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Geochemical Trace of Silicon Isotopes of Intrusions and Ore Veins Related to Alkali-rich Porphyry Deposits in Western Yunnan, China 被引量:3
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作者 LIUXianfan YANGZhengxi LIUJiaduo WUDechao ZHANGChenjiang LIYouguo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第2期459-462,共4页
Western Yunnan is the well-known polymetallic province in China. It is characterized by copper-gold mineralization related to Cenozoic alkali-rich porphyry. This paper analyzes the silicon isotope data obtained from f... Western Yunnan is the well-known polymetallic province in China. It is characterized by copper-gold mineralization related to Cenozoic alkali-rich porphyry. This paper analyzes the silicon isotope data obtained from four typical alkali-rich porphyry deposits based on the dynamic fractionation principle of silicon isotope. The study shows that the ore materials should originate mainly from alkali-rich magmas, together with silicon-rich mineralizing fluids. The process of mineralization was completed by auto-metasomatism, i.e. silicon-rich mineralizing fluids (including alkali-rich porphyry and wall-rock strata) replaced and altered the country rocks and contaminated with crustal rocks during the crystallization of alkali-rich magmas. Such a process is essentially the continuance of the metasomatism of mantle fluids in crust's mineralization. This provides important evidence of silicon isotopic geochemistry for better understanding the mineralization of the Cenozoic alkali-rich porphyry polymetallic deposits 展开更多
关键词 alkali-rich porphyry deposit intrusion and ore vein silicon isotopic dynamic fractionation geochemical trace Cenozoic era in western Yunnan
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Reduced magma generation and its implications for the Pulang giant porphyry Cu-polymetallic deposit in Northwest Yunnan,China
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作者 Jingwei Guan Tao Ren +3 位作者 Lei Wang Shenjin Guan Lianrong Wu Baosheng Shi 《Acta Geochimica》 EI CAS CSCD 2024年第4期802-813,共12页
The Pulang giant porphyry Cu-Mo polymetallic deposit is located in the Zhongdian area in the center of the Sanjiang Tethys tectonic domain,which was formed by the westward subduction of the Garze-Litang oceanic slab b... The Pulang giant porphyry Cu-Mo polymetallic deposit is located in the Zhongdian area in the center of the Sanjiang Tethys tectonic domain,which was formed by the westward subduction of the Garze-Litang oceanic slab beneath the Zhongza massif.Chalcopyrite-pyrrhotite-pyritemolybdenite occurs as disseminations,veins,veinlets,and stockworks distributed in the K-silicate alteration zone in the monzonite porphyry,which is superimposed by propylitization.The chemical compositions of biotite and amphibole analyzed by electron probe microanalysis(EPMA)indicate that the ore-forming magma and exsolved fluids experienced a continuous decrease in the oxygen fugacity(fO_(2)).Primary amphibolite and biotite(type I)crystallized at relatively high temperatures(744-827°C)and low fO_(2)(log fO_(2)=−12.26 to−11.91)during the magmatic stage.Hydrothermal fluids exsolved from the magma have a relatively lower temperature(621-711°C)and fO_(2)(log fO_(2)=−14.36 to−13.32)than the original magma.In addition,the presence of a high abundance of pyrrhotite and an insufficiency of primary magnetite and sulfate in the ore(i.e.,anhydrite and gypsum)indicate that the deposit may be a reduced porphyry deposit.Magma and fluid fO_(2)results,combined with previous research on magmatic fO_(2)at the Pulang deposit,indicate that the magma associated with the reduced Pulang ore assemblages was initially generated as a highly oxidized magma that was subsequently reduced by sedimentary rocks of the Tumugou Formation. 展开更多
关键词 porphyry deposit Oxygen fugacity(fO_(2)) Contamination of surrounding rock Pulang Zhongdian arc
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Application of tensor CSAMT with high-power orthogonal signal sources in Jiama porphyry copper deposit,South Tibet 被引量:2
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作者 Peng-liang Yu Ting Qu +3 位作者 Ri-zheng He Jian-li Liu Su-fen Wang Xiao-long Chen 《China Geology》 CAS CSCD 2023年第1期37-49,共13页
The Jiama porphyry copper deposit in Tibet is one of the proven supergiant copper deposits in the Qinghai-Tibet Plateau at present,with the reserves of geological resources equivalent to nearly 20×10^(6) t.Howeve... The Jiama porphyry copper deposit in Tibet is one of the proven supergiant copper deposits in the Qinghai-Tibet Plateau at present,with the reserves of geological resources equivalent to nearly 20×10^(6) t.However,it features wavy and steep terrain,leading to extremely difficult field operation and heavy interference.This study attempts to determine the effects of the tensor controlled-source audiomagnetotellurics(CSAMT)with high-power orthogonal signal sources(also referred to as the high-power tensor CSAMT)when it is applied to the deep geophysical exploration in plateaus with complex terrain and mining areas with strong interference.The test results show that the high current provided by the highpower tensor CSAMT not only greatly improved the signal-to-noise ratio but also guaranteed that effective signals were received in the case of a long transmitter-receiver distance.Meanwhile,the tensor data better described the anisotropy of deep geologic bodies.In addition,the tests also show that when the transmitting current reaches 60 A,it is still guaranteed that strong enough signals can be received in the case of the transmitter-receiver distance of about 25 km,sounding curves show no near field effect,and effective exploration depth can reach 3 km.The 2D inversion results are roughly consistent with drilling results,indicating that the high-power tensor CSAMT can be used to achieve nearly actual characteristics of underground electrical structures.Therefore,this method has great potential for application in deep geophysical exploration in plateaus and mining areas with complex terrain and strong interference,respectively.This study not only serves as important guidance on the prospecting in the Qinghai-Tibet Plateau but also can be used as positive references for deep mineral exploration in other areas. 展开更多
关键词 Jiama porphyry copper deposit Supergiant copper polymetallic deposit Tensor CSAMT of 150 kw High power 2D inversion Deep prospecting Mineral exploration engineering Xizang(Tibet)
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Petrogenesis and Physicochemical Conditions of Fertile Porphyry in Non-arc Porphyry Mineralization:A Case from Habo Porphyry Cu-Mo Deposits,SW China 被引量:1
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作者 ZHANG Aiping ZHENG Yuanchuan +4 位作者 SHEN Yang Qi Qunjia WANG Zixuan WU Changda WANG Lu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第2期469-485,共17页
The Habo deposit is a typical porphyry Cu-Mo deposit in the Ailaoshan–Red River metallogenic belt.Ore minerals in the Habo deposit typically occur as veins in the monzonite porphyry.Zircon U-Pb dating suggests that t... The Habo deposit is a typical porphyry Cu-Mo deposit in the Ailaoshan–Red River metallogenic belt.Ore minerals in the Habo deposit typically occur as veins in the monzonite porphyry.Zircon U-Pb dating suggests that the monzonite porphyry formed at 35.07±0.38 Ma.The monzonite porphyry is characterized by high SiO_(2),Al_(2)O_(3),K_(2)O and Na_(2)O contents,with A/CNK ratios ranging from 0.97 to 1.02.All samples exhibit fractionated REE patterns,characterized by high(La/Yb)N ratios(9.4–13.6,average of 11.2).They show adakite-like geochemical features,high Sr concentrations(627–751 ppm,average of 700 ppm),low Y concentrations(15.13–16.86 ppm,average of 15.81 ppm)and high Sr/Y values(39.5–47.4,average of 44.3).These samples have high initial^(87)Sr/^(86)Sr ratios(0.7074–0.7076)and negativeεNd(t)values(-5.1 to-3.7),whereas the zirconεHf(t)values range from-2.2 to+0.4,suggesting that the monzonite porphyry was derived from the partial melting of a thickened juvenile lower crust.The oxygen fugacity,calculated on the basis of the chemical composition of the amphiboles,shows?NNO values ranging from+1.65 to+2.16(average of 1.94)and lg(fO_(2))ranging from-12.72 to-11.99(average of-12.25),indicating that the monzonite porphyry has high oxygen fugacity.Zircons have high Ce^(4+)/Ce^(3+)ratios(29.29–164.24,average of 84.92),with high?FMQ values ranging from+0.50 to+1.51(average of 0.87)and high lg(fO_(2))values ranging from-14.72 to-12.85(average of-14.07),which also indicates that the oxygen fugacity of the magma was high.The dissolved water content of the Habo monzonite porphyry is 9.5–11.5 wt%,according to the geochemical characteristics,zircon-saturation thermometry(692–794°C)and the mineral phases(amphibole,no plagioclase)in the deep magma chamber.Combined with previous studies,we propose that the high oxygen fugacity and high water content of magma played key roles in controlling the formation of the Habo and other Cu-Mo-Au deposits in the Ailaoshan–Red River metallogenic belt. 展开更多
关键词 magmatic oxidation state water content monzonite porphyry Habo porphyry Cu-Mo deposit Ailaoshan-Red River metallogenic belt
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Geology, geochronology, and exploration of the Jiama giant porphyry copper deposit (11 Mt), Tibet, China: A review 被引量:1
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作者 Bin Lin Ju-xing Tang +8 位作者 Pan Tang Wen-bao Zheng Yang Song Fa-qiao Li Qiu-feng Leng Zhi-chao Wang Jing Qi Miao Sun Juan David Bello Rodríguez 《China Geology》 CAS CSCD 2023年第2期338-357,I0042-I0045,共24页
Jiama,with more than 11 Mt of copper metal,is the largest porphyry-skarn copper system in the Gangdese metallogenic belt,Tibet,China,creating ideal conditions for deciphering the origin of porphyry ores in a collision... Jiama,with more than 11 Mt of copper metal,is the largest porphyry-skarn copper system in the Gangdese metallogenic belt,Tibet,China,creating ideal conditions for deciphering the origin of porphyry ores in a collision setting.Despite massive studies of the geology,chronology,petrogenesis,and ore-related fluids and their sources in Jiama,there is a lack of systematic summaries and reviews of this system.In contrast to traditional porphyry copper systems in a subduction setting,recent studies and exploration suggest that the Jiama deposit includes porphyry-type Mo-Cu,skarn-type Cu polymetallic,vein-type Au and manto orebodies.This paper reviews the latest studies on the geology,chronology,petrogenesis,fluid inclusions,and isotopic geochemistry(hydrogen,oxygen,sulfur,and lead)of the Jiama deposit.Accordingly,a multi-center complex mineralization model was constructed,indicating that multi-phase intrusions from the same magma reservoir can form multiple hydrothermal centers.These centers are mutually independent and form various orebodies or are superimposed on each other and form thick,high-grade orebodies.Finally,a new comprehensive exploration model was established for the Jiama porphyry copper system.Both models established in this study help to refine the theories on continental-collision metallogeny and porphyry copper systems. 展开更多
关键词 Copper deposit porphyry copper system O-S-Pb isotope Multicenter complex mineralization Comprehensive exploration model Mineral exploration engineering Gangdese metallogenic belt JIAMA TIBET
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Textural and compositional variation of mica from the Dexing porphyry Cu deposit:constraints on the behavior of halogens in porphyry systems
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作者 Yan Liu Jian-Feng Gao +1 位作者 Liang Qi Kang Min 《Acta Geochimica》 EI CAS CSCD 2023年第2期221-240,共20页
The Dexing porphyry deposit is the largest porphyry Cu–Mo–Au deposit in South China.Biotite composition can record the physicochemical conditions and evolution history of magmatic-hydrothermal system.Biotite from th... The Dexing porphyry deposit is the largest porphyry Cu–Mo–Au deposit in South China.Biotite composition can record the physicochemical conditions and evolution history of magmatic-hydrothermal system.Biotite from the Dexing porphyry deposit could be divided to three types:primary magmatic biotite(Bi-M),hydrothermal altered magmatic biotite(Bi-A)and hydrothermal biotite(Bi-H).The temperature of Bi-M and Bi-H range from 719 to 767℃ and 690 to 727℃,respectively.Both magmatic and hydrothermal biotite have high Fe^(3+)/Fe^(2+)ratios(from 0.18 to 0.24)and XMgvalues(from 0.57 to 0.66),indicating a high oxygen fugacity.BiM has F lower than Bi-A and Bi-H(up to 0.26 wt%),but has Cl(Cl=0.18–0.30 wt%)similar to Bi-A and Bi-H(Cl=0.21–0.35 wt%),suggesting that high Cl/F ratios of early hydrothermal fluid may result from the exsolution from high Cl magma.From potassic alteration zone to phyllic and propylitic alteration zones,Cl decreases with increasing Cu,whereas F increases roughly.Therefore,Cl mostly originate from magma,but enrichment of F possibly results from reaction of fluids and Neoproterozoic strata.Negative correlation between Cl and Cu indicates that Cl might act as an important catalyst during Cu mineralization process.Biotite from Dexing has similar halogen compositions to other porphyry Cu-/Mo deposits in the world.Chlorine contents of hydrothermal fluid may be critical for Cu transportation and enrichment,while consumption of Cl would promote Cu deposition. 展开更多
关键词 HALOGEN Dexing porphyry deposit BIOTITE GEOCHEMISTRY porphyry Cu deposit
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Geology and mineralization of the Duobaoshan supergiant porphyry Cu-Au-Mo-Ag deposit(2.36 Mt)in Heilongjiang Province,China:A review
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作者 Sen Zhang Nan Ju +10 位作者 Guo-bin Zhang Yuan-dong Zhao Yun-sheng Ren Bao-shan Liu Hui Wang Rong-rong Guo Qun Yang Zhen-ming Sun Feng-ming Xu Ke-yong Wang Yu-jie Hao 《China Geology》 CAS CSCD 2023年第1期100-136,共37页
The reserves of the Duobaoshan porphyry Cu-Au-Mo-Ag deposit(also referred to as the Duobaoshan porphyry Cu deposit)ranks first among the copper deposits in China and 33rd among the porphyry copper deposits in the worl... The reserves of the Duobaoshan porphyry Cu-Au-Mo-Ag deposit(also referred to as the Duobaoshan porphyry Cu deposit)ranks first among the copper deposits in China and 33rd among the porphyry copper deposits in the world.It has proven resources of copper(Cu),molybdenum(Mo),gold(Au),and silver(Ag)of 2.28×10^(6)t,80×10^(3)t,73 t,and 1046 t,respectively.The major characteristics of the Duobaoshan porphyry Cu deposit are as follows.It is located in a zone sandwiched by the Siberian,North China,and paleo-Pacific plates in an island arc tectonic setting and was formed by the Paleozoic mineralization and the Mesozoic mineralization induced by superposition and transformation.The metallogenic porphyries are the Middle Hercynian granodiorite porphyries.The alterations of surrounding rocks are distributed in a ring form.With silicified porphyries at the center,the alteration zones of K-feldspar,biotite,sericite,and propylite occur from inside to outside.This deposit is composed of 215 ore bodies(including 14 major ore bodies)in four mineralized zones.Ore body No.X in the No.3 mineralized zone has the largest resource reserves,accounting for more than 78%of the total reserves of the deposit.Major ore components include Cu,Mo,Au,Ag,Se,and Ga,which have an average content of 0.46%,0.015%,0.16 g/t,1.22 g/t,0.0003%,and 0.001%-0.003%,respectively.The ore minerals of this deposit primarily include pyrite,chalcopyrite,bornite,and molybdenite,followed by magnetite,hematite,rutile,gelenite,and sphalerite.The ore-forming fluids of this deposit were magmatic water in the early metallogenic stage and then the mixture of meteoric water and magmatic water at the late metallogenic stage.The ore-forming fluids experienced three stages.The ore-forming fluids of stageⅠhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 375-650℃,and ore-forming pressure of 110-160 MPa.The ore-forming fluids of stageⅡhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 310-350℃,and ore-forming pressure of 58-80 MPa.The ore-forming fluids of stageⅢhad a hydrochemical type of Na Cl-H_(2)O,an ore-forming temperature of 210-290℃,and ore-forming pressure of 5-12 MPa.The CuAu-Mo-Ag mineralization mainly occurred at stagesⅠandⅡ,with the ore-forming materials having a mixed crust-mantle source.The Duobaoshan porphyry Cu deposit was formed in the initial subduction environment of the Paleo-Asian Ocean Plate during the Early Ordovician.Then,due to the closure of the Mongol-Okhotsk Ocean and the subduction and compression of the Paleo-Pacific Ocean,a composite orogenic metallogenic model of the deposit was formed.In other words,it is a porphyry-epithermal copper-gold polymetallic mineralization system of composite orogeny consisting of Paleozoic island arcs and Mesozoic orogeny and extension. 展开更多
关键词 Cu-Au-Mo-Ag deposit porphyry MINERALIZATION Mineralization model Mineral exploration engineering Prospecting modle Duobaoshan Heilongjiang China
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Geology and mineralization of the Daheishan supergiant porphyry molybdenum deposit(1.65 Bt),Jilin,China:A review
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作者 Nan Ju Di Zhang +11 位作者 Guo-bin Zhang Sen Zhang Chuan-tao Ren Yun-sheng Ren Hui Wang Yue Wu Xin Liu Lu Shi Rong-rong Guo Qun Yang Zhen-ming Sun Yu-jie Hao 《China Geology》 CAS CSCD 2023年第3期494-530,共37页
The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with tot... The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with total molybdenum reserves of 1.65 billion tons,an average molybdenum ore grade of 0.081%,and molybdenum resources of 1.09 million tons.The main ore body is housed in the granodiorite porphyry plutons and their surrounding inequigranular granodiorite plutons,with high-grade ores largely located in the ore-bearing granodiorite porphyries in the middle-upper part of the porphyry plutons.Specifically,it appears as an ore pipe with a large upper part and a small lower part,measuring about 1700 m in length and width,extending for about 500 m vertically,and covering an area of 2.3 km^(2).Mineralogically,the main ore body consists of molybdenite,chalcopyrite,and sphalerite horizontally from its center outward and exhibits molybdenite,azurite,and pyrite vertically from top to bottom.The primary ore minerals include pyrite and molybdenite,and the secondary ore minerals include sphalerite,chalcopyrite,tetrahedrite,and scheelite,with average grades of molybdenum,copper,sulfur,gallium,and rhenium being 0.081%,0.033%,1.67%,0.001%,and 0.0012%,respectively.The ore-forming fluids of the Daheishan deposit originated as the CO_(2)-H_(2)O-NaCl multiphase magmatic fluid system,rich in CO_(2)and bearing minor amounts of CH4,N2,and H2S,and later mixed with meteoric precipitation.In various mineralization stages,the ore-forming fluids had homogenization temperatures of>420℃‒400℃,360℃‒350℃,340℃‒230℃,220℃‒210℃,and 180℃‒160℃and salinities of>41.05%‒9.8%NaCleqv,38.16%‒4.48%NaCleqv,35.78%‒4.49%NaCleqv,7.43%NaCleqv,and 7.8%‒9.5%NaCleqv,respectively.The mineralization of the Daheishan deposit occurred at 186‒167 Ma.The granites closely related to the mineralization include granodiorites(granodiorite porphyries)and monzogranites(monzogranite porphyries),which were mineralized after magmatic evolution(189‒167 Ma).Moreover,these mineralization-related granites exhibit low initial strontium content and high initial neodymium content,indicating that these granites underwent crust-mantle mixing.The Daheishan deposit formed during the Early-Middle Jurassic,during which basaltic magma underplating induced the lower-crust melting,leading to the formation of magma chambers.After the fractional crystallization of magmas,ore-bearing fluids formed.As the temperature and pressure decreased,the ore-bearing fluids boiled drops while ascending,leading to massive unloading of metal elements.Consequently,brecciated and veinlet-disseminated ore bodies formed. 展开更多
关键词 Molybdenum deposit porphyry type Granodiorite porphyry Crust-mantle mixing METALLIZATION U-Pb age O-S-Pb isotope Re isotope Inclusion type Ore-bearing fluid Metallogenic model Prospecting model Mineral exploration engineering
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Texture and Geochemistry of Multi-stage Hydrothermal Scheelite in the Mamupu Cu-Au-Mo(-W)Deposit,Eastern Tibet:Implications for Tungsten Mineralization in the Yulong Belt
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作者 ZHANG Xiaoxu TANG Juxing +7 位作者 LIN Bin WANG Qin HE Liang YAN Gang SHAO Rui WU Qiang DU Qiu ZHAXI Pingcuo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期701-716,共16页
Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace ... Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming fluids.Three different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide veins.The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage.Compared with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i ratios.These features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition.Sch B shows dark(Sch B-I)and light(Sch B-II)domains under CL imaging.From Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually enriched.Sch C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde stage.The Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity.The extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit. 展开更多
关键词 SCHEELITE GEOCHEMISTRY Mamupu Cu deposit Yulong porphyry copper belt eastern Tibet
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3D electrical structure of porphyry copper deposit:A case study of Shaxi copper deposit 被引量:3
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作者 陈向斌 吕庆田 严加永 《Applied Geophysics》 SCIE CSCD 2012年第3期270-278,360,共10页
Located in Lu-Zong ore concentration area, middle-lower Yangtze metallogenic belt, ShaXi porphyry copper deposit is a typical hydrothermal deposit. To investigate the distribution of deep ore bodies and spatial charac... Located in Lu-Zong ore concentration area, middle-lower Yangtze metallogenic belt, ShaXi porphyry copper deposit is a typical hydrothermal deposit. To investigate the distribution of deep ore bodies and spatial characteristics of host structures, an AMT survey was conducted in mining area. Eighteen pseudo-2D resistivity sections were constructed through careful processing and inversion. These sections clearly show resistivity difference between the Silurian sandstones formation and quartz diorite porphyry and this porphyry copper formation was controlled by the highly resistive anticlines. Using 3D block Kxiging interpolation method and 3D visualization techniques, we constructed a detailed 3D resistivity model of quartz diorite porphyry which shows the shape and spatial distribution of deep ore bodies. This case study can serve as a good example for future ore prospecting in and around this mining area. 展开更多
关键词 AMT 3D resistivity characteristics porphyry copper deposit Kriging interpolation 3D visualization
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Chronology and Crust-Mantle Mixing of Ore-forming Porphyry of the Bangongco: Evidence from Zircon U-Pb Age and Hf Isotopes of the Naruo Porphyry Copper-Gold Deposit 被引量:14
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作者 ZHOU Xiong FEI Guangchun +3 位作者 ZHOU Yu WEN Chunqi ZHANG Yi YUE Xiangyuan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第1期217-228,共12页
The Naruo porphyry copper-gold deposit (hereinafter referred to as the Naruo deposit) in Tibet is a potentially ultra-large, typical gold-rich porphyry copper deposit, which was recently discovered in the Bangongco-... The Naruo porphyry copper-gold deposit (hereinafter referred to as the Naruo deposit) in Tibet is a potentially ultra-large, typical gold-rich porphyry copper deposit, which was recently discovered in the Bangongco-Nujiang metallogenic belt. This study analyzed U-Ph chronology and Hf isotopes of the ore-bearing granodiorite porphyry in the Naruo deposit using the LA-ICPMS dating technique. The results show that the weighted average age is 124.03±0.94Ma (MSWD=1.7, n=20), and 2±6pb/23SU isocbron age is 126.2±2.7 Ma (MSWD=1.02, n=20), both of which are within the error. The weighted average age represents the crystallization age of the granodiorite porphyry, which indicates that the ore-bearing porphyry in the Naruo deposit area was formed in the Early Cretaceous and further implies that the Neo-tethys Ocean had not been closed before 124 Ma under a typical island-arc subduction environment. The εGr(t) of zircons from the granodiorite porphyry varies from 2.14 to 9.07, with an average of 5.18, and all zircons have εRf(t) values greater than 0; 176Hf/177Hf ratio is relatively high (0.282725-0.282986). Combined with the zircon age--Hf isotope correlation diagram, the aforementioned data indicate that the source reservoir might be a region that is mixed with depleted mantle and ancient crust, which possibly contains more materials sourced from depleted mantle. Rock-forming ages and ore-forming ages of the Duolong ore concentrate area are 120-124 Ma and 118-119 Ma, respectively, which indicate 124-118 Ma represents the main rockforming and ore-forming stage within the area. The Naruo deposit is located in the north of the Bangongco-Nujiang suture, and it yielded a zircon LA-ICPMS age of 124.03 Ma. This indicates the Bangongco-Nujiang oceanic basin subducted towards the north at about 124 Ma, and the Neo-tethys Ocean had not been closed before the middle Early Cretaceous. It is possible that the crust-mantle mixing formed the series of large and giant porphyry copper-gold deposits in the Bangongco. 展开更多
关键词 gold-rich porphyry copper deposit ore-bearing porphyry zircon LA-ICPMS dating Hfisotope Bangongco-Nujiang suture Naruo Tibet
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Origin of the Newly Discovered Zhunuo Porphyry Cu-Mo-Au Deposit in the Western Part of the Gangdese Porphyry Copper Belt in the Southern Tibetan Plateau,SW China 被引量:19
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作者 HUANG Yong LI Guangming +4 位作者 DING Jun DAI Jie YAN Guoqiang DONG Suiliang HUANG Hanxiao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第1期109-134,共26页
The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz ... The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz diorite porphyry, diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry. The quartz diorite porphyry yielded zircon U-Pb ages of 51.9±0.7 Ma(Eocene) using LA-ICP-MS, whereas the diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry yielded ages ranging from 16.2±0.2 to 14.0±0.2 Ma(Miocene). CuMo-Au mineralization is mainly hosted in the Miocene granodiorite porphyry. Samples from all granitoid plutons have geochemical compositions consistent with high-K calc-alkaline series magmatism. The samples display highly fractionated light rare-earth element(REE) distributions and heavy REE distributions with weakly negative Eu anomalies on chondrite-normalized REE patterns. The trace element distributions exhibit positive anomalies for large-ion lithophile elements(Rb, K, U, Th and Pb) and negative anomalies for high-field-strength elements(Nb and Ti) relative to primitive mantlenormalized values. The Eocene quartz diorite porphyry yielded εNd(t) values ranging from-3.6 to-5.2,(-(87)Sr/-(86)Sr)i values in the range 0.7046–0.7063 and initial radiogenic Pb isotopic compositions with ranges of 18.599–18.657 -(206)Pb/-(204)Pb, 15.642–15.673 -(207)Pb/-(204)Pb and 38.956–39.199 -(208)Pb/-(204)Pb. In contrast, the Miocene granitoid plutons yielded ε(Nd)(t) values ranging from-6.1 to-7.3 and(87Sr/86Sr)i values in the range 0.7071–0.7078 with similar Pb isotopic compositions to the Eocene quart diorite. The Sr-Nd-Pb isotopic compositions of the rocks are consistent with formation from magma containing a component of remelted ancient crust. Zircon grains from the Eocene quartz diorite have ε(Hf)(t) values ranging from-5.2 to +0.9 and two-stage Hf model ages ranging from 1.07 to 1.46 Ga, while zircon grains from the Miocene granitoid plutons have ε(Hf)(t) values from-9.9 to +4.2 and two-stage Hf model ages ranging from 1.05–1.73 Ga, indicating that the ancient crustal component likely derives from Paleo- to Mesoproterozoic basement. This source is distinct from that of most porphyry Cu-Mo-Au deposits in the eastern part of the Gangdese porphyry copper belt, which likely originated from juvenile crust. We therefore consider melting of ancient crustal basement to have contributed significantly to the formation Miocene porphyry Cu-Mo-Au deposits in the western part of the Gangdese porphyry copper belt. 展开更多
关键词 Zircon U-Pb dating Sr-Nd-Pb-Hf isotope Zhunuo porphyry Cu-Mo-Au deposit Gangdese porphyry copper belt
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40Ar-39Ar Dating of Albite and Phlogopite from Porphyry Iron Deposits in the Ningwu Basin in East-Central China and Its Significance 被引量:20
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作者 YUJinjie MAOJingwen 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第2期435-442,共8页
40Ar-39Ar dating of albite from the Meishan and Taocun iron deposits yields plateau ages of 122.90±0.16 Ma and 124.89±0.30 Ma, and isochron ages of 122.60±0.16 Ma and 124.90±0.29 Ma, respectively. ... 40Ar-39Ar dating of albite from the Meishan and Taocun iron deposits yields plateau ages of 122.90±0.16 Ma and 124.89±0.30 Ma, and isochron ages of 122.60±0.16 Ma and 124.90±0.29 Ma, respectively. Phlogopite from the Zhongshan-Gushan ore field has a plateau age of 126.7±0.17 Ma and an isochron age of 127.21±1.63 Ma. Analysis of regional geodynamic evolution of the middle-lower Yangtze River region suggests that the porphyry iron deposits were formed as a result of large-scale lithosphere delamination and strong sinistral strike-slip movement of the Tancheng Lujiang fault zone. The copper, molybdenum and gold deposit system in the middle-lower Yangtze River region was formed during the stress transition period of the eastern China continent. 展开更多
关键词 albite and phlogopite 40Ar- 39Ar dating porphyry iron deposit DELAMINATION Ningwu
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The geology, structure and mineralisation of the Oyu Tolgoi porphyry copper-gold-molybdenum deposits, Mongolia: A review 被引量:9
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作者 T.M.(Mike) Porter 《Geoscience Frontiers》 SCIE CAS CSCD 2016年第3期375-407,共33页
The Oyu Tolgoi cluster of seven porphyry Cu-Au-Mo deposits in southern Mongolia,define a narrow,linear,12 km long,almost continuously mineralised trend,which contains in excess of 42 Mt of Cu and1850 t of Au,and is am... The Oyu Tolgoi cluster of seven porphyry Cu-Au-Mo deposits in southern Mongolia,define a narrow,linear,12 km long,almost continuously mineralised trend,which contains in excess of 42 Mt of Cu and1850 t of Au,and is among the largest high grade porphyry Cu-Au deposits in the world.These deposits lie within the Gurvansayhan island-arc terrane,a fault bounded segment of the broader Silurian to Carboniferous Kazakh-Mongol arc,located towards the southern margin of the Central Asian Orogenic Belt,a collage of magmatic arcs that were periodically active from the late Neoproterozoic to PermoTriassic,extending from the Urals Mountains to the Pacific Ocean.Mineralisation at Oyu Tolgoi is associated with multiple,overlapping,intrusions of late Devonian(~372 to 370 Ma) quartzmonzodiorite intruding Devonian(or older) juvenile,probably intra-oceanic arc-related,basaltic lavas and lesser volcaniclastic rocks,unconformably overlain by late Devonian(~370 Ma) basaltic to dacitic pyroclastic and volcano sedimentary rocks.These quartz-monzodiorite intrusions range from earlymineral porphyritic dykes,to larger,linear,syn-,late- and post-mineral dykes and stocks.Ore was deposited within syn-mineral quartz-monzodiorites,but is dominantly hosted by augite basalts and to a lesser degree by overlying dacitic pyroclastic rocks.Following ore deposition,an allochthonous plate of older Devonian(or pre-Devonian) rocks was overthrust and a post-ore biotite granodiorite intruded at~365 Ma.Mineralisation is characterised by varying,telescoped stages of intrusion and alteration.Early A-type quartz veined dykes were followed by Cu-Au mineralisation associated with potassic alteration,mainly K-feldspar in quartz-monzodiorite and biotite-magnetite in basaltic hosts.Downward reflux of cooled,late-magmatic hydrothermal fluid resulted in intense quartz-sericite retrograde alteration in the upper parts of the main syn-mineral intrusions,and an equivalent chlorite-muscovite/illite-hematite assemblage in basaltic host rocks.Uplift,facilitated by syn-mineral longitudinal faulting,brought sections of the porphyry deposit to shallower depths,to be overprinted and upgraded by late stage,shallower,advanced argillic alteration and high sulphidation mineralisation.Key controls on the location,size and grade of the deposit cluster include(i) a long-lived,narrow faulted corridor;(ii) multiple pulses of overlapping intrusion within the same structure;and(iii) enclosing reactive,mafic dominated wall rocks,focussing ore. 展开更多
关键词 Tectonic setting porphyry copper-gold-molybdenum deposit High sulphidation GEOLOGY ALTERATION STRUCTURE
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Geology, Geochemistry and Origin of the Hongshan Porphyry-Cryptoexplosive Breccia Type Copper Deposit in Huichang County, Jiangxi Prvince 被引量:6
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作者 ZHOU Jiyuan CUI Bingfang CHEN Shizhong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第1期19-29,共11页
The Hongshan porphyry-cryptoexplosive breccia type copper deposit occurs in a metamorphic rock series of the Mesoproterozoic Zhongcun Group. Orebodies are distributed inside and outside porphyry-cryptoexplosive brecci... The Hongshan porphyry-cryptoexplosive breccia type copper deposit occurs in a metamorphic rock series of the Mesoproterozoic Zhongcun Group. Orebodies are distributed inside and outside porphyry-cryptoexplosive breccia pipes. The deposit involves five ore-forming types, i.e the porphyry type, cryptoexplosive breccia type, contact-zone veinlet-disseminated type, in-pipe fracture-zone filling-replacement type and out-of-pipe fracture-zone filling-replacement type, forming an ore-forming system of “five ore-forming types within a single rock body”. Fluid inclusion and isotope geochemical studies indicate the following: S, Pb, O and Sr were derived from the lower crust, Nd was derived from the continental crust or depleted mantle and rare earth elements (REE) and trace elements have the crustal source characters; fluids consist dominantly of formation water, metamorphic water and ***meteoric water with a part of magmatic mater, heat came from porphyry while the latter originated from partial melting caused by shear heating in the lower crust and upper mantle. According to its origin the deposit is classified as the hypabyssal and near-surface, meso- and hypothermal copper deposit associated with the late Yanshanian porphyry-cryptoexplosive breccia. 展开更多
关键词 porphyry cryptoexplosive breccia copper deposit Hongshan Huichand JIANGXI
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Geology,Geochemistry and Zircon U-Pb Geochronology of Porphyries in the Dabate Mo-Cu Deposit,Western Tianshan,China:Petrogenesis and Tectonic Implications 被引量:8
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作者 DUAN Shigang ZHANG Zuoheng +1 位作者 WANG Dachuan LI Fengming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第2期530-544,共15页
The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the D... The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I(gray white color with large phenocrysts), granite porphyry II(pink color with small phenocrysts) and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites:(1) They have high SiO2 content(70.93–80.18 wt% and 72.14–72.64 wt%, respectively), total alkali(7.58–8.95 wt% and 9.35–9.68 wt%, respectively), mafic index(0.95–0.98 and 0.93–0.94, respectively) and felsic index(0.79–0.94 and 0.89–0.91, respectively);(2) They are characterized by pronounced negative Eu anomaly, "seagullstyle" chondrite-normalized REE patterns and "tetrad effect" of REE;(3) They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting. 展开更多
关键词 porphyry Cu-Mo deposit post-collisional extension zircon U-Pb age PETROGENESIS Dabate TIANSHAN Proto-Tethys
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Geological and Geochemical Characteristics and Genesis of the Shaxi Porphyry Copper (Gold) Deposits, Anhui Province 被引量:5
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作者 XU Zhaowen QIU Jiansheng +3 位作者 REN Qijiang XU Wenyi NIU Cuiyi FU Bin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第1期8-18,共11页
The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± ... The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± 1.6 Ma. Geochemically, the rock is rich in alkalis (especially sodium), light rare earth elements (LREE) and large-ion lithophile elements (LILE), and has a relatively low initial strontium isotopic ratio (Isr=0.7058); thus it is the product of differentiation of crust-mantle mixing source magma. The model of alteration and mineralization zoning is similar to the Hollister (1974) diorite model. The ore fluids have a relatively high salinity and contain significant amounts of CO2, Ca2+, Na+ and ***CI?. The homogenization temperatures of fluid inclusions for the main mineralization stage range from 280 to 420°C, the δ18O values of the ore fluids vary from 3.51 to 5.52 %, the δD values are in the range between ?82.4 and ?59.8 %, the δ34S values of sulphides vary from ?0.3 to 2.49 %, and the δ13C values of CO2 in inclusions range between ?2.66 and ?6.53 %. Isotope data indicate that the hydrothermal ore fluids and ore substances of the Shaxi porphyry copper (gold) deposits were mainly derived from magmatic systems. 展开更多
关键词 geological and geochemical characteristics genesis of the deposit porphyry copper (gold) deposit Shaxi ANHUI
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Geochronology and Geochemistry of Metallogenetic Porphyry Bodies from the Nongping Au-Cu Deposit in the Eastern Yanbian Area, NE China: Implications for Metallogenic Environment 被引量:7
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作者 REN Yunsheng JU Nan +3 位作者 ZHAO Hualei WANG Hui HOU Kejun LIU Shen 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第3期619-629,共11页
The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichm... The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichment in sodium, and classified into sodic rocks of low-K tholeiitic basalt series. Except slightly low Sr content, the rock basically has the geochemical characteristics of the adakite: relatively high A12O3 content, relatively low MgO content, depletion in Y and Yb; relative enrichment in large ion lithophile elements (LILEs) and light rare-earth elements (LREEs), relatively low content of high field strength elements (HFSEs); positive Eu anomaly or weak negative Eu anomaly. In situ zircon dating technology LA-MC-ICP-MS was used to conduct single-grain zircon dating of biotite granodiorite porphyry, and the results show that the age of metallogenetic porphyry body is 100.04±0.88 Ma, indicating that the porphyry bodies were emplaced in the late Cretaceous period. According to the regional tectonic setting and the comparison with the same kind of deposits, we think that the metallogenetic porphyry bodies in the Nongping Au-Cu deposit have a close genetic connection with the subduction of the Pacific plate in the late Yanshanian period. The adakitic magma generated from partial melting of the subducting plate has high formation temperature, high oxygen fugacity, and volatile constituents' enrichment, so it is helpful for enrichment of metallogenetic elements and plays an important role in the formation of porphyry Au-Cu deposits in this region. 展开更多
关键词 porphyry body zircon U-Pb dating adakitic rock Nongping Au-Cu deposit
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Geochemical Characteristics and Zonation of Primary Halos of Pulang Porphyry Copper Deposit,Northwestern Yunnan Province,Southwestern China 被引量:11
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作者 陈永清 黄静宁 梁贞 《Journal of China University of Geosciences》 SCIE CSCD 2008年第4期371-377,共7页
The Pulang (普朗) porphyry copper deposit, located in the southern segment of the Yidun-Zhongdian (义敦-中甸) island arc ore-forming belt of the Tethys-Himalaya ore-forming domain, is a recently discovered large c... The Pulang (普朗) porphyry copper deposit, located in the southern segment of the Yidun-Zhongdian (义敦-中甸) island arc ore-forming belt of the Tethys-Himalaya ore-forming domain, is a recently discovered large copper deposit. Compared with the composition of granodiorite in China, the porphyry rocks in this area are enriched in W, Mo, Cu, Au, As, Sb, F, V, and Na2O (K1≥1.2). Compared with the composition of fresh porphyry rocks in this district, the mineralized rocks are enriched in Cu, Au, Ag, Mo, Pb, Zn, W, As, Sb, and K2O (K2≥1.2). Some elements show clear anomalies, such as Zn, Ag, Cu, Au, W, and Mo, and can be regarded as pathfinders for prospecting new ore bodies in depth. It has been inferred from factor analysis that the Pulang porphyry copper deposit may have undergone the multiple stages of alteration and mineralization: (a) Cu-Au mineralization; (b) W-Mo mineralization; and (c) silicification and potassic metasomatism in the whole ore-forming process. A detailed zonation sequence of indicator elements is obtained using the variability index of indicator elements as follows: Zn→Ag→Cu→Au→W→Mo. According to this zonation, an index such as (Ag*Zn)D/(Mo×W)D can be constructed and regarded as a significant criterion for predicting the Cu potential at a particular depth. 展开更多
关键词 Pulang porphyry copper deposit zonation of primary halo assessment of Cu potential at depth Tethys-Himalaya ore-forming domain southwestern China
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Integration of Deep-time Digital Data for Mapping Clusters of Porphyry Copper Mineral Deposits 被引量:3
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作者 CHENG Qiuming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第S01期8-10,共3页
1 Introduction PCDs are generated in continental arcs in response to plate converging processes(subduction and collision)(Hou et al.,2009;Richards,2013).It is generally accepted that the formation of PCDs is associate... 1 Introduction PCDs are generated in continental arcs in response to plate converging processes(subduction and collision)(Hou et al.,2009;Richards,2013).It is generally accepted that the formation of PCDs is associated with igneous activities either originating from lower crust or upper mantle,with contributions of crusts during the evolution of continental lithosphere. 展开更多
关键词 porphyry MINERAL depositS MINERAL depositS clustering simulation and prediction plate TECTONICS big data
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