ATH/ADP配比对EVA阻燃性能及机理转变的影响

针对氢氧化铝(ATH)在对乙烯-醋酸乙烯酯共聚物(EVA)阻燃效率低的问题,将二乙基次磷酸铝(ADP)和ATH复配,用以提高EVA阻燃性能。本研究采用垂直燃烧(UL-94)、极限氧指数(LOI)和锥形量热仪(CONE)对材料的阻燃性能进行研究。结果表明,和EVA/ATH复合材料相比,当ATH和ADP质量比为2∶1和1∶2时,垂直燃烧等级均从无等级提高到V-0级,LOI分别从34.5%提高到37.8%和42.8%。通过不同测试方法对以上两种配比的样品进行阻燃机理分析。结果表明,在ATH和ADP质量比为2:1的样品中,热分解释放的含磷化合物含量较低,而且形成的磷酸铝(AlPO4)促使炭层更致密连续,热分解产生的残炭量高于理论值,因此该配比下阻燃机理以凝聚相为主导。在ATH和ADP质量比为1∶2的样品中,炭层孔洞较多,热分解产生的残炭量低于理论值,但气相产物中出现较多含磷化合物,因此该配比下阻燃机理以气相主导。

CHITOSAN FOR ENHANOEMENT OF ANTACID ABILITY OF PHARMAOEUTICAL ALUMINUM HYDROXIDE:IN VITRO STUDIES

In this paper, the antacid ability of chitosan/aluminum hydroxide mixture granules was investigated in vitro. It is found that chitosan can not only improve acidneutralizing rate of pharmaceutical aluminum hydroxide, but also elevate its acidconsuming capacity. But in alkaline, chitosan can depress the reaction of aluminum hydroxide with alkaline.

协效阻燃剂对mPE-LLD/ATH/MH复合材料性能影响

为提高茂金属线型低密度聚乙烯(mPE-LLD)的阻燃和综合力学性能,以乙烯-辛烯共聚物(POE)和乙烯-乙酸乙烯酯共聚物(EVAC)为增韧剂,马来酸酐接枝线型低密度聚乙烯(PE-LLD-g-MAH)为增容剂,氢氧化铝/氢氧化镁(ATH/MH)为主阻燃剂,滑石粉(Talc)和硼酸锌(ZB)为协效阻燃剂,通过熔融共混制备mPE-LLD阻燃复合材料。采用极限氧指数(LOI)、垂直燃烧试验、热重和拉伸试验,研究了mPE-LLD/ATH/MH和mPE-LLD/Talc/ZB/ATH/MH复合材料的热稳定性、阻燃和力学性能,并与mPE-LLD/磷氮阻燃剂(PN)/纳米蒙脱土(nano-OMMT)复合材料的性能进行了比较。研究表明:固定阻燃剂(ATH,MH,ZB,Talc)总质量分数为60%,用质量分数为12%的Talc/ZB替代ATH/MH,使复合材料的拉伸强度略有下降,断裂伸长率提高;Talc/ZB质量比为1∶1,复合材料的断裂伸长率提高了50.2%,复合材料的拉伸强度(9.7 MPa)和断裂伸长率(294.0%)高于mPE-LLD/60%(PN/nano-OMMT);Talc/ZB质量比由5∶1降至1∶5,复合材料的600℃质量保持率和热稳定性提高,高于mPE-LLD/60%(ATH/MH)。Talc/ZB质量比为5∶1时,mPE-LLD/60%(Talc/ZB/ATH/MH)的LOI值(31.6%)高于mPE-LLD/60%(PN/nano-OMMT)的LOI值(30.8%)和mPE-LLD/70%(ATH/MH)的LOI值(30.7%),Talc/ZB和ATH/MH具有协同阻燃性。

Adsorption behavior of condensed phosphate on aluminum hydroxide

Sodium pyrophosphate （pyro-P, Na4P2OT）, sodium tripolyphosphate （tripoly-P, Na3P3O10）, and sodium hexametaphosphate （meta-P, （NaPO3）6） were selected as the model compounds of condensed phosphate to investigate the adsorption behavior of condensed phosphate on aluminum hydroxide. The adsorption was found to be endothermic and divisible into two stages： （1） fast adsorption within 1 h; and （2） slow adsorption between 1 and 24 h. The modified Freundlich model simulated the fast adsorption stage well; the slow adsorption stage was described well by the first-order kinetics. The activation energies of pyro-P, tripoly-P, and meta-P adsorption on aluminum hydroxide were determined to be 20.2, 22.8 and 10.9 kJ/mol P adsorbed, respectively, in the fast adsorption stage and to be 66.3, 53.5 and 72.5 kJ/mol P adsorbed, respectively, in the slow adsorption stage. The adsorption increased the negative charge of the aluminum hydroxide surface. Transmission electron microscopy and energy dispersive X-ray analysis analyses provided evidence that the adsorption was not uniform on the surface and that the small crystals contributed more to the fast adsorption than the normal sites did. The results from X-ray fluorescence spectrometry and X-ray photoelectron spectroscopy tests also revealed the uneven adsorption of condensed phosphate as a function of the penetration depth. More condensed phosphates were adsorbed on the outer surface of aluminum hydroxide than in its inner parts.

ATR-FTIR and XPS study on the structure of complexes formed upon the adsorption of simple organic acids on aluminum hydroxide

Information on the binding of organic ligands to metal （hydr）oxide surfaces is useful for understanding the adsorption behaviour of natural organic matter on metal （hydr）oxide. In this study, benzoate and salicylate were employed as the model organic ligands and aluminum hydroxide as the metal hydroxide. The attenuated total reflectance Fourier transform infrared （ATR-FTIR） spectra revealed that the ligands benzoate and salicylate do coordinate directly with the surface of hydrous aluminum hydroxide, thereby forming innersphere surface complexes. It is concluded that when the initial pH is acidic or neutral, monodentate and bridging complexes are to be formed between benzoate and aluminum hydroxide while bridging complexes predominate when the initial pH is alkalic. Monodentate and bridging complexes can be formed at pH 5 while precipitate and bridging complexes are formed at pH 7 when salicylate anions are adsorbed on aluminum hydroxide. The X-ray photoelectron （XP） spectra demonstrated the variation of C 1 s binding energy in the salicyate and phenolic groups before and after adsorption. It implied that the benzoate ligands are adsorbed through the complexation between carboxylate moieties and the aluminum hydroxide surface, while both carboxylate group and phenolic group are involved in the complexation reaction when salicylate is adsorbed onto aluminum hydroxide. The information offered by the XPS confirmed the findings obtained with ATR-FTIR.

Kinetics and leaching behaviors of aluminum from pharmaceutical blisters in sodium hydroxide solution

A hydrometallurgical process was developed for recycling pharmaceutical blisters.Leaching aluminum from pharmaceutical blisters using sodium hydroxide(NaOH) solutions was investigated with respect to leaching behaviors and kinetics.AL9(34) orthogonal design of experiments suggests that the most significant factor is NaOH concentration followed by temperature and leaching time.Factorial experiments demonstrate that the leaching rate of aluminum increases with increasing of the factors.The optimum conditions are temperature of 70 °C,leaching time of 20 min,NaOH concentration of 1.25 mol/L,liquid-to-solid mass ratio of 15:1 and agitation speed of 400 r/min.Under optimum conditions,the leaching rate is up to 100%,implying that aluminum and polyvinyl chloride(PVC) plastic in pharmaceutical blisters are separated completely.Kinetics of leaching aluminum is best described by the product layer diffusion control model,and the activation energy is calculated to be 19.26 kJ/mol.

Synergistic Flame Retardant Effect of Ammonium Polyphosphate and Aluminum Hydroxide on Polyurethane

The flame-retardant properties of polyurethane(PU)containing ammonium polyphosphate(APP)and aluminum hydroxide(ATH)were investigated.Moreover,the flame retardant performance was investigated through thermogravimetric analysis,limiting oxygen index(LOI),vertical combustion(UL 94),and cone calorimeter.When 15 wt%APP and 5 wt%ATH were added together,the PU/15%APP/5%ATH sample shows better thermal stability and flame-retardant properties.When 15 wt%APP and 5 wt%ATH were added together,the LOI value of the PU/15%APP/5%ATH sample was 30.5%,and UL 94 V-0 rating was attained.Compared with PU,the peak heat release rate(PHRR),total heat release(THR),and average effective heat combustion(av-EHC)of the PU/15%APP/5%ATH sample decreased by 43.1%,21.0%,and 29.4%,respectively.In addition,the flame-retardant mechanism was investigated through cone calorimeter.The APP/ATH addition simultaneously exerted condensed phase and gas phase flame retardant effects.APP and ATH have synergistic flame retardant properties.

Comparative study on simultaneous removal of calcium and sulfate ions from flotation recycling water by aluminum hydroxide

Due to the environmental policies and economic reasons,the water used in some flotation operations of complex sulfide ores is recirculated,causing the ion concentration of some species to increase over time,affecting the flotation of the minerals of interest.In this work,an experimental and thermodynamic analysis of the synthetic solutions was presented with a high content of calcium and sulfate ions.The study focused on evaluating the use of two aluminum compounds for the precipitation of Ca^(2+)and SO_(4)^(2−)in the form of ettringite.The amorphous aluminum hydroxide was found to be more efficient than the crystalline one,giving rise to 83%calcium and 91%sulfate removal.The XRD analysis of the solids showed the main reaction product of ettringite,accompanied by small amounts of calcite,due to the absorption of atmospheric carbon dioxide.The final solution after the chemical treatment showed residual calcium and sulfate concentrations below 200 mg/L.Finally,the kinetics of calcium removal appeared to correspond to a second order reaction with respect to calcium concentration,with an apparent activation energy of 53.48 kJ/mol,which may suggest that the ettringite precipitation process is governed by the chemical reaction.

MORPHOLOGY AND PROPERTIES OF LINEAR LOW-DENSITY POLYETHYLENE HIGHLY LOADED WITH ALUMINUM HYDROXIDE

An experimental study was carried out to investigate the effects of isopropoxy tri(dioctyl pyrophosphoryl) titanate coupling agent on the mechanical performance, rheological property and microstructures of polyethylene highly loaded with aluminum hydroxide (Al(OH)(3)) composite, It was found that the addition of coupling agent results in reduced tensile strength and increased percentage elongation of the filled systems. Silane crosslinkable polyethylene substituting for polyethylene as matrix improves the tensile strength of the composite, while the percentage elongation of the composite still remains at a desired level. Melt viscosity of the composite will be improved by addition of titanate coupling agent. Microstructures of the composites were also studied by means of the scanning electron microscopy (SEM) technique. SEM micrographs reveal that finer dispersion of Al(OH)(3) will be obtained upon treatment of titanate and a transition from brittle to tough fracture takes place before and after silane crosslinking structure is introduced into polyethylene highly filled with Al(OH)(3) composite.

Thermal stability and oil absorption of aluminum hydroxide treated by dry modification with phosphoric acid

The dry modification of aluminum hydroxide powders with phosphoric acid and the effects of modification of technological conditions on thermal stability, morphology and oil absorption of aluminum hydroxide powders were investigated. The results show that the increase of mass ratio of phosphoric acid to aluminum hydroxide, the decrease of mass concentration of phosphoric acid and prolongation of mixing time are favorable to the improvement of thermal stability of aluminum hydroxide; when the mass ratio of phosphoric acid to aluminum hydroxide is 5:100, the mass concentration of phosphoric acid is 200 g/L and the mixing time is 10 min, the initial temperature of loss of crystal water in aluminum hydroxide rises from about 192.10 to 208.66 ℃, but the dry modification results in the appearance of agglomeration and macro-aggregate in the modified powders, and the oil absorption of modified powders becomes higher than that of original aluminum hydroxide.

Efficacy of Aluminum Hydroxides as Inhibitors of Alkali-Silica Reactions

A comparative study of amorphous and crystalline forms of commercial aluminum hydroxides as inhibitors of alkalisilica reactions in Portland cement mortars has been performed. It was found that at dosages of 1% to 3%, amorphous aluminum hydroxide can efficiently inhibit alkali-silica expansion of Portland cement compositions. High inhibiting activity of amorphous Al(OH)3 additives may be explained by their ability to actively bind Ca(OH)2 formed by the hydration of silicate phases of cement, to form ettringite (with participation of gypsum). Crystalline Al(OH)3 additives that do not possess the ability to interact with Ca(OH)2 even after additional grinding, however, demonstrate week properties to inhibit alkali-silica expansion. This may indicate that the inhibitory effect of Al(OH)3 at least—partly, may be given by its influence on the concentration of Al3+ ions in the pore solution. Some expansion of the samples with admixtures of Al(OH)3 observed during the alkaline expansion accelerated test procedure is not associated with the formation of ettringite and is only due to alkali-silicate reactions.

Thermal stability and oil absorption of aluminum hydroxide treated by dry modification with different modifiers

The thermal stability, particle size and morphology and oil absorption of aluminum hydroxide(ATH) treated by drymodification with three different modifiers were investigated. The experimental results show that the thermal stability of ATHpowder is markedly improved by dry modification technology with the following modifiers such as phosphoric acid, polyacrylic acidand the mixture of phosphoric acid and polyacrylic acid. The best effect comes from pure phosphoric acid, and the initial temperaturefor the loss of crystal water of ATH powder modified with pure polyacrylic acid can reach about 202 ℃ that is approximately 10 ℃higher than that of ATH powder before modification. The phenomena of agglomeration and macro-aggregate badly exist in ATHpowder modified with the modifiers containing phosphoric acid. The growth of particles and agglomerations of powders are notevident in ATH powder modified with pure polyacrylic acid. The oil absorption of ATH powder modified with the modifierscontaining phosphoric acid is apparently larger than that of original ATH powder and ATH powder modified with pure polyacrylicacid. The oil absorption of the ATH powder modified with pure polyacrylic acid is slightly smaller than that of original ATH powder.

Preparation of ultrafine α-Al_2O_3 powders by catalytic sintering of ammonium aluminum carbonate hydroxide at low temperature

The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate（Al2（SO4）3） and ammonium carbonate（（NH4）2CO3）. The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts （AT） on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.

Numerical simulation of high temperature air combustion in aluminum hydroxide gas suspension calcinations

The high temperature air combustion(HiTAC) process in gas suspension calcinations(GSC) was studied by using a CFD software FLUENT that can simulate the three-dimensional physical model of GSC with the k-epsilon turbulent viscous model, PDF non-premixed combustion species model, P1 radiation model, thermal and prompt NO pollution model. The simulation vividly describes the distributions of the temperature, velocity and consistency fields. Finally, the optimal operation conditions and igniter configuration of particular fuel combustion are obtained by analyzing and comparing the simulation results. And the emission quantity of NOx, CO and CO2 deduced from computation can play a role as reference. These optimal and estimated values are beneficial to practical operation.

Studies on Y- Potential of Positive Sol of Magnesium Aluminum Hydroxide

The IEP of magnesium aluminum hydroxide was predicted with the modified Yoon′s equation, and the effect of electrolyte on the Y- potential of the sol was studied by electrophoresis method. The results showed that the calculated IEP values with the modified Yoon′s equation agreed well with the experimental ones. With the increase of the ionic radius of monovalent anions (Cl -, Br -, I -) the ζ potential decreased. The same was true for CO 2- 3, SO 2- 4 but the sign of the Y- potential reversed from positive to negative. For Al 3+ , Ca 2+ , Mg 2+ , however, the ζ potential increased with the increase of the concentration of Al 3+ , Ca 2+ , Mg 2+ .

Effect of Aluminum Hydroxide Adjuvant on the Immunogenicity of the 2009 Pandemic Influenza A/H1N1 Vaccine:Multi-level Modeling of Data with Repeated Measures

Objective To evaluate the effect of the aluminum hydroxide （Al-OH） adjuvant on the 2009 pandemic influenza A/H1N1 （pH1N1） vaccine. Methods In a multicenter, double-blind, randomized, placebo-controlled trial, participants received two doses of split-virion formulation containing 15 ug hemagglutinin antigen, with or without aluminum hydroxide （N-OH）. We classified the participants into six age categories （〉61 years, 41-60 years, 19-40 years, 13-18 years, 8-12 years, and 3-7 years） and obtained four blood samples from each participant on days 0, 21, 35, and 42 following the first dose of immunization. We assessed vaccine immunogenicity by measuring the geometric mean titer （GMT） of hemagglutination inhibiting antibody. We used a two-level model to evaluate the fixed effect of aluminum Al-OH and other factors, accounting for repeated measures. Results The predictions of repeated measurement on GMTs of formulations with or without Al-OH, were 80.35 and 112.72, respectively. Al-OH significantly reduced immunogenicity after controlling for time post immunization, age-group and gender. Conclusion The Al-OH adjuvant does not increase but actually reduces the immunogenicity of the split-virion pH1N1 vaccine.

Coordination Structure of Aluminum in Magnesium Aluminum Hydroxide Studied by (27)Al NMR

The coordination structure of aluminum in magnesium aluminum hydroxide was studied by 27Al NMR. The result showed that tetrahedral aluminum (AlIV) existed in magnesium aluminum hydroxide, and the contents of AlIV increased with the increase of the ratio of Al/Mg and with the peptizing temperature. AlIV originated from the so-called Al13 polymer with the structure of one Al tetrahedron surrounded by twelve Al octahedrons.

Influence of the Precipitating Reagents and Dispersants on the Formation Nano-Aluminum Hydroxide

The influence of the precipitating reagents and dispersants on the formation of nano-aluminum hydroxide from sodium aluminate solution by chemical precipitation was investigated. The influence of the dispersed seeds on the decomposi-tion process was investigated too. The alkaline aluminate solutions were used as original solutions with a concentration of Al2O3 having 14.78 g/dm3, αk—1.6 and127 g/dm3, αk—1.6. For the precipitation processes there were used follow-ing precipitating reagents—solutions HCl, NaHCO3 and NH4HCO3 with a concentration of 80 g/dm3, dispersants—PEG 6000, (NaPO3)6 and Tween 20. For the decomposition process the dispersed seeds and factories seeds were used. Structural studies of the aluminum hydroxide particles were carried out by means of the electron-probe microanalysis and scanning electron microscopy, and phase composition of products was determined by means of X-ray diffraction analysis. Ammonium bicarbonate and Tween 20 were determined as the optimal precipitating reagent and dispersant, correspondingly, resulting in dispersed aluminum hydroxide, which is used as a seed in the decomposition process. It was established that this product in form of dispersed seed considerably reduces the duration of the decomposition process;the maximal decomposition of solution (73.9%) was observed after injection of dispersеd aluminum hydroxide into solution. The final aluminum hydroxide having 90% of particles less than 100 nanometers was obtained within 7 hours of steady decreasing temperature from 70°C to 48°C.

Lead Ions Sorption from Waste Solution Using Aluminum Hydroxide Modified Diatomite

This study investigated the effectiveness of aluminum modified diatomite in removing lead from aqueous solution. Scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray Fluorescence (XRF) and infrared spectroscopy were used to characterize the modified absorbents. Effects of several variables like pH, adsorbent dose, initial concentration and the reaction temperature on lead sorption were also investigated. Langmuir and Freundlich isotherm models were applied to describe the equilibrium data. Values of △H, △G and △S illustrated that the adsorption of lead is an endothermic process of nature. Comparing with the natural diatomite, the adsorption efficiency for the lead ions increased from 12.06% to 61.36% which indicated that aluminum modified diatomite can be used as a potential absorbent for lead ions.

Study on Isoelectric Point of Magnesium Aluminum Hydroxide

Yoon's equation which predicted point of zero charge of complex oxide should predict the zero point of net charge (ZPNC) of mixture of variable and permanent charge rather than the point of zero charge (PZC) of the variable charge component. The calculated values with modified Yoon's equation agreed with the experimental values.