Based on the basic formula of the confidence interval and the sampling error of mathematical statistics, the mathematical statistics method of evaluating application effects of a new type of gas anchor was given in th...Based on the basic formula of the confidence interval and the sampling error of mathematical statistics, the mathematical statistics method of evaluating application effects of a new type of gas anchor was given in this paper. By the method mentioned above, the confidence interval and the sampling errors of the relevant mean value differences of Daqing Oilfield S block’s 150 wells, according to the mean value differences of the liquid producing capacity per day, the oil production per day, the submergence depth of the 10 sampling test wells, in which before and after a new type of gas anchor were laid down, were calculated. The calculation results show that a new type of gas anchor has a better effect of increasing oil production of oil well and enhancing pump efficiency. Through the real value differences analysis of the liquid producing capacity per day, the oil production per day, the submergence depth of 150 wells mentioned above, in which before and after a new type of gas anchor were laid down, it was verified. By using the confidence interval and the sampling errors of the liquid producing capacity per day, the oil production per day, the submergence depth mentioned above, in which before and after a new type of gas anchor were laid down, the application effects of a new type of gas anchor could be evaluated. And a mathematical statistics method of evaluation application effects of a new type of gas anchor is presented.展开更多
To research the anchoring effect of large deformation bolt,tensile and drawing models are established.Then,the evolution laws of drawing force,bolt axial force and interfacial shear stress are analyzed.Additionally,th...To research the anchoring effect of large deformation bolt,tensile and drawing models are established.Then,the evolution laws of drawing force,bolt axial force and interfacial shear stress are analyzed.Additionally,the influence of structure element position on the anchoring effect of large deformation bolt is discussed.At last,the energy-absorbing support mechanism is discussed.Results show that during the drawing process of normal bolt,drawing force,bolt axial force and interfacial shear stress all gradually increase as increasing the drawing displacement,but when the large deformation bolt enters the structural deformation stage,these three values will keep stable;when the structure element of large deformation bolt approaches the drawing end,the fluctuation range of drawing force decreases,the distributions of bolt axial force and interfacial shear stress of anchorage section are steady and the increasing rate of interfacial shear stress decreases,which are advantageous for keeping the stress stability of the anchorage body.During the working process of large deformation bolt,the strain of bolt body is small,the working resistance is stable and the distributions of bolt axial force and interfacial shear stress are steady.When a rock burst event occurs,the bolt and bonding interface cannot easily break,which weakens the dynamic disaster degree.展开更多
Motivated by our recent work,in this work,we present the numerical study of the anchoring effect on the Frederiks threshold field in a nematic liquid crystal doped with ferroelectric colloidal nanoparticles.Assuming w...Motivated by our recent work,in this work,we present the numerical study of the anchoring effect on the Frederiks threshold field in a nematic liquid crystal doped with ferroelectric colloidal nanoparticles.Assuming weak anchoring conditions,we employ the relaxation method and Maxwell construction to numerically solve the Euler–Lagrangian differential equation for the total free energy together the Rapini–Papoular surface energy to take into account anchoring of nematic liquid crystal molecules at the substrates.In this study,we focus our attention on obtaining the phase diagrams of Frederiks transition for different values of anchoring strength which have been not computed in our previous work.In this way,the effect of nanoparticle radius,nanoparticle volume fraction,nanoparticle polarization,and cell thickness on the Frederiks transition for different values of anchoring conditions are summarized in the phase diagrams.The numerical results show that by increasing the nanoparticles size and nanoparticle volume fraction in the ferronematic system,the Frederiks threshold field is strongly reduced.展开更多
The physical effects on surface and flexoelectric polarization in a weak anchoring nematic liquid crystal cell are investigated systematically. We derive the analytic expressions of two effective anchoring energies fo...The physical effects on surface and flexoelectric polarization in a weak anchoring nematic liquid crystal cell are investigated systematically. We derive the analytic expressions of two effective anchoring energies for lower and upper substrates respectively as well as their effective anchoring strengths and corresponding tilt angles of effective easy direction.All of these quantities are relevant to the magnitudes of both two polarizations and the applied voltage U. Based on these expressions, the variations of effective anchoring strength and the tilt angle with the applied voltage are calculated for the fixed values of two polarizations. For an original weak anchoring hybrid aligned nematic cell, it may be equivalent to a planar cell for a small value of U and has a threshold voltage. The variation of reduced threshold voltage with reduced surface polarization strength is also calculated. The role of surface polarization is important without the adsorptive ions considered.展开更多
In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by th...In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by the clamping segment of anchor was studied. Taking the deformation of all parts in clamping segment in the transverse direction into consideration, the calculation formula for the increment of anchoring force was proposed based on the linear elastic hypotheses. The proposed model is verified by experiments and conclusions are drawn that the anchoring force is influenced mainly by the inclination angle of clamping pieces, the length of clamping part and the thickness of bonding medium. Especially, the thickness of bonding medium should be lowered in design to improve the synergistic effect of anchors.展开更多
The paper analyses quantitatively the anchoring effect of tensioned bolts on surrounding rock strength, and defines two concepts: one is the surrounding rock strength increased amount Δτ13 and the other is the stren...The paper analyses quantitatively the anchoring effect of tensioned bolts on surrounding rock strength, and defines two concepts: one is the surrounding rock strength increased amount Δτ13 and the other is the strength influence factor k. The anchoring effect of tensioned bolts is considered to increase a strength increased amount Δτ13 where Δτ13 is the product k and ten-sioned load p, i. e. Δτ13 = kp, where k is a function of two variables x and y. The distribu-tive properties both Δτ13 and k are also discussed in the paper, obtaining some useful results for designing bolting support parameters.展开更多
The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious int...The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable GPEs.Here,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium salts.TEP is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-CH_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP surprisingly.Anchored TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface layers.Such coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 cycles.This study paves a new way to make nonflammable GPE that is compatible with Li metal anode.展开更多
A new dynamically installed plate anchor, the Flying Wing Anchor~?, has been developed as a sustainable anchor concept for deep-water offshore wind turbines. The anchor is firstly installed by free-fall penetration an...A new dynamically installed plate anchor, the Flying Wing Anchor~?, has been developed as a sustainable anchor concept for deep-water offshore wind turbines. The anchor is firstly installed by free-fall penetration and then followed by drag embedment. If the anchor is subjected to environmental loads, it dives deeper to mobilize a higher capacity. This study presents a series of free-fall penetration tests with model anchors in different weights to assess the anchor behavior during the free-fall penetration performance in one-layer soil with a constant shear strength profile. Anchor velocities and embedment depths were measured by a magnetometer. An energy-based model and a force-based model were calibrated against the test results of model anchors with different weights. Based on the calibrated force-based model, a series of design charts were developed to estimate the embedment depth of anchors in different sizes and with different impact velocities in various marine clays. The framework to plot design charts presented herein can be potentially applied to other dynamically installed anchors to predict embedment depth in engineering practice.展开更多
The cutter head will be stuck when the shield machine pass through the area existing anchor left by foundation construction of surrounding high-rise building.Subsurface excavation method is an efficient way to remove ...The cutter head will be stuck when the shield machine pass through the area existing anchor left by foundation construction of surrounding high-rise building.Subsurface excavation method is an efficient way to remove the existed anchor.In this paper,a three-dimensional finite element model is developed to study stability of cross-channel excavation.The time-spatial effects of arch crown settlement,intrados uplift and side wall horizontal convergence are analyzed according to different excavation size,lining thickness and lining order.The results show that the excavation size is the main factor to control the deformation of the surrounding soil,especially in arch crown settlement;The influence of lining thickness on the spatial effect of surrounding soil deformation is obvious when the excavation size is large,but little on the time effect;The influence of the lining order on the deformation of the surrounding soil is obvious,in particular,the larger the excavation size,the more obvious advantages of the lining order.Finally,based on the time-spatial effects comparison of nine excavation schemes of the cross-channel,an optimum excavation scheme is adopted in the actual project.展开更多
The shuttle effect seriously impedes the development and practical application of lithium sulfur(Li-S)batteries.It is still a long-term challenge to find effective anchoring materials to hinder the shuttle effect of L...The shuttle effect seriously impedes the development and practical application of lithium sulfur(Li-S)batteries.It is still a long-term challenge to find effective anchoring materials to hinder the shuttle effect of Li-S batteries.Using carbon allotrope as anchoring materials is an effective strategy to alleviate the shuttling effect.However,the influence factors of carbon allotrope on the adsorption performance of LIPSS at the atomic level are not clear,which limits the application of carbon allotrope in Li-S batteries.Herein,using first-principles simulations,a systematical calculation of carbon allotropes with various ring size(6 ≤S≤16) and shape is conducted to understand the adsorption mechanism.The results show that the T-G monolayers with suitable ring structure and high charge transfer can significantly enhance the interaction between the monolayer and LiPSs,allowing them to have high capacity and high coulombic efficiency.Further diffusion studies show that LiPSs on the T-G monolayer have the low diffusion barriers,which ensures the charging and discharging rate of batteries.Our studies could provide material design principles of carbon allotrope monolayers used as anchoring materials of the high performance Li-S batteries.展开更多
Joining metal to plastic can lighten weight of products to reduce energy consumption.However,it is difficult to achieve high-strength welding between metal and plastic.To address this problem,the methods of surface te...Joining metal to plastic can lighten weight of products to reduce energy consumption.However,it is difficult to achieve high-strength welding between metal and plastic.To address this problem,the methods of surface texture pretreatment and laser irradiation welding was proposed to achieve the high-strength connection of metal and plastic.In this study,with different parameters of laser power and texture morphology,1060 Al with surface texture treatment was joined to polyethylene terephthalate(PET)by laser irradiation welding from metal side.Study showed that as the laser power increased,the tensile shear strength of joints increased first,and decreased thereafter.Tensile shear tests demonstrated that the mechanical force of joint was strengthened contributed to mechanical anchorage formed by surface texture.The depth-width ratio of the texture grooves affected the tensile shear process of the joint.According to the result of temperature simulation,the existence of texture grooves reduced the heat transfer efficiency,and the heat dissipation at interface was also impeded in course of laser welding.Finally,the maximum tensile strength of 1060Al-PET joint reached 48.4 MPa,which was close to the strength of PET matrix.The bonding mechanism of the 1060Al-PET joints was composed of mechanical bonding and chemical bonding.This study proposes an effective method to join metal to plastic which achieved high-strength connection between metal and plastic.展开更多
Lithium-sulfur batteries have attracted attention because of their high energy density.However,the "shuttle effect" caused by the dissolving of polysulfide in the electrolyte has greatly hindered the widespr...Lithium-sulfur batteries have attracted attention because of their high energy density.However,the "shuttle effect" caused by the dissolving of polysulfide in the electrolyte has greatly hindered the widespread commercial use of lithiumsulfur batteries.In this paper,a novel two-dimensional TiS2/graphene heterostructure is theoretically designed as the anchoring material for lithium-sulfur batteries to suppress the shuttle effect.This heterostructure formed by the stacking of graphene and TiS2 monolayer is the van der Waals type,which retains the intrinsic metallic electronic structure of graphene and TiS2 monolayer.Graphene improves the electronic conductivity of the sulfur cathode,and the transferred electrons from graphene enhance the polarity of the TiS2 monolayer.Simulations of the polysulfide adsorption show that the TiS2/graphene hetero structure can maintain good metallic properties and the appropriate adsorption energies of 0.98-3.72 eV,which can effectively anchor polysulfides.Charge transfer analysis suggests that further enhancement of polarity is beneficial to reduce the high proportion of van der Waals(vdW) force in the adsorption energy,thereby further enhancing the anchoring ability.Low Li2 S decomposition barrier and Li-ion migration barrier imply that the heterostructure has the ability to catalyze fast electrochemical kinetic processes.Therefore,TiS2/graphene heterostructure could be an important candidate for ideal anchoring materials of lithium-sulfur batteries.展开更多
A new method for determining the incremental cohesion △Cm of surrounding rock due to prestressed cable anchor is presented, and the formulas for △Cm are deduced and △Cm distributions also are discussed, based on th...A new method for determining the incremental cohesion △Cm of surrounding rock due to prestressed cable anchor is presented, and the formulas for △Cm are deduced and △Cm distributions also are discussed, based on the two anchorage effects, one is the effect with the prestressed vaIue △σ3 of cable anchor improving the stress state of surrounding rock and increasing the surrounding rock strength, the other is the fully encapsulated effect. The determined incremental cohesion △Cm is subiected to the model test and field measurement in the references, and coincides well with those tested results. The formulas for △Cm can be used in designing supoport parameters and related numerical analyses of prestressed cable anchor.展开更多
Supporting soft rock roadways in coal mines has long posed a formidable challenge. Addressing issues such as the formation of soft rock strata, poor fracture development, limited tolerance, and the frequent and severe...Supporting soft rock roadways in coal mines has long posed a formidable challenge. Addressing issues such as the formation of soft rock strata, poor fracture development, limited tolerance, and the frequent and severe damage sustained by conventional bolts due to their low elongation and bearing capacity, this study employs bottom expansion and filling technology. It combines theoretical analysis with booster bolt pull-out tests to scrutinize the radial stress distribution of bolts under extrusion forces. Moreover, it conducts a comparative analysis of bolt bearing characteristics under varying radial pressurization conditions, delving into the impact of radial directional increases in compressive stress on bolt anchoring performance.展开更多
文摘Based on the basic formula of the confidence interval and the sampling error of mathematical statistics, the mathematical statistics method of evaluating application effects of a new type of gas anchor was given in this paper. By the method mentioned above, the confidence interval and the sampling errors of the relevant mean value differences of Daqing Oilfield S block’s 150 wells, according to the mean value differences of the liquid producing capacity per day, the oil production per day, the submergence depth of the 10 sampling test wells, in which before and after a new type of gas anchor were laid down, were calculated. The calculation results show that a new type of gas anchor has a better effect of increasing oil production of oil well and enhancing pump efficiency. Through the real value differences analysis of the liquid producing capacity per day, the oil production per day, the submergence depth of 150 wells mentioned above, in which before and after a new type of gas anchor were laid down, it was verified. By using the confidence interval and the sampling errors of the liquid producing capacity per day, the oil production per day, the submergence depth mentioned above, in which before and after a new type of gas anchor were laid down, the application effects of a new type of gas anchor could be evaluated. And a mathematical statistics method of evaluation application effects of a new type of gas anchor is presented.
基金Project(2019SDZY02)supported by the Major Scientific and Technological Innovation Project of Shandong Provincial Key Research Development Program,ChinaProject(51904165)supported by the National Natural Science Foundation of ChinaProject(ZR2019QEE026)supported by the Shandong Provincial Natural Science Foundation,China。
文摘To research the anchoring effect of large deformation bolt,tensile and drawing models are established.Then,the evolution laws of drawing force,bolt axial force and interfacial shear stress are analyzed.Additionally,the influence of structure element position on the anchoring effect of large deformation bolt is discussed.At last,the energy-absorbing support mechanism is discussed.Results show that during the drawing process of normal bolt,drawing force,bolt axial force and interfacial shear stress all gradually increase as increasing the drawing displacement,but when the large deformation bolt enters the structural deformation stage,these three values will keep stable;when the structure element of large deformation bolt approaches the drawing end,the fluctuation range of drawing force decreases,the distributions of bolt axial force and interfacial shear stress of anchorage section are steady and the increasing rate of interfacial shear stress decreases,which are advantageous for keeping the stress stability of the anchorage body.During the working process of large deformation bolt,the strain of bolt body is small,the working resistance is stable and the distributions of bolt axial force and interfacial shear stress are steady.When a rock burst event occurs,the bolt and bonding interface cannot easily break,which weakens the dynamic disaster degree.
基金the support of Shiraz University of Technology Research Council
文摘Motivated by our recent work,in this work,we present the numerical study of the anchoring effect on the Frederiks threshold field in a nematic liquid crystal doped with ferroelectric colloidal nanoparticles.Assuming weak anchoring conditions,we employ the relaxation method and Maxwell construction to numerically solve the Euler–Lagrangian differential equation for the total free energy together the Rapini–Papoular surface energy to take into account anchoring of nematic liquid crystal molecules at the substrates.In this study,we focus our attention on obtaining the phase diagrams of Frederiks transition for different values of anchoring strength which have been not computed in our previous work.In this way,the effect of nanoparticle radius,nanoparticle volume fraction,nanoparticle polarization,and cell thickness on the Frederiks transition for different values of anchoring conditions are summarized in the phase diagrams.The numerical results show that by increasing the nanoparticles size and nanoparticle volume fraction in the ferronematic system,the Frederiks threshold field is strongly reduced.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11274088,11374087,and11304074)the Natural Science Foundation of Hebei Province,China(Grant No.A2014202123)+1 种基金the Research Project of Hebei Provincial Education Department,China(Grant No.QN2014130)the Key Subject Construction Project of Hebei Provincial University,China
文摘The physical effects on surface and flexoelectric polarization in a weak anchoring nematic liquid crystal cell are investigated systematically. We derive the analytic expressions of two effective anchoring energies for lower and upper substrates respectively as well as their effective anchoring strengths and corresponding tilt angles of effective easy direction.All of these quantities are relevant to the magnitudes of both two polarizations and the applied voltage U. Based on these expressions, the variations of effective anchoring strength and the tilt angle with the applied voltage are calculated for the fixed values of two polarizations. For an original weak anchoring hybrid aligned nematic cell, it may be equivalent to a planar cell for a small value of U and has a threshold voltage. The variation of reduced threshold voltage with reduced surface polarization strength is also calculated. The role of surface polarization is important without the adsorptive ions considered.
基金Project(BK20140553)supported by Jiangsu Province Science Foundation for Youths,ChinaProject(51478209)supported by the National Natural Science Foundation of China
文摘In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by the clamping segment of anchor was studied. Taking the deformation of all parts in clamping segment in the transverse direction into consideration, the calculation formula for the increment of anchoring force was proposed based on the linear elastic hypotheses. The proposed model is verified by experiments and conclusions are drawn that the anchoring force is influenced mainly by the inclination angle of clamping pieces, the length of clamping part and the thickness of bonding medium. Especially, the thickness of bonding medium should be lowered in design to improve the synergistic effect of anchors.
文摘The paper analyses quantitatively the anchoring effect of tensioned bolts on surrounding rock strength, and defines two concepts: one is the surrounding rock strength increased amount Δτ13 and the other is the strength influence factor k. The anchoring effect of tensioned bolts is considered to increase a strength increased amount Δτ13 where Δτ13 is the product k and ten-sioned load p, i. e. Δτ13 = kp, where k is a function of two variables x and y. The distribu-tive properties both Δτ13 and k are also discussed in the paper, obtaining some useful results for designing bolting support parameters.
基金supported by the National Natural Science Foundation of China(Nos.52172214,52272221,52171182)the Postdoctoral Innovation Project of Shandong Province(No.202102003)+2 种基金The Key Research and Development Program of Shandong Province(2021ZLGX01)the Qilu Young Scholar ProgramHPC Cloud Platform of Shandong University are also thanked.
文摘The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable GPEs.Here,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium salts.TEP is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-CH_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP surprisingly.Anchored TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface layers.Such coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 cycles.This study paves a new way to make nonflammable GPE that is compatible with Li metal anode.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51809231 and 51988101)。
文摘A new dynamically installed plate anchor, the Flying Wing Anchor~?, has been developed as a sustainable anchor concept for deep-water offshore wind turbines. The anchor is firstly installed by free-fall penetration and then followed by drag embedment. If the anchor is subjected to environmental loads, it dives deeper to mobilize a higher capacity. This study presents a series of free-fall penetration tests with model anchors in different weights to assess the anchor behavior during the free-fall penetration performance in one-layer soil with a constant shear strength profile. Anchor velocities and embedment depths were measured by a magnetometer. An energy-based model and a force-based model were calibrated against the test results of model anchors with different weights. Based on the calibrated force-based model, a series of design charts were developed to estimate the embedment depth of anchors in different sizes and with different impact velocities in various marine clays. The framework to plot design charts presented herein can be potentially applied to other dynamically installed anchors to predict embedment depth in engineering practice.
基金The National Natural Science Foundation of China(No.41404096,51678536,51509224)The Scientific and Technological Research Program of Henan Province(No.152102310066)Outstanding Young Talent Research Fund of Zhengzhou University(1621323001)for which the authors are grateful.
文摘The cutter head will be stuck when the shield machine pass through the area existing anchor left by foundation construction of surrounding high-rise building.Subsurface excavation method is an efficient way to remove the existed anchor.In this paper,a three-dimensional finite element model is developed to study stability of cross-channel excavation.The time-spatial effects of arch crown settlement,intrados uplift and side wall horizontal convergence are analyzed according to different excavation size,lining thickness and lining order.The results show that the excavation size is the main factor to control the deformation of the surrounding soil,especially in arch crown settlement;The influence of lining thickness on the spatial effect of surrounding soil deformation is obvious when the excavation size is large,but little on the time effect;The influence of the lining order on the deformation of the surrounding soil is obvious,in particular,the larger the excavation size,the more obvious advantages of the lining order.Finally,based on the time-spatial effects comparison of nine excavation schemes of the cross-channel,an optimum excavation scheme is adopted in the actual project.
基金supports by the National Natural Science Foundation of China (NSFC, Grant No. 51471124)Natural Science Foundation of Shaanxi Province, China (2020JM-218 and 2019JM-189)National Key R&D Program of China (2018YFB0905600)。
文摘The shuttle effect seriously impedes the development and practical application of lithium sulfur(Li-S)batteries.It is still a long-term challenge to find effective anchoring materials to hinder the shuttle effect of Li-S batteries.Using carbon allotrope as anchoring materials is an effective strategy to alleviate the shuttling effect.However,the influence factors of carbon allotrope on the adsorption performance of LIPSS at the atomic level are not clear,which limits the application of carbon allotrope in Li-S batteries.Herein,using first-principles simulations,a systematical calculation of carbon allotropes with various ring size(6 ≤S≤16) and shape is conducted to understand the adsorption mechanism.The results show that the T-G monolayers with suitable ring structure and high charge transfer can significantly enhance the interaction between the monolayer and LiPSs,allowing them to have high capacity and high coulombic efficiency.Further diffusion studies show that LiPSs on the T-G monolayer have the low diffusion barriers,which ensures the charging and discharging rate of batteries.Our studies could provide material design principles of carbon allotrope monolayers used as anchoring materials of the high performance Li-S batteries.
基金Supported by Natural Science Foundation of Jilin Province,China(20200201230JC).
文摘Joining metal to plastic can lighten weight of products to reduce energy consumption.However,it is difficult to achieve high-strength welding between metal and plastic.To address this problem,the methods of surface texture pretreatment and laser irradiation welding was proposed to achieve the high-strength connection of metal and plastic.In this study,with different parameters of laser power and texture morphology,1060 Al with surface texture treatment was joined to polyethylene terephthalate(PET)by laser irradiation welding from metal side.Study showed that as the laser power increased,the tensile shear strength of joints increased first,and decreased thereafter.Tensile shear tests demonstrated that the mechanical force of joint was strengthened contributed to mechanical anchorage formed by surface texture.The depth-width ratio of the texture grooves affected the tensile shear process of the joint.According to the result of temperature simulation,the existence of texture grooves reduced the heat transfer efficiency,and the heat dissipation at interface was also impeded in course of laser welding.Finally,the maximum tensile strength of 1060Al-PET joint reached 48.4 MPa,which was close to the strength of PET matrix.The bonding mechanism of the 1060Al-PET joints was composed of mechanical bonding and chemical bonding.This study proposes an effective method to join metal to plastic which achieved high-strength connection between metal and plastic.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62104168,11604235,andU1510132)the Beijing Institute of Technology Research Fund Program for Young Scholars+2 种基金the Natural Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi,China(Grant No.2019L0309)the Natural Science Foundation of Shanxi Province,China(Grant Nos.201901D111125 and 20210302123201)the Shanxi Scholarship Council of China。
文摘Lithium-sulfur batteries have attracted attention because of their high energy density.However,the "shuttle effect" caused by the dissolving of polysulfide in the electrolyte has greatly hindered the widespread commercial use of lithiumsulfur batteries.In this paper,a novel two-dimensional TiS2/graphene heterostructure is theoretically designed as the anchoring material for lithium-sulfur batteries to suppress the shuttle effect.This heterostructure formed by the stacking of graphene and TiS2 monolayer is the van der Waals type,which retains the intrinsic metallic electronic structure of graphene and TiS2 monolayer.Graphene improves the electronic conductivity of the sulfur cathode,and the transferred electrons from graphene enhance the polarity of the TiS2 monolayer.Simulations of the polysulfide adsorption show that the TiS2/graphene hetero structure can maintain good metallic properties and the appropriate adsorption energies of 0.98-3.72 eV,which can effectively anchor polysulfides.Charge transfer analysis suggests that further enhancement of polarity is beneficial to reduce the high proportion of van der Waals(vdW) force in the adsorption energy,thereby further enhancing the anchoring ability.Low Li2 S decomposition barrier and Li-ion migration barrier imply that the heterostructure has the ability to catalyze fast electrochemical kinetic processes.Therefore,TiS2/graphene heterostructure could be an important candidate for ideal anchoring materials of lithium-sulfur batteries.
文摘A new method for determining the incremental cohesion △Cm of surrounding rock due to prestressed cable anchor is presented, and the formulas for △Cm are deduced and △Cm distributions also are discussed, based on the two anchorage effects, one is the effect with the prestressed vaIue △σ3 of cable anchor improving the stress state of surrounding rock and increasing the surrounding rock strength, the other is the fully encapsulated effect. The determined incremental cohesion △Cm is subiected to the model test and field measurement in the references, and coincides well with those tested results. The formulas for △Cm can be used in designing supoport parameters and related numerical analyses of prestressed cable anchor.
文摘Supporting soft rock roadways in coal mines has long posed a formidable challenge. Addressing issues such as the formation of soft rock strata, poor fracture development, limited tolerance, and the frequent and severe damage sustained by conventional bolts due to their low elongation and bearing capacity, this study employs bottom expansion and filling technology. It combines theoretical analysis with booster bolt pull-out tests to scrutinize the radial stress distribution of bolts under extrusion forces. Moreover, it conducts a comparative analysis of bolt bearing characteristics under varying radial pressurization conditions, delving into the impact of radial directional increases in compressive stress on bolt anchoring performance.