Different contents of biodiesel and petrodiesel were incorporated into diesel engine oils. The oxidative stability, detergency and antiwear performance of the formulated diesel oils were evaluated. The results indicat...Different contents of biodiesel and petrodiesel were incorporated into diesel engine oils. The oxidative stability, detergency and antiwear performance of the formulated diesel oils were evaluated. The results indicated that, compared with petrodiesel, biodiesel was more liable to promote oxidation degradation of diesel oils, leading to worse oxidative stability, detergency and antiwear ability of the oils.展开更多
A heterocyclic derivative of (2 sulphurone benzothiazole) 3 methyl dodecanoate was synthesized. Its tribological performance when added to liquid paraffin was evaluated on a four ball tester and a ring on block machin...A heterocyclic derivative of (2 sulphurone benzothiazole) 3 methyl dodecanoate was synthesized. Its tribological performance when added to liquid paraffin was evaluated on a four ball tester and a ring on block machine. Results indicate that compared with the base oil the wear resistance and load carrying capacities of the oil with novel additive are improved, and the friction coefficient is decreased. There is an optimal content of the novel compound, at which the corresponding oil gives the highest maximum non seizure load. Above the content, the load carrying capacity of the oil is not increased but decreased. The nature of the film formed on the rubbed surface was investigated by X ray photoelectron spectroscopy (XPS) analysis, and the action mechanism of the novel compound was discussed. [展开更多
CeF3. CaF2, (CF)n, SbF3, and CeO2 were selected as the high temperature solid additives in a lithium grease, and their friction, wear, and extreme pressure properties were evaluated on an Optimol-SRV wear tester. The ...CeF3. CaF2, (CF)n, SbF3, and CeO2 were selected as the high temperature solid additives in a lithium grease, and their friction, wear, and extreme pressure properties were evaluated on an Optimol-SRV wear tester. The effect of additive on the fiber structure of soap was studied by means of the transmission electron microscopy(TEM). The corrosive property of grease containing additive was evaluated by copper strip corrosion test. Thermal decomposition behaviors of the additives were studied by thermogravimetry(TG) tester. The adhesive strength of rubbing surface film was measured by automatic scratch tester and the wear surface was detected by means of X-ray photoelectron spectroscopy (XPS). The test results showed that the grease containing CeF3 has good anti-wear, anti-friction, and EP performances, and has high adhesive strength of rubbing surface film.The greases containing CaF2 or (CF)n are good in antiwear and anti-friction properties, but poor in extreme pressure function. The tribological properties of the grease containing SbF3 are decreased.And the addition of CeO2 in grease was useless. Finally the mechanism of fluoride additive was proposed in this paper.展开更多
Simulated adsorptive experiments using the axletree and lubricating oil containing anticorrosion additive were conducted,and the UV absorbance of the lubricating oil before and after the adsorptive experiments was mea...Simulated adsorptive experiments using the axletree and lubricating oil containing anticorrosion additive were conducted,and the UV absorbance of the lubricating oil before and after the adsorptive experiments was measured.Through the UV spectral measurements the difference in UV absorbance of the lubricating oil before and after the adsorptive experiments was identified,the adsorbed quantity of anticorrosion additive in the interfacial film between lubricating oil and bearing was calculated using the Lambert-Bell principle to verify the adsorption of corrosion inhibitor on the surface of friction pairs.Adsorption experiments on lubricating oil containing both antiwear and anticorrosion additives were carried out and the UV absorbance of lubricating oil samples before and after the experiments was measured to determine the difference in the UV absorbance among lubricating oil samples with the same mass fraction of anticorrosion additive and different mass fractions of antiwear additive.By measuring the ultraviolet spectral absorbance of lubricating oil samples and calculating the adsorbed quantity of anticorrosion additive in the interfacial film it was possible to determine the influence of antiwear additive on the quantity of adsorbed anticorrosion additive on the surface of friction pairs and verify the competitive adsorption relationship between the antiwear additive and the anticorrosion additive.展开更多
基金the financial support from the Natural Science Foundation of Chongqing(Project NO. CSTC, 2011JJA90020)the Science Foundation for Young Teachers of Logistical Engineering University
文摘Different contents of biodiesel and petrodiesel were incorporated into diesel engine oils. The oxidative stability, detergency and antiwear performance of the formulated diesel oils were evaluated. The results indicated that, compared with petrodiesel, biodiesel was more liable to promote oxidation degradation of diesel oils, leading to worse oxidative stability, detergency and antiwear ability of the oils.
文摘A heterocyclic derivative of (2 sulphurone benzothiazole) 3 methyl dodecanoate was synthesized. Its tribological performance when added to liquid paraffin was evaluated on a four ball tester and a ring on block machine. Results indicate that compared with the base oil the wear resistance and load carrying capacities of the oil with novel additive are improved, and the friction coefficient is decreased. There is an optimal content of the novel compound, at which the corresponding oil gives the highest maximum non seizure load. Above the content, the load carrying capacity of the oil is not increased but decreased. The nature of the film formed on the rubbed surface was investigated by X ray photoelectron spectroscopy (XPS) analysis, and the action mechanism of the novel compound was discussed. [
文摘CeF3. CaF2, (CF)n, SbF3, and CeO2 were selected as the high temperature solid additives in a lithium grease, and their friction, wear, and extreme pressure properties were evaluated on an Optimol-SRV wear tester. The effect of additive on the fiber structure of soap was studied by means of the transmission electron microscopy(TEM). The corrosive property of grease containing additive was evaluated by copper strip corrosion test. Thermal decomposition behaviors of the additives were studied by thermogravimetry(TG) tester. The adhesive strength of rubbing surface film was measured by automatic scratch tester and the wear surface was detected by means of X-ray photoelectron spectroscopy (XPS). The test results showed that the grease containing CeF3 has good anti-wear, anti-friction, and EP performances, and has high adhesive strength of rubbing surface film.The greases containing CaF2 or (CF)n are good in antiwear and anti-friction properties, but poor in extreme pressure function. The tribological properties of the grease containing SbF3 are decreased.And the addition of CeO2 in grease was useless. Finally the mechanism of fluoride additive was proposed in this paper.
文摘Simulated adsorptive experiments using the axletree and lubricating oil containing anticorrosion additive were conducted,and the UV absorbance of the lubricating oil before and after the adsorptive experiments was measured.Through the UV spectral measurements the difference in UV absorbance of the lubricating oil before and after the adsorptive experiments was identified,the adsorbed quantity of anticorrosion additive in the interfacial film between lubricating oil and bearing was calculated using the Lambert-Bell principle to verify the adsorption of corrosion inhibitor on the surface of friction pairs.Adsorption experiments on lubricating oil containing both antiwear and anticorrosion additives were carried out and the UV absorbance of lubricating oil samples before and after the experiments was measured to determine the difference in the UV absorbance among lubricating oil samples with the same mass fraction of anticorrosion additive and different mass fractions of antiwear additive.By measuring the ultraviolet spectral absorbance of lubricating oil samples and calculating the adsorbed quantity of anticorrosion additive in the interfacial film it was possible to determine the influence of antiwear additive on the quantity of adsorbed anticorrosion additive on the surface of friction pairs and verify the competitive adsorption relationship between the antiwear additive and the anticorrosion additive.
