Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries.

Discovery of a geomorphological analog to Martian araneiforms in the Qaidam Basin, Tibetan Plateau

Araneiforms are spider-like ground patterns that are widespread in the southern polar regions of Mars.A gas erosion process driven by the seasonal sublimation of CO_(2) ice was proposed as an explanation for their formation,which cannot occur on Earth due to the high climatic temperature.In this study,we propose an alternative mechanism that attrib-utes the araneiform formation to the erosion of upwelling salt water from the subsurface,relying on the identification of the first terrestrial analog found in a playa of the Qaidam Basin on the northern Tibetan Plateau.Morphological analysis indicates that the structures in the Qaidam Basin have fractal features comparable to araneiforms on Mars.A numerical model is developed to investigate the araneiform formation driven by the water-diffusion mechanism.The simulation res-ults indicate that the water-diffusion process,under varying ground conditions,may be responsible for the diverse aranei-form morphologies observed on both Earth and Mars.Our numerical simulations also demonstrate that the orientations of the saltwater diffusion networks are controlled by pre-existing polygonal cracks,which is consistent with observations of araneiforms on Mars and Earth.Our study thus suggests that a saltwater-related origin of the araneiform is possible and has significant implications for water searches on Mars.

Experimental and computational optimization of Prussian blue analogues as high-performance cathodes for sodium-ion batteries:A review

In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.

The Analogy between the Immune System and Human Life

The immune system operates as a complex organization with distinct roles and functions. Excitingly we recognized the similarities between the cellular dynamics of the immune system and our lives, activities, and behaviors. Observing the immune system can guide how to respond to various daily situations, including when to react, tolerate, or ignore. Recognizing this analogy between our lives and the immune system should motivate us to adopt a wisdom-based approach when investigating the mechanisms and future discoveries related to this system and to deepen our understanding of this complex system with newfound respect. In this context, the present review examines several integral biological processes of the immune system by drawing parallels between them and human life, activities, and behaviors to learn how we must behave based on the insights offered by this complex organization. The literature search was conducted in international databases such as PubMed/MEDLINE and Google Scholar search engine using English equivalent keywords from 1998 up to April 2023. The search strategy used the following subject heading terms: Immune system, analogy, human life, cellular dynamics, memory, tolerance, and ignorance. In conclusion, the immune system is a complex organization comprising various cells interacting within specific sites and networks, communicating, drawing experiences, and learning how to tolerate certain conditions that make it share certain similarities with human life.

An Adaptive Control Strategy for Energy Storage Interface Converter Based on Analogous Virtual Synchronous Generator

In the DC microgrid,the lack of inertia and damping in power electronic converters results in poor stability of DC bus voltage and low inertia of the DC microgrid during fluctuations in load and photovoltaic power.To address this issue,the application of a virtual synchronous generator(VSG)in grid-connected inverters control is referenced and proposes a control strategy called the analogous virtual synchronous generator(AVSG)control strategy for the interface DC/DC converter of the battery in the microgrid.Besides,a flexible parameter adaptive control method is introduced to further enhance the inertial behavior of the AVSG control.Firstly,a theoretical analysis is conducted on the various components of the DC microgrid,the structure of analogous virtual synchronous generator,and the control structure’s main parameters related to the DC microgrid’s inertial behavior.Secondly,the voltage change rate tracking coefficient is introduced to adjust the change of the virtual capacitance and damping coefficient flexibility,which further strengthens the inertia trend of the DC microgrid.Additionally,a small-signal modeling approach is used to analyze the approximate range of the AVSG’s main parameters ensuring system stability.Finally,conduct a simulation analysis by building the model of the DC microgrid system with photovoltaic(PV)and battery energy storage(BES)in MATLAB/Simulink.Simulation results from different scenarios have verified that the AVSG control introduces fixed inertia and damping into the droop control of the battery,resulting in a certain level of inertia enhancement.Furthermore,the additional adaptive control strategy built upon the AVSG control provides better and flexible inertial support for the DC microgrid,further enhances the stability of the DC bus voltage,and has a more positive impact on the battery performance.

A Low-Power 12-Bit SAR ADC for Analog Convolutional Kernel of Mixed-Signal CNN Accelerator

As deep learning techniques such as Convolutional Neural Networks(CNNs)are widely adopted,the complexity of CNNs is rapidly increasing due to the growing demand for CNN accelerator system-on-chip(SoC).Although conventional CNN accelerators can reduce the computational time of learning and inference tasks,they tend to occupy large chip areas due to many multiply-and-accumulate(MAC)operators when implemented in complex digital circuits,incurring excessive power consumption.To overcome these drawbacks,this work implements an analog convolutional filter consisting of an analog multiply-and-accumulate arithmetic circuit along with an analog-to-digital converter(ADC).This paper introduces the architecture of an analog convolutional kernel comprised of low-power ultra-small circuits for neural network accelerator chips.ADC is an essential component of the analog convolutional kernel used to convert the analog convolutional result to digital values to be stored in memory.This work presents the implementation of a highly low-power and area-efficient 12-bit Successive Approximation Register(SAR)ADC.Unlink most other SAR-ADCs with differential structure;the proposed ADC employs a single-ended capacitor array to support the preceding single-ended max-pooling circuit along with minimal power consumption.The SARADCimplementation also introduces a unique circuit that reduces kick-back noise to increase performance.It was implemented in a test chip using a 55 nm CMOS process.It demonstrates that the proposed ADC reduces Kick-back noise by 40%and consequently improves the ADC’s resolution by about 10%while providing a near rail-to-rail dynamic rangewith significantly lower power consumption than conventional ADCs.The ADC test chip shows a chip size of 4600μm^(2)with a power consumption of 6.6μW while providing an signal-to-noise-and-distortion ratio(SNDR)of 68.45 dB,corresponding to an effective number of bits(ENOB)of 11.07 bits.

High-Bandwidth,Low-Power CMOS Transistor Based CAB for Field Programmable Analog Array

This article presents an integrated current mode configurable analog block(CAB)system for field-programmable analog array(FPAA).The proposed architecture is based on the complementary metal-oxide semiconductor(CMOS)transistor level design where MOSFET transistors operating in the saturation region are adopted.The proposed CAB architecture is designed to implement six of thewidely used current mode operations in analog processing systems:addition,subtraction,integration,multiplication,division,and pass operation.The functionality of the proposed CAB is demonstrated through these six operations,where each operation is chosen based on the user’s selection in the CAB interface system.The architecture of the CAB system proposes an optimized way of designing and integrating only three functional cells with the interface circuitry to achieve the six operations.Furthermore,optimized programming and digital tuning circuitry are implemented in the architecture to control and interface with the functional cells.Moreover,these designed programming and tuning circuitries play an essential role in optimizing the performance of the proposed design.Simulation of the proposed CMOS Transistor Based CAB system is carried out using Tanner EDA Tools in 0.35μm standard CMOS technology.The design uses a±1.5 V power supply and results in maximum 3 dB bandwidth of 34.9 MHz and an approximate size of 0.0537 mm2.This demonstrates the advantages of the design over the current state-of-the-art designs presented for comparison in this article.Consequently,the proposed design has a clear aspect of simplicity,low power consumption,and high bandwidth operation,which makes it a suitable candidate for mobile telecommunications applications.

Structural Variation between the Western and Eastern Kuqa Fold-and-thrust Belt,China:Insights from Seismic Interpretation and Analog Modeling

The Kuqa fold-and-thrust belt exhibits apparent structural variation in the western and eastern zone.Two salt layer act as effective decollements and influence the varied deformation.In this study,detailed seismic interpretations and analog modeling are presented to construct the suprasalt and subsalt structures in the transfer zone of the middle Kuqa and investigate the influence of the two salt layers.The results reveal that the relationship of the two salt layers changes from separated to connected,and then overlapped toward the foreland in the transfer zone.Different structural models are formed in the suprasalt and subsalt units due to the interaction of the two salt layers.The imbricate thrust faults form two broom-like fault systems in the subsalt units.The suprasalt units develop detached folds terminating toward the east in the region near the orogenic belt.Whereas,two offset anticlines with different trends develop at the frontal edge of the lower salt layer and the trailing edge of the upper salt layer,respectively.According to exploration results in this region,the relationship between suprasalt and subsalt structures has an influence on hydrocarbon accumulation.We believe that the connected deformation contains high-risk plays while the decoupled deformation contains well-preserved plays.

Performance optimization of tri-gate junctionless FinFET using channel stack engineering for digital and analog/RF design

This manuscript explores the behavior of a junctionless tri-gate FinFET at the nano-scale region using SiGe material for the channel.For the analysis,three different channel structures are used:(a)tri-layer stack channel(TLSC)(Si-SiGe-Si),(b)double layer stack channel(DLSC)(SiGe-Si),(c)single layer channel(SLC)(S_(i)).The I−V characteristics,subthreshold swing(SS),drain-induced barrier lowering(DIBL),threshold voltage(V_(t)),drain current(ION),OFF current(IOFF),and ON-OFF current ratio(ION/IOFF)are observed for the structures at a 20 nm gate length.It is seen that TLSC provides 21.3%and 14.3%more ON current than DLSC and SLC,respectively.The paper also explores the analog and RF factors such as input transconductance(g_(m)),output transconductance(gds),gain(gm/gds),transconductance generation factor(TGF),cut-off frequency(f_(T)),maximum oscillation frequency(f_(max)),gain frequency product(GFP)and linearity performance parameters such as second and third-order harmonics(g_(m2),g_(m3)),voltage intercept points(VIP_(2),VIP_(3))and 1-dB compression points for the three structures.The results show that the TLSC has a high analog performance due to more gm and provides 16.3%,48.4%more gain than SLC and DLSC,respectively and it also provides better linearity.All the results are obtained using the VisualTCAD tool.

Dynamic Analogical Association Algorithm Based on Manifold Matching for Few-Shot Learning

At present,deep learning has been well applied in many fields.However,due to the high complexity of hypothesis space,numerous training samples are usually required to ensure the reliability of minimizing experience risk.Therefore,training a classifier with a small number of training examples is a challenging task.From a biological point of view,based on the assumption that rich prior knowledge and analogical association should enable human beings to quickly distinguish novel things from a few or even one example,we proposed a dynamic analogical association algorithm to make the model use only a few labeled samples for classification.To be specific,the algorithm search for knowledge structures similar to existing tasks in prior knowledge based on manifold matching,and combine sampling distributions to generate offsets instead of two sample points,thereby ensuring high confidence and significant contribution to the classification.The comparative results on two common benchmark datasets substantiate the superiority of the proposed method compared to existing data generation approaches for few-shot learning,and the effectiveness of the algorithm has been proved through ablation experiments.

A 5MS/s 12-Bit Successive Approximation Analog-to-Digital Converter

With the continuous development of science and technology, digital signal processing is more and more widely used in various fields. Among them, the analog-to-digital converter (ADC) is one of the key components to convert analog signals to digital signals. As a common type of ADC, 12-bit sequential approximation analog-to-digital converter (SAR ADC) has attracted extensive attention for its performance and application. This paper aims to conduct in-depth research and analysis of 12-bit SAR ADC to meet the growing demands of digital signal processing. This article designs a 12-bit, successive approximation analog-to-digital converter (SAR ADC) with a sampling rate of 5 MS/s. The overall circuit adopts a fully differential structure, with key modules including DAC capacitor array, comparator, and control logic. According to the DAC circuit in this paper, a fully differential capacitor DAC array structure is proposed to reduce the area of layout DAC. The comparator uses a digital dynamic comparator to improve the ADC conversion speed. The chip is designed based on the SMIC180 nm CMOS process. The simulation results show that when the sampling rate is 5 MS/s, the effective bit of SAR ADC is 11.92 bit, the SNR is 74.62 dB, and the SFDR is 89.24 dB.

Optimal Stack Generation for CMOS Analog Modules with Parasitic and Mismatch Constraints

The performances of analog circuits depend greatly on the layout parasitics and mismatches.Novel techniques are proposed for modeling the distributed parasitic capacitance,parasitic parameter mismatch due to process gradient and the inner stack routing mismatch.Based on the proposed models,an optimal stack generation technique is developed to control the parasitics and mismatches,optimize the stack shape and ensure the generation of an Eulerian graph for a given CMOS analog module.An OPA circuit example is given to demonstrate that the circuit performances such as unit gain bandwidth and phase margin are enhanced by the proposed layout optimization method.

Design and Analysis of Analog Front-End of Passive RFID Transponders

An analog front-end of HF passive RFID transponders compatible with ISO/IEC 18000-3 is presented.Design considerations, especially the power transmission in the RFID transponder, are analyzed. Based on these considerations,an analog front-end is presented with novel architecture, high power conversion efficiency, low voltage, low power consumption, and high performance in an environment of noise and power fluctuation. The circuit is implemented in a Chartered 0.35μm standard CMOS process. The experimental results show that the chip can satisfy the design target well.

Design of an Analog Front End for Passive UHF RFID Transponder IC

This paper introduces a high-performance analog front end for a passive UHF RFID transponder IC, which is compatible with the ISO/IEC 18000-6B standard,operating at the 915MHz ISM band with a total supply current consumption less than 8μA. There are no external components, except for the antenna. The passive IC＇s power supply is taken from the energy of the received RF electromagnetic field with the help of a Schottky diode rectifier. The RFID analog front end includes a local oscillator, clock generator, power on reset circuit, matching network and backscatter,rectifier,regulator, and AM demodulator. The IC, whose reading distance is more than 3m,is fabricated with a Chartered 0.35μm two-poly four-metal CMOS process with Schottky diodes and is EEPROM supported. The core size is 300μm × 720μm.

Laser Measurement and Intensity Evaluation of Intake Swirl in Engine Using a Water Analog

The intake swirl in the cylinder was induced by a swirler which was fixed in one of two intake ports. In order to understand the characteristics of the intake swirl, a transparent water analog was designed which simulated 150 type single cylinder engine. At the same time, the particle image velocimetry was used to measure the flow fields induced by various swirlers in the analog. After measurement, a new method was presented to evaluate the intensity of the intake swirl. Then, when the measured sections, the lifts of valve and the swirlers were different, the calculated results of the flow field were compared.

Cloning and Analysis of NBS-LRR Type Resistance Gene Analogues in Sweet Potato (Ipomoea batatas)

The degenerate primers were designed based on the conserved NBS-LRR motifs among the known disease-resistance genes. A fragment of about 500 bp was amplified from genomic DNA of sweet potato using the specifically designed degenerate primers. After cloning and sequencing, 20 NBS-LRR type of disease-resistance gene analogue （RGAs） in sweet potato were observed. The deduced amino acid sequence of DNA fragment contains the conserved motifs of NBS-LRR type RGAs, such as P-loop, Kinase-2α, Kinase-3α and GLPL domain. The 20 RGAs could be sorted into two subclasses, namely TIR- NBS-LRR type and non-TIR-NBS-LRR type. Compared with the known resistance genes including N, L6 and M, the percentages of homologous amino acid sequence in 10 TIR-NBS-LRR range between 21% -44%. While other 10 non-TIR-NBS-LRR assume 15% -46% homology with the known resistance genes （Prf, RPM1, RPS2, etc. ）. Consequently the RGAs may further be used as molecular marker for screening the candidate disease-resistance genes in sweet potato.

Experimental Research on Multi-lateral Wells by the Electric Field Analogue Model

There is a close theoretical similarity between water pressure gradients in aquifers and applied voltage gradients in aqueous solutions. A series of electric field analogue experiments has been conducted by focusing on symmetrical multi-lateral wells and dual-lateral wells of arbitrary angles between laterals. This research not only evaluates the productivity equations of a symmetrical multi-lateral well showing the effect of angles on productivity, but also proposes the concept of the multi-lateral productivity coefficient. Moreover, the multi-lateral productivity coefficient equation is designed to calculate the productivity of dual-lateral wells of variable angles, which is in turn supported by experiment. It also helps provide the experimental basis for optimizing the configuration, and building the semi-analytic productivity model, of multi-lateral wells.

基于Analog Discovery 2的巨磁阻效应实验系统

将口袋式仪表Analog Discovery 2及其配套控制软件WaveForms引入巨磁阻效应实验,替代直流电源、信号发生器、示波器、数字信号控制器等传统仪表,完成信号的激发、采集以及处理.由Analog Discovery 2驱动螺线管、巨磁阻传感器、直流电机和步进电机等部件,可以实现巨磁阻传感器R-B基本特征曲线和高速转动转速的快速测量,还可以结合齿轮状铁磁体,实现低速转动的准确测量及微小角位移的定标和测量.各主要部件采用三维调整架固定,偏置永磁铁也配备了不同形状的导磁头,方便学生观察不同条件下的实验现象,完成更具有开放性和创新性的实验内容.

Treatment of central precocious puberty by GnRH analogs： long-term outcome in men

In boys, central precocious puberty （CPP） is the appearance of secondary sex characteristics driven by pituitary gonadotropin secretion before the age of 9 years. In the last years, relevant improvements in the treatment of CPP have been achieved. Because CPP is rare in boys, the majority of papers on this issue focus on girls and do not address specific features of male patients regarding end results and safety. In the present paper, recent advances of CPP management with GnRH analogs in men are summarized. End results in untreated and treated patients are also reviewed by an analysis of the recently published literature on treatment of CPP in men. The available data indicate that therapy with GnRH analogs can improve final height into the range of target height without significant adverse short-term and long-term effects, but longer follow-up of larger series of patients is still required to draw definitive conclusions.

Synthesis of Phenylpropanoid Glycoside Analogs

The regioselective acylation of unprotected phenylethyl glucoside withcinnamoyl chloride leads to 6-OH cin-namoylated glucoside. In this manner, thirteen phenylpropanoidglycoside analogs were designed and prepared. Their structure was confirmed by ~1H NMR and ^(13)CNMR spectra.