Alkali-activated slag concrete (AASC) is a new green building material. The amount of CO_(2) produced by AASC is 1/5th of that produced by ordinary Portland cement concrete (OPCC). In addition, AASC promotes the reuse...Alkali-activated slag concrete (AASC) is a new green building material. The amount of CO_(2) produced by AASC is 1/5th of that produced by ordinary Portland cement concrete (OPCC). In addition, AASC promotes the reuse of slag and other wastes and saves resources. Furthermore, the scope of use of slag has been expanded. The progress of the research on the hydration characteristics, microstructure, interfacial transition zone, and pore structure of AASC based on the relevant literatures was analyzed and summarized in this study. The influences of the slag composition, the type and dosage of the alkali activator, and the curing conditions on the hydration characteristics and the microstructure of the AASC were discussed. Relatively few research results on the microstructure of AASC are available, and the relevant conclusions are not completely consistent. Moreover, there are many constraints on the development of AASC (e.g., complex composition of raw materials of slag, large shrinkage deformation, and low fluidity). Therefore, further research is required.展开更多
Synthesis of autoclaved aerated concrete (AAC) has been carried out with carbide slag addition, and the carbide slag could be used as a main material to produce the AAC with the compressive strength about 2 MPa and ...Synthesis of autoclaved aerated concrete (AAC) has been carried out with carbide slag addition, and the carbide slag could be used as a main material to produce the AAC with the compressive strength about 2 MPa and the density below 0.6 g.cm-3. In this study, quartz sand acted as frame structure phase in the matrix, and quartz addition also influenced the Si/Ca of starting material. Tobermorite and CSH gel were formed readily at 62%, which seemed to enhance the compressive strength of samples. Curing time seemed to affect the morphology of phase produced, and specimen with the plate-like tobermorite formed at 10 h appeared to have a better compressive strength development than the fiber-like one at 18 h. The higher curing temperature seemed to favor the tobermorite and CSH gel formation, which also exerted a significant effect on the strength development of the samples. On the micro-scale, the formed CSH gel was filled in the interface of the matrix, and the tobermorite appeared to grow in internal-surface of the pores and interstices. The tobermorite or/and CSH formation seemed to densify the matrix, and therefore enhanced the strength of the samples.展开更多
To provide basic data for the reasonable mixing design of the alkali-activated (AA) foamed concrete as a thermal insulation material for a floor heating system, 9 concrete mixes with a targeted dry density less than 4...To provide basic data for the reasonable mixing design of the alkali-activated (AA) foamed concrete as a thermal insulation material for a floor heating system, 9 concrete mixes with a targeted dry density less than 400 kg/m3 were tested. Ground granulated blast-furnace slag (GGBS) as a source material was activated by the following two types of alkali activators: 10% Ca(OH)2 and 4% Mg(NO3)2, and 2.5% Ca(OH)2 and 6.5% Na2SiO3. The main test parameters were water-to-binder (W/B) ratio and the substitution level (RFA) of fly ash (FA) for GGBS. Test results revealed that the dry density of AA GGBS foamed concrete was independent of the W/B ratio an RFA, whereas the compressive strength increased with the decrease in W/B ratio and with the increase in RFA up to 15%, beyond which it decreased. With the increase in the W/B ratio, the amount of macro capillaries and artificial air pores increased, which resulted in the decrease of compressive strength. The magnitude of the environmental loads of the AA GGBS foamed concrete is independent of the W/B ratio and RFA. The largest reduction percentage was found in the photochemical oxidation potential, being more than 99%. The reduction percentage was 87% - 93% for the global warming potential, 81% - 84% for abiotic depletion, 79% - 84% for acidification potential, 77% - 85% for eutrophication potential, and 73% - 83% for human toxicity potential. Ultimately, this study proved that the developed AA GGBS foamed concrete has a considerable promise as a sustainable construction material for nonstructural element.展开更多
基金would like to acknowledge the National Natural Science Foundation of China(51590914 and 51608432)Natural Science Foundation of Shaanxi Province(2019JQ-481).
文摘Alkali-activated slag concrete (AASC) is a new green building material. The amount of CO_(2) produced by AASC is 1/5th of that produced by ordinary Portland cement concrete (OPCC). In addition, AASC promotes the reuse of slag and other wastes and saves resources. Furthermore, the scope of use of slag has been expanded. The progress of the research on the hydration characteristics, microstructure, interfacial transition zone, and pore structure of AASC based on the relevant literatures was analyzed and summarized in this study. The influences of the slag composition, the type and dosage of the alkali activator, and the curing conditions on the hydration characteristics and the microstructure of the AASC were discussed. Relatively few research results on the microstructure of AASC are available, and the relevant conclusions are not completely consistent. Moreover, there are many constraints on the development of AASC (e.g., complex composition of raw materials of slag, large shrinkage deformation, and low fluidity). Therefore, further research is required.
基金Funded by the National Natural Science Foundation of China(Nos.51272180,51072138)
文摘Synthesis of autoclaved aerated concrete (AAC) has been carried out with carbide slag addition, and the carbide slag could be used as a main material to produce the AAC with the compressive strength about 2 MPa and the density below 0.6 g.cm-3. In this study, quartz sand acted as frame structure phase in the matrix, and quartz addition also influenced the Si/Ca of starting material. Tobermorite and CSH gel were formed readily at 62%, which seemed to enhance the compressive strength of samples. Curing time seemed to affect the morphology of phase produced, and specimen with the plate-like tobermorite formed at 10 h appeared to have a better compressive strength development than the fiber-like one at 18 h. The higher curing temperature seemed to favor the tobermorite and CSH gel formation, which also exerted a significant effect on the strength development of the samples. On the micro-scale, the formed CSH gel was filled in the interface of the matrix, and the tobermorite appeared to grow in internal-surface of the pores and interstices. The tobermorite or/and CSH formation seemed to densify the matrix, and therefore enhanced the strength of the samples.
文摘To provide basic data for the reasonable mixing design of the alkali-activated (AA) foamed concrete as a thermal insulation material for a floor heating system, 9 concrete mixes with a targeted dry density less than 400 kg/m3 were tested. Ground granulated blast-furnace slag (GGBS) as a source material was activated by the following two types of alkali activators: 10% Ca(OH)2 and 4% Mg(NO3)2, and 2.5% Ca(OH)2 and 6.5% Na2SiO3. The main test parameters were water-to-binder (W/B) ratio and the substitution level (RFA) of fly ash (FA) for GGBS. Test results revealed that the dry density of AA GGBS foamed concrete was independent of the W/B ratio an RFA, whereas the compressive strength increased with the decrease in W/B ratio and with the increase in RFA up to 15%, beyond which it decreased. With the increase in the W/B ratio, the amount of macro capillaries and artificial air pores increased, which resulted in the decrease of compressive strength. The magnitude of the environmental loads of the AA GGBS foamed concrete is independent of the W/B ratio and RFA. The largest reduction percentage was found in the photochemical oxidation potential, being more than 99%. The reduction percentage was 87% - 93% for the global warming potential, 81% - 84% for abiotic depletion, 79% - 84% for acidification potential, 77% - 85% for eutrophication potential, and 73% - 83% for human toxicity potential. Ultimately, this study proved that the developed AA GGBS foamed concrete has a considerable promise as a sustainable construction material for nonstructural element.