Effect of Sintering Temperature on the Microstructure and Mechanical Properties of Nanocrystalline Cemented Carbide

WC-Co nanocrystalline nitrogen-containing cemented carbides were prepared by vacuum sintering and low pressure sintering.The sintering processes of Cr_(2)(C,N)doped nano WC-Co powders were studied by using thermogravimetric analysis(TGA)and differential scanning calorimetry(DSC).The effect of sintering temperature on the microstructure and mechanical properties of nanocrystalline cemented carbide was studied by scanning electron microscope(SEM),high resolution transmission electron microscope(HRTEM)and mechanical property test.The results showed that the nano WC grains began to grow in the solid phase sintering stage.A high-performance nano-nitrogen-containing cemented carbide with uniform microstructure and good interfacial bonding can be obtained by increasing the sintering temperature to 1380℃.It has a transverse rupture strength(TRS)of 5057 MPa and a hardness of 1956 HV30.

Temperature dependence of mechanical properties and damage evolution of hot dry rocks under rapid cooling

Understanding the differences in mechanical properties and damage characteristics of granitoid under high temperatures is crucial for exploring deep geothermal resources.This study analyzes the evolution of the acoustic emission(AE)characteristics and mechanical parameters of granodiorite and granite after heating and water cooling by uniaxial compression and variable-angle shear tests under different temperature gradients.We identify their changes in mesostructure and mineral composition with electron probe microanalysis and scanning electron microscopy.Results show that these two hot dry rocks have similar diagenetic minerals and microstructure,but show significantly different mechanical and acoustic characteristics,and even opposing evolution trends in a certain temperature range.At the temperatures ranging from 100℃to 500℃,the compressive and shear mechanical properties of granodiorite switch repeatedly between weakening and strengthening,and those of granite show a continuous weakening trend.At 600℃,both rocks exhibit a deterioration of mechanical properties.The damage mode of granite is characterized by initiating at low stress,exponential evolutionary activity,and intensified energy release.In contrast,granodiorite exhibits the characteristics of initiating at high stress,volatile evolutionary activity,and intermittent energy release,due to its more stable microstructure and fewer thermal defects compared to granite.As the temperature increases,the initiation and propagation of secondary cracks in granodiorite are suppressed to a certain extent,and the seismicity and brittleness are enhanced.The subtle differences in grain size,microscopic heterogeneity,and mineral composition of the two hot dry rocks determine the different acoustic-mechanical characteristics under heating and cooling,and the evolution trends with temperature.These findings are of great significance for the scientific and efficient construction of rock mass engineering by rationally utilizing different rock strata properties.

Effect of annealing temperature on microstructure and mechanical properties of Mg-Zn-Zr-Nd alloy with large final rolling deformation

In this study,the Mg-3Zn-0.5Zr-χNd(χ=0,0.6)alloys were subjected to final rolling treatment with large deformation of 50%.The impact of annealing temperatures on the microstructure and mechanical properties was investigated.The rolled Mg-3Zn-0.5Zr-0.6Nd alloy exhibited an ultimate tensile strength of 386 MPa,a yield strength of 361 MPa,and an elongation of 7.1%.Annealing at different temperatures resulted in reduced strength and obviously increased elongation for both alloys.Optimal mechanical properties for the Mg-3Zn-0.5Zr-0.6Nd alloy were achieved after annealing at 200℃,with an ultimate tensile strength of 287 MPa,a yield strength of 235 MPa,and an elongation of 26.1%.The numerous deformed microstructures,twins,and precipitated phases in the rolled alloy could impede the deformation at room temperature and increase the work hardening rate.After annealing,a decrease in the work hardening effect and an increase in the dynamic recovery effect were obtained due to the formation of fine equiaxed grains,and the increased volume fraction of precipitated phases,which significantly improved the elongation of the alloy.Additionally,the addition of Nd element could enhance the annealing recrystallization rate,reduce the Schmid factor difference between basal and prismatic slip systems,facilitate multi-system slip initiation and improve the alloy plasticity.

Difference in extrusion temperature dependences of microstructure and mechanical properties between extruded AZ61 and AZ91 alloys

The effects of extrusion temperature on the microstructure and tensile properties of extruded AZ61 and AZ91 alloys are investigated by subjecting them to hot extrusion at 300 and 400℃.Although the average grain size of the extruded AZ61 alloy slightly increases from 9.5 to 12.6μm with increasing extrusion temperature,its resultant microstructural variation is insignificant.In contrast,the average grain size of the extruded AZ91 alloy significantly increases from 5.7 to 22.5μm with increasing extrusion temperature,and the type of Mg17Al12 precipitates formed in it changes from fine dynamic precipitates with a spherical shape to coarse static precipitates with a lamellar structure.As the extrusion temperature increases,the tensile yield strength of the extruded AZ61 alloy increases from 183 to 197 MPa while that of the extruded AZ91 alloy decreases from 232 to 224 MPa.The tensile elongations of the extruded AZ61 and AZ91 alloys decrease with increasing extrusion temperature,but the degree of decrease is significant in the latter alloy.These different extrusion temperature dependences of the tensile properties of the extruded AZ61 and AZ91 alloys are discussed in terms of their microstructural characteristics,strengthening mechanisms,and crack initiation sites.

Higher Grain-Filling Rate in Inferior Spikelets of Tolerant Rice Genotype Offset Grain Yield Loss under Post-Anthesis High Night Temperatures

Increased nighttime respiratory losses decrease the amount of photoassimilates available for plant growth and yield. We hypothesized that the increased respiratory carbon loss under high night temperatures(HNT) could be compensated for by increased photosynthesis during the day following HNT exposure. Two rice genotypes, Vandana(HNT-sensitive) and Nagina 22(HNT-tolerant), were exposed to HNT(4 ℃ above the control) from flowering to physiological maturity. They were assessed for alterations in the carbon balance of the source(flag leaf) and its subsequent impact on grain filling dynamics and the quality of spatially differentiated sinks(superior and inferior spikelets). Both genotypes exhibited significantly higher night respiration rates. However, only Nagina 22 compensated for the high respiration rates with an increased photosynthetic rate, resulting in a steady production of total dry matter under HNT. Nagina 22 also recorded a higher grain-filling rate, particularly at 5 and 10 d after flowering, with 1.5- and 4.0-fold increases in the translocation of ^(14)C sugars to the superior and inferior spikelets, respectively. The ratio of photosynthetic rate to respiratory rate on a leaf area basis was negatively correlated with spikelet sterility, resulting in a higher filled spikelet number and grain weight per plant, particularly for inferior grains in Nagina 22. Grain quality parameters such as head rice recovery, high-density grains, and gelatinization temperature were maintained in Nagina 22. An increase in the rheological properties of rice flour starch in Nagina 22 under HNT indicated the stability of starch and its ability to reorganize during the cooling process of product formation. Thus, our study showed that sink adjustments between superior and inferior spikelets favored the growth of inferior spikelets, which helped to offset the reduction in grain weight under HNT in the tolerant genotype Nagina 22.

Mechanical properties and damage constitutive model of sandstone after acid corrosion and high temperature treatments

Aiming at the problem of temperature-mechanics-chemical(T-M-C)action encountered by rocks in underground engineering,sandstone was selected as the sample for acid corrosion treatment at pH 1,3,5 and 7,the acid corrosion treated samples were then subjected to high-temperature experiments at 25,300,600,and 900℃,and triaxial compression experiments were conducted in the laboratory.The experimental results show that the superposition of chemical damage and thermal damage has a significant impact on the quality,wave velocity,porosity and compression failure characteristics of the rock.Based on the Lemaitre strain equivalent hypothesis theory,the damage degree of rock material was described by introducing damage variables,and the spatial mobilized plane(SMP)criterion was adopted.The damage constitutive model can well reflect the stress-strain characteristics of the rock triaxial compression process,which verified the rationality and reliability of the model parameters.The experiment and constitutive model analyzed the change law of mechanical properties of rock after chemical corrosion and high temperature thermal damage,which had certain practical significance for rock engineering construction.

High Temperature Rheological Performance of Graphene Modified Rubber Asphalt

To elucidate the high temperature rheological capability of graphene modified rubber asphalt,three contents of graphene and crumb rubber were prepared by a combination of mechanical agitation and high speed shearing machine,then used dynamic shear rheological test(DSR)and multiple stress creep recovery(MSCR)tests to evaluate.The hardness and softening point with rotational viscosity of samples raised with the addition of graphene,especially the addition of 0.04%.Dynamic shear rheological test revealedthat the dynamic shear modulus G*,rutting factor G*/Sin δ,and zero shear viscosity(ZSV)of graphene-modified rubber asphalt were greatly influenced along with graphene-increased,on the contrary,phase angle δ which characterize the viscoelastic ratio of asphalt decreased.Multiple stress creep recovery(MSCR)tests showed that the graphene-enhanced rubber asphalt had high-temperature stability through non-recoverable creep compliance(Jnr).Based on these findings,graphene-modified rubber asphalt binders with the addition of 0.04% graphene had good viscoelastic properties as well as high temperature rutting resistance performance.In the meantime,G*/Sin δ,ZSV,and Jnr100,Jnr3200 have good correlation,which can reveal the excellent high-temperature stability performance of asphalt.

Research and Prediction on the Properties of Concrete at Cryogenic Temperature Based on Gray Theory

To solve the cryogenic temperature problems faced by all-concrete liquefied natural gas(ACLNG)storage tanks during servicing,a low temperature resistant and high strength concrete(LHC)was designed from the perspectives of reducing water-binder ratio,removing coarse aggregates,optimizing composite mineral admixture and utilizing steel fibers.The variation laws of compressive and tensile strength,elastic modulus and Poisson’s ratio for C60 concrete and LHC were compared and analyzed under the temperatures from 10 to-165℃through uniaxial compression and tensile tests.The rapid freezing method was adopted to analyze the evolution process of mass and relative dynamic elastic modulus loss rates for C60 and LHC in 0-300 freeze-thaw cycles.The gas permeability test was carried out,and the laws of gas permeability coefficient varied with temperature and cryogenic freeze-thaw cycles were obtained.Then,the grey dynamic model GM(1,1)was used to predict the variation laws of physical and mechanical parameters on the basis of the test data.The test results demonstrate that the compressive strength,elastic modulus and Poisson’s ratio for both C60 and LHC increase significantly from 10 to-165℃,but the specific variation laws are difierent,and there is a phenomenon that some parameters decrease after reaching a critical temperature range for C60.The uniaxial tensile strength increases first and then decreases as temperature decreases,and finally increases slightly at-165℃for both C60 and LHC.The mass and relative dynamic elastic modulus loss rates of LHC are much lower than that of C60 under different freeze-thaw cycles.The gas permeability coefficient of C60 declines gradually with the drop of temperature,and increases gradually with the number of freeze-thaw cycles while the gas permeability coefficient of LHC basically remains stable and is much lower than that of C60.Therefore,such a conclusion can be drawn that LHC has better properties at cryogenic temperature.On the premise of providing consistent functional mode,GM(1,1)can predict the test data with high accuracy,which well reflects the variation laws of relevant parameters.

Elevated Temperature Properties of Bamboo Shaving Reinforced Geopolymer Composites

Geopolymer is a new alternative cement binder to produce concrete.In the present study,a novel geopolymer composites containing bamboo shaving(0–2 wt.%)were fabricated and exposed to the temperatures of 200℃,400℃,600℃and 800℃.Physical properties,micro-structure,and mechanical strengths of the geopolymer composites were evaluated before and after heating in order to understand their thermal properties,which are essential for the use as building materials.As the temperature rises,the drying shrinkage and apparent porosity of the composites increase,while the compressive and bending strengths decrease.At the temperature range of 200℃–800℃,the residual compressive strength rates of the geopolymer composite containning 2 wt.%bamboo shaving were respective 73.8%,61.47%,56.16%,and 29.56%,meanwhile,the residual flexural strength rates were respective 46.69%,8.68%,2.52%,and 2.33%.Correspondingly,the residual compressive strength rates of pure geopolymer were respective 72.81%,61.99%,54.55%,and 14.64%;the residual flexural strength rates were 48.87%,5.69%,3.22%,and 2.47%,respectively.Scanning electron microscope(SEM),optical microscope,and X-ray diffractometry(XRD)were applied to find the microscopic changes.The strength loss in the geopolymer composites was mainly because of the thermal degradation of bamboo shaving and shrinkage of geopolymer matrix.Bamboo shaving has great potential as reinforcer in developing low-cost geopolymer composites and may be used for applications up to 400℃.

Wire arc additive manufacturing of a heat-resistant Al-Cu-Ag-Sc alloy:microstructures and high-temperature mechanical properties

With a high energy efficiency,low geometric limitation,and low cracking susceptivity to cracks,wire arc additive manufacturing(WAAM)has become an ideal substitute for casting in the manufacturing of load-bearing high strength aluminum components in aerospace industry.Recently,in scientific researches,the room temperature mechanical performance of additive manufactured high strength aluminum alloys has been continuously broken through,and proves these alloys can achieve comparable or even higher properties than the forged counterpart.Since the aluminum components for aerospace usage experience high-low temperature cycling due to the absence of atmosphere protection,the high temperature performances of additive manufactured high strength aluminum alloys are also important.However,few research focuses on that.A special 2319Ag Sc with 0.4 wt.%Ag and 0.2 wt.%Sc addition designed for high temperature application is deposited successfully via cold metal transfer(CMT)based on WAAM.The microstructures and high temperature tensile properties are investigated.The results show that the as-deposited 2319Ag Sc alloy presents an alternate distribution of columnar grains and equiaxed grains with no significant textures.Main second phases are Al_(2)Cu and Al3Sc,while co-growth of Al_(2)Cu and bulk Al_(3)Sc is found on the grain boundary.During manufacturing,nanoscale Al_(2)Cu can precipitate out from the matrix.Ag and Mg form nano-scaleΩphase on the Al_(2)Cu precipitates.At 260℃,average yield strengths in the horizontal direction and vertical direction are 87 MPa±2 MPa,87 MPa±4 MPa,while average ultimate tensile strengths are 140 MPa±7 MPa,141 MPa±11 MPa,and average elongations are 11.0%±2.5%,13.5%±3.0%.Anisotropy in different directions is weak.

Comparison of mechanical properties in high temperature and thermal treatment granite

Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious form, stress-strain curve, peak strength, peak strain and elastic modulus with temperature were analyzed and the essence of rock failure modes was explored. The results indicate that, compared with granite after the high temperature treatment, the brittle-ductile transition critical temperature is lower, the densification stage is longer, the elastic modulus is smaller and the damage is larger under high temperature. In addition, the peak stress is lower and the peak strain is greater, but both of them change more obviously with the increase of temperature compared with that of granite after the high temperature treatment. Furthermore, the failure modes of granite after the high temperature treatment and under high temperature show a remarkable difference. Below 100 ℃, the failure modes of granite under both conditions are the same, presenting splitting failure. However, after 100 ℃, the failure modes of granite after the high temperature treatment and under high temperature present splitting failure and shear failure, respectively.

Effect of temperature on dielectric property and microwave heating behavior of low grade Panzhihua ilmenite ore

The permittivity of low grade Panzhuhua ilmenite ore at 2.45 GHz in the temperatures from 20 ℃ up to 100 ℃ was measured using the technology of open-ended coaxial sensor combined with theoretical computation. The results show that both the real （ε′） and imaginary （ε′） part of complex permittivity （ε′-jε′） of the ilmenite significantly increase with temperature. The loss tangent （tanδ） is a quadratic function of temperature, and the penetration depth of ilmenite decreases with temperature increase from 20 ℃to 100 ℃ The increase of the sample temperature under microwave radiation displays a nonlinear relationship between the temperature （T） and microwave heating time （t）. The positive feedback interaction between complex permittivity and sample temperature amplifies the interaction between ilmenite and the microwave radiation. The optimum dimensions for uniform heat deposition vary from 10 cm to 5 cm （about two power penetration depths） in a sample being irradiated from both sides in a 2.45 GHz microwave field when temperature increases from room temperature to 100 ℃

Rheological properties of warm mix asphalt binder by DSR test at medium temperature

The rheological properties including the complex modulus G＊ and the phase angle δof matrix and warm mix asphalt （WMA）binders were measured by using the dynamic shear rheometer （DSR ） test at the medium temperature ranging from 16 to 40 ℃,and the relationships between the fatigue factor G＊ sinδand the matrix binder property,WMA additive and test temperature were established.It is found that G＊ decreases with the increasing temperature while δincreases inversely,and G＊ of the asphalt binder with high WMA additive dosage is large,and δis small.G＊sinδexponentially decreases with the increasing temperature and linearly increases with the increase in additive dosage,and the amplitudes of variation are large at low temperatures and high additive dosages.The effect of WMA additive on the rheological property is more remarkable for the matrix asphalt binder with low G＊.Besides,aging has a great effect on the property of matrix asphalt binder,and a slight effect on the interaction between asphalt and additive.The high additive dosage can increase the fatigue cracking potential of the asphalt binder.

Influence of pyrolysis temperature on structure and dielectric properties of polycarbosilane derived silicon carbide ceramic

β-SiC ceramic powders were obtained by pyrolyzing polycarbosilane in vacuum at 800-1200 °C. The β-SiC ceramic powders were characterized by TGA/DSC, XRD and Raman spectroscopy. The dielectric properties of β-SiC ceramic powders were investigated by measuring their complex permittivity by rectangle wave guide method in the frequency range of 8.2-18 GHz. The results show that both real part ε′ and imaginary part ε″ of complex permittivity increase with increasing pyrolysis temperature. The mechanism was proposed that order carbon formed at high temperature resulted in electron relaxation polarization and conductance loss, which contributes to the increase in complex permittivity.

Molecular dynamics study on temperature and strain rate dependences of mechanical tensile properties of ultrathin nickel nanowires

Based on the EAM potential, a molecular dynamics study on the tensile properties of ultrathin nickel nanowires in the （100〉 orientation with diameters of 3.94, 4.95 and 5.99 nm was presented at different temperatures and strain rates. The temperature and strain rate dependences of tensile properties were investigated. The simulation results show that the elastic modulus and the yield strength are gradually decreasing with the increase of temperature, while with the increase of the strain rate, the stress--strain curves fluctuate more intensely and the ultrathin nickel nanowires rupture at one smaller and smaller strain. At an ideal temperature of 0.01 K, the yield strength of the nanowires drops rapidly with the increase of strain rate, and at other temperatures the strain rate has a little influence on the elastic modulus and the yield strength. Finally, the effects of size on the tensile properties of ultrathin nickel nanowires were briefly discussed.

Mechanical properties of Mg-6Gd-1Y-0.5Zr alloy processed by low temperature thermo-mechanical treatment

An as-solution treated Mg-6Gd-1Y-0.4Zr alloy was processed by low temperature thermo-mechanical treatments （LT-TMT）, including cold tension with various strains followed by aging at 200 °C to peak hardness. The results show that the precipitation kinetics of the alloy experienced LT-TMT is greatly accelerated and the aging time to peak hardness is greatly decreased with increasing tensile strain. The tensile yield strength, ultimate tensile strength and elongation at room temperature of the alloy after cold tension with strain of 10% and peak aging at 200 °C are 251 MPa, 296 MPa and 8%, respectively, which are superior to the commercial heat-resistant WE54 alloy, although the latter has a higher rare earth element content.

Dielectric properties and temperature increase characteristics of zinc oxide dust from fuming furnace

Cavity perturbation method was used to determine the dielectric properties （ε′,ε″, and tanδ） of zinc oxide dust in different apparent densities. The process was conducted to study the microwave-absorption properties of zinc oxide dust and the feasibility of microwave roasting zinc oxide dust to remove fluorine and chlorine. The dielectric constant, dielectric loss, and loss tangent were proportional to the apparent density of zinc oxide dust. The effects of sample mass and microwave power on the temperature increase characteristics under the microwave field were also studied. The results show that the apparent heating rate of the zinc oxide dust increases with the increase in microwave roasting power and decreases with the increase in the sample mass. The temperature of the samples reaches approximately 800 ＆#176;C after microwave treatment for 8 min, which indicates that the zinc oxide dust has strong microwave-absorption ability.

Effects of Storage Temperature on Pasting Properties of Brown Rice

[Objective] The aim of this study was to explore the effects of storage temperature on pasting properties of brown rice.[Method] Rapid viscosity analyzer was used to determine the viscosity of brown rice under different storage temperatures（30,25,20 and 15 ℃）.[Result] The peak viscosity value increased with storage time prolonging.The higher the storage temperature was,the more rapidly the increasing of peak viscosity value;different storage temperatures and storage time showed significant effects on peak viscosity value of brown rice;the difference on peak viscosity value of brown rice under different storage temperatures was significant.The hot viscosity value of brown rice stored under 30 and 25 ℃ gradually increased with the storage time prolonging;and storage time and storage temperature showed significant effects on hot viscosity value;there was extremely significant difference on hot viscosity value of brown rice under 30,25 and 20,15 ℃.The breakdown value showed a first increasing and then decreasing trend with the storage time prolonging;storage temperature and storage time had extremely significant effect on the breakdown value of brown rice;the breakdown value of brown rice among each storage temperature was extremely significant.The final viscosity of brown rice increased with storage time prolonging.The higher the temperature was,the higher the increasing rate of final viscosity;storage time and temperature showed extremely significant effect on the final viscosity of brown rice;the difference on final viscosity among different storage temperature treatments was extremely significant.The changes on setback value of brown rice under different storage temperature treatments were different with the storage time prolonging;and the storage temperature showed extremely significant effect on the setback value of brown rice.[Conclusion] The study had provided theoretical basis for the storage of brown rice.

Effects of temperature on tensile properties and deformation behavior of GH4586A superalloy

Effects of temperature on tensile properties and deformation behavior of the nickel-based superalloy GH4586A have been investigated. The results showed that deforming temperature has no effect on the microstructure of the alloy, while tensile properties are thermo-sensitive. With the increasing testing temperature the strength of the alloy decreased, and the ductility increased. While, the ductility of the alloy decreased weakly at the temperature range of 823 K to 923 K. And the main reason can be considered as the easily-broken of the MC type block carbides due to the stress concentration at the interface between the matrix and carbides to form the micro-cracks during the deforming process.

Effects of pouring temperature and cylinder temperature on microstructures and mechanical properties of rheomoulding AZ91D alloy

An advanced rheomoulder,which is a device in the integration of melting metal,storage,slurry preparation,transportation and injection forming,was introduced and used to manufacture rheomoulding AZ91 D alloy.Effects of pouring temperature and cylinder temperature on microstructures and mechanical properties of rheomoulding AZ91 D alloy were investigated.The results show that the process can obtain such rheomoulding AZ91 D in which primary α-Mg particles are fine,spherical and uniformly distributed in the matrix.With the decrease of pouring temperature,the morphology of primary α-Mg particles changes from coarse rosette-like to fine spherical shape gradually.As the cylinder temperature decreases,the average size of primary α-Mg particles decreases firstly and then substantially maintains stable while the sphericity and solid fraction increase continuously.Also,decreasing pouring temperature or cylinder temperature properly contributes to improving mechanical properties of rheomoulding AZ91 D for the refinement of α-Mg particles and the decrease of porosity fraction.Furthermore,rheomoulding AZ91 D performs much better than thixomoulding,rheo-diecasting and high pressure die-casting（HPDC） in terms of mechanical properties.Compared with HPDC,the tensile strength,yield strength and elongation are increased by 27.8%,15.7% and 121%,respectively.