In the present work, the response surface method software was used with five measurement levels with three factors.These were applied for the optimization of operating parameters that affected gas separation performan...In the present work, the response surface method software was used with five measurement levels with three factors.These were applied for the optimization of operating parameters that affected gas separation performance of polyurethane–zeolite 3A, ZSM-5 mixed matrix membranes.The basis of the experiments was a rotatable central composite design(CCD).The three independent variables studied were: zeolite content(0–24 wt%), operating temperature(25–45 ℃) and operating pressure(0.2–0.1 MPa).The effects of these three variables on the selectivity and permeability membranes were studied by the analysis of variance(ANOVA).Optimal conditions for the enhancement of gas separation performances of polyurethane–3A zeolite were found to be 18 wt%, 30 ℃ and 0.8 MPa respectively.Under these conditions, the permeabilities of carbon dioxide, methane, oxygen and nitrogen gases were measured at 138.4, 22.9, 15.7 and 6.4 Barrer respectively while the CO_2/CH_4, CO_2/N_2 and O_2/N_2 selectivities were 5.8, 22.5 and 2.5, respectively.Also, the optimal conditions for improvement of the gas separation performance of polyurethane–ZSM 5 were found to be 15.64 wt%, 30 ℃ and 4 bar.The permeabilities of these four gases(i.e.carbon dioxide, methane, oxygen and nitrogen) were 164.7, 21.2, 21.5 and 8.1 Barrer while the CO_2/CH_4, CO_2/N_2 and O_2/N_2 selectivities were 7.8, 20.6 and 2.7 respectively.展开更多
A series of laboratory screening tests have been performed with the objective of evalu-ating the effect of feed rate, screen length and screen motion on the quality of separation achieved. The statistic analysis and r...A series of laboratory screening tests have been performed with the objective of evalu-ating the effect of feed rate, screen length and screen motion on the quality of separation achieved. The statistic analysis and results derived from it are discussed. Suggestions for future work with the objective of assessing the industrial significance of the research to the optimisation and design of screening processes are presented.展开更多
文摘In the present work, the response surface method software was used with five measurement levels with three factors.These were applied for the optimization of operating parameters that affected gas separation performance of polyurethane–zeolite 3A, ZSM-5 mixed matrix membranes.The basis of the experiments was a rotatable central composite design(CCD).The three independent variables studied were: zeolite content(0–24 wt%), operating temperature(25–45 ℃) and operating pressure(0.2–0.1 MPa).The effects of these three variables on the selectivity and permeability membranes were studied by the analysis of variance(ANOVA).Optimal conditions for the enhancement of gas separation performances of polyurethane–3A zeolite were found to be 18 wt%, 30 ℃ and 0.8 MPa respectively.Under these conditions, the permeabilities of carbon dioxide, methane, oxygen and nitrogen gases were measured at 138.4, 22.9, 15.7 and 6.4 Barrer respectively while the CO_2/CH_4, CO_2/N_2 and O_2/N_2 selectivities were 5.8, 22.5 and 2.5, respectively.Also, the optimal conditions for improvement of the gas separation performance of polyurethane–ZSM 5 were found to be 15.64 wt%, 30 ℃ and 4 bar.The permeabilities of these four gases(i.e.carbon dioxide, methane, oxygen and nitrogen) were 164.7, 21.2, 21.5 and 8.1 Barrer while the CO_2/CH_4, CO_2/N_2 and O_2/N_2 selectivities were 7.8, 20.6 and 2.7 respectively.
文摘A series of laboratory screening tests have been performed with the objective of evalu-ating the effect of feed rate, screen length and screen motion on the quality of separation achieved. The statistic analysis and results derived from it are discussed. Suggestions for future work with the objective of assessing the industrial significance of the research to the optimisation and design of screening processes are presented.
