FTIR, UV-visible , fluorescence spectra and calculation of CPK model indicated that poly(1-naphthol) synthesized and assembled by horseradish peroxidase(HRP) in aqueous micelle was constructed with orderly helical co...FTIR, UV-visible , fluorescence spectra and calculation of CPK model indicated that poly(1-naphthol) synthesized and assembled by horseradish peroxidase(HRP) in aqueous micelle was constructed with orderly helical conformation, which was the lowest energy conformation of the polymer under this condition and resulted in an advanced c-conjugated system.展开更多
[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were ...[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were studied as well as their distribution in water and soil. Effects of rationing on desorption of PCBs were also analyzed. [Result]The potential of single surfactant to enhance the desorption of PCBs from soil in order was Tween 80 SDBS HTAB. Three surfactants were largely adsorbed on soil and the sorption followed HTABTween 80SDBS. The desorption of PCBs increased significantly and linearly with the increase of aqueous micelle concentration of surfactants. [Conclusion]Enhancing effect of three surfactants on PCBs desorption were obtained,which will provide theoretical basis for further analyzing.展开更多
文摘FTIR, UV-visible , fluorescence spectra and calculation of CPK model indicated that poly(1-naphthol) synthesized and assembled by horseradish peroxidase(HRP) in aqueous micelle was constructed with orderly helical conformation, which was the lowest energy conformation of the polymer under this condition and resulted in an advanced c-conjugated system.
基金Supported by the National Natural Science Fund (20947003)~~
文摘[Objective]The aim of this paper was to provide theoretical basis for study on enhancement of surfactants to desorption of PCBs from soil. [Method]The desorption effects of surfactants SDBs,Tween 80,HTAB on PCBs were studied as well as their distribution in water and soil. Effects of rationing on desorption of PCBs were also analyzed. [Result]The potential of single surfactant to enhance the desorption of PCBs from soil in order was Tween 80 SDBS HTAB. Three surfactants were largely adsorbed on soil and the sorption followed HTABTween 80SDBS. The desorption of PCBs increased significantly and linearly with the increase of aqueous micelle concentration of surfactants. [Conclusion]Enhancing effect of three surfactants on PCBs desorption were obtained,which will provide theoretical basis for further analyzing.
