High-efficiency perovskite solar cells（PSCs） reported hitherto have been mostly prepared in a moisture and oxygen-free glove-box atmosphere, which hampers upscaling and real-time performance assessment of this excit...High-efficiency perovskite solar cells（PSCs） reported hitherto have been mostly prepared in a moisture and oxygen-free glove-box atmosphere, which hampers upscaling and real-time performance assessment of this exciting photovoltaic technology. In this work, we have systematically studied the feasibility of allambient-processing of PSCs and evaluated their photovoltaic performance. It has been shown that phasepure crystalline tetragonal MAPbI;perovskite films are instantly formed in ambient air at room temperature by a two-step spin coating process, undermining the need for dry atmosphere and post-annealing.All-ambient-processed PSCs with a configuration of FTO/TiO;/MAPbI;/Spiro-OMeTAD/Au achieve opencircuit voltage（990 mV） and short-circuit current density（20.31 mA/cm;） comparable to those of best reported glove-box processed devices. Nevertheless, device power conversion efficiency is still constrained at 5% by the unusually low fill-factor of 0.25. Dark current–voltage characteristics reveal poor conductivity of hole-transporting layer caused by lack of oxidized spiro-OMe TAD species, resulting in high seriesresistance and decreased fill-factor. The study also establishes that the above limitations can be readily overcome by employing an inorganic p-type semiconductor, copper thiocyanate, as ambient-processable hole-transporting layer to yield a fill-factor of 0.54 and a power conversion efficiency of 7.19%. The present findings can have important implications in industrially viable fabrication of large-area PSCs.展开更多
基于无机CsPbI_(2)Br的碳基无空穴传输层钙钛矿太阳能电池(carbon based hole transport material freeperovskite solar cells,C-PSCs)具有成本低、易制备和稳定性好等优点而受到广泛关注。研究了空气环境下制备高效稳定的平面异质结Cs...基于无机CsPbI_(2)Br的碳基无空穴传输层钙钛矿太阳能电池(carbon based hole transport material freeperovskite solar cells,C-PSCs)具有成本低、易制备和稳定性好等优点而受到广泛关注。研究了空气环境下制备高效稳定的平面异质结CsPbI_(2)Br C-PSCs的2种制备工艺。首先,通过对反溶剂材料的种类及用量、钙钛矿前驱体溶液浓度等参数的优化,在反溶剂为800μL、钙钛矿前驱体溶液浓度为1.2 mol/L的条件下,采用一步溶液法成功制备了光电转换效率为9.87%的CsPbI_(2)Br C-PSCs。其次,为摆脱一步溶液法对有毒反溶剂的依赖,引入低温预退火工艺,通过对预退火时间及温度、钙钛矿前驱体溶液浓度等参数的优化,在空气环境下,预退火温度为80℃、钙钛矿前驱体溶液浓度为1.6 mol/L且未使用反溶剂的条件下获得了10.52%的最佳光电转化效率,同时CsPbI_(2)Br钙钛矿的退火温度可降低至240℃,并且未封装的器件在空气环境下显示出了较好的稳定性。展开更多
对于1 k Hz以上声波,海面起伏会对浅海声传播产生显著影响,现有的噪声预报模型在建模过程中基本没有考虑海面起伏的影响.针对这一问题,本文基于传输理论建立了随机起伏界面下噪声场垂直相关性和指向性模型,仿真分析了海面起伏对噪声强...对于1 k Hz以上声波,海面起伏会对浅海声传播产生显著影响,现有的噪声预报模型在建模过程中基本没有考虑海面起伏的影响.针对这一问题,本文基于传输理论建立了随机起伏界面下噪声场垂直相关性和指向性模型,仿真分析了海面起伏对噪声强度、垂直相关性与指向性的影响.结果表明,对于表面噪声,海面随机起伏使声波能量从中间阶简正波向低阶和高阶简正波转移,而对噪声强度起主要贡献的一般是中间阶简正波,所以海面起伏使得噪声强度减弱;简正波之间能量的耦合导致垂直平面上不同掠射角方向上到达的声波响应发生变化,经由海面反射大掠射角到达的声波响应以及中小角度到达的声波响应变弱,而经由海底反射大掠射角到达的声波响应变强;海面随机起伏还会扰动各阶简正波相位,使不同阶简正波互相关性变弱,致使噪声场的空间相关性也变弱.展开更多
文摘High-efficiency perovskite solar cells（PSCs） reported hitherto have been mostly prepared in a moisture and oxygen-free glove-box atmosphere, which hampers upscaling and real-time performance assessment of this exciting photovoltaic technology. In this work, we have systematically studied the feasibility of allambient-processing of PSCs and evaluated their photovoltaic performance. It has been shown that phasepure crystalline tetragonal MAPbI;perovskite films are instantly formed in ambient air at room temperature by a two-step spin coating process, undermining the need for dry atmosphere and post-annealing.All-ambient-processed PSCs with a configuration of FTO/TiO;/MAPbI;/Spiro-OMeTAD/Au achieve opencircuit voltage（990 mV） and short-circuit current density（20.31 mA/cm;） comparable to those of best reported glove-box processed devices. Nevertheless, device power conversion efficiency is still constrained at 5% by the unusually low fill-factor of 0.25. Dark current–voltage characteristics reveal poor conductivity of hole-transporting layer caused by lack of oxidized spiro-OMe TAD species, resulting in high seriesresistance and decreased fill-factor. The study also establishes that the above limitations can be readily overcome by employing an inorganic p-type semiconductor, copper thiocyanate, as ambient-processable hole-transporting layer to yield a fill-factor of 0.54 and a power conversion efficiency of 7.19%. The present findings can have important implications in industrially viable fabrication of large-area PSCs.
文摘基于无机CsPbI_(2)Br的碳基无空穴传输层钙钛矿太阳能电池(carbon based hole transport material freeperovskite solar cells,C-PSCs)具有成本低、易制备和稳定性好等优点而受到广泛关注。研究了空气环境下制备高效稳定的平面异质结CsPbI_(2)Br C-PSCs的2种制备工艺。首先,通过对反溶剂材料的种类及用量、钙钛矿前驱体溶液浓度等参数的优化,在反溶剂为800μL、钙钛矿前驱体溶液浓度为1.2 mol/L的条件下,采用一步溶液法成功制备了光电转换效率为9.87%的CsPbI_(2)Br C-PSCs。其次,为摆脱一步溶液法对有毒反溶剂的依赖,引入低温预退火工艺,通过对预退火时间及温度、钙钛矿前驱体溶液浓度等参数的优化,在空气环境下,预退火温度为80℃、钙钛矿前驱体溶液浓度为1.6 mol/L且未使用反溶剂的条件下获得了10.52%的最佳光电转化效率,同时CsPbI_(2)Br钙钛矿的退火温度可降低至240℃,并且未封装的器件在空气环境下显示出了较好的稳定性。
文摘对于1 k Hz以上声波,海面起伏会对浅海声传播产生显著影响,现有的噪声预报模型在建模过程中基本没有考虑海面起伏的影响.针对这一问题,本文基于传输理论建立了随机起伏界面下噪声场垂直相关性和指向性模型,仿真分析了海面起伏对噪声强度、垂直相关性与指向性的影响.结果表明,对于表面噪声,海面随机起伏使声波能量从中间阶简正波向低阶和高阶简正波转移,而对噪声强度起主要贡献的一般是中间阶简正波,所以海面起伏使得噪声强度减弱;简正波之间能量的耦合导致垂直平面上不同掠射角方向上到达的声波响应发生变化,经由海面反射大掠射角到达的声波响应以及中小角度到达的声波响应变弱,而经由海底反射大掠射角到达的声波响应变强;海面随机起伏还会扰动各阶简正波相位,使不同阶简正波互相关性变弱,致使噪声场的空间相关性也变弱.
