The diastereoselective three-component reaction of aldehydes, allyl bromide, and （S）-2-chlorotetrafluoroethancsulfinamide was achieved in the presence of zinc powder and titanium（IV） isopropoxide. Compared to （S...The diastereoselective three-component reaction of aldehydes, allyl bromide, and （S）-2-chlorotetrafluoroethancsulfinamide was achieved in the presence of zinc powder and titanium（IV） isopropoxide. Compared to （S）-tert-butanesulfinamide, the reaction used zinc powder instead of indium and better results were obtained with aromatic aldehydes. Moreover, opposite stereoselectivity is observed.展开更多
基金Project supported by the National Natural Science Foundation of China （No. 20872166）.
文摘The diastereoselective three-component reaction of aldehydes, allyl bromide, and （S）-2-chlorotetrafluoroethancsulfinamide was achieved in the presence of zinc powder and titanium（IV） isopropoxide. Compared to （S）-tert-butanesulfinamide, the reaction used zinc powder instead of indium and better results were obtained with aromatic aldehydes. Moreover, opposite stereoselectivity is observed.
