through their GS MS spectra and the possible mechanism of the degradation of alachlor is discussed as well.展开更多
We used a ultrasound/Fe2＋/H2O2 process in continuous dosing mode to degrade the alachlor. Experimental results indicated that lower pH levels enhanced the degradation and mineralization of alachlor. The maximum alach...We used a ultrasound/Fe2＋/H2O2 process in continuous dosing mode to degrade the alachlor. Experimental results indicated that lower pH levels enhanced the degradation and mineralization of alachlor. The maximum alachlor degradation （initial alachlor concentration of 50 mg/L） was as high as 100% at pH 3 with ultrasound of 100 Watts, 20 mg/L of Fe2＋, 2 mg/min of H2O2 and 20℃ within 60 min reaction combined with 46.8% total organic carbon removal. Higher reaction temperatures inhibited the degradation of alachlor. Adequate dosages of Fe2＋ and H2O2 in ultrasound/Fe2＋/H2O2 process not only enhance the degradation efficiency of alachlor but also save the operational cost than the sole ultrasound or Fenton process. A continuous dosing mode ultrasound/Fe2＋/H2O2 process was proven as an effective method to degrade the alachlor.展开更多
研究了高铁氧化-活性污泥串联耦合工艺去除水中甲草胺的效能。高铁首先氧化降解废水中的甲草胺分子,然后进一步氧化其降解中间物。优化工艺条件下(高铁/甲草胺摩尔比2∶1,pH 7.0),高铁可在10 m in内完全去除40 mg/L甲草胺,但无法实现对...研究了高铁氧化-活性污泥串联耦合工艺去除水中甲草胺的效能。高铁首先氧化降解废水中的甲草胺分子,然后进一步氧化其降解中间物。优化工艺条件下(高铁/甲草胺摩尔比2∶1,pH 7.0),高铁可在10 m in内完全去除40 mg/L甲草胺,但无法实现对甲草胺的完全矿质化,氧化后水体中仍有大量CODC r残留。延长高铁氧化时间可提高甲草胺废水的可生化性,并降低废水对活性污泥处理能力的抑制。优化工艺条件下高铁处理含40 mg/L甲草胺废水20 m in可去除44.3%的CODC r;其可生化性指标(BOD5/CODC r)提高到0.87以上。该高铁氧化废水与市政污水按一定体积比混合后,可进一步采用活性污泥工艺最终对其实现完全矿质化过程。展开更多
基金Project supported by the Funds for Creative Research Groups of China(No. 50621804)the National Natural Science Foundation of China (No.50538090)the Beijing Academic Innovation Group in SustainableWater/Waste Recycle Technologies (No. BJE10016200611).
文摘Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.
文摘Alachlor is used widely as a herbicide,but is an environmental endocrine disruptor. O 3/H 2O 2 system is used as catalyst to delve on the degradation efficiency of alachlor. The amount of the catalyst H 2O 2,the pH value of the soluble, the temperature and quality of water sample are changed to investigate the effect of these factors on the degradation of alachlor. The degradation of alachlor is qualitatively analyzed through their GS MS spectra and the possible mechanism of the degradation of alachlor is discussed as well.
基金supported by the National Science Council, Republic of China (No. 101-2221-E-264-005)
文摘We used a ultrasound/Fe2＋/H2O2 process in continuous dosing mode to degrade the alachlor. Experimental results indicated that lower pH levels enhanced the degradation and mineralization of alachlor. The maximum alachlor degradation （initial alachlor concentration of 50 mg/L） was as high as 100% at pH 3 with ultrasound of 100 Watts, 20 mg/L of Fe2＋, 2 mg/min of H2O2 and 20℃ within 60 min reaction combined with 46.8% total organic carbon removal. Higher reaction temperatures inhibited the degradation of alachlor. Adequate dosages of Fe2＋ and H2O2 in ultrasound/Fe2＋/H2O2 process not only enhance the degradation efficiency of alachlor but also save the operational cost than the sole ultrasound or Fenton process. A continuous dosing mode ultrasound/Fe2＋/H2O2 process was proven as an effective method to degrade the alachlor.
