South China can be divided into four metallogenic belts:The Middle-Lower Yangtze Metallogenic Belt(MLYB),Qinzhou-Hangzhou Metallogenic Belt(QHMB),Nanling Metallogenic Belt(NLMB),and Wuyi Metallogenic Belt(WYMB).The ma...South China can be divided into four metallogenic belts:The Middle-Lower Yangtze Metallogenic Belt(MLYB),Qinzhou-Hangzhou Metallogenic Belt(QHMB),Nanling Metallogenic Belt(NLMB),and Wuyi Metallogenic Belt(WYMB).The major mineralization in the four metallogenic belts is granite-related Cu–Au–Mo and porphyrite Fe-apatite,porphyry Cu(Au),and epithermal Pb–Zn–Ag,hydrothermal Cu–Au–Pb–Zn–Ag,and granite-related skarn-type and quartz-veins W–Sn,respectively.Low-temperature thermochronology,including fissiontrack and U-Th/He dating,has been widely used to constrain tectonic thermal evolution and ore deposits preservation.Understanding fission-track annealing and He diffusion kinetics in accessory minerals,such as zircon and apatite,is essential for dating and applications.In this study,previous zircon fission-track(ZFT)and apatite fission-track(AFT)ages in South China were collected.The result shows that the ZFT ages are mainly concentrated at140–90 Ma,and the AFT ages are mainly distributed at70–40 Ma.The age distribution and inversion temperature–time paths reveal heterogeneous exhumation histories in South China.The MLYB experienced Late CretaceousCenozoic extremely slow exhumation after rapid cooling in the Early Cretaceous.The northern QHMB(i.e.from southern Anhui province to the Hangzhou Bay)had a relatively faster rate of uplifting and denudation than the southern QHMB in the Cretaceous.Subsequently,the northern QHMB rapidly exhumed,while the continuously slow exhumation operated the southern QHMB in the Cenozoic.The southern NLMB had a more rapid cooling rate than the northern NLMB during the Cretaceous time,and the whole NLMB experienced rapid cooling in the Cenozoic,except that the southern Hunan province had the most rapid cooling rate.The WYMB possibly had experienced slow exhumation since the Late Cretaceous.The exhumation thickness of the four metallogenic belts since90 Ma is approximately calculated as follows:the MLYB≤3.5 km,the northern QHMB concentrated at3.5–5.5 km,and the southern QHMB usually less than3.5 km,the NLMB 4.5–6.5 km and the WYMB<3.5 km.The exhumation thickness of the NLMB is corresponding to the occurrence of the world-class W deposits,which were emplaced into a deeper depth of 1.5–8 km.As such,we infer that the uplifting and denudation processes of the four metallogenic belts have also played an important role in dominated ore deposits.展开更多
Amorphous ribbons with(Nd_(0.75)Pr_(0.25))_(9.5)Fe_(76)X_4B_(10.5)(X=Nb, Zr) nominal composition were annealed by conventional and microwave-assisted annealing furnaces, respectively. The thermal decompo...Amorphous ribbons with(Nd_(0.75)Pr_(0.25))_(9.5)Fe_(76)X_4B_(10.5)(X=Nb, Zr) nominal composition were annealed by conventional and microwave-assisted annealing furnaces, respectively. The thermal decomposition process, structure and magnetic properties of products were characterized by a thermal differential scanning calorimeter(DSC), X-ray diffraction(XRD) and a vibrating sample magnetometer(VSM). The addition of Nb and Zr increased the glass-forming ability(GFA) of as-spun ribbons. The proportion of Nd_2Fe_(14)B and α-Fe could be adjusted with power from 800 to 2000 W in microwave annealing process, during which the well-coupling between the soft and hard magnetic phase and higher coercivity reached up to 780.2 and 815.4 kA/m for(Nb,Zr)-doped alloys. The best magnetic properties of ribbons could be obtained by annealing at 650 oC for 10 min under the microwave power of 2000 W.展开更多
Micro-alloying effects of yttrium on the recrystallization behavior of an alumina-forming austenitic(AFA)stainless steel were investigated.It was found that the grain growth kinetics of the steels doped with differe...Micro-alloying effects of yttrium on the recrystallization behavior of an alumina-forming austenitic(AFA)stainless steel were investigated.It was found that the grain growth kinetics of the steels doped with different amounts of yttrium(i.e.,0,0.05 and 0.10mass% Y)could be described by an Arrhenius type empirical equation.Added Y could interact with carbon and influence the morphology of carbides both inside grains and on the grain boundaries,thus altering the grain boundary mobility and grain growth.The steel doped with 0.05mass% yttrium showed the highest activation energy of grain growth and the most retarded recrystallization behavior,which mainly resulted from the high density of fine carbides both inside grains and on the grain boundaries.However,excess addition of0.10mass% Y induced coarsening and then lowered density of carbides,which alleviated the yttrium effects.The results also manifest that micro-alloying of rare-earth elements such as yttrium is an effective way for controlling grain growth behavior during recrystallization of AFA steels,which may have great implications on engineering applications.展开更多
基金the National Science Fund for Distinguished Young Scholars(42025301)Natural Science Foundation of China(41673057)。
文摘South China can be divided into four metallogenic belts:The Middle-Lower Yangtze Metallogenic Belt(MLYB),Qinzhou-Hangzhou Metallogenic Belt(QHMB),Nanling Metallogenic Belt(NLMB),and Wuyi Metallogenic Belt(WYMB).The major mineralization in the four metallogenic belts is granite-related Cu–Au–Mo and porphyrite Fe-apatite,porphyry Cu(Au),and epithermal Pb–Zn–Ag,hydrothermal Cu–Au–Pb–Zn–Ag,and granite-related skarn-type and quartz-veins W–Sn,respectively.Low-temperature thermochronology,including fissiontrack and U-Th/He dating,has been widely used to constrain tectonic thermal evolution and ore deposits preservation.Understanding fission-track annealing and He diffusion kinetics in accessory minerals,such as zircon and apatite,is essential for dating and applications.In this study,previous zircon fission-track(ZFT)and apatite fission-track(AFT)ages in South China were collected.The result shows that the ZFT ages are mainly concentrated at140–90 Ma,and the AFT ages are mainly distributed at70–40 Ma.The age distribution and inversion temperature–time paths reveal heterogeneous exhumation histories in South China.The MLYB experienced Late CretaceousCenozoic extremely slow exhumation after rapid cooling in the Early Cretaceous.The northern QHMB(i.e.from southern Anhui province to the Hangzhou Bay)had a relatively faster rate of uplifting and denudation than the southern QHMB in the Cretaceous.Subsequently,the northern QHMB rapidly exhumed,while the continuously slow exhumation operated the southern QHMB in the Cenozoic.The southern NLMB had a more rapid cooling rate than the northern NLMB during the Cretaceous time,and the whole NLMB experienced rapid cooling in the Cenozoic,except that the southern Hunan province had the most rapid cooling rate.The WYMB possibly had experienced slow exhumation since the Late Cretaceous.The exhumation thickness of the four metallogenic belts since90 Ma is approximately calculated as follows:the MLYB≤3.5 km,the northern QHMB concentrated at3.5–5.5 km,and the southern QHMB usually less than3.5 km,the NLMB 4.5–6.5 km and the WYMB<3.5 km.The exhumation thickness of the NLMB is corresponding to the occurrence of the world-class W deposits,which were emplaced into a deeper depth of 1.5–8 km.As such,we infer that the uplifting and denudation processes of the four metallogenic belts have also played an important role in dominated ore deposits.
基金Project supported by State Key Laboratory for Advanced Metals and Materials of China(2013-Z02)the Project of Shanghai Science and Technology Committee(16090503600)
文摘Amorphous ribbons with(Nd_(0.75)Pr_(0.25))_(9.5)Fe_(76)X_4B_(10.5)(X=Nb, Zr) nominal composition were annealed by conventional and microwave-assisted annealing furnaces, respectively. The thermal decomposition process, structure and magnetic properties of products were characterized by a thermal differential scanning calorimeter(DSC), X-ray diffraction(XRD) and a vibrating sample magnetometer(VSM). The addition of Nb and Zr increased the glass-forming ability(GFA) of as-spun ribbons. The proportion of Nd_2Fe_(14)B and α-Fe could be adjusted with power from 800 to 2000 W in microwave annealing process, during which the well-coupling between the soft and hard magnetic phase and higher coercivity reached up to 780.2 and 815.4 kA/m for(Nb,Zr)-doped alloys. The best magnetic properties of ribbons could be obtained by annealing at 650 oC for 10 min under the microwave power of 2000 W.
基金Item Sponsored by National Natural Science Foundation of China(51531001,51422101,51371003,51271212)111 Project(B07003)+3 种基金International Science and Technology Cooperation Program of China(2015DFG52600)Program for Changjiang Scholars and Innovative Research Team in University of China(IRT_14R05)Fundamental Research Fund for the Central Universities of China(FRF-TP-15-004C1,FRF-TP-14-009C1)Top-Notch Young Talents Program of China
文摘Micro-alloying effects of yttrium on the recrystallization behavior of an alumina-forming austenitic(AFA)stainless steel were investigated.It was found that the grain growth kinetics of the steels doped with different amounts of yttrium(i.e.,0,0.05 and 0.10mass% Y)could be described by an Arrhenius type empirical equation.Added Y could interact with carbon and influence the morphology of carbides both inside grains and on the grain boundaries,thus altering the grain boundary mobility and grain growth.The steel doped with 0.05mass% yttrium showed the highest activation energy of grain growth and the most retarded recrystallization behavior,which mainly resulted from the high density of fine carbides both inside grains and on the grain boundaries.However,excess addition of0.10mass% Y induced coarsening and then lowered density of carbides,which alleviated the yttrium effects.The results also manifest that micro-alloying of rare-earth elements such as yttrium is an effective way for controlling grain growth behavior during recrystallization of AFA steels,which may have great implications on engineering applications.