Surface molecularly imprinted polymers (SMIPs) for selective adsorption of ampicillin sodium were synthesized using surface molecular imprinting technique with silica gel as a support. The physical and morphological...Surface molecularly imprinted polymers (SMIPs) for selective adsorption of ampicillin sodium were synthesized using surface molecular imprinting technique with silica gel as a support. The physical and morphological characteristics of the polymers were investigated by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), elemental analysis and nitrogen adsorption-desorption test. The obtained results showed that the SMIPs displayed great adsorption capacity (13.5 lag/mg), high recognition ability (the imprinted factor is 3.2) and good binding kinetics for ampicillin sodium. Finally, as solid phase extraction adsorbents, the SMIPs coupled with HPLC method were validated and applied for the enrichment, purification and determination of anapicillin sodium in real milk and blood samples. The averages of spiked accuracy ranged from 92.1% to 107.6%. The relative standard deviations of intra- and inter-day precisions were less than 4.6%. This study provides a new and promising method for enriching, extracting and determining ampicillin sodium in complex biological samples.展开更多
A new one-dimensional double chain coordination polymer, [Na(cbsH)(H2O)3]n (cbsH = 4-carboxy-benzenesulfonic anion), has been synthesized by aqueous reaction, structurally described, and thermally characterized....A new one-dimensional double chain coordination polymer, [Na(cbsH)(H2O)3]n (cbsH = 4-carboxy-benzenesulfonic anion), has been synthesized by aqueous reaction, structurally described, and thermally characterized. It crystallizes in the triclinic system, space group P with a = 5.645(4), b = 7.905(5), c = 13.043(8) , α = 89.391(7), β = 80.637(7), γ = 82.845(7)°, V = 569.8(6) 3, Z = 2, C7H11NaO8S, Mr = 278.21, Dc = 1.622 Kg/m3, F(000) = 288, R = 0.0260 and wR = 0.0697. The title compound consists of one-dimensional double chains. 4-Carboxy-benzenesulfonic acid acts as a bridging bidentate ligand to link two sodium(I) ions to form a binuclear structure. Remarkably, the sodium(I) ion behaves as a metal bridge so that the binuclear structure units are connected to construct a one-dimensional double chain polymer. Furthermore, a 3-D framework is assembled through intermolecular hydrogen bonds. Thermogravimetric analysis shows that this compound begins losing the free solvent molecules at 106 ℃ and decompounding completely at 580 ℃.展开更多
Enabling highly reversible sodium(Na) metal anodes in a polymer electrolyte(PE) system is critical for realizing next-generation batteries with lower cost,higher energy,and improved safety.However,the uneven Na deposi...Enabling highly reversible sodium(Na) metal anodes in a polymer electrolyte(PE) system is critical for realizing next-generation batteries with lower cost,higher energy,and improved safety.However,the uneven Na deposition and high Na/PE interphase resistance lead to poor reversibility and short cycle life of Na metal anodes.To tackle these problems,here a variety of metal nanoparticles(M-np,M=Al,Sn,In or Au) are deposited onto copper(Cu) foils to synthesize binder-free M-np@Cu substrates for Na plating/stripping.Notably,the Au-np@Cu substrate provides abundant preferential nucleation/growth sites,decreasing Na nucleation barrier and thus promoting uniform Na deposition.Accordingly,stable Na metal anodes are achieved with high reversible capacities,long cycle life,and high usage of Na.With the Au-np@Cu/Na anode and PE,the full cell using a commercial bulk sulfur cathode exhibits a reversible capacity of>400 mAh g^(-1) with near-100% Coulombic efficiency over 200 cycles.展开更多
The sodium chloride methanol solution process is conducted on the conventional poly(3-hexylthiophene)(P3HT)/[6,6]-phenyl-C61-butyric acid methyl ester(PC_(61)BM) polymer bulk heterojunction solar cells. The de...The sodium chloride methanol solution process is conducted on the conventional poly(3-hexylthiophene)(P3HT)/[6,6]-phenyl-C61-butyric acid methyl ester(PC_(61)BM) polymer bulk heterojunction solar cells. The device exhibits a power conversion efficiency of up to 3.36%, 18% higher than that of the device without the solution process. The measurements of the active layer by x-ray photoelectron spectroscopy(XPS), atomic force microscopy(AFM), and ultraviolet photoelectron spectroscopy(UPS) indicate a slight phase separation in the vertical direction and a sodium chloride distributed island-like interface between the active layer and the cathode. The capacitance–voltage(C–V) and impedance spectroscopy measurements prove that the sodium chloride methanol process can reduce the electron injection barrier and improve the interfacial contact of polymer solar cells. Therefore, this one-step solution process not only optimizes the phase separation in the active layers but also forms a cathode buffer layer, which can enhance the generation, transport, and collection of photogenerated charge carriers in the device simultaneously. This work indicates that the inexpensive and non-toxic sodium chloride methanol solution process is an efficient one-step method for the low cost manufacturing of polymer solar cells.展开更多
Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in m...Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of^12 nm,high surface area of 401 m2 g−1,and large pore volume of 0.53 cm3 g−1.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.展开更多
Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassiun persulfate as the initiator. The effect of suspension parameters, ...Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassiun persulfate as the initiator. The effect of suspension parameters, such as volume ratio of continuous phase and dispersed phase,type and dosage of suspending agents, on water absorbency of the starch grafted polymer was studied.Different starch derivatives were also investigated.Superabsorbents made of cationic starch has higher water absorbency than that made of native corn starch.展开更多
Poly(ethylene methyl phosphate)-poly(ethylene glycol)-poly(ethylene methyl phosphate) triblock copolymers carrying hydroxyl group at both chain ends were synthesized with sodium poly(ethylene glycol)ate as initiator. ...Poly(ethylene methyl phosphate)-poly(ethylene glycol)-poly(ethylene methyl phosphate) triblock copolymers carrying hydroxyl group at both chain ends were synthesized with sodium poly(ethylene glycol)ate as initiator. The effects of the factors such as solvent, amount of the initiator and reaction time were investigated. The copolymers were characterized by IR, H-1-NMR, H-1{P-31}-NMR, C-13-NMR, P-31{H-1}-NMR, and DSC. High molecular weight of the copolymer and high yield of the polymerization were achieved within 3 min at 25 degrees C. The polymerization process was studied by P-31{H-1}-NMR and transesterification was found during longer polymerization time.展开更多
One new polymer, [Na(NPHSNPAB)(CH3OH)]n, where NPHSNPAB stands for Nphenyl-2-[2-hydroxy-3-sulfo-5-nitrophenylhydrazone]butadione-1,3, has been synthesized and characterized by ^1H NMR and FTIR spectroscopy and sin...One new polymer, [Na(NPHSNPAB)(CH3OH)]n, where NPHSNPAB stands for Nphenyl-2-[2-hydroxy-3-sulfo-5-nitrophenylhydrazone]butadione-1,3, has been synthesized and characterized by ^1H NMR and FTIR spectroscopy and single-crystal X-ray diffraction. For this complex: C(17)H(17)N4NaO9S, Mr = 476.39, triclinic system, space group P1, a = 8.8741(18), b = 10.942(2), c = 12.039(2) A, α = 65.74(3), β = 77.49(3), γ = 84.30(3)o, V = 1040.3(4) A3, Z = 2, Dc = 1.521 g/cm^3, λ = 0.71073 A, F(000) = 492, S = 1.106, R = 0.0614 and w R = 0.1423 for 2945 observed reflections with I 〉 2(I). X-ray structural analysis revealed that the structure of NPHSNPAB framework was almost planar by C–H···O, N–H···O, O–H···O, and O–H···S hydrogen bonds. Moreover, sodium(I) center was bound by six O and one N atoms, forming the coordination polymer. The molecular packing diagram showed complicated hydrogen bonds and π···π stacking interaction in the polymer. The average bond distance of the two dicyclic units(3.768 A) indicated strong π···π stacking interaction. The complex displays greenyellow emission at room temperature.展开更多
A new cobalt-sodium coordination polymer [CoNa(C_9H_9N_3O_2S)_2·H_2O]_2·C_2H_3N·H_2O(1) has been synthesized with cobalt chloride,2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide(L) an...A new cobalt-sodium coordination polymer [CoNa(C_9H_9N_3O_2S)_2·H_2O]_2·C_2H_3N·H_2O(1) has been synthesized with cobalt chloride,2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide(L) and sodium hydroxide.It crystallizes in the triclinic space group P1,with a = 9.972(4),b = 10.923(4),c = 13.489(5) ?,α = 108.005(10),β = 92.728(10),γ = 93.16(1)o,V = 1392.0(9) ?~3,Mr = 1151.95,Dc = 1.374 g/cm^3,Z = 2,F(000) = 592,the final GOOF = 1.126,R = 0.1091 and wR = 0.2412.Each unit molecule consists of two cobalt ions and two sodium ions bridged by four 2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide anions.The coordination environment of Co ion is CoO_2N_2S_2,giving a distorted octahedral geometry and the Na(1) ion is NaO_4N,giving a distorted square pyramidal geometry.The results show that 1 shows one strong intense fluorescence emission wavelength of 429 nm with an excitation wavelength of 376 nm,and the electron transfer of 1 is irreversible in electrode reactions.展开更多
All-solid-state sodium-ion battery is regarded as the next generation battery to replace the current commercial lithium-ion battery, with the advantages of abundant sodium resources, low price and high-level safety. A...All-solid-state sodium-ion battery is regarded as the next generation battery to replace the current commercial lithium-ion battery, with the advantages of abundant sodium resources, low price and high-level safety. As one critical component in sodium-ion battery, solid-state electrolyte should possess superior operational safety and design simplicity, yet reasonable high room-temperature ionic conductivity. This paper gives a comprehensive review on the recent progress in solid-state electrolyte materials for sodium-ion battery, including inorganic ceramic/glass-ceramic, organic polymer and ceramic-polymer composite electrolytes, and also provides a comparison of the ionic conductivity in various solid-state electrolyte materials. The development of solid-state electrolytes suggests a bright future direction: all solid-state sodium-ion battery could be fully used to power all electric road vehicles, portable electronic devices and large-scale grid support.展开更多
The effectiveness of a superabsorbent polymer of sodium polyacrylate was studied, with emphasis on water management, i.e., absorption, retention and desorption in the soil. The polymer was applied in plots with a sand...The effectiveness of a superabsorbent polymer of sodium polyacrylate was studied, with emphasis on water management, i.e., absorption, retention and desorption in the soil. The polymer was applied in plots with a sandy soil near Grandola (southern Portugal). Characterization of the most relevant physical and chemical properties of the polymer was made, namely, its specific gravity, particle diameter, capacity of water absorption and desorption. In the plots with and without the polymer, soil moisture was continuously monitored, and grassland biomass samples were collected and weighed. The results reflected the effective role of the polymer both in the improvement of the water regime in the soil and in the substantial increment of grassland productivity.展开更多
The objective of this study is to develop chitosaneanionic polymers based extendedrelease tablets and test the feasibility of using this system for the sustained release of highly water-soluble drugs with high drug lo...The objective of this study is to develop chitosaneanionic polymers based extendedrelease tablets and test the feasibility of using this system for the sustained release of highly water-soluble drugs with high drug loading.Here,the combination of sodium valproate(VPS)and valproic acid(VPA)were chosen as the model drugs.Anionic polymers studied include xanthan gum(XG),carrageenan(CG),sodium carboxymethyl cellulose(CMC-Na)and sodium alginate(SA).The tablets were prepared by wet granulation method.In vitro drug release was carried out under simulated gastrointestinal condition.Drug release mechanism was studied.Compared with single polymers,chitosaneanionic polymers based system caused a further slowdown of drug release rate.Among them,CS exanthan gum matrix system exhibited the best extended-release behavior and could extend drug release for up to 24 h.Differential scanning calorimetry(DSC)and Fourier transform infrared spectroscopy(FTIR)studies demonstrated that polyelectrolyte complexes(PECs)were formed on the tablet surface,which played an important role on retarding erosion and swelling of the matrix in the later stage.In conclusion,this study demonstrated that it is possible to develop highly water-soluble drugs loaded extendedrelease tablets using chitosaneanionic polymers based system.展开更多
Acrylonitrile-sodium styrene sulfonate copolymer/layered double hydroxides nanocomposites were prepared by in situ aqueous precipitation copolymerization of acrylonitrile(AN)and sodium styrene sulfonate(SSS)in the pre...Acrylonitrile-sodium styrene sulfonate copolymer/layered double hydroxides nanocomposites were prepared by in situ aqueous precipitation copolymerization of acrylonitrile(AN)and sodium styrene sulfonate(SSS)in the presence of 4-vinylbenzene sulfonate intercalated layered double hydroxides(MgAl-VBS LDHs)and transferred to acrylonitrile-styrene sulfonic acid(AN-SSA)copolymer/LDHs nanocomposites as a proton-conducting polymer electrolyte.MgAl-VBS LDHs were prepared by a coprecipitation method,and the structure and composition of MgAl-VBS LDHs were determined by X-ray diffraction(XRD),infrared spectroscopy,and elemental analysis.X-ray diffraction result of AN-SSS copolymer/LDHs nanocomposites indicated that the LDHs layers were well dispersed in the AN-SSS copolymer matrix.All the AN-SSS copolymer/LDHs nanocomposites showed significant enhancement of the decomposition temperatures compared with the pristine AN-SSS copolymer,as identified by the thermogravimetric analysis.The methanol crossover was decreased and the proton conductivity was highly enhanced for the AN-SSA copolymer/LDHs nanocomposite electrolyte systems.In the case of the nanocomposite electrolyte containing 2%(by mass)LDHs,the proton conductivity of 2.60×10 -3 S·m -1 was achieved for the polymer electrolyte.展开更多
Constipation is a common functional gastrointestinal disorder which has caused much discomfort affecting the quality of life. The prevalence of constipation in the general population is approximately 20%(1)Various kin...Constipation is a common functional gastrointestinal disorder which has caused much discomfort affecting the quality of life. The prevalence of constipation in the general population is approximately 20%(1)Various kinds of laxatives were introduced such as bulking agent, stool softener, stimulant, and osmotic agent (2)Fixed dose combination with bisacodyl as a stimulant and docusate sodium as a stool softener, Ducolax STM, was developed as enteric coated tablets targeting colon.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 81573391 and 81173024)the National Key Projects of China (No. 812277802)
文摘Surface molecularly imprinted polymers (SMIPs) for selective adsorption of ampicillin sodium were synthesized using surface molecular imprinting technique with silica gel as a support. The physical and morphological characteristics of the polymers were investigated by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), elemental analysis and nitrogen adsorption-desorption test. The obtained results showed that the SMIPs displayed great adsorption capacity (13.5 lag/mg), high recognition ability (the imprinted factor is 3.2) and good binding kinetics for ampicillin sodium. Finally, as solid phase extraction adsorbents, the SMIPs coupled with HPLC method were validated and applied for the enrichment, purification and determination of anapicillin sodium in real milk and blood samples. The averages of spiked accuracy ranged from 92.1% to 107.6%. The relative standard deviations of intra- and inter-day precisions were less than 4.6%. This study provides a new and promising method for enriching, extracting and determining ampicillin sodium in complex biological samples.
基金supported by Henan tackle key problem of science and technology (No. 072102270034)
文摘A new one-dimensional double chain coordination polymer, [Na(cbsH)(H2O)3]n (cbsH = 4-carboxy-benzenesulfonic anion), has been synthesized by aqueous reaction, structurally described, and thermally characterized. It crystallizes in the triclinic system, space group P with a = 5.645(4), b = 7.905(5), c = 13.043(8) , α = 89.391(7), β = 80.637(7), γ = 82.845(7)°, V = 569.8(6) 3, Z = 2, C7H11NaO8S, Mr = 278.21, Dc = 1.622 Kg/m3, F(000) = 288, R = 0.0260 and wR = 0.0697. The title compound consists of one-dimensional double chains. 4-Carboxy-benzenesulfonic acid acts as a bridging bidentate ligand to link two sodium(I) ions to form a binuclear structure. Remarkably, the sodium(I) ion behaves as a metal bridge so that the binuclear structure units are connected to construct a one-dimensional double chain polymer. Furthermore, a 3-D framework is assembled through intermolecular hydrogen bonds. Thermogravimetric analysis shows that this compound begins losing the free solvent molecules at 106 ℃ and decompounding completely at 580 ℃.
基金support from the Early Career Faculty grant (80NSSC18K1514) from NASA’s Space Technology Research Grants Programsupport from the startup funds at Thayer School of Engineering,Dartmouth College。
文摘Enabling highly reversible sodium(Na) metal anodes in a polymer electrolyte(PE) system is critical for realizing next-generation batteries with lower cost,higher energy,and improved safety.However,the uneven Na deposition and high Na/PE interphase resistance lead to poor reversibility and short cycle life of Na metal anodes.To tackle these problems,here a variety of metal nanoparticles(M-np,M=Al,Sn,In or Au) are deposited onto copper(Cu) foils to synthesize binder-free M-np@Cu substrates for Na plating/stripping.Notably,the Au-np@Cu substrate provides abundant preferential nucleation/growth sites,decreasing Na nucleation barrier and thus promoting uniform Na deposition.Accordingly,stable Na metal anodes are achieved with high reversible capacities,long cycle life,and high usage of Na.With the Au-np@Cu/Na anode and PE,the full cell using a commercial bulk sulfur cathode exhibits a reversible capacity of>400 mAh g^(-1) with near-100% Coulombic efficiency over 200 cycles.
基金supported by the Fundamental Research Funds for the Central Universities,China(Grant No.2014JBZ009)the National Natural Science Foundation of China(Grant Nos.61274063,61377028,61475014,and 61475017)
文摘The sodium chloride methanol solution process is conducted on the conventional poly(3-hexylthiophene)(P3HT)/[6,6]-phenyl-C61-butyric acid methyl ester(PC_(61)BM) polymer bulk heterojunction solar cells. The device exhibits a power conversion efficiency of up to 3.36%, 18% higher than that of the device without the solution process. The measurements of the active layer by x-ray photoelectron spectroscopy(XPS), atomic force microscopy(AFM), and ultraviolet photoelectron spectroscopy(UPS) indicate a slight phase separation in the vertical direction and a sodium chloride distributed island-like interface between the active layer and the cathode. The capacitance–voltage(C–V) and impedance spectroscopy measurements prove that the sodium chloride methanol process can reduce the electron injection barrier and improve the interfacial contact of polymer solar cells. Therefore, this one-step solution process not only optimizes the phase separation in the active layers but also forms a cathode buffer layer, which can enhance the generation, transport, and collection of photogenerated charge carriers in the device simultaneously. This work indicates that the inexpensive and non-toxic sodium chloride methanol solution process is an efficient one-step method for the low cost manufacturing of polymer solar cells.
基金financially supported by the Natural Science Foundation of China (Grant Nos.51773062 and 61831021)
文摘Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of^12 nm,high surface area of 401 m2 g−1,and large pore volume of 0.53 cm3 g−1.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.
文摘Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassiun persulfate as the initiator. The effect of suspension parameters, such as volume ratio of continuous phase and dispersed phase,type and dosage of suspending agents, on water absorbency of the starch grafted polymer was studied.Different starch derivatives were also investigated.Superabsorbents made of cationic starch has higher water absorbency than that made of native corn starch.
基金Supported by the National Natural Science Foundation of China.
文摘Poly(ethylene methyl phosphate)-poly(ethylene glycol)-poly(ethylene methyl phosphate) triblock copolymers carrying hydroxyl group at both chain ends were synthesized with sodium poly(ethylene glycol)ate as initiator. The effects of the factors such as solvent, amount of the initiator and reaction time were investigated. The copolymers were characterized by IR, H-1-NMR, H-1{P-31}-NMR, C-13-NMR, P-31{H-1}-NMR, and DSC. High molecular weight of the copolymer and high yield of the polymerization were achieved within 3 min at 25 degrees C. The polymerization process was studied by P-31{H-1}-NMR and transesterification was found during longer polymerization time.
基金supported by the Soft Science project of Shanxi Province(No.2013041020-03)the National Natural Science Foundation of China(No.51174275)
文摘One new polymer, [Na(NPHSNPAB)(CH3OH)]n, where NPHSNPAB stands for Nphenyl-2-[2-hydroxy-3-sulfo-5-nitrophenylhydrazone]butadione-1,3, has been synthesized and characterized by ^1H NMR and FTIR spectroscopy and single-crystal X-ray diffraction. For this complex: C(17)H(17)N4NaO9S, Mr = 476.39, triclinic system, space group P1, a = 8.8741(18), b = 10.942(2), c = 12.039(2) A, α = 65.74(3), β = 77.49(3), γ = 84.30(3)o, V = 1040.3(4) A3, Z = 2, Dc = 1.521 g/cm^3, λ = 0.71073 A, F(000) = 492, S = 1.106, R = 0.0614 and w R = 0.1423 for 2945 observed reflections with I 〉 2(I). X-ray structural analysis revealed that the structure of NPHSNPAB framework was almost planar by C–H···O, N–H···O, O–H···O, and O–H···S hydrogen bonds. Moreover, sodium(I) center was bound by six O and one N atoms, forming the coordination polymer. The molecular packing diagram showed complicated hydrogen bonds and π···π stacking interaction in the polymer. The average bond distance of the two dicyclic units(3.768 A) indicated strong π···π stacking interaction. The complex displays greenyellow emission at room temperature.
基金Supported by Scientific Research Found of Hunan Provincial Education Department of China(17A049,17C0226)Industry and Research Key Project of Hengyang City(2017KJ155,2017KJ193)Doctoral Scientific Research Foundation of Hengyang Normal University(17D01)
文摘A new cobalt-sodium coordination polymer [CoNa(C_9H_9N_3O_2S)_2·H_2O]_2·C_2H_3N·H_2O(1) has been synthesized with cobalt chloride,2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide(L) and sodium hydroxide.It crystallizes in the triclinic space group P1,with a = 9.972(4),b = 10.923(4),c = 13.489(5) ?,α = 108.005(10),β = 92.728(10),γ = 93.16(1)o,V = 1392.0(9) ?~3,Mr = 1151.95,Dc = 1.374 g/cm^3,Z = 2,F(000) = 592,the final GOOF = 1.126,R = 0.1091 and wR = 0.2412.Each unit molecule consists of two cobalt ions and two sodium ions bridged by four 2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide anions.The coordination environment of Co ion is CoO_2N_2S_2,giving a distorted octahedral geometry and the Na(1) ion is NaO_4N,giving a distorted square pyramidal geometry.The results show that 1 shows one strong intense fluorescence emission wavelength of 429 nm with an excitation wavelength of 376 nm,and the electron transfer of 1 is irreversible in electrode reactions.
基金supported by National University of Singapore, the National Natural Science Foundation of China (NSFC 51572182, 11502036, 11372104, 11632004)the Natural Science Fund of the city of Chongqing (cstc2015jcyj A0577)The Key Program for International Science and Technology Cooperation Projects of the Ministry of Science and Technology of China (No. 2016YFE0125900)
文摘All-solid-state sodium-ion battery is regarded as the next generation battery to replace the current commercial lithium-ion battery, with the advantages of abundant sodium resources, low price and high-level safety. As one critical component in sodium-ion battery, solid-state electrolyte should possess superior operational safety and design simplicity, yet reasonable high room-temperature ionic conductivity. This paper gives a comprehensive review on the recent progress in solid-state electrolyte materials for sodium-ion battery, including inorganic ceramic/glass-ceramic, organic polymer and ceramic-polymer composite electrolytes, and also provides a comparison of the ionic conductivity in various solid-state electrolyte materials. The development of solid-state electrolytes suggests a bright future direction: all solid-state sodium-ion battery could be fully used to power all electric road vehicles, portable electronic devices and large-scale grid support.
文摘The effectiveness of a superabsorbent polymer of sodium polyacrylate was studied, with emphasis on water management, i.e., absorption, retention and desorption in the soil. The polymer was applied in plots with a sandy soil near Grandola (southern Portugal). Characterization of the most relevant physical and chemical properties of the polymer was made, namely, its specific gravity, particle diameter, capacity of water absorption and desorption. In the plots with and without the polymer, soil moisture was continuously monitored, and grassland biomass samples were collected and weighed. The results reflected the effective role of the polymer both in the improvement of the water regime in the soil and in the substantial increment of grassland productivity.
文摘The objective of this study is to develop chitosaneanionic polymers based extendedrelease tablets and test the feasibility of using this system for the sustained release of highly water-soluble drugs with high drug loading.Here,the combination of sodium valproate(VPS)and valproic acid(VPA)were chosen as the model drugs.Anionic polymers studied include xanthan gum(XG),carrageenan(CG),sodium carboxymethyl cellulose(CMC-Na)and sodium alginate(SA).The tablets were prepared by wet granulation method.In vitro drug release was carried out under simulated gastrointestinal condition.Drug release mechanism was studied.Compared with single polymers,chitosaneanionic polymers based system caused a further slowdown of drug release rate.Among them,CS exanthan gum matrix system exhibited the best extended-release behavior and could extend drug release for up to 24 h.Differential scanning calorimetry(DSC)and Fourier transform infrared spectroscopy(FTIR)studies demonstrated that polyelectrolyte complexes(PECs)were formed on the tablet surface,which played an important role on retarding erosion and swelling of the matrix in the later stage.In conclusion,this study demonstrated that it is possible to develop highly water-soluble drugs loaded extendedrelease tablets using chitosaneanionic polymers based system.
基金Supported by Program for New Century Excellent Talents in University(NCET-07-0738)
文摘Acrylonitrile-sodium styrene sulfonate copolymer/layered double hydroxides nanocomposites were prepared by in situ aqueous precipitation copolymerization of acrylonitrile(AN)and sodium styrene sulfonate(SSS)in the presence of 4-vinylbenzene sulfonate intercalated layered double hydroxides(MgAl-VBS LDHs)and transferred to acrylonitrile-styrene sulfonic acid(AN-SSA)copolymer/LDHs nanocomposites as a proton-conducting polymer electrolyte.MgAl-VBS LDHs were prepared by a coprecipitation method,and the structure and composition of MgAl-VBS LDHs were determined by X-ray diffraction(XRD),infrared spectroscopy,and elemental analysis.X-ray diffraction result of AN-SSS copolymer/LDHs nanocomposites indicated that the LDHs layers were well dispersed in the AN-SSS copolymer matrix.All the AN-SSS copolymer/LDHs nanocomposites showed significant enhancement of the decomposition temperatures compared with the pristine AN-SSS copolymer,as identified by the thermogravimetric analysis.The methanol crossover was decreased and the proton conductivity was highly enhanced for the AN-SSA copolymer/LDHs nanocomposite electrolyte systems.In the case of the nanocomposite electrolyte containing 2%(by mass)LDHs,the proton conductivity of 2.60×10 -3 S·m -1 was achieved for the polymer electrolyte.
文摘Constipation is a common functional gastrointestinal disorder which has caused much discomfort affecting the quality of life. The prevalence of constipation in the general population is approximately 20%(1)Various kinds of laxatives were introduced such as bulking agent, stool softener, stimulant, and osmotic agent (2)Fixed dose combination with bisacodyl as a stimulant and docusate sodium as a stool softener, Ducolax STM, was developed as enteric coated tablets targeting colon.