Corrosion behavior of co-gasification slag of furfural residue and coal on alumina-silica refractories

Gasification of furfural residue with coal can realize its efficient and clean utilization.But the high alkali metal content in furfural slag is easy to cause the corrosion of gasifier refractory.Two gasification coals with different silica alumina ratio and a furfural residue were selected in the study.The effects of furfural residue additions on corrosion of silica brick,corundum brick,high alumina brick and mullite brick were investigated by using XRD,SEM-EDS and Factsage Software,and the corrosion mechanism was analyzed.With increasing furfural residue addition,the permeability of the slags to high-aluminium-bearing refractories first decreases and then increases,while the permeability on silica brick shows a slight decrease trend.Leucite(KAlSi_(2)O_(6))with high-melting temperature is generated from the reaction of K_(2)O and SiO_(2)in slag with Al_(2)O_(3)in refractories after furfural residue is added,which hinders the infiltration of slag in refractories.Kaliophilite(KAlSiO_(4))of low-melting point is formed when K_(2)O content increases,and this contributes to the infiltration of slag in refractories.The acid-base reaction between slag and silica brick is distinctly occurred,more slag reacts with SiO_(2)in the silicon brick,resulting in a decrease in the amount of slag infiltrating into the silicon brick as furfural residue is added.The corrosion of silica brick is mainly caused by the acid-base reaction,while the corrosion of three alumina based refractory bricks of corundum,mullite and high alumina brick is determined by slag infiltration.A linear correlation between the percolation rate and slag viscosity is established,the slag permeability increases with decreasing viscosity,resulting in stronger permeability for the high Si/Al ratio slag with lower viscosity.

Investigation of Microstructure and Phase Composition of Chromic Oxide, AZS/Cr and High-alumina Refractories after Exposure of Basalt and Aluminaboronsilicate Glasses Melts

The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been studied.The mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic analysis.On the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.

The 9^(th) International Symposium on Refractories

Organizedby The Chinese Society for Metals The Chinese Ceramic Society Sinosteel Luoyang Institute of Refractories Research Co.,Ltd.Sponsored by Refractories Committee of The Chinese Society for Metals Sinosteel Luonai Materials Technology Corporation Co-Sponsoredby State Key Laboratory of Advanced Refractories The State Key Laboratory of Refractories and Metallurgy Refractories Press Indian Refractory Makers Association The Federation for International Refractory Research and Education.

Microwave-assisted Synthesis of Al_(4)SiC_(4) and Its Effect on Properties of MgO-C Refractories

Al_(4)SiC_(4) was synthesized from Al powder, silicon carbide, and graphite by microwave sintering, and characterized by XRD and SEM. Then the synthesized material was added to the magnesia carbon refractory brick to study its effect on the oxidation resistance, apparent porosity, bulk density, elastic modulus, and modulus of rupture. It is found that Al_(4)SiC_(4) can be synthesized by microwave sintering at 1 300 ℃ and the addition of Al_(4)SiC_(4)-containing material as an antioxidant can enhance the oxidation resistance of the magnesia carbon refractory brick.

Effect of ZrC Modified Graphite on Structure and Properties of Low-carbon Al_(2)O_(3)-C Refractories

To address the issues of reduced performance and shortened lifespan during the low-carbonizating process of Al_(2)O_(3)-C refractories,nano-crystalline ZrC modified graphite was prepared using Zr powder and flake graphite as raw materials,with NaCl and NaF mixed salt serving as the medium.The flake graphite was gradually replaced by ZrC modified graphite in the preparation of Al_(2)O_(3)-C refractories,and its impact on the material’s structure and properties was investigated.The results indicate that,compared to samples with only flake graphite,the introduction of 1 mass%to 5 mass%nano-crystalline ZrC modified graphite can significantly enhance the mechanical performance of low-carbon Al_(2)O_(3)-C refractories.When 5 mass%ZrC modified graphite is added,the mechanical properties of the samples are optimal,with the cold modulus of rupture and elastic modulus reaching 22.5 MPa and 65.0 GPa,respectively.

Effects of Al_(2)O_(3)-SiO_(2) Raw Material Types on Properties of Anorthite Based Insulation Refractories

To optimize their Al_(2)O_(3)-SiO_(2) raw materials,anorthite based insulation refractories were prepared by the in-situ sintering process combined with the foaming method after sintering at 1350℃for 3 h,using green and pollution-free kaolin,kyanite,andalusite and sillimanite as Al_(2)O_(3)-SiO_(2) raw materials,respectively,and industrial CaCO_(3) as the CaO source.Effects of Al_(2)O_(3)-SiO_(2) raw material types on the physical properties,phase composition and microstructure were investigated.The results are as follows.All samples prepared by different Al_(2)O_(3)-SiO_(2) raw materials have hexagonal flake anorthite and a small amount of mullite and corundum.Their bulk density and thermal conductivity decrease in the order of using kaolin,andalusite,kyanite and sillimanite as the Al_(2)O_(3)-SiO_(2) raw material,but their apparent porosity increases.Moreover,in the sample with kaolin,the bonding between anorthite crystals on the pore walls is closer than that of the other samples,which is conducive to increasing the cold crushing strength.The bonding between anorthite crystals on pore walls gradually decreases in the order of using kyanite,andalusite and sillimanite as the Al_(2)O_(3)-SiO_(2) raw material,thus their cold crushing strength decreases accordingly.In comprehensive consideration,the properties of the sample from kyanite are the optimal.Its apparent porosity,thermal conductivity and cold crushing strength are 84.6%,0.141 W·m^(-1)·K^(-1) and 1.89 MPa,respectively.

Risk stratification for radioactive iodine refractoriness using molecular alterations in distant metastatic differentiated thyroid cancer

Objective: Patients with radioactive iodine-refractory differentiated thyroid cancer(RAIR-DTC) are often diagnosed with delay and constrained to limited treatment options. The correlation between RAI refractoriness and the underlying genetic characteristics has not been extensively studied.Methods: Adult patients with distant metastatic DTC were enrolled and assigned to undergo next-generation sequencing of a customized 26-gene panel(Thyro Lead). Patients were classified into RAIR-DTC or non-RAIR groups to determine the differences in clinicopathological and molecular characteristics. Molecular risk stratification(MRS) was constructed based on the association between molecular alterations identified and RAI refractoriness, and the results were classified as high, intermediate or low MRS.Results: A total of 220 patients with distant metastases were included, 63.2% of whom were identified as RAIRDTC. Genetic alterations were identified in 90% of all the patients, with BRAF(59.7% vs. 17.3%), TERT promoter(43.9% vs. 7.4%), and TP53 mutations(11.5% vs. 3.7%) being more prevalent in the RAIR-DTC group than in the non-RAIR group, except for RET fusions(15.8% vs. 39.5%), which had the opposite pattern. BRAF and TERT promoter are independent predictors of RAIR-DTC, accounting for 67.6% of patients with RAIR-DTC. MRS was strongly associated with RAI refractoriness(P<0.001), with an odds ratio(OR) of high to low MRS of 7.52 [95%confidence interval(95% CI), 3.96-14.28;P<0.001] and an OR of intermediate to low MRS of 3.20(95% CI,1.01-10.14;P=0.041).Conclusions: Molecular alterations were associated with RAI refractoriness, with BRAF and TERT promoter mutations being the predominant contributors, followed by TP53 and DICER1 mutations. MRS might serve as a valuable tool for both prognosticating clinical outcomes and directing precision-based therapeutic interventions.

Abstracts Selectedfrom Naihuo Cailiao(Refractories)——A Bimonthly in Chinese

Research progress on hydration resistance of magnesia-calcia refractories/Huang Ren,Li Kezhuo,Xie Houbo,Gao Ruihong,Huang Zhong,Zhang Haijun,Zhang Shaowei//Naihuo Cailiao.-2022,56(4):277Abstract:Magnesia-calcia refractories are widely used in the iron and steel smelting industry because of their advantages of steel liquid purification,high refractoriness,good thermal shock resistance and high corrosion resistance in basic slag.However,MgO and CaO usually hydrate in the process of manufacturing.

Abstracts Selectedfrom Naihuo Cailiao (Refractories)--A Bimonthly in Chinese

Preparation of lightweight insulation materials from forsterite and fly ash cenesphere/Xie Zhe,Deng Chengji,Dong Bo,Ding Jun,Zhu Hongxi,Zhou Nian,Yu Chao//Naihuo Callao-202256(5);:369 Abstract:In order to reduce the raw material cost and the sintering temperature,lightweight insulation materials were fabricated using forsterite and fly ash cenesphere as main raw materials,and borax as the texturizer,heat treating at 800。C for 1 h.The influence of the borax addition(5%,10%,20%and 30%,by mass)on the phase.composition,the microstructure,and the properties of the materials was studied.

Call for Papers of ISR2024 The 9th International Symposium on Refractories

International Symposium on Refractories(ISR)is a serial international symposium and has been held successfully for eight sessions:the 1^(st)(ISR1988)in Hangzhou,the 2^(nd)(ISR1992)in Beijing,the 3^(rd)(ISR1998)in Beijing,the 4^(th)(ISR2003)in Dalian,the 5^(th)(ISR2007)in Beijing.

Steam Oxidation Resistance Comparison of Several Silicon Carbide Refractories at Elevated Temperatures

The oxidation tests of different SiC refractories including Si3N4-SiC bricks,Si3N4-Si2N2O-SiC bricks from China(SNO-1),Si3N4-Si2N2O-SiC bricks from overseas(SNO-2),SiAlON-SiC bricks,oxides bonded SiC bricks,self-bonded SiC bricks as well as SiC castables were carried out in the steam atmosphere(1 000 ℃,32 kg·m-3·h-1)for different durations(100,200,300,400 and 500 h).The mass,the volume,the bulk density and the apparent porosity before and after the oxidation were tested.The XRD and SEM analyses were conducted.The results indicate that:(1)under the steam atmosphere condition(1 000 ℃,32 kg·m-3·h-1),as the oxidation time increases from 0 to 500 h,the volume and the mass of the silicon carbide refractories increase,while the bulk density decreases;in terms of the apparent porosity,oxides bonded SiC bricks and SiC castables present an increasing trend,Si3N4-SiC bricks,SiAlON-SiC bricks and self-bonded SiC bricks present an increasing trend first and then a decreasing trend,and Si3N4-Si2N2O-SiC bricks present a decreasing trend or a trend of decreasing first and then increasing;(2)as for Si3N4-Si2N2O-SiC bricks,SNO-1 and SNO-2 have basically the same chemical and phase composition,SNO-2 has the lower mass change rate than SNO-1 during oxidation from 200-500 h,which indicates that SNO-2 has the better steam oxidation resistance than SNO-1.

Effect of Ferric Nitrate Loading Mode on Properties of Si_(3)N_(4) Composite MgO-C Refractories Prepared by Nitridation

In order to investigate the effect of the catalyst loading mode on the mechanical properties of Si_(3)N_(4) composite MgO-C refractories prepared by nitridation,fused magnesia,flake graphite,silicon powder,and phenolic resin were used as the main raw materials,and ferric nitrate as the catalyst to prepare refractories by nitriding at 1350℃.The effects of different catalyst supports(silicon powder,silicon powder+phenolic resin)on the formation of Si_(3)N_(4) in MgO-C refractories and the properties of refractories were studied.The results show that the silicon powder+resin catalyst support promotes the participation ofα-Si_(3)N_(4) in the reaction to generateβ-Si_(3)N_(4) and MgSiN_(2),and generates more SiC.However,this loading mode causes more gas to escape from the refractories and loosens the material structure,which reduces the mechanical properties.On the contrary,MgO-C refractories prepared by nitridation with silicon powder-supported catalysts under the same conditions show higher density and better mechanical properties.

Effect of Al Powder and Si Powder Additions on Structure and Properties of Unburned Magnesium Aluminate Spinel Refractories

Unburned magnesium aluminate spinel refractories were prepared using sintered magnesium aluminate spinel as the main raw material,phenolic resin as the binder,aluminum powder(2%,4%,and 6%by mass)and silicon powder(when Al powder addition is 4%,Si powder addition varies:1%and 2%,by mass)as additives.The effects of the Al powder and Si powder additions on the properties and microstructure of the refractories heat treated at different temperatures(1000,1400,and 1600℃for 3 h)were studied.The results show that the Al powder addition can greatly enhance the cold modulus of rupture of the samples fired at 1000 or 1400℃,and meanwhile AlN reinforcement phase forms in the matrix,which greatly improves the hot modulus of rupture of the samples at 1400℃;however,the heat treatment at 1600℃has little influence on the strength;the addition of Al powder and Si powder results in the formation of low melting point phases,greatly reducing the hot modulus of rupture.However,the low melting point phases promote sintering,which enhances the density and the cold modulus of rupture,and decreases the volume change during heating.The samples added with Al and Si all have higher cold modulus of rupture than those added with Al powder only.

Identification of the key genes and mechanisms associated with transcatheter arterial chemoembolisation refractoriness in hepatocellular carcinoma

BACKGROUND Transcatheter arterial embolisation(TACE)is the primary treatment for intermediate-stage hepatocellular carcinoma(HCC)patients while some HCC cases have shown resistance to TACE.AIM To investigate the key genes and potential mechanisms correlated with TACE refractoriness in HCC.METHODS The microarray datasets of TACE-treated HCC tissues,HCC and non-HCC tissues were collected by searching multiple public databases.The respective differentially expressed genes(DEGs)were attained via limma R package.Weighted gene co-expression network analysis was employed for identifying the significant modules related to TACE non-response.TACE refractoriness-related genes were obtained by intersecting up-regulated TACE-associated and HCC-associated DEGs together with the genes in significant modules related to TACE nonresponse.The key genes expression in the above two pairs of samples was compared respectively via Wilcoxon tests and standard mean differences model.The prognostic value of the key genes was evaluated by Kaplan-Meier curve.Multivariate analysis was utilised to investigate the independent prognostic factor in key genes.Single-cell RNA(scRNA)sequencing analysis was conducted to explore the cell types in HCC.TACE refractoriness-related genes activity was calculated via AUCell packages.The CellChat R package was used for the investigation of the cell–cell communication between the identified cell types.RESULTS HCC tissues of TACE non-responders(n=66)and TACE responders(n=81),HCC(n=3941)and non-HCC(n=3443)tissues were obtained.The five key genes,DLG associated protein 5(DLGAP5),Kinesin family member 20A(KIF20A),Assembly factor for spindle microtubules(ASPM),Kinesin family member 11(KIF11)and TPX2 microtubule nucleation factor(TPX2)in TACE refractoriness-related genes,were identified.The five key genes were all up-regulated in the TACE non-responders group and the HCC group.High expression of the five key genes predicted poor prognosis in HCC.Among the key genes,TPX2 was an independent prognostic factor.Four cell types,hepatocytes,embryonic stem cells,T cells and B cells,were identified in the HCC tissues.The TACE refractoriness-related genes expressed primarily in hepatocytes and embryonic stem cells.Hepatocytes,as the providers of ligands,had the strongest interaction with embryonic stem cells that provided receptors.CONCLUSION Five key genes(DLGAP5,KIF20A,ASPM,KIF11 and TPX2)were identified as promoting refractory TACE.Hepatocytes and embryonic stem cells were likely to boost TACE refractoriness.

Major Trends in Refractories Industry at the Beginning of the 21^(st) Century

An analysis of the present and of the future of the refractories industry is being presented , considering some important technical, economical, human and environmental issues , on a worldwide basis. Refractories are still neededas confinement materials to prevent heat and mass transferlosses in many diverse manufacturing industries , and will remain so , but the main challenges , this industry do needto meet, are to adjust to an overcapacity production , to cope with new needs of the customers , in particular the'outsourcing' , which is a new customer / supplier relationship being adopted by many of them, and to keep the research and development alive in a more and more competitive arena. Among the direct consequences , are the need to keep the education world in refractory engineering training alive and to cope with macro and micro projects to change the image of the Refractories , from a commodity material to a sophisticated 'high-tech' composite material . Some suggestions are provided in the text.

Reactive wetting phenomena of MgO-C refractories in contact with CaO-SiO_2 slag

Wetting phenomena between MgO C and CaO SiO2 slags were investigated by varying carbon content.A sessile drop technique was adopted to study the wetting phenomena in conjunction with a high speed camera for the observation of intrinsic wetting phenomena.The results show that the high content of SiO2 and the presence of Al2O3 in slags enhance the diffusion of Mg2+,leading to the promotion of reactive wetting.The carbon in MgO C refractory impedes the penetration of slags by repelling the slag and slowing the diffusion of Mg2+.This accounts for the non-wetting behavior of the slag on MgO C refractory with 17% (mass fraction) carbon similar to that of graphite.

Effect of Heat Treatment Temperature on Properties of Chinese Calcined Flint Clay Based Plastic Refractories

Effects of different heat treatment temperatures on properties of Chinese calcined flint clay based plastic refractories were investigated using Chinese calcined flint clay as starting material, aluminum sulfate and fireclay as binding system. The results showed that with temperature rising, Chinese calcined flint clay based plastic refractories shrinked firstly and then expanded. The modulus of rupture （MOR） and the cold crushing strength （CCS） inereased firstly and then decreased from 110 ℃ to 600 ℃ , then increased obviously. Thermal expansion coefficient increased from 110 ℃ to 760 ℃, decreased from 760 ℃ to 1 300 ℃ , and increased from 1 300 ℃ to1500 ℃.

Current Situation and Development of Refractories for Clean Steel Production

The low cost and high efficient clean steels metallur- gy has been focused much attention in China. Among the factors affecting the cleanliness and consequent quali- ty of steel products, refractories are one of the key fac- tors. Meanwhile the restriction of resource, energy and environment is getting stronger, thus the improvement of refractories becontes much more important. In this paper, refractories selection principle Jbr clean steel production according to their thermodynamic features was ex- plained; refractories for tundLsh and flow control in con- tinuous casting, which play important roles in prohibi- ring secondary contamination of molten steel, were intro- duced. Moreover, new development of low-carbon and carbon-free refractory materials was also described.

AI_4C_3 Hydration Thermochemical Analysis for Burned Carbon-containing Refractories with Al

In this paper, X-ray diffractogram analysis and SEM observation of Al$ C$ formed at high temperature from carbon-containing refractories ivith Al have been carried out. Aluminum added to carbon-containing refractories reacts with C（s） to form Al^ C^（s） gradually during heating from 600 ’C to 1200^0 . It is considered that the interlocked structure of Al^ C-$ plate crystals promotes the outstanding increase of hot modulus of rupture of carbon-containing refractories with Al. The HMOR of carbon-containing refractories added with Al additive from 0 to 5wt% increases by 2.8 times being from 6.5MPa to 18.2MPa. After a thermochemical calculation for hydration reaction processes ofAl^C^ and H^O （g）, the equilibrium partial pressure chart ofH^O （g） in H^O-A^C^-Al^ OH)} system vs various temperatures has been attained . The H2 0 （g） partial pressure in the air needed for the Al^ C3 hydration reaction is no more than 10;18 atm at the temperature below 120t . It is considered that the burned carbon-containing re

Highlights of Recent Advances in Refractories for Iron and Steel Industry in China

Recently procured outstanding achievements in iron and steel industry in China are presented by data or facts in steel output, energy consumption, technical and economical indicators and advanced technologies that are being adopted. The latest achievements in refractonries for this biggest user industry are reviewed, covering new refractories for CDQ coke oven, BF hearth, AOD Lining, long life tundish, SEN for clean steel making and regenerative reheating furnace . The reciprocal relationship is obvious that the rapid development of iron and steel industry has given an impetus to the advance of refractories industry, which in return has contributed greatly to the former.