Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering case...Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering cases,the effectiveness of the analogue test method is verified by comparing it with the traditional anchor pile method and self-balanced method.Taking the self-balanced test of the bridge pile foundation in the Songhua River as an example,the conversion factor of sandy soil and weathered mudstone are confirmed by the analogue test method.The results show that the conversion factor of sandy soil and weathered mudstone in the Songhua River area should consider the geological conditions and the construction technology,etc.The standard values are relatively conservative.It is suggested that the engineering application should be properly revised.The recommended range of the conversion factor of sandy soil in this area is 0.65 to 0.85,and that of weathered mudstone is 1.0.展开更多
Sm-doped Fe_(2)O_(3)catalysts,with a homogeneous distribution of Sm in Fe_(2)O_(3)nanoparticles,were synthesized using a citric acid-assisted sol-gel method.Kinetic studies show that the reaction rate for NO_(x)reduct...Sm-doped Fe_(2)O_(3)catalysts,with a homogeneous distribution of Sm in Fe_(2)O_(3)nanoparticles,were synthesized using a citric acid-assisted sol-gel method.Kinetic studies show that the reaction rate for NO_(x)reduction using the optimal catalyst(0.06 mol%doping of Sm in Fe_(2)O_(3))was nearly 11 times higher than that for pure Fe_(2)O_(3),when calculated based on specific surface area.Furthermore,the Fe_(0.94)Sm_(0.06)O_(x)catalyst maintains>83%NO_(x)conversion for 168 h at a high space velocity in the presence of SO_(2)and H_(2)O at 250℃.A substantial amount of surface-adsorbed oxygen was generated on the surface of Fe_(0.94)Sm_(0.06)O_(x),which promoted NO oxidation and the subsequent fast reaction between NO_(x)and NH_(3).The adsorption and activation of NH_(3)was also enhanced by Sm doping.In addition,Sm doping facilitated the decomposition of NH_(4)HSO_(4)on the surface of Fe_(0.94)Sm_(0.06)O_(x),resulting in its high activity and stability in the presence of SO_(2)+H_(2)O.展开更多
The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain,the transition zone between the Dabie Moun...The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain,the transition zone between the Dabie Mountain Area and Jianghan Plain.It’s a great field test site to study the material and energy exchange among rainfall,soil moisture,and groundwater of the Earth’s critical zone in subtropical monsoon climate plain areas.This paper analyzed the connection between rainfall and volume water content(VWC)of soil at different depths of several soil profiles,and the dynamic feature of groundwater was discussed,which reveals the rainfall infiltration recharge of Quaternary Upper Pleistocene strata.The results show that the Quaternary Upper Pleistocene aquifer groundwater accepts a little direct rainfall recharge,while the lateral recharge is the main supplement source.There were 75 effective rainfall events among 120 rainfall events during the monitoring period,with an accumulated amount of 672.9 mm,and the percentages of effective rainfall amount and duration time were 62.50%and 91.56%,respectively.The max evaporation depth at the upper part in Quaternary cohesive soil was no less than 1.4 m.The soil profile was divided into four zones:(1)The sensitive zone of rainfall infiltration within 1.4 m,where the material and energy exchange frequently near the interface between atmosphere and soil;(2)the buffer zone of rainfall infiltration between 1.4 m and 3.5 m;(3)the migration zone of rainfall infiltration between 3.5 m and 5.0 m;and(4)the rainfall infiltration and groundwater level co-influenced zone below 5.0 m.The results revealed the reaction of soil moisture and groundwater to rainfall in the area covered by cohesive soil under humid climate in Earth’s critical zone,which is of great theoretical and practical significance for groundwater resources evaluation and development,groundwater environmental protection,ecological environmental improvement,drought disaster prevention,and flood disaster prevention in subtropical monsoon climate plain areas.展开更多
The chemical conversion coating was formed on Mg alloy for low cost and harmlessness in environment by using the colloidal silica as the main component.The film formed at 298 K was thick,which was thought to be the co...The chemical conversion coating was formed on Mg alloy for low cost and harmlessness in environment by using the colloidal silica as the main component.The film formed at 298 K was thick,which was thought to be the combination of Si and O.In salt spray test,the ratio of black rust on the specimen that did not conducted chemical conversion treatment was five times or more than those of the chemical conversion treated specimen.The film of chemical conversion coating produced by alkali treatment process was thinner than the specimen produced in basic chemical conversion treatment solution.展开更多
The corrosion protection property and morphology of colloidal silica conversion films as an alternative to chemical conversion coating(CCC) films were examined. The corrosion behavior was investigated in 3% NaCl solut...The corrosion protection property and morphology of colloidal silica conversion films as an alternative to chemical conversion coating(CCC) films were examined. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques. Corrosion was implied by the appearance of red rust on the specimen surface. The results show that in 3% NaCl solution, red rust appears at 15-20, 55-70, and 75-85 d on Zn-electroplated steel, colloidal silica conversion-coated specimens, and chemical conversion-coated, specimens, respectively. In the salt spray test, the colloidal silica film provides better corrosion protection than CCC film, i.e., red rust appears at 96 h on the Zn-electroplated steel sheet, at 432 h on the CCC films, and at 888 h on silica conversion coating.展开更多
Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalys...Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalyst preparation based on the issues from the mass transfer of produced wax from F-T synthesis will be discussed. Recent progresses on C2-oxygenate synthesis from syngas over a Rh/SiO2 catalyst and a 10 thousands ton/a demonstration test facility in China will be built in 2010 will be reported in the second section. A naphtha and diesel distillate which cut off the heavier end of S-F-A distribution direct synthesis with low methane selectivity from syngas over a Co/AC1 catalyst and a 10000 ton/a demonstration test with a bubble column slurry reactor will be talked about in this speech. A high α-alcohols of C2-C18 direct synthesis with more than 50 wt% selectivity and low methane and methanol selectivities from syngas over a Co2C/AC2 catalyst,a 3000 ton/a demonstration test with a bubble column slurry reactor and the primary fundamental understandings will be detailedly discussed in the forth section. In situ formation of homogeneous active sites on the surface of supported Rh heterogeneous catalysts and their application in hydroformylation of olefins will be introduced in fifth section.展开更多
利用格点化降水观测数据集(CN05.1)以及ECMWF再分析资料(ERA5),分析1961—2020年夏季西南地区东部(Eastern Southwest China,ESWC)的降水、水汽含量及降水转化率特征,并利用天气学分析方法初步探究地形分布对降水转化率空间分布差异的影...利用格点化降水观测数据集(CN05.1)以及ECMWF再分析资料(ERA5),分析1961—2020年夏季西南地区东部(Eastern Southwest China,ESWC)的降水、水汽含量及降水转化率特征,并利用天气学分析方法初步探究地形分布对降水转化率空间分布差异的影响,最后利用中尺度数值模式WRF4.0(Weather Research and Forecasting Model)设计地形敏感性试验验证地形对西南地区东部夏季降水的作用。结果表明:(1)1961—2020年夏季西南地区东部的降水呈现东多西少的分布特征,但水汽含量却在其东南部和西北部存在两个大值区,水汽大值区降水转化率偏低,强降水区与水汽含量大值区分布存在明显差异,通过分析强降水区与水平风场及垂直速度场的形势配合发现地形是导致此差异的重要因素。(2)WRF模式能较好地模拟出西南地区东部夏季降水的空间分布特征,通过地形敏感性试验发现,区域内大娄山、方斗山及大巴山组成的西南-东北向山地地形分布对降水强度有显著影响,地形高度的降低将导致区域东南部降水量显著减少。(3)敏感性试验中将区域地形高度分别降低一半和去除地形后,区域东南部的降水在月时间尺度中将分别减少9.89%和19.90%。地形高度的改变也会引起区域垂直速度、水平风场、水汽输送及水汽辐合量发生改变,当地形高度降低后,上升运动及西南风明显减弱,水汽输送强度降低,水汽辐合量减少,不利于降水形成。展开更多
基金The National Key Research and Development Program(No.2017YFC0703408)the National Natural Science Foundation of China(No.51478109,51678145,51878160)
文摘Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering cases,the effectiveness of the analogue test method is verified by comparing it with the traditional anchor pile method and self-balanced method.Taking the self-balanced test of the bridge pile foundation in the Songhua River as an example,the conversion factor of sandy soil and weathered mudstone are confirmed by the analogue test method.The results show that the conversion factor of sandy soil and weathered mudstone in the Songhua River area should consider the geological conditions and the construction technology,etc.The standard values are relatively conservative.It is suggested that the engineering application should be properly revised.The recommended range of the conversion factor of sandy soil in this area is 0.65 to 0.85,and that of weathered mudstone is 1.0.
文摘Sm-doped Fe_(2)O_(3)catalysts,with a homogeneous distribution of Sm in Fe_(2)O_(3)nanoparticles,were synthesized using a citric acid-assisted sol-gel method.Kinetic studies show that the reaction rate for NO_(x)reduction using the optimal catalyst(0.06 mol%doping of Sm in Fe_(2)O_(3))was nearly 11 times higher than that for pure Fe_(2)O_(3),when calculated based on specific surface area.Furthermore,the Fe_(0.94)Sm_(0.06)O_(x)catalyst maintains>83%NO_(x)conversion for 168 h at a high space velocity in the presence of SO_(2)and H_(2)O at 250℃.A substantial amount of surface-adsorbed oxygen was generated on the surface of Fe_(0.94)Sm_(0.06)O_(x),which promoted NO oxidation and the subsequent fast reaction between NO_(x)and NH_(3).The adsorption and activation of NH_(3)was also enhanced by Sm doping.In addition,Sm doping facilitated the decomposition of NH_(4)HSO_(4)on the surface of Fe_(0.94)Sm_(0.06)O_(x),resulting in its high activity and stability in the presence of SO_(2)+H_(2)O.
基金the project“1:50000 regional hydrogeological survey in the Dabie Mountains contiguous destitute area”(121201009000172522)from Wuhan Center of Geological Survey,China Geological Survey(CGS).
文摘The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain,the transition zone between the Dabie Mountain Area and Jianghan Plain.It’s a great field test site to study the material and energy exchange among rainfall,soil moisture,and groundwater of the Earth’s critical zone in subtropical monsoon climate plain areas.This paper analyzed the connection between rainfall and volume water content(VWC)of soil at different depths of several soil profiles,and the dynamic feature of groundwater was discussed,which reveals the rainfall infiltration recharge of Quaternary Upper Pleistocene strata.The results show that the Quaternary Upper Pleistocene aquifer groundwater accepts a little direct rainfall recharge,while the lateral recharge is the main supplement source.There were 75 effective rainfall events among 120 rainfall events during the monitoring period,with an accumulated amount of 672.9 mm,and the percentages of effective rainfall amount and duration time were 62.50%and 91.56%,respectively.The max evaporation depth at the upper part in Quaternary cohesive soil was no less than 1.4 m.The soil profile was divided into four zones:(1)The sensitive zone of rainfall infiltration within 1.4 m,where the material and energy exchange frequently near the interface between atmosphere and soil;(2)the buffer zone of rainfall infiltration between 1.4 m and 3.5 m;(3)the migration zone of rainfall infiltration between 3.5 m and 5.0 m;and(4)the rainfall infiltration and groundwater level co-influenced zone below 5.0 m.The results revealed the reaction of soil moisture and groundwater to rainfall in the area covered by cohesive soil under humid climate in Earth’s critical zone,which is of great theoretical and practical significance for groundwater resources evaluation and development,groundwater environmental protection,ecological environmental improvement,drought disaster prevention,and flood disaster prevention in subtropical monsoon climate plain areas.
文摘The chemical conversion coating was formed on Mg alloy for low cost and harmlessness in environment by using the colloidal silica as the main component.The film formed at 298 K was thick,which was thought to be the combination of Si and O.In salt spray test,the ratio of black rust on the specimen that did not conducted chemical conversion treatment was five times or more than those of the chemical conversion treated specimen.The film of chemical conversion coating produced by alkali treatment process was thinner than the specimen produced in basic chemical conversion treatment solution.
文摘The corrosion protection property and morphology of colloidal silica conversion films as an alternative to chemical conversion coating(CCC) films were examined. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques. Corrosion was implied by the appearance of red rust on the specimen surface. The results show that in 3% NaCl solution, red rust appears at 15-20, 55-70, and 75-85 d on Zn-electroplated steel, colloidal silica conversion-coated specimens, and chemical conversion-coated, specimens, respectively. In the salt spray test, the colloidal silica film provides better corrosion protection than CCC film, i.e., red rust appears at 96 h on the Zn-electroplated steel sheet, at 432 h on the CCC films, and at 888 h on silica conversion coating.
文摘Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalyst preparation based on the issues from the mass transfer of produced wax from F-T synthesis will be discussed. Recent progresses on C2-oxygenate synthesis from syngas over a Rh/SiO2 catalyst and a 10 thousands ton/a demonstration test facility in China will be built in 2010 will be reported in the second section. A naphtha and diesel distillate which cut off the heavier end of S-F-A distribution direct synthesis with low methane selectivity from syngas over a Co/AC1 catalyst and a 10000 ton/a demonstration test with a bubble column slurry reactor will be talked about in this speech. A high α-alcohols of C2-C18 direct synthesis with more than 50 wt% selectivity and low methane and methanol selectivities from syngas over a Co2C/AC2 catalyst,a 3000 ton/a demonstration test with a bubble column slurry reactor and the primary fundamental understandings will be detailedly discussed in the forth section. In situ formation of homogeneous active sites on the surface of supported Rh heterogeneous catalysts and their application in hydroformylation of olefins will be introduced in fifth section.
文摘利用格点化降水观测数据集(CN05.1)以及ECMWF再分析资料(ERA5),分析1961—2020年夏季西南地区东部(Eastern Southwest China,ESWC)的降水、水汽含量及降水转化率特征,并利用天气学分析方法初步探究地形分布对降水转化率空间分布差异的影响,最后利用中尺度数值模式WRF4.0(Weather Research and Forecasting Model)设计地形敏感性试验验证地形对西南地区东部夏季降水的作用。结果表明:(1)1961—2020年夏季西南地区东部的降水呈现东多西少的分布特征,但水汽含量却在其东南部和西北部存在两个大值区,水汽大值区降水转化率偏低,强降水区与水汽含量大值区分布存在明显差异,通过分析强降水区与水平风场及垂直速度场的形势配合发现地形是导致此差异的重要因素。(2)WRF模式能较好地模拟出西南地区东部夏季降水的空间分布特征,通过地形敏感性试验发现,区域内大娄山、方斗山及大巴山组成的西南-东北向山地地形分布对降水强度有显著影响,地形高度的降低将导致区域东南部降水量显著减少。(3)敏感性试验中将区域地形高度分别降低一半和去除地形后,区域东南部的降水在月时间尺度中将分别减少9.89%和19.90%。地形高度的改变也会引起区域垂直速度、水平风场、水汽输送及水汽辐合量发生改变,当地形高度降低后,上升运动及西南风明显减弱,水汽输送强度降低,水汽辐合量减少,不利于降水形成。