The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon elect...The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon electronic packaging materials to meet the needs of aviation,aerospace,and electronic packaging fields.We used the powder metallurgy method and high-temperature hot pressing technology to prepare SiC/Al-Si composite materials with different SiC contents(5vol%,10vol%,15vol%,and 20vol%).The results showed that as the SiC content increased,the tensile strength of the composite material first increased and then decreased.The tensile strength was the highest when the SiC content was 15%;the sintering temperature significantly affected the composite material’s structural density and mechanical properties.Findings indicated 700℃was the optimal sintering and the optimal SiC content of SiC/Al-Si composite materials was between 10%and 15%.Besides,the sintering temperature should be strictly controlled to improve the material’s structural density and mechanical properties.展开更多
Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the...Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the addition of additive AlF_(3)(0,0.5%,1.0%,1.5%,2.0%and 2.5%,by mass)on the phase composition and the microstructure of the synthesized products were investigated.The results show that:(1)ZrB_(2)-ZrO_(2)-SiC composite powder can be synthesized by carbothermal reduction at 1500℃in flowing argon atmosphere;ZrB_(2) and ZrO_(2) are granular-like,and SiC crystals are fiberous;(2)with the soaking time increasing,the amount of ZrB_(2) increases,the amounts of m-ZrO_(2) and SiC decrease,and the total amount of non-oxides ZrB_(2),SiC and ZrC gradually increases;the optimal soaking time is 3 h;(3)compared with the sample without AlF_(3),the sample with 0.5% AlF_(3) has decreased m-ZrO_(2)amount,noticeably increased ZrB_(2) amount but decreased SiC amount;however,when the addition of AlF_(3) increases from 0.5%to 2.5%,the m-ZrO_(2) amount increases,the ZrB_(2)amount decreases,and the SiC amount changes slightly;the optimum AlF_(3)addition is 0.5%.展开更多
Al2O3-SiC-C specimens were prepared using white fused corundum （3-1,≤1 and ≤0.044 mm）,Al2O3-SiC composite powders （d50 ≤ 5 μm）,α-Al2O3 micropowder （d50 =1.2 μm）,SiC powder （≤ 0.044 mm）,flake graphite （...Al2O3-SiC-C specimens were prepared using white fused corundum （3-1,≤1 and ≤0.044 mm）,Al2O3-SiC composite powders （d50 ≤ 5 μm）,α-Al2O3 micropowder （d50 =1.2 μm）,SiC powder （≤ 0.044 mm）,flake graphite （≤ 0.088 mm）,Si powder （d50 =42.8 μm） and B4C powder （d50 ≤10 μm） as main starting materials,and thermosetting phenolic resin as binder.4%,8%,12% and 16% （in mass,the same hereinafter） of Al2O3-SiC composite powders substituted the same quantity of α-Al2O3 micropowder ＋ SiC powder.Effects of composite powder additions on apparent porosity,bulk density,cold modulus of rupture,cold crushing strength,hot modulus of rupture （1 400 ℃）,thermal shock resistance （1 100 ℃,water quenching） and oxidation resistance （1 000 and 1 500 ℃） of Al2O3-SiC -C specimens after 180 ℃ curing,1 000 ℃ 3 h carbon-embedded firing and 1 500 ℃ 3 h carbon-embedded firing,respectively,were researched.The results indicate that：（1） with the increase of Al2O3-SiC composite powder,cold strengths of the cured specimens decline,those of the specimens fired at 1 000 ℃ change a little,and those of the specimens fired at 1 500 ℃ change a little except for an obvious improvement of cold crushing strength ; （2） with the increase of Al2O3-SiC composite powder,hot modulus of rupture at 1 400 ℃ decreases and thermal shock resistance enhances significantly; （3） when Al2O3-SiC composite powder addition is 4%,the oxidation resistance at 1 500 ℃ is the best,and the reason may be the composite powder is finer and more active,which is beneficial to form dense mullite protective layer to retard the O2 diffusion into the specimens.展开更多
In order to improve oxidation resistance and ther- mal shock resistance of Al2O3-C refractories, two groups of specimens were prepared with phenolic resin as binder, adding 0, 2 wt% , 4 wt% and 6 wt% commercial SiC or...In order to improve oxidation resistance and ther- mal shock resistance of Al2O3-C refractories, two groups of specimens were prepared with phenolic resin as binder, adding 0, 2 wt% , 4 wt% and 6 wt% commercial SiC or ZrO2-SiC composite powder synthesized from zircon respectively to Al2O3- C refractories, pressing at 200 MPa, drying fully at 250℃, and then carbon embedded firing at 1400℃ for 2 h. Oxidation resistance and thermal shock resistance were researched, phase composition was analyzed by XRD. The results showed that the oxidation of SiC in additives could protect carbon in specimens effectively and thus decreased the mass loss ratio and oxidation area, and improved the oxidation resistance of the specimen. Thermal shock resistance was improved owing to the micro crack toughening of ZrO2 and grain toughening of SiC. In this experiment, the specimens with 6 wt% ZrO2 -SiC composite powder or 6 wt% SiC powder had the best oxidation resistance and thermal shock resistance.展开更多
Nanocrystalline tungsten carbide-cobalt (WC-Co) composite powders produced through spray thermal decomposition-continuous reduction and carburization technology were used to prepare φ3.25 mm×38 mm ultrafine tung...Nanocrystalline tungsten carbide-cobalt (WC-Co) composite powders produced through spray thermal decomposition-continuous reduction and carburization technology were used to prepare φ3.25 mm×38 mm ultrafine tungsten carbide-cobalt (WC-Co) cemented carbide rods through vacuum sintering plus sinterhip technology. The microstructure, Vickers hardness, density and Rockwell A hardness (HRA), transverse rupture strength (TRS), saturated magnetization and coercivity force were tested. The results show that the average grain size of the sintering body prepared through vacuum sintering plus sinterhip technology was 430 nm; transverse rupture strength (TRS) was 3850 MPa; Vickers hardness was 1890 and Rockwell A hardness of sintering body was 93. High strength and high hardness ultrafine WC-Co cemented carbide rods used to manufacture printed circuit board (PCB) drills were obtained.展开更多
The Al2O3 -SiC composite powders were prepared in argon atmosphere rising coal gangue and carbonaceous materials （ carbon black, active carbon and antbravite） as starting materials by carbothermal reduction. Effects...The Al2O3 -SiC composite powders were prepared in argon atmosphere rising coal gangue and carbonaceous materials （ carbon black, active carbon and antbravite） as starting materials by carbothermal reduction. Effects of excessive carbon addition, carbon types. temperature, soaking time. shaping pressure, types and amount of additives on phase composition and micro-structure of the Al2O3 - SiC composite powders were investigated. The re.suits indicate that： temperature, soaking time and chloride additi＇ve have significant influence on the synthesized Al2O3 -SiC composite powders. Based on the results, the optimized Al2O3 -SiC composite powders , Al2O3 58 mass% and SiC 42 mass%, with particle size d50 ≤5μm were prepared using coal gangue and carbon black as starting materials after 3 h firing at 1550 ℃. and proper additive addition could reduce the temperattlre by 50 ℃.展开更多
文摘The objective of this study is to improve the mechanical properties and machining performance of high thermal conductivity and low expansion silicon carbide dispersion-strengthened hypereutectic aluminum-silicon electronic packaging materials to meet the needs of aviation,aerospace,and electronic packaging fields.We used the powder metallurgy method and high-temperature hot pressing technology to prepare SiC/Al-Si composite materials with different SiC contents(5vol%,10vol%,15vol%,and 20vol%).The results showed that as the SiC content increased,the tensile strength of the composite material first increased and then decreased.The tensile strength was the highest when the SiC content was 15%;the sintering temperature significantly affected the composite material’s structural density and mechanical properties.Findings indicated 700℃was the optimal sintering and the optimal SiC content of SiC/Al-Si composite materials was between 10%and 15%.Besides,the sintering temperature should be strictly controlled to improve the material’s structural density and mechanical properties.
基金supported by National Natural Science Foundation of China(52172031 and 51872266)Henan Provincial Science and Technology Research Project(222102230030).
文摘Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the addition of additive AlF_(3)(0,0.5%,1.0%,1.5%,2.0%and 2.5%,by mass)on the phase composition and the microstructure of the synthesized products were investigated.The results show that:(1)ZrB_(2)-ZrO_(2)-SiC composite powder can be synthesized by carbothermal reduction at 1500℃in flowing argon atmosphere;ZrB_(2) and ZrO_(2) are granular-like,and SiC crystals are fiberous;(2)with the soaking time increasing,the amount of ZrB_(2) increases,the amounts of m-ZrO_(2) and SiC decrease,and the total amount of non-oxides ZrB_(2),SiC and ZrC gradually increases;the optimal soaking time is 3 h;(3)compared with the sample without AlF_(3),the sample with 0.5% AlF_(3) has decreased m-ZrO_(2)amount,noticeably increased ZrB_(2) amount but decreased SiC amount;however,when the addition of AlF_(3) increases from 0.5%to 2.5%,the m-ZrO_(2) amount increases,the ZrB_(2)amount decreases,and the SiC amount changes slightly;the optimum AlF_(3)addition is 0.5%.
文摘Al2O3-SiC-C specimens were prepared using white fused corundum （3-1,≤1 and ≤0.044 mm）,Al2O3-SiC composite powders （d50 ≤ 5 μm）,α-Al2O3 micropowder （d50 =1.2 μm）,SiC powder （≤ 0.044 mm）,flake graphite （≤ 0.088 mm）,Si powder （d50 =42.8 μm） and B4C powder （d50 ≤10 μm） as main starting materials,and thermosetting phenolic resin as binder.4%,8%,12% and 16% （in mass,the same hereinafter） of Al2O3-SiC composite powders substituted the same quantity of α-Al2O3 micropowder ＋ SiC powder.Effects of composite powder additions on apparent porosity,bulk density,cold modulus of rupture,cold crushing strength,hot modulus of rupture （1 400 ℃）,thermal shock resistance （1 100 ℃,water quenching） and oxidation resistance （1 000 and 1 500 ℃） of Al2O3-SiC -C specimens after 180 ℃ curing,1 000 ℃ 3 h carbon-embedded firing and 1 500 ℃ 3 h carbon-embedded firing,respectively,were researched.The results indicate that：（1） with the increase of Al2O3-SiC composite powder,cold strengths of the cured specimens decline,those of the specimens fired at 1 000 ℃ change a little,and those of the specimens fired at 1 500 ℃ change a little except for an obvious improvement of cold crushing strength ; （2） with the increase of Al2O3-SiC composite powder,hot modulus of rupture at 1 400 ℃ decreases and thermal shock resistance enhances significantly; （3） when Al2O3-SiC composite powder addition is 4%,the oxidation resistance at 1 500 ℃ is the best,and the reason may be the composite powder is finer and more active,which is beneficial to form dense mullite protective layer to retard the O2 diffusion into the specimens.
文摘In order to improve oxidation resistance and ther- mal shock resistance of Al2O3-C refractories, two groups of specimens were prepared with phenolic resin as binder, adding 0, 2 wt% , 4 wt% and 6 wt% commercial SiC or ZrO2-SiC composite powder synthesized from zircon respectively to Al2O3- C refractories, pressing at 200 MPa, drying fully at 250℃, and then carbon embedded firing at 1400℃ for 2 h. Oxidation resistance and thermal shock resistance were researched, phase composition was analyzed by XRD. The results showed that the oxidation of SiC in additives could protect carbon in specimens effectively and thus decreased the mass loss ratio and oxidation area, and improved the oxidation resistance of the specimen. Thermal shock resistance was improved owing to the micro crack toughening of ZrO2 and grain toughening of SiC. In this experiment, the specimens with 6 wt% ZrO2 -SiC composite powder or 6 wt% SiC powder had the best oxidation resistance and thermal shock resistance.
基金This work was supported by open foundation of State Key Laboratory of Advanced Technology for Materials Synthesis&Processing,Wuhan University of Technology under grant No.200301126the Postdoctoral Science Foundation of China under grant No.2003034504the Chinese 863 programme under grant No.2002A A302504.
文摘Nanocrystalline tungsten carbide-cobalt (WC-Co) composite powders produced through spray thermal decomposition-continuous reduction and carburization technology were used to prepare φ3.25 mm×38 mm ultrafine tungsten carbide-cobalt (WC-Co) cemented carbide rods through vacuum sintering plus sinterhip technology. The microstructure, Vickers hardness, density and Rockwell A hardness (HRA), transverse rupture strength (TRS), saturated magnetization and coercivity force were tested. The results show that the average grain size of the sintering body prepared through vacuum sintering plus sinterhip technology was 430 nm; transverse rupture strength (TRS) was 3850 MPa; Vickers hardness was 1890 and Rockwell A hardness of sintering body was 93. High strength and high hardness ultrafine WC-Co cemented carbide rods used to manufacture printed circuit board (PCB) drills were obtained.
文摘The Al2O3 -SiC composite powders were prepared in argon atmosphere rising coal gangue and carbonaceous materials （ carbon black, active carbon and antbravite） as starting materials by carbothermal reduction. Effects of excessive carbon addition, carbon types. temperature, soaking time. shaping pressure, types and amount of additives on phase composition and micro-structure of the Al2O3 - SiC composite powders were investigated. The re.suits indicate that： temperature, soaking time and chloride additi＇ve have significant influence on the synthesized Al2O3 -SiC composite powders. Based on the results, the optimized Al2O3 -SiC composite powders , Al2O3 58 mass% and SiC 42 mass%, with particle size d50 ≤5μm were prepared using coal gangue and carbon black as starting materials after 3 h firing at 1550 ℃. and proper additive addition could reduce the temperattlre by 50 ℃.
