The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization origi...The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.展开更多
Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericiti...Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.展开更多
Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to cla...Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1) replacement of earlier magnetite by pyrite and carbonaceous material;(2) alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate (mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.展开更多
The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisa...The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.展开更多
The gold mineralization of the Tondabo prospect, located in the northern part of the Oumé-Toumodi-Fettêkro greenstone belt, is mainly hosted in the rhyodacite and to a lesser extent in the mafic volcanics (v...The gold mineralization of the Tondabo prospect, located in the northern part of the Oumé-Toumodi-Fettêkro greenstone belt, is mainly hosted in the rhyodacite and to a lesser extent in the mafic volcanics (volcanic lavas and volcanoclastites). These rocks were affected by a hydrothermal alteration marked by quartz veins and veinlets associated with crystals of carbonates, sericite, epidote and sulfides. This hydrothermal alteration induced a pervasive alteration of the surrounding bodies with silicification, chloritization, carbonation and sericitization of the feldspars. The metalliferous paragenesis contains an abundant pyrite, with rare pyrrhotite and chalcopyrite. This mineralization indicates that the Tondabo gold prospect exhibits lithological control. The mineralized deposits are generally affected by a S1 schistosity oriented mainly N000-010° and minority N040-050° with a general dip of 60°-80°to the West;however with rare N-S orientations with a dip of 60°-80° to the East. The drilling intervals show that the highest gold contents are linked to the quartz-carbonates veins and veinlets, which are located in the highly deformed zones, characterizing local shear zones.展开更多
The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic bel...The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic belt of Urumia-Dokhtar. Rocky outcrops in this area are mainly in two types of volcanic and plutonic. Volcanic Rocks with the age of Eocene are Trachyte to trachyandesite and andesite to basalt-andesite. Plutonic stones with the age of Oligo-Miocene to Miocene are in types of quartz diorite, quartz monzonite, Monzonite and Semi-acidic volcanic domes and granite aplite. Due to having dominant fault systems with trends of NW-SE and NE-SW in an intersectional manner in this area, vein-veinlets Siliciclastic sulfide mineralization can be observed in line with the same faults. Monzonite intrusive rocks are considered as host stone of these mineralizations. The information obtained from field observations and laboratory studies confirms the main alteration along with mineralization in types of silicic and pyrite, sericite, carbonate, argillic and propylitic. Mineralogy Paragenesis in the study area includes Pyrite, chalcopyrite, bornite, colitis, malachite, hematite and goethite and the most important Gang minerals including quartz, calcite, albite, sericite, kaolinite, pyrophyllite, epidote, alunite and jarosite, and according to carried out studies, copper, gold and silver are among mineralizing elements and elements such as molybdenum, cadmium, arsenic and mercury show anomalies as accompanying and guidance elements in some of the samples. The grade of copper in this area in sulfide siliciclastic veins is 1% to 3% and the grade of gold is 130 ppm and the grade of silver is reportable from 0.5 ppm to 6 ppm. Based on the geothermometry studies of fluid inclusions, homogenization temperature from 150°C?to 300°C?and the salinity grade from 4 to 5.5 percent indicate the fact that an epithermal hydrothermal system in final stages controls the mineralization of the area.展开更多
REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized. The Do...REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized. The Dongping gold deposit, which is located in northwestern Hebei Province, China, occurring in the inner contact zone of the Shuiquangou syenite complex, is spatially, and probably genetically, related to the syenite. The deposit was formed under the moderate to high temperature (220℃ to 320℃), weakly acidic to weakly alkaline, rather high f O 2 (lgf O 2=-30 ~- 34) environment. The REE study of the host rocks, altered wall rocks, ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification. The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite. The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages. LREE/HREE ratios in the gangue quartz and hydrothermal K-feldspars are relatively low. The most significant observation is that the gangue quartz shows significant positive Eu anomaly, whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process. Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce. The REE, Y, U, Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins. As the ores were deposited under a rather oxidized environment, Ce 4+ predominated over Ce 3+. The precipitation of the former in the form of CeO 2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks. In contrast, Eu was present mainly in a low valence state (Eu 2+). The geochemical differences from the other REE 3+ and much less sites in the secondary minerals to accommodate the Eu released from the original minerals resulted in the enrichment of Eu in the fluids. The mobility and differentiation of REE and the coherent mobilities of Y, U, Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization. The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.展开更多
The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage miner...The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage mineralization due to shearing, middle-stagemineralization due to hydrothermal alteration, and late-stage mineralization due toweathering, leaching and concentration at shallow depths. Shearing played a dominant role inthe formation of gold orebodies.展开更多
The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted hi...The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.展开更多
基金financially supported by the project of the China Geological Survey(DD20230292,DD20242591)。
文摘The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.
基金co-founded by the National Natural Science Foundation of China(42002090,41930428)National Key Research and Development Program of China(No.2018YFC0604200)+3 种基金Open Research Fund Program of State Key Laboratory of Nuclear Resources and Environment,East China University of Technology(No.NRE1915)Open Research Fund Program of Jiangxi Engineering Laboratory on Radioactive Geoscience and Big Data Technology(JELRGBDT202006)International Geoscience Programme(IGCP675)Jiangxi province graduate student innovation special fund project(YC2019-S271,DHYC-202001)。
文摘Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.
基金jointly supported by the National Key Research and Development Project of China (Grant No.2016YFC0600307)the National Key Basic Research Development Program (973 Program+1 种基金 Grant No.2015CB452606)the fundamental research funds of university teachers(No.53200959708 and No.2-9-2018-126)
文摘Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1) replacement of earlier magnetite by pyrite and carbonaceous material;(2) alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate (mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.
文摘The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.
文摘The gold mineralization of the Tondabo prospect, located in the northern part of the Oumé-Toumodi-Fettêkro greenstone belt, is mainly hosted in the rhyodacite and to a lesser extent in the mafic volcanics (volcanic lavas and volcanoclastites). These rocks were affected by a hydrothermal alteration marked by quartz veins and veinlets associated with crystals of carbonates, sericite, epidote and sulfides. This hydrothermal alteration induced a pervasive alteration of the surrounding bodies with silicification, chloritization, carbonation and sericitization of the feldspars. The metalliferous paragenesis contains an abundant pyrite, with rare pyrrhotite and chalcopyrite. This mineralization indicates that the Tondabo gold prospect exhibits lithological control. The mineralized deposits are generally affected by a S1 schistosity oriented mainly N000-010° and minority N040-050° with a general dip of 60°-80°to the West;however with rare N-S orientations with a dip of 60°-80° to the East. The drilling intervals show that the highest gold contents are linked to the quartz-carbonates veins and veinlets, which are located in the highly deformed zones, characterizing local shear zones.
文摘The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic belt of Urumia-Dokhtar. Rocky outcrops in this area are mainly in two types of volcanic and plutonic. Volcanic Rocks with the age of Eocene are Trachyte to trachyandesite and andesite to basalt-andesite. Plutonic stones with the age of Oligo-Miocene to Miocene are in types of quartz diorite, quartz monzonite, Monzonite and Semi-acidic volcanic domes and granite aplite. Due to having dominant fault systems with trends of NW-SE and NE-SW in an intersectional manner in this area, vein-veinlets Siliciclastic sulfide mineralization can be observed in line with the same faults. Monzonite intrusive rocks are considered as host stone of these mineralizations. The information obtained from field observations and laboratory studies confirms the main alteration along with mineralization in types of silicic and pyrite, sericite, carbonate, argillic and propylitic. Mineralogy Paragenesis in the study area includes Pyrite, chalcopyrite, bornite, colitis, malachite, hematite and goethite and the most important Gang minerals including quartz, calcite, albite, sericite, kaolinite, pyrophyllite, epidote, alunite and jarosite, and according to carried out studies, copper, gold and silver are among mineralizing elements and elements such as molybdenum, cadmium, arsenic and mercury show anomalies as accompanying and guidance elements in some of the samples. The grade of copper in this area in sulfide siliciclastic veins is 1% to 3% and the grade of gold is 130 ppm and the grade of silver is reportable from 0.5 ppm to 6 ppm. Based on the geothermometry studies of fluid inclusions, homogenization temperature from 150°C?to 300°C?and the salinity grade from 4 to 5.5 percent indicate the fact that an epithermal hydrothermal system in final stages controls the mineralization of the area.
文摘REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized. The Dongping gold deposit, which is located in northwestern Hebei Province, China, occurring in the inner contact zone of the Shuiquangou syenite complex, is spatially, and probably genetically, related to the syenite. The deposit was formed under the moderate to high temperature (220℃ to 320℃), weakly acidic to weakly alkaline, rather high f O 2 (lgf O 2=-30 ~- 34) environment. The REE study of the host rocks, altered wall rocks, ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification. The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite. The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages. LREE/HREE ratios in the gangue quartz and hydrothermal K-feldspars are relatively low. The most significant observation is that the gangue quartz shows significant positive Eu anomaly, whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process. Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce. The REE, Y, U, Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins. As the ores were deposited under a rather oxidized environment, Ce 4+ predominated over Ce 3+. The precipitation of the former in the form of CeO 2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks. In contrast, Eu was present mainly in a low valence state (Eu 2+). The geochemical differences from the other REE 3+ and much less sites in the secondary minerals to accommodate the Eu released from the original minerals resulted in the enrichment of Eu in the fluids. The mobility and differentiation of REE and the coherent mobilities of Y, U, Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization. The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.
基金This paper represents partial results of a major project(No,49290100)supported by the National Natural Science Foundation of China.
文摘The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage mineralization due to shearing, middle-stagemineralization due to hydrothermal alteration, and late-stage mineralization due toweathering, leaching and concentration at shallow depths. Shearing played a dominant role inthe formation of gold orebodies.
基金This work is financially supported by the Special Fund for Foreign Mineral Resources Risk Exploration(201210B01600234).
文摘The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.