Bulk Al/Al_3Zr composite was prepared by a combination of mechanical alloying(MA) and hot extrusion processes. Elemental Al and Zr powders were milled for up to 10 h and heat treated at 600℃ for 1 h to form stable Al...Bulk Al/Al_3Zr composite was prepared by a combination of mechanical alloying(MA) and hot extrusion processes. Elemental Al and Zr powders were milled for up to 10 h and heat treated at 600℃ for 1 h to form stable Al_3Zr. The prepared Al_3Zr powder was then mixed with the pure Al powder to produce an Al–Al_3Zr composite. The composite powder was finally consolidated by hot extrusion at 550℃. The mechanical properties of consolidated samples were evaluated by hardness and tension tests at room and elevated temperatures. The results show that annealing of the 10-h-milled powder at 600℃ for 1 h led to the formation of a stable Al_3Zr phase. Differential scanning calorimetry(DSC) results confirmed that the formation of Al_3Zr began with the nucleation of a metastable phase, which subsequently transformed to the stable tetragonal Al_3Zr structure. The tension yield strength of the Al-10wt%Al_3Zr composite was determined to be 103 MPa, which is approximately twice that for pure Al(53 MPa). The yield stress of the Al/Al_3Zr composite at 300℃ is just 10% lower than that at room temperature, which demonstrates the strong potential for the prepared composite to be used in high-temperature structural applications.展开更多
The article considers one of the possible approaches to the solution of an urgent issue of metal consumption reduction, increase of operating life and maximum operating temperature as well as reduction of irrecoverabl...The article considers one of the possible approaches to the solution of an urgent issue of metal consumption reduction, increase of operating life and maximum operating temperature as well as reduction of irrecoverable losses of platinum products and alloys when operating under high temperature conditions, particularly for glassblowing and single crystal growing crucibles. A two-layered composite material based on platinum-group metals and corundum plasma ceramics is thoroughly investigated. A successful experience of crucibles exploitation, designed for production of high temperature optical glasses from the composite and results of the research on composite material specimens are described.展开更多
The effect of Cu,Fe and Ni on high-temperature mechanical performance and fatigue properties of ZL114A alloy was studied through high temperature fatigue test and SEM.The results show that the three elements have a de...The effect of Cu,Fe and Ni on high-temperature mechanical performance and fatigue properties of ZL114A alloy was studied through high temperature fatigue test and SEM.The results show that the three elements have a detrimental influence on high temperature cyclic fatigue life.When the contents (mass fraction) of Fe,Cu and Ni in ZL114A alloy are 0.28%,1.53% and 0.16%,respectively,the high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved from 194 MPa and 40.2 MPa to 236 MPa and 48.2 MPa by alloying.The main reason that high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved significantly is that the three elements greatly improve the proportion of Cu/Mg in ZL114A alloy and nickel content.展开更多
In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) s...In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.展开更多
Since the discovery of hydride superconductors,a significant challenge has been to reduce the pressure required for their stabilization.In this context,we propose that alloying could be an effective strategy to achiev...Since the discovery of hydride superconductors,a significant challenge has been to reduce the pressure required for their stabilization.In this context,we propose that alloying could be an effective strategy to achieve this.We focus on a series of alloyed hydrides with the AMH_(6)composition,which can be made via alloying A15 AH_(3)(A=Al or Ga)with M(M=a group IIIB or IVB metal),and study their behavior under pressure.Seven of them are predicted to maintain the A15-type structure,similar to AH_(3)under pressure,providing a platform for studying the effects of alloying on the stability and superconductivity of AH_(3).Among these,the A15-type phases of AlZrH_(6)and AlHfH_(6)are found to be thermodynamically stable in the pressure ranges of 40–150 and 30–181 GPa,respectively.Furthermore,they remain dynamically stable at even lower pressures,as low as 13 GPa for AlZrH_(6)and 6 GPa for AlHfH_(6).These pressures are significantly lower than that required for stabilizing A15 AlH3.Additionally,the introduction of Zr or Hf increases the electronic density of states at the Fermi level compared with AlH3.This enhancement leads to higher critical temperatures(Tc)of 75 and 76 K for AlZrH_(6)and AlHfH_(6)at 20 and 10 GPa,respectively.In the case of GaMH_(6)alloys,where M represents Sc,Ti,Zr,or Hf,these metals reinforce the stability of the A15-type structure and reduce the lowest thermodynamically stable pressure for GaH_(3) from 160 GPa to 116,95,80,and 85 GPa,respectively.Particularly noteworthy are the A15-type GaMH_(6)alloys,which remain dynamically stable at low pressures of 97,28,5,and 6 GPa,simultaneously exhibiting high Tc of 88,39,70,and 49 K at 100,35,10,and 10 GPa,respectively.Overall,these findings enrich the family of A15-type superconductors and provide insights for the future exploration of high-temperature hydride superconductors that can be stabilized at lower pressures.展开更多
The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show t...The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show that the pattern of positive SST-surface wind speed correlations is anchored by strong SST gradient and marine atmospheric boundary layer (MABL) height front, with active warm and cold-ocean eddies around. The MABL has an obvious transitional structure along the strong SST front, with greater (lesser) heights over the north (south) side. The significant positive SST-surface wind-speed perturbation correlations are mostly found over both strong warm and cold eddies. The surface wind speed increases (decreases) about 0.32 (0.41) m/s and the MABL elevates (drops) approximate 55 (54) m per 1℃ of SST perturbation induced by warm (cold) eddies. The response of the surface wind speed to SST perturbations over the mesoscale eddies is mainly attributed to the momentum vertical mixing in the MABL, which is confirmed by the linear relationships between the downwind (crosswind) SST gradient and wind divergence (curl).展开更多
Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu...Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloy powders(HEAs)with both large aspect ratios and thin intergranular amorphous layers are constructed by a multistage mechanical alloying strategy,aiming to achieve excellent and temperature-stable permeability and EMW absorption.A single-phase face-centered cubic structure with good ductility and high crystallinity is obtained as wet milling precursors,via precisely controlling dry milling time.Then,HEAs are flattened to improve aspect ratios by synergistically regulating wet milling time.FeCoNiCr_(0.4)Cu_(0.2) HEAs with dry milling 20 h and wet milling 5 h(D20)exhibit higher and more stable permeability because of larger aspect ratios and thinner intergranular amorphous layers.The maximum reflection loss(RL)of D20/SiO_(2) composites is greater than-7 dB with 5 mm thickness,and EMW absorption bandwidth(RL<-7 dB)can maintain between 523 and 600 MHz from-50 to 150℃.Furthermore,relying on the“cocktail effect”of HEAs,D20 sample also exhibits excellent corrosion resistance and high Curie temperature.This work provides a facile and tunable strategy to design MHz electromagnetic absorbers with temperature stability,broadband,and resistance to harsh environments.展开更多
Applications, theoretical analysis and numerical methods are introduced for the simulation of mechanical models and principles of the porous flow in high temperature, high salt, complicated geology and large-scale res...Applications, theoretical analysis and numerical methods are introduced for the simulation of mechanical models and principles of the porous flow in high temperature, high salt, complicated geology and large-scale reservoirs in this paper. Considering petroleum geology, geochemistry, computational permeation fluid mechanics and computer technology, we state the models of permeation fluid mechanics and put forward a sequence of implicit upwind difference iteration schemes based on refined fractional steps of the upstream, which can compute the pressures, the saturation and the concentrations of different chemistry components. A type of software applicable in major industries has been completed and carried out in numerical analysis and simulations of oil extraction in Shengli Oil-field, which brings huge economic benefits and social benefits. This software gives many characters: spatial steps are taken as ten meters, the number of nodes is up to hundreds of thousands and simulation time period can be tens of years and the high-order accuracy can be promised in numerical data. Precise analysis is present for simplified models of this type and that provides a tool to solve the international famous problem.展开更多
The high temperature(HT)thermal stability and mechanical properties of Al-5%Cu(AC)and Al-5%Cu-0.2%Mn-0.2 Zr%(ACMZ)alloys from 573 to 673 K were systematically studied.The results displayed that micro-alloying addition...The high temperature(HT)thermal stability and mechanical properties of Al-5%Cu(AC)and Al-5%Cu-0.2%Mn-0.2 Zr%(ACMZ)alloys from 573 to 673 K were systematically studied.The results displayed that micro-alloying additions of Zr and Mn elements have presented a significant role in stabilizing the main strengthening metastableθ′precipitates at a temperature as high as 573 K.Simultaneously,the HT tensile test demonstrated that ACMZ alloy retained their strength of(88.6±8.8)MPa,which was much higher than that of AC alloy((32.5±0.8)MPa)after the thermal exposure at 573 K for 200 h.Finally,the underlying mechanisms of strength and ductility enhancement mechanism of the ACMZ alloy at HT were discussed in detail.展开更多
The temperature effects on the electrical performance of a large area multicrystalline silicon solar cell with back-contact technology have been studied in a desert area under ambient conditions using the current shun...The temperature effects on the electrical performance of a large area multicrystalline silicon solar cell with back-contact technology have been studied in a desert area under ambient conditions using the current shunt measuring technique. Therefore, most of the problems encountered with traditional measuring techniques are avoided. The temperature dependency of the current shunt from 5oC up to 50oC has been investigated. Its temperature coefficient proves to be negligible which means that the temperature dependency of the solar cell is completely independent of the current shunt. The solar module installed in a tilted position at the optimum angle of the location, has been tested in two different seasons (winter and summer). The obtained solar cell short circuit current, open circuit voltage and output power are correlated with the measured incident radiation in both seasons and all results are discussed.展开更多
Cu-Zn and Cu-Cr powders were milled with an attritor mill at room temperature,-10,-20 and-30℃,respectively.Phase transformation and morphology evolution of the alloyed powder were investigated by X-ray diffractometry...Cu-Zn and Cu-Cr powders were milled with an attritor mill at room temperature,-10,-20 and-30℃,respectively.Phase transformation and morphology evolution of the alloyed powder were investigated by X-ray diffractometry(XRD),X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).The results show that lowering temperature can delay mechanical alloying(MA)process of Cu-Zn system with negative mixing enthalpy,and promote MA process of Cu-Cr system with positive mixing enthalpy.As for Cu-Cr and Cu-Zn powders milled at-10℃,lamellar structures are firstly formed,while fewer lamellar particles can be found when the powder is milled at-20℃.When the alloyed powder is annealed at 1 000℃,Cu(Cr)solid solution is decomposed and Cr precipitates from Cu matrix,whereas Cu(Zn)solid solution keeps stable.展开更多
In the present work, we have studied the temporal evolution of aluminum alloy plasma produced by the fundamental (1064 nm) of a Q-switched Nd:YAG laser by placing the target material in air at atmospheric pressure. Th...In the present work, we have studied the temporal evolution of aluminum alloy plasma produced by the fundamental (1064 nm) of a Q-switched Nd:YAG laser by placing the target material in air at atmospheric pressure. The four Al I-neutral lines at 308.21, 309.27, 394.40 and 369.15 nm as well as Al II-ionic lines at 281.61, 385.64 and 466.30 nm are used for the determination of the electron temperature Te using Saha-Boltzmann plot method. The neutral aluminum lines were found to suffer from optical thickness which manifested itself on the form of scattered points around the Saha-Boltzmann line. The isolated optically thin hydrogen Hα-line at 656.27 nm appeared in the spectra under the same experimental conditions was used to correct the Al I-lines which contained some optical thickness. The measurements were repeated at different delay times ranging from 1 to 5 μs. The comparison between the deduced electron temperatures from aluminum neutral lines before correction against the effect self-absorption to that after correction revealed a precise value in temperature. The results sure that, in case of the presence of self-absorption effect the temperature varies from (1.4067 - 1.2548 eV) as the delay time is varied from 0 to 5 μs. Whereas, in the case of repairing against the effect, it varies from (1.2826 - 0.8961 eV) for the same delay time variation.展开更多
Alloying is a good approach to increasing its strength but leads to a reduction of damping to pure magnesium.Classifying the alloying characteristics of various alloying elements in magnesium alloys and their combined...Alloying is a good approach to increasing its strength but leads to a reduction of damping to pure magnesium.Classifying the alloying characteristics of various alloying elements in magnesium alloys and their combined effects on the damping and mechanical properties of magnesium alloys is important.In this paper,the properties of the Mg-0.6wt%X binary alloys were analyzed through strength measurements and dynamic mechanical analysis.The effects of foreign atoms on solid-solution strengthening and dislocation damping were studied comprehensively.The effect of solid solubility on damping capacity can be considered from two perspectives:the effect of single solid-solution atoms on the damping capacities of the alloy,and the effect of solubility on the damping capacities of the alloy.The results provide significant information that is useful in developing high-strength,high-damping magnesium alloys.This study will provide scientific guidance regarding the development of new types of damping magnesium alloys.展开更多
Our research objective was to expand the very limited knowledgebase pertaining to the ecology of fringing coral reefs in the Gulf of Suez, Egypt. Specifically, determine dominant coral species and investigate why this...Our research objective was to expand the very limited knowledgebase pertaining to the ecology of fringing coral reefs in the Gulf of Suez, Egypt. Specifically, determine dominant coral species and investigate why this reef is capable of surviving at such a high-latitude and extreme harsh environment. Data collection included annual reef surveys, randomized quadrat sampling, five permanent video transects and in situ seawater temperature. Of the known Gulf of Suez 35 taxa, only six (Acropora humilis, A. microclados, A. hemprichii, Litophyton arboretum, Stylophora pistillata, Porites columna, and P. plantulata), compose 94% of the reef's coral cover. Coral dominance across species shifted drastically during the study period. However, the six coral dominance remained unchanged, while some decreased others increased. These six coral taxa regularly experience daily changes in seawater temperature and seasonal variations that exceed These extreme temperatures variation and the fact that only six coral taxa dominance remained unchanged, suggest that these corals may have developed a mechanism to cope with extreme seawater temperatures as evidenced by their continued growth and survival over the study period. We speculate that species dominance shift occurred largely as a result of a local oil spill rather than exposure to extreme temperatures. Further scrutiny of these species and the mechanisms by which they are able to thrive is recommended, as they hold the potential to benefit other coral communities as a resilient transplant species and model for understanding coral survivability in extreme environmental conditions.展开更多
The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metalli...The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.展开更多
To effectively solve the problem of lost circulation and well kick frequently occurring during the drilling of abnormally high temperature and pressure fractured-vuggy reservoirs in the Tazhong block, a rigid particle...To effectively solve the problem of lost circulation and well kick frequently occurring during the drilling of abnormally high temperature and pressure fractured-vuggy reservoirs in the Tazhong block, a rigid particle material, GZD, with high temperature tolerance, high rigidity(> 8 MPa) and low abrasiveness has been selected based on geological characteristics of the theft zones in the reservoirs. Through static pressure sealing experiments, its dosage when used alone and when used in combination with lignin fiber, elastic material SQD-98 and calcium carbonate were optimized, and the formula of a new type(SXM-I) of compound lost circulation material with high temperature tolerance and high strength was formed. Its performance was evaluated by compatibility test, static sealing experiment and sand bed plugging experiment. The test results show that it has good compatibility with drilling fluid used commonly and is able to plug fractures and vugs, the sealed fractures are able to withstand the static pressure of more than 9 MPa and the cumulative leakage is 13.4 mL. The mud filtrate invasion depth is only 2.5 cm in 30 min when the sand bed is made of particles with sizes between 10 mesh and 20 mesh. Overall, with good sealing property and high temperature and high pressure tolerance, the lost circulation material provides strong technical support for the safety drilling in the block.展开更多
The aim of this work was to investigate the effect of lithium chloride (LiCl) on the fibre length distribution, melting temperature and the rheological characteristics of high yield pulp fibre reinforced polyamide bio...The aim of this work was to investigate the effect of lithium chloride (LiCl) on the fibre length distribution, melting temperature and the rheological characteristics of high yield pulp fibre reinforced polyamide biocomposite. The inorganic salt lithium chloride (LiCl) was used to decrease the melting and processing temperature of bio-based polyamide 11. The extrusion method and Brabender mixer approaches were used to carry out the compounding process. The densities and fibre content were found to be increased after processing using both compounding methods. The HYP fibre length distribution analysis realized using the FQA equipment showed an important fibre-length reduction after processing by both techniques. The rheological properties of HYP-reinforced net and modified bio-based polyamide 11 “PA11” (HYP/PA11) composite were investigated using a capillary rheometer. The rheological tests were performed in function of the shear rate for different temperature conditions. The low-temperature process compounding had higher shear viscosity;this was because during the process the temperature was low and the mixing and melting were induced by the high shear rate created during compounding process. Experimental test results using the extrusion process showed a steep decrease in shear viscosity with increasing shear rate, and this melt-flow characteristic corresponds to shear-thinning behavior in HYP/PA11, and this steep decrease in the melt viscosity can be associated to the hydrolyse reaction of nylon for high pulp fibre moisture content at high temperature. In addition to the low processing temperature, the melt viscosity of the biocomposite using the Brabender mixer approach increases with increasing shear rate, and this stability in the increase even at high shear rate for high pulp moisture content is associated to the presence of inorganic salt lithium chloride which creates the hydrogen bonds with pulp during the compounding process.展开更多
The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grindi...The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grinding) and after additional chemical etching. The changes in the microstructure of tubes due to the interaction with steam were investigated. A comparison was made between the oxidation rate of this material (weight gain) and the data on the oxidation of other alloys for nuclear power plants. The oxidation rate of Zr1Nb(0.1% O) is close to the oxidation rate of other zirconium alloys. It is shown that after chemical treatment of the surface of the samples there is a more even growth of oxide films, and they have a smaller thickness for the same time of exposure than after mechanical grinding. Surface treatment before oxidation also affects the change of microstructure of samples when heated to high temperatures.展开更多
In this paper, the model output machine learning (MOML) method is proposed for simulating weather consultation, which can improve the forecast results of numerical weather prediction (NWP). During weather consultation...In this paper, the model output machine learning (MOML) method is proposed for simulating weather consultation, which can improve the forecast results of numerical weather prediction (NWP). During weather consultation, the forecasters obtain the final results by combining the observations with the NWP results and giving opinions based on their experience. It is obvious that using a suitable post-processing algorithm for simulating weather consultation is an interesting and important topic. MOML is a post-processing method based on machine learning, which matches NWP forecasts against observations through a regression function. By adopting different feature engineering of datasets and training periods, the observational and model data can be processed into the corresponding training set and test set. The MOML regression function uses an existing machine learning algorithm with the processed dataset to revise the output of NWP models combined with the observations, so as to improve the results of weather forecasts. To test the new approach for grid temperature forecasts, the 2-m surface air temperature in the Beijing area from the ECMWF model is used. MOML with different feature engineering is compared against the ECMWF model and modified model output statistics (MOS) method. MOML shows a better numerical performance than the ECMWF model and MOS, especially for winter. The results of MOML with a linear algorithm, running training period, and dataset using spatial interpolation ideas, are better than others when the forecast time is within a few days. The results of MOML with the Random Forest algorithm, year-round training period, and dataset containing surrounding gridpoint information, are better when the forecast time is longer.展开更多
文摘Bulk Al/Al_3Zr composite was prepared by a combination of mechanical alloying(MA) and hot extrusion processes. Elemental Al and Zr powders were milled for up to 10 h and heat treated at 600℃ for 1 h to form stable Al_3Zr. The prepared Al_3Zr powder was then mixed with the pure Al powder to produce an Al–Al_3Zr composite. The composite powder was finally consolidated by hot extrusion at 550℃. The mechanical properties of consolidated samples were evaluated by hardness and tension tests at room and elevated temperatures. The results show that annealing of the 10-h-milled powder at 600℃ for 1 h led to the formation of a stable Al_3Zr phase. Differential scanning calorimetry(DSC) results confirmed that the formation of Al_3Zr began with the nucleation of a metastable phase, which subsequently transformed to the stable tetragonal Al_3Zr structure. The tension yield strength of the Al-10wt%Al_3Zr composite was determined to be 103 MPa, which is approximately twice that for pure Al(53 MPa). The yield stress of the Al/Al_3Zr composite at 300℃ is just 10% lower than that at room temperature, which demonstrates the strong potential for the prepared composite to be used in high-temperature structural applications.
文摘The article considers one of the possible approaches to the solution of an urgent issue of metal consumption reduction, increase of operating life and maximum operating temperature as well as reduction of irrecoverable losses of platinum products and alloys when operating under high temperature conditions, particularly for glassblowing and single crystal growing crucibles. A two-layered composite material based on platinum-group metals and corundum plasma ceramics is thoroughly investigated. A successful experience of crucibles exploitation, designed for production of high temperature optical glasses from the composite and results of the research on composite material specimens are described.
基金Project(G09003.8-4)supported by the National Science and Technology Major Project of ChinaProject supported by Fund of Chongqing University Large-Scale Equipment,China
文摘The effect of Cu,Fe and Ni on high-temperature mechanical performance and fatigue properties of ZL114A alloy was studied through high temperature fatigue test and SEM.The results show that the three elements have a detrimental influence on high temperature cyclic fatigue life.When the contents (mass fraction) of Fe,Cu and Ni in ZL114A alloy are 0.28%,1.53% and 0.16%,respectively,the high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved from 194 MPa and 40.2 MPa to 236 MPa and 48.2 MPa by alloying.The main reason that high temperature tensile strength and cyclic fatigue of ZL114A alloy are improved significantly is that the three elements greatly improve the proportion of Cu/Mg in ZL114A alloy and nickel content.
基金financially supported by the National Science and Technology Major Project of China (No. 2012ZX04010-081)the National High-Tech Research and Development Program of China (No. 2013AA040404)
文摘In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.
基金supported by the Natural Science Foundation of China(Grant Nos.52022089,52372261,52288102,and 11964026)the National Key R&D Program of China(Grant No.2022YFA1402300)+5 种基金the Natural Science Foundation of Hebei Province(Grant No.E2022203109)the Doctoral Fund of Henan University of Technology(Grant No.31401579)P.L.thanks the Science and Technology Leading Talents and Innovation Team Building Projects of the Inner Mongolia Autonomous Region(Grant No.GXKY22060)financial support from the Spanish Ministry of Science and Innovation(Grant No.FIS2019-105488GB-I00)the Department of Education,Universities and Research of the Basque Government and the University of the Basque Country(Grant No.IT1707-22)the National Science Foundation(Grant No.DMR-2136038)for financial support.
文摘Since the discovery of hydride superconductors,a significant challenge has been to reduce the pressure required for their stabilization.In this context,we propose that alloying could be an effective strategy to achieve this.We focus on a series of alloyed hydrides with the AMH_(6)composition,which can be made via alloying A15 AH_(3)(A=Al or Ga)with M(M=a group IIIB or IVB metal),and study their behavior under pressure.Seven of them are predicted to maintain the A15-type structure,similar to AH_(3)under pressure,providing a platform for studying the effects of alloying on the stability and superconductivity of AH_(3).Among these,the A15-type phases of AlZrH_(6)and AlHfH_(6)are found to be thermodynamically stable in the pressure ranges of 40–150 and 30–181 GPa,respectively.Furthermore,they remain dynamically stable at even lower pressures,as low as 13 GPa for AlZrH_(6)and 6 GPa for AlHfH_(6).These pressures are significantly lower than that required for stabilizing A15 AlH3.Additionally,the introduction of Zr or Hf increases the electronic density of states at the Fermi level compared with AlH3.This enhancement leads to higher critical temperatures(Tc)of 75 and 76 K for AlZrH_(6)and AlHfH_(6)at 20 and 10 GPa,respectively.In the case of GaMH_(6)alloys,where M represents Sc,Ti,Zr,or Hf,these metals reinforce the stability of the A15-type structure and reduce the lowest thermodynamically stable pressure for GaH_(3) from 160 GPa to 116,95,80,and 85 GPa,respectively.Particularly noteworthy are the A15-type GaMH_(6)alloys,which remain dynamically stable at low pressures of 97,28,5,and 6 GPa,simultaneously exhibiting high Tc of 88,39,70,and 49 K at 100,35,10,and 10 GPa,respectively.Overall,these findings enrich the family of A15-type superconductors and provide insights for the future exploration of high-temperature hydride superconductors that can be stabilized at lower pressures.
基金Supported by the China’s National Key Research and Development Projects(No.2016YFA0601803)the National Natural Science Foundation of China(Nos.41490641,41521091,U1606402)the Qingdao National Laboratory for Marine Science and Technology(No.2017ASKJ01)
文摘The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show that the pattern of positive SST-surface wind speed correlations is anchored by strong SST gradient and marine atmospheric boundary layer (MABL) height front, with active warm and cold-ocean eddies around. The MABL has an obvious transitional structure along the strong SST front, with greater (lesser) heights over the north (south) side. The significant positive SST-surface wind-speed perturbation correlations are mostly found over both strong warm and cold eddies. The surface wind speed increases (decreases) about 0.32 (0.41) m/s and the MABL elevates (drops) approximate 55 (54) m per 1℃ of SST perturbation induced by warm (cold) eddies. The response of the surface wind speed to SST perturbations over the mesoscale eddies is mainly attributed to the momentum vertical mixing in the MABL, which is confirmed by the linear relationships between the downwind (crosswind) SST gradient and wind divergence (curl).
基金the Supported by Program for the National Natural Science Foundation of China(No.52071053,U1704253,52103334)China Postdoctoral Science Foundation(2020M670748,2020M680946)the Fundamental Research Funds for the Central Universities(DUT20GF111).
文摘Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloy powders(HEAs)with both large aspect ratios and thin intergranular amorphous layers are constructed by a multistage mechanical alloying strategy,aiming to achieve excellent and temperature-stable permeability and EMW absorption.A single-phase face-centered cubic structure with good ductility and high crystallinity is obtained as wet milling precursors,via precisely controlling dry milling time.Then,HEAs are flattened to improve aspect ratios by synergistically regulating wet milling time.FeCoNiCr_(0.4)Cu_(0.2) HEAs with dry milling 20 h and wet milling 5 h(D20)exhibit higher and more stable permeability because of larger aspect ratios and thinner intergranular amorphous layers.The maximum reflection loss(RL)of D20/SiO_(2) composites is greater than-7 dB with 5 mm thickness,and EMW absorption bandwidth(RL<-7 dB)can maintain between 523 and 600 MHz from-50 to 150℃.Furthermore,relying on the“cocktail effect”of HEAs,D20 sample also exhibits excellent corrosion resistance and high Curie temperature.This work provides a facile and tunable strategy to design MHz electromagnetic absorbers with temperature stability,broadband,and resistance to harsh environments.
文摘Applications, theoretical analysis and numerical methods are introduced for the simulation of mechanical models and principles of the porous flow in high temperature, high salt, complicated geology and large-scale reservoirs in this paper. Considering petroleum geology, geochemistry, computational permeation fluid mechanics and computer technology, we state the models of permeation fluid mechanics and put forward a sequence of implicit upwind difference iteration schemes based on refined fractional steps of the upstream, which can compute the pressures, the saturation and the concentrations of different chemistry components. A type of software applicable in major industries has been completed and carried out in numerical analysis and simulations of oil extraction in Shengli Oil-field, which brings huge economic benefits and social benefits. This software gives many characters: spatial steps are taken as ten meters, the number of nodes is up to hundreds of thousands and simulation time period can be tens of years and the high-order accuracy can be promised in numerical data. Precise analysis is present for simplified models of this type and that provides a tool to solve the international famous problem.
基金financial supports from the National Natural Science Foundation of China(No.52071207)the China Postdoctoral Science Foundation(Nos.2019TQ0193,2019M661497)+1 种基金the National Key Research and Development Program of China(No.2018YFB1106302)Anhui Provincial Engineering Research Center of Aluminum Matrix Composites,China(No.2017WAMC002)。
文摘The high temperature(HT)thermal stability and mechanical properties of Al-5%Cu(AC)and Al-5%Cu-0.2%Mn-0.2 Zr%(ACMZ)alloys from 573 to 673 K were systematically studied.The results displayed that micro-alloying additions of Zr and Mn elements have presented a significant role in stabilizing the main strengthening metastableθ′precipitates at a temperature as high as 573 K.Simultaneously,the HT tensile test demonstrated that ACMZ alloy retained their strength of(88.6±8.8)MPa,which was much higher than that of AC alloy((32.5±0.8)MPa)after the thermal exposure at 573 K for 200 h.Finally,the underlying mechanisms of strength and ductility enhancement mechanism of the ACMZ alloy at HT were discussed in detail.
文摘The temperature effects on the electrical performance of a large area multicrystalline silicon solar cell with back-contact technology have been studied in a desert area under ambient conditions using the current shunt measuring technique. Therefore, most of the problems encountered with traditional measuring techniques are avoided. The temperature dependency of the current shunt from 5oC up to 50oC has been investigated. Its temperature coefficient proves to be negligible which means that the temperature dependency of the solar cell is completely independent of the current shunt. The solar module installed in a tilted position at the optimum angle of the location, has been tested in two different seasons (winter and summer). The obtained solar cell short circuit current, open circuit voltage and output power are correlated with the measured incident radiation in both seasons and all results are discussed.
基金Project(20050698017)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of ChinaKey Project(105159)supported by Chinese Ministry of EducationProject(NCET-05-0839)supported by Program for New Century Excellent Talents in University
文摘Cu-Zn and Cu-Cr powders were milled with an attritor mill at room temperature,-10,-20 and-30℃,respectively.Phase transformation and morphology evolution of the alloyed powder were investigated by X-ray diffractometry(XRD),X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).The results show that lowering temperature can delay mechanical alloying(MA)process of Cu-Zn system with negative mixing enthalpy,and promote MA process of Cu-Cr system with positive mixing enthalpy.As for Cu-Cr and Cu-Zn powders milled at-10℃,lamellar structures are firstly formed,while fewer lamellar particles can be found when the powder is milled at-20℃.When the alloyed powder is annealed at 1 000℃,Cu(Cr)solid solution is decomposed and Cr precipitates from Cu matrix,whereas Cu(Zn)solid solution keeps stable.
文摘In the present work, we have studied the temporal evolution of aluminum alloy plasma produced by the fundamental (1064 nm) of a Q-switched Nd:YAG laser by placing the target material in air at atmospheric pressure. The four Al I-neutral lines at 308.21, 309.27, 394.40 and 369.15 nm as well as Al II-ionic lines at 281.61, 385.64 and 466.30 nm are used for the determination of the electron temperature Te using Saha-Boltzmann plot method. The neutral aluminum lines were found to suffer from optical thickness which manifested itself on the form of scattered points around the Saha-Boltzmann line. The isolated optically thin hydrogen Hα-line at 656.27 nm appeared in the spectra under the same experimental conditions was used to correct the Al I-lines which contained some optical thickness. The measurements were repeated at different delay times ranging from 1 to 5 μs. The comparison between the deduced electron temperatures from aluminum neutral lines before correction against the effect self-absorption to that after correction revealed a precise value in temperature. The results sure that, in case of the presence of self-absorption effect the temperature varies from (1.4067 - 1.2548 eV) as the delay time is varied from 0 to 5 μs. Whereas, in the case of repairing against the effect, it varies from (1.2826 - 0.8961 eV) for the same delay time variation.
基金financially supported by the National Natural Science Foundation of China(Nos.51361010 and 51665012)the Jiangxi Province Science Fund for Distinguished Young Scholars(Nos.20171BCB23061 and 2018ACB21020)
文摘Alloying is a good approach to increasing its strength but leads to a reduction of damping to pure magnesium.Classifying the alloying characteristics of various alloying elements in magnesium alloys and their combined effects on the damping and mechanical properties of magnesium alloys is important.In this paper,the properties of the Mg-0.6wt%X binary alloys were analyzed through strength measurements and dynamic mechanical analysis.The effects of foreign atoms on solid-solution strengthening and dislocation damping were studied comprehensively.The effect of solid solubility on damping capacity can be considered from two perspectives:the effect of single solid-solution atoms on the damping capacities of the alloy,and the effect of solubility on the damping capacities of the alloy.The results provide significant information that is useful in developing high-strength,high-damping magnesium alloys.This study will provide scientific guidance regarding the development of new types of damping magnesium alloys.
文摘Our research objective was to expand the very limited knowledgebase pertaining to the ecology of fringing coral reefs in the Gulf of Suez, Egypt. Specifically, determine dominant coral species and investigate why this reef is capable of surviving at such a high-latitude and extreme harsh environment. Data collection included annual reef surveys, randomized quadrat sampling, five permanent video transects and in situ seawater temperature. Of the known Gulf of Suez 35 taxa, only six (Acropora humilis, A. microclados, A. hemprichii, Litophyton arboretum, Stylophora pistillata, Porites columna, and P. plantulata), compose 94% of the reef's coral cover. Coral dominance across species shifted drastically during the study period. However, the six coral dominance remained unchanged, while some decreased others increased. These six coral taxa regularly experience daily changes in seawater temperature and seasonal variations that exceed These extreme temperatures variation and the fact that only six coral taxa dominance remained unchanged, suggest that these corals may have developed a mechanism to cope with extreme seawater temperatures as evidenced by their continued growth and survival over the study period. We speculate that species dominance shift occurred largely as a result of a local oil spill rather than exposure to extreme temperatures. Further scrutiny of these species and the mechanisms by which they are able to thrive is recommended, as they hold the potential to benefit other coral communities as a resilient transplant species and model for understanding coral survivability in extreme environmental conditions.
文摘The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.
基金Supported by the China National Science and Technology Major Project(2011ZX05042-002-001)
文摘To effectively solve the problem of lost circulation and well kick frequently occurring during the drilling of abnormally high temperature and pressure fractured-vuggy reservoirs in the Tazhong block, a rigid particle material, GZD, with high temperature tolerance, high rigidity(> 8 MPa) and low abrasiveness has been selected based on geological characteristics of the theft zones in the reservoirs. Through static pressure sealing experiments, its dosage when used alone and when used in combination with lignin fiber, elastic material SQD-98 and calcium carbonate were optimized, and the formula of a new type(SXM-I) of compound lost circulation material with high temperature tolerance and high strength was formed. Its performance was evaluated by compatibility test, static sealing experiment and sand bed plugging experiment. The test results show that it has good compatibility with drilling fluid used commonly and is able to plug fractures and vugs, the sealed fractures are able to withstand the static pressure of more than 9 MPa and the cumulative leakage is 13.4 mL. The mud filtrate invasion depth is only 2.5 cm in 30 min when the sand bed is made of particles with sizes between 10 mesh and 20 mesh. Overall, with good sealing property and high temperature and high pressure tolerance, the lost circulation material provides strong technical support for the safety drilling in the block.
文摘The aim of this work was to investigate the effect of lithium chloride (LiCl) on the fibre length distribution, melting temperature and the rheological characteristics of high yield pulp fibre reinforced polyamide biocomposite. The inorganic salt lithium chloride (LiCl) was used to decrease the melting and processing temperature of bio-based polyamide 11. The extrusion method and Brabender mixer approaches were used to carry out the compounding process. The densities and fibre content were found to be increased after processing using both compounding methods. The HYP fibre length distribution analysis realized using the FQA equipment showed an important fibre-length reduction after processing by both techniques. The rheological properties of HYP-reinforced net and modified bio-based polyamide 11 “PA11” (HYP/PA11) composite were investigated using a capillary rheometer. The rheological tests were performed in function of the shear rate for different temperature conditions. The low-temperature process compounding had higher shear viscosity;this was because during the process the temperature was low and the mixing and melting were induced by the high shear rate created during compounding process. Experimental test results using the extrusion process showed a steep decrease in shear viscosity with increasing shear rate, and this melt-flow characteristic corresponds to shear-thinning behavior in HYP/PA11, and this steep decrease in the melt viscosity can be associated to the hydrolyse reaction of nylon for high pulp fibre moisture content at high temperature. In addition to the low processing temperature, the melt viscosity of the biocomposite using the Brabender mixer approach increases with increasing shear rate, and this stability in the increase even at high shear rate for high pulp moisture content is associated to the presence of inorganic salt lithium chloride which creates the hydrogen bonds with pulp during the compounding process.
文摘The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grinding) and after additional chemical etching. The changes in the microstructure of tubes due to the interaction with steam were investigated. A comparison was made between the oxidation rate of this material (weight gain) and the data on the oxidation of other alloys for nuclear power plants. The oxidation rate of Zr1Nb(0.1% O) is close to the oxidation rate of other zirconium alloys. It is shown that after chemical treatment of the surface of the samples there is a more even growth of oxide films, and they have a smaller thickness for the same time of exposure than after mechanical grinding. Surface treatment before oxidation also affects the change of microstructure of samples when heated to high temperatures.
基金supported by the National Key Research and Development Program of China (Grant Nos. 2018YFF0300104 and 2017YFC0209804)the National Natural Science Foundation of China (Grant No. 11421101)Beijing Academy of Artifical Intelligence (BAAI)
文摘In this paper, the model output machine learning (MOML) method is proposed for simulating weather consultation, which can improve the forecast results of numerical weather prediction (NWP). During weather consultation, the forecasters obtain the final results by combining the observations with the NWP results and giving opinions based on their experience. It is obvious that using a suitable post-processing algorithm for simulating weather consultation is an interesting and important topic. MOML is a post-processing method based on machine learning, which matches NWP forecasts against observations through a regression function. By adopting different feature engineering of datasets and training periods, the observational and model data can be processed into the corresponding training set and test set. The MOML regression function uses an existing machine learning algorithm with the processed dataset to revise the output of NWP models combined with the observations, so as to improve the results of weather forecasts. To test the new approach for grid temperature forecasts, the 2-m surface air temperature in the Beijing area from the ECMWF model is used. MOML with different feature engineering is compared against the ECMWF model and modified model output statistics (MOS) method. MOML shows a better numerical performance than the ECMWF model and MOS, especially for winter. The results of MOML with a linear algorithm, running training period, and dataset using spatial interpolation ideas, are better than others when the forecast time is within a few days. The results of MOML with the Random Forest algorithm, year-round training period, and dataset containing surrounding gridpoint information, are better when the forecast time is longer.