Unusual intense infrared-to-ultraviolet upconversion luminescence was observed in YF3：yb3＋（20%）/Tm3＋（1%） nanocrystals under 980 ran excitation. The intense ultraviolet emissions （1I6→^3H6, ^1I6→3F4, and ^1D2...Unusual intense infrared-to-ultraviolet upconversion luminescence was observed in YF3：yb3＋（20%）/Tm3＋（1%） nanocrystals under 980 ran excitation. The intense ultraviolet emissions （1I6→^3H6, ^1I6→3F4, and ^1D2→^3H6） were affirmed arisillg from the excitation processes of five-photon and four-photon. In comparison with the bulk sample with the same chemical compositions, ultraviolet upconversion luminescence of the nanocrystals was markedly enhanced. Spectral analysis indicated that the enhancement was attributed to the decrease of Judd-Ofelt parameter Ω2, which precluded the transition rate from 3F2 to 3F4, enhanced the energy transfer process and populated the ^1D2 level： ^3F2→^3H6 （Tm^3＋）： 3H4→^1D2 （Tm^3＋）.展开更多
基金supported by the National Natural Science Foundation of China (10474096 and 50672030)
文摘Unusual intense infrared-to-ultraviolet upconversion luminescence was observed in YF3：yb3＋（20%）/Tm3＋（1%） nanocrystals under 980 ran excitation. The intense ultraviolet emissions （1I6→^3H6, ^1I6→3F4, and ^1D2→^3H6） were affirmed arisillg from the excitation processes of five-photon and four-photon. In comparison with the bulk sample with the same chemical compositions, ultraviolet upconversion luminescence of the nanocrystals was markedly enhanced. Spectral analysis indicated that the enhancement was attributed to the decrease of Judd-Ofelt parameter Ω2, which precluded the transition rate from 3F2 to 3F4, enhanced the energy transfer process and populated the ^1D2 level： ^3F2→^3H6 （Tm^3＋）： 3H4→^1D2 （Tm^3＋）.
