Hydrothermal liquefaction(HTL)and pyrolysis(Py)of Loktak lake biomass mixture of water hyacinth(WH)and para grass(PG)were carried out at 260-300℃ and 300-500℃ to compare the products yield and chemical characteristi...Hydrothermal liquefaction(HTL)and pyrolysis(Py)of Loktak lake biomass mixture of water hyacinth(WH)and para grass(PG)were carried out at 260-300℃ and 300-500℃ to compare the products yield and chemical characteristics of the products.In case of HTL,the maximum bio-oil yield was obtained 13.34 wt.%at 280℃ while for Py,the maximum bio-oil yield was observed 38.8 wt.%at 350℃.The obtained bio-oils and bio-chars were analyzed using GC-MS,FT-IR,NMR,TGA,TOC,and SEM.GC-MS analysis of the bio-oils were showed that the HTL bio-oil majorly contains of nitrogen containing compounds whereas the Py bio-oil contains majority of phenolic compounds.Other compounds like ketones,alcohols,acids were also observed in bio-oil.Higher intensity broad band at 3300-3500 cm^(−1) was observed in the Py bio-oil compared to HTL bio-oil.TGA and proximate analysis of bio-char revealed the higher devolatilization occured during the HTL compared to Py process.The surface morphology of the HTL bio-char was found to be rough and fragmented as compared to the pyrolysis bio-char,clearly showing the biomass macromolecules breakdown differently in HTL and Py process.展开更多
Dear Editor,In aquatic environments,cyanobacteria usually proliferate faster than other phytoplankton assemblages during warm seasons,particularly in eutrophic waters(Ma et al.,2015).Microcystis,a common cyanobacteria...Dear Editor,In aquatic environments,cyanobacteria usually proliferate faster than other phytoplankton assemblages during warm seasons,particularly in eutrophic waters(Ma et al.,2015).Microcystis,a common cyanobacterial genus that potentially produces microcystins(MCs)and nontoxic strains,dominates in eutrophic freshwater bodies,and its biomass increases quickly during the warm period;these changes result in increased water turbidity and changes in light quality and quantity in the water column(Li and Li,2012).Additionally,展开更多
文摘Hydrothermal liquefaction(HTL)and pyrolysis(Py)of Loktak lake biomass mixture of water hyacinth(WH)and para grass(PG)were carried out at 260-300℃ and 300-500℃ to compare the products yield and chemical characteristics of the products.In case of HTL,the maximum bio-oil yield was obtained 13.34 wt.%at 280℃ while for Py,the maximum bio-oil yield was observed 38.8 wt.%at 350℃.The obtained bio-oils and bio-chars were analyzed using GC-MS,FT-IR,NMR,TGA,TOC,and SEM.GC-MS analysis of the bio-oils were showed that the HTL bio-oil majorly contains of nitrogen containing compounds whereas the Py bio-oil contains majority of phenolic compounds.Other compounds like ketones,alcohols,acids were also observed in bio-oil.Higher intensity broad band at 3300-3500 cm^(−1) was observed in the Py bio-oil compared to HTL bio-oil.TGA and proximate analysis of bio-char revealed the higher devolatilization occured during the HTL compared to Py process.The surface morphology of the HTL bio-char was found to be rough and fragmented as compared to the pyrolysis bio-char,clearly showing the biomass macromolecules breakdown differently in HTL and Py process.
基金supported by the Henan Province Science Projects for Colleges and Universities (15A610011)the City Science and Technology Project (20140659)+1 种基金the Fund Project for Doctor (D2014009)the Henan Institute of Engineering Innovation Team Building Program (CXTD2014005)
文摘Dear Editor,In aquatic environments,cyanobacteria usually proliferate faster than other phytoplankton assemblages during warm seasons,particularly in eutrophic waters(Ma et al.,2015).Microcystis,a common cyanobacterial genus that potentially produces microcystins(MCs)and nontoxic strains,dominates in eutrophic freshwater bodies,and its biomass increases quickly during the warm period;these changes result in increased water turbidity and changes in light quality and quantity in the water column(Li and Li,2012).Additionally,