Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were...Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were reanalyzed. The new quantitative analysis results show that when cryolite ratio（CR） is less than 2, AlF4- is the dominant anion in the melts, and its mole fraction is about 0.70 for melts with CR=1.5 and 0.50 for melts with CR=2. When CR is more than 2.5, the mole fraction of AlF6^3- is relatively large, which is around 0.45 for melts with CR=2.5. Ionic structure of Na3AlF6-Al2O3 melts was investigated by UV-Raman spectroscopy. Octahedral AlF6^3- and tetrahedral AlF4- are proved to exist with possible partial replacement of F- by O^2-. Al2O2F4^2- with a large scattering coefficient also exists in the melts in which alumina concentration is more than 4% （mass fraction）. The increase of temperature causes blue-shift of the bands in the Raman spectra.展开更多
Ion implantation has played a unique role in the fabrication of optical waveguide devices.Tb'-doped aluminum borosilicate(TDAB)glass has been considered as an important magneto-optical material.In this work,near-i...Ion implantation has played a unique role in the fabrication of optical waveguide devices.Tb'-doped aluminum borosilicate(TDAB)glass has been considered as an important magneto-optical material.In this work,near-infrared waveguides have been manufactured by the(5.5+6.0)MeV C^3+ion implantation with doses of(4.0+8.0)×10^13 ions·cm^-2 in the TDAB glass.The modes propagated in the TDAB glass waveguide were recorded by a prism-coupling system.The finite-difference beam propagation method(FD-BPM)was carried out to simulate the guiding characteristics of the TDAB glass waveguide.The TDAB glass waveguide allows the light propagation with a single-mode at 1.539μm and can serve as a potential candidate for future waveguide isolators.展开更多
基金Project (51004034) supported by the National Natural Science, ChinaProject(N090302009) supported by the Fundamental Research Funds for the Central Universities, China
文摘Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were reanalyzed. The new quantitative analysis results show that when cryolite ratio（CR） is less than 2, AlF4- is the dominant anion in the melts, and its mole fraction is about 0.70 for melts with CR=1.5 and 0.50 for melts with CR=2. When CR is more than 2.5, the mole fraction of AlF6^3- is relatively large, which is around 0.45 for melts with CR=2.5. Ionic structure of Na3AlF6-Al2O3 melts was investigated by UV-Raman spectroscopy. Octahedral AlF6^3- and tetrahedral AlF4- are proved to exist with possible partial replacement of F- by O^2-. Al2O2F4^2- with a large scattering coefficient also exists in the melts in which alumina concentration is more than 4% （mass fraction）. The increase of temperature causes blue-shift of the bands in the Raman spectra.
基金This work was financially supported by the National Natural Science Foundation of China(Grant Nos.11405041,51502144 and 61475189).
文摘Ion implantation has played a unique role in the fabrication of optical waveguide devices.Tb'-doped aluminum borosilicate(TDAB)glass has been considered as an important magneto-optical material.In this work,near-infrared waveguides have been manufactured by the(5.5+6.0)MeV C^3+ion implantation with doses of(4.0+8.0)×10^13 ions·cm^-2 in the TDAB glass.The modes propagated in the TDAB glass waveguide were recorded by a prism-coupling system.The finite-difference beam propagation method(FD-BPM)was carried out to simulate the guiding characteristics of the TDAB glass waveguide.The TDAB glass waveguide allows the light propagation with a single-mode at 1.539μm and can serve as a potential candidate for future waveguide isolators.
