Purpose: Perforated peptic ulcer is an emergency condition. Laparoscopic ulcer repair is a feasible and safe procedure. The aim of this study was to research the efficacy of laparoscopic repair of peptic ulcer and to ...Purpose: Perforated peptic ulcer is an emergency condition. Laparoscopic ulcer repair is a feasible and safe procedure. The aim of this study was to research the efficacy of laparoscopic repair of peptic ulcer and to discuss the causes of conversion from laparoscopy to laparotomy. Methods: We collected 34 patients with perforated peptic ulcer underwent laparoscopic surgery from October 2003 to October 2008. Thirty four patients with perforated peptic ulcer underwent laparoscopic intervention and 6 cases were converted to laparotomy. The demographics, laboratory data, perioperative data, morbidity and mortality were compared. Results: In demographics of two groups, there were no significant differences in sex, age, location, and mean duration of symptoms of acute abdominal pain. However, there were significant differences in median size of perforation, mean duration of history of peptic ulcer related pain, and the experiences of surgeon. There were no significant differences in the laboratory data and perioperative data of two groups. In morbidity?and mortality of two groups, there were no significant differences in leakage, wound infection, intra-abdominal abscess, ileus, urinary tract infection, pneumonia, and mortality, but there was significant difference in overall morbidity in two groups. Conclusions: Laparoscopic repair of perforated peptic ulcer is safe and could be used in routine clinical practice. However, patients with larger perforations (>10 mm), longer duration of history peptic ulcer related pain (>2 years), and learning curve of surgeon could be associated with conversion rate. It is associated with higher morbidity in patients with conversion from laparoscopy to laparotomy.展开更多
Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and ...Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and pseudomorphic conversion to SrC2 O4·H2O occurs. In the second step, SrC2 O4·H2O reacts with H2C2O4 to form H[Sr(C2 O4)1.5(H2O)]. Sr(HC2 O4)(C2 O4)0.5·H2 O crystallizes during cooling of the reaction mixture to room temperature if the solution reaches the saturation concentration of (H[Sr(C2O4)1.5(H2O)]. The aims of this study are the derivation of reaction rate equations and the determination of the kinetic parameters such as pre-exponential factor, apparent activation energy and order of H2C2O4 concentration for each reaction step.Fractional conversions of SrSO4 were calculated using the quantitative amounts of dissolved S and Sr. It was determined that the reaction rate increased at the initial time of reaction by increasing the temperature using solutions with approximately same H2C2O4 concentrations. The reaction extends very slowly after a certain time in solutions with low H2C2O4 concentration and ends by the formation of a protective layer of SrC2O4-H2O around the surfaces of solid particles. Fractional conversion of SrSO4 is increased by increasing concentration of H2C2O4 at constant temperature. Kinetic model equations were derived using shrinking core model for each step.展开更多
Sampling rate conversion finds great use in the area of multirate signal processing, communications system, speech processing system, etc. In this paper, we describe a structure of 72 MHz/54 MHz sampling rate conversi...Sampling rate conversion finds great use in the area of multirate signal processing, communications system, speech processing system, etc. In this paper, we describe a structure of 72 MHz/54 MHz sampling rate conversion system which is applied to HDTV system. First, we discuss the theoretical model of a 4/3 conversion scheme and then design the hardware structure implemented in parallel and illustrate the subsystem structure in detail. Finally, the phase diagrams are presented to show the relations between the clocks.展开更多
The conversion rates of SO2 to SO42- and NO2 to HNO3+NO3- are estimated from the field-data obtained in Beijing in summer, 1988. The results show that the conversion rate of NO2 is about four times as much as that of ...The conversion rates of SO2 to SO42- and NO2 to HNO3+NO3- are estimated from the field-data obtained in Beijing in summer, 1988. The results show that the conversion rate of NO2 is about four times as much as that of SO2; The conversion rates have a diurnal variation in a day. On the average, the rate of SO2 is estimated to be 4.7% h-1 during the daytime and 3.4% h-1 during the nighttime. Similarly, the rate of NO2 is estimated to be 17.2% h-1 and 12% h-1 respectively.展开更多
Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal...Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal and seasonal variations, with maximum readings at noon or afternoon, similar to 80x10(6)OH/cm(3) in summer and similar to 20x10(6)-40x10(6)OH/cm(3) in fall. On the basis of measured data, the reaction rates related to the photochemical process of HO(x) (OH+HO(2)) were derived and characteristics of atmospheric chemical processes in the city were analyzed. The results showed that conversion rates of atmospheric OH and HO(2) in the summer of Beijing City were about 700x10(6) molecule/(cm(3) . s) and 600x10(6)molecule/(cm(3) . s), respectively. And the net production of OH in the air of the city mainly originated from the photolysis of the gaseous HNO(2), and the main sink of OH were the photochemical reactions with VOCs, NO(2), HCHO and CO. It was different from the clean area.展开更多
This paper concerns the influence of temperature and local concentration of oxygen on the conversion efficiency of carbon into CO, CO2, CH4, C3H8, C2H4, C2H2, C2H6, C6H6, during the thermal degradation of plastic bags...This paper concerns the influence of temperature and local concentration of oxygen on the conversion efficiency of carbon into CO, CO2, CH4, C3H8, C2H4, C2H2, C2H6, C6H6, during the thermal degradation of plastic bags and millet stalks. The experimental device used is the tubular kiln, coupled to an analyzer Fourier Transform Infrared (FTIR) and a Non Dispersive Infrared analyzer (NDIR). Temperatures are considered between 800 and 1000°C. Local concentrations of oxygen during thermal degradation are 0%, 10% and 21%. On the one hand results obtained on the influence of temperature show that for each type of thermal degradation and whatever the temperature of the combustion, the rate of conversion of carbon remains substantially the same. In the case of plastic bags, the rate of carbon converted during pyrolysis is about 90% of carbon converted during reductive combustion. On the other hand, with millet stalks, the carbon converted represents only 60% of the rate of carbon converted during combustion to 10% oxygen. 1 to 2% of carbon not analyzed is in the form of aromatic compounds that are found most often in the soot and/or tar from this combustion system. Moreover, whatever the temperature, the overall efficiency of carbon conversion increases linearly with the local concentration of oxygen. During the thermal degradation of plastic bags, we see that the reducer environment has fostered the conversion of 7% of carbon more while the presence of oxygen in double proportion promotes the conversion of 27% carbon. Regarding the influence of the local content of oxygen, it is clear that for plastic bags, the reactions of oxidation of CO into CO2 tend to be favored for the benefit of those of hydrocarbons into CO. The formation of CO and CO2 by oxidation of light hydrocarbons is primarily from gaseous compounds CH4 and C2H4. At 950°C, we have also acetylene (C2H2) which is involved in the production of carbon oxides. At 1000°C, benzene (C6H6) heavily involved in the formation of CO and CO2. However, with millet stalks, more the local content of oxygen increases, more combustion is better, that is to say that the oxidation reactions producing CO2 are faster than the oxidation reactions of hydrocarbons into CO. The rate of carbon converted into CO and CO2 is higher for millet stalks than for plastic bags, due to this oxygen levels higher in millet stalks than in plastic bags. Similarly, for the millet stalks, from pyrolysis to combustion (at 10 and 21% oxygen), there is practically no hydrocarbon emitted.展开更多
This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for wheat by data mining method based on data of"3414 fertilizer field trials"of whea...This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for wheat by data mining method based on data of"3414 fertilizer field trials"of wheat by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of wheat for plot was that,Y N≈a+b×optimum nitrogen application amount+c×optimum fertilizer amount of K+d×rainfall in growth season,Y P≈a+b×optimum fertilizer amount of K+c×rainfall in growth season,Y K≈a+b×temperature in growth season+c×rainfall in growth season-d×optimum yield-e×optimum nitrogen application amount,respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships.No significant relationships:13,of which 8 were soil nutrients,the results showed that soil nutrients had little effect on nutrient conversion rate and fertilizer utilization ratio;consistent significant relationships:4,they were all nitrogen and phosphorus,explaining the importance of nitrogen and phosphorus;contrary significant relationships:6,they were all nitrogen and phosphorus,illustrating that phosphorus and nitrogen had inhibitory effect;complementary significant relationships:31,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the measuring index of fertilizer efficiency in one season,while the nutrient conversion rate was the measuring index of fertilizer efficiency in more seasons.It showed that the fertilizer utilization rate was significantly correlated,or the nutrient conversion rate was significantly correlated.展开更多
This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for rice by data mining method based on data of"3414 fertilizer field trials"of rice ...This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for rice by data mining method based on data of"3414 fertilizer field trials"of rice by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of rice for plot was that,Y N≈a+b×optimum yield+c×optimum fertilizer amount of K,Y P≈a+b×optimum yield,Y K≈a respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships:①no significant relationships:25,of which 14 were soil nutrients and 9 were environmental factors,the results showed that soil nutrients and environmental factors had little effect on nutrient yield ratio and fertilizer utilization ratio;②consistent significant relationships:2,one was that yield ratio and utilization ratio of N were positively correlated with the optimum production,explaining the importance of N for production,the other was that yield ratio and utilization ratio of P had a significantly positive correlation with conversion rate and utilization ratio of N,illustrating that nitrogen and phosphorus had mutual promotion;③contrary significant relationships:5,these showed as negative correlations of fertilizer utilization ratio and positive correlation of nutrient conversion ratio;④complementary significant relationships:22,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the index of fertilizer efficiency in one season,while the nutrient conversion rate was the index of fertilizer efficiency in more seasons,which showed that the fertilizer utilization rate was significantly correlated,or the nutrient conversion rate was significantly correlated.展开更多
This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for maize by data mining method based on data of"3414 fertilizer field trials"of maiz...This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for maize by data mining method based on data of"3414 fertilizer field trials"of maize by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of maize for plot was that,Y N≈a+b×optimum yield,Y P≈a+b×optimum yield-c×optimum nitrogen application amount-d×optimum potassium application amount,Y K≈a-b×optimum nitrogen application amount-c×temperature in growth season-d×rainfall in growth season,respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships.No significant relationships:22,of which 16 were soil nutrients and 5 were environmental factors,the results showed that soil nutrients and environmental factors had little effect on nutrient conversion rate and fertilizer utilization ratio;consistent significant relationships:14,illustrating that conversion rate and utilization ratio of maize were consistent in most cases,and it was because that maize was planted for a long term,and its fertilizer absorption law was basically stable;contrary significant relationships:0,illustrating that there was no reverse relationship between conversion rate and utilization ratio of maize;complementary significant relationships:18,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the measuring index of fertilizer efficiency in one season,while the nutrient conversion rate was the measuring index of fertilizer efficiency in more seasons.It showed that the fertilizer utilization ratio was significantly correlated,or the nutrient conversion rate was significantly correlated.展开更多
The high mortality rate in hepatocellular carcinoma(HCC)is partially due to the fact that a significant number of patients are diagnosed at an intermediate or advanced stage,with surgical treatment options unavailable...The high mortality rate in hepatocellular carcinoma(HCC)is partially due to the fact that a significant number of patients are diagnosed at an intermediate or advanced stage,with surgical treatment options unavailable.Conversion therapy,which involves both locoregional and systemic treatments,has the potential to downstage tumors in selected patients with initially unresectable HCC,thereby making surgical treatment a possibility and potentially increasing long-term survival.To optimize the conversion rate,it is necessary to maximize successful conversions and clearly define the target population for conversion treatment through a collaborative effort.In this review article,we summarize the clinical experience and evidence for conversion therapy in patients with‘potentially resectable’HCC from four perspectives:1)defining the target population for conversion therapy,2)selecting the appropriate conversion strategy,placing emphasis on the utilization of combination therapy that exhibits a significant objective response rate,3)determining the timing and urgency of surgical resection,4)promoting the adoption of a multidisciplinary team model.The authors are optimistic that with the continuous progress in treatment and a deeper understanding of HCC,the success rate of HCC conversion therapy will increase,and the overall survival of HCC patients will be prolonged.展开更多
On the basis of continuous tests and batch tests, conversion regular patterns of acetate, propionate and butyrate in activated sludge at different heights of the UASB reactor were conducted. Results indicated that the...On the basis of continuous tests and batch tests, conversion regular patterns of acetate, propionate and butyrate in activated sludge at different heights of the UASB reactor were conducted. Results indicated that the conversion capacity of the microbe is decided by the substrate characteristic when sole VFA is used as the only substrate. But when mixed substrates are used,the conversion regulations would have changed accordingly. Relationships of different substrates vary according to their locations. In the whole reactor, propionate's conversion is restrained by acetate and butyrate of high concentration. On the top and at the bottom of the reactor, conversion of acetate, but butyrate, is restrained by propionate. And in the midst, acetate's conversion is accelerated by propionate while that of butyrate is restrained. It is proved, based on the analysis of specific conversion rate, that the space distribution of the microbe is the main factor that affects substrates' conversion. The ethanol type fermentation of the acidogenic phase is the optimal acid type fermentation for the two phase anaerobic process.展开更多
Using 19-year satellite altimetric data, variations in the eddy kinetic energy, energy exchanges and interaction between the eddy fi eld and mean fl ow are discussed for the Kuroshio south of Japan. In the seasonal cy...Using 19-year satellite altimetric data, variations in the eddy kinetic energy, energy exchanges and interaction between the eddy fi eld and mean fl ow are discussed for the Kuroshio south of Japan. In the seasonal cycle, the eddy kinetic energy level is a minimum in December/January and a maximum in April/May. In addition to seasonal variations, the eddy kinetic energy undergoes interannual changes. The energy transfers mainly from the mean fl ow to the eddy fi eld in the Kuroshio south of Japan, and dominant energy exchanges mainly occur along the Kuroshio path south of Japan in each year from 1993 to 2011. In addition, there is often barotropic instability south of Honshu. Regarding interactions between the eddy fi eld and mean fl ow, cyclonic and anticyclonic accelerations are also found along the Kuroshio path and they fl ank each other. There is cyclonic acceleration always imposed on southeast of Kyushu, and anticyclonic acceleration dominates south of Honshu from 2001 to mid-2005. Reynolds stress is used to explain the dynamic process of energy exchange. Furthermore, lag-correlation and linear regression analysis show that variability of the energy conversion rate and Reynolds stress involve responses to eddy acceleration at two time scales. The enhanced eddy acceleration induces large Reynolds stress, and enhanced Reynolds stress or barotropic instability further enforces energy transfer from the mean fl ow to the eddy fi eld.展开更多
In order to achieve high-efficiency alkali conversion and impurity removal of high titanium slag under the condition of low alkali concentration,a new way of oxygen-rich alkali conversion in KOH solution was proposed....In order to achieve high-efficiency alkali conversion and impurity removal of high titanium slag under the condition of low alkali concentration,a new way of oxygen-rich alkali conversion in KOH solution was proposed.The conversion law of element occurrence state and the influence of the conversion conditions on the titanium conversion rate and removal rate of silicon and aluminum were studied.The results showed that the KOH solution converted the titanium oxide in high titanium slag into whisker-like potassium titanate.Silicon and aluminum elements were dissolved into the solution.Under the following conditions,KOH concentration of 6 mol/L,conversion temperature of 260℃,initial oxygen partial pressure of 2 MPa,liquid−solid ratio of 35 mL/g,conversion time of 4 h,and high titanium slag particle size of 48−74μm,the conversion rate of titanium was 97.0%,and the removal rates of silicon and aluminum were 90.2%and 76.2%,respectively.Oxygen-rich alkali conversion product was converted to rutile with a TiO_(2) grade of 99.1%by acid hydrolysis conversion.展开更多
The electrochemical conversion of carbon dioxide(CO_(2))has been attracting increasingly research interest in the past decade,with the ultimate goal of utilizing electricity from renewable energy to realize carbon neu...The electrochemical conversion of carbon dioxide(CO_(2))has been attracting increasingly research interest in the past decade,with the ultimate goal of utilizing electricity from renewable energy to realize carbon neutrality,as well as economic and energy benefits.Nonetheless,the capture and concentrating of CO_(2) cost a substantial portion of energy,while almost all the reported researches showed CO_(2) electroreduction under high concentrations of(typically pure)CO_(2) reactants,and only very few recent studies have investigated the capability of applying low CO_(2) concentrations(such as~10%in flue gases).In this work,we first demonstrated the electroreduction of 0.03%CO_(2)(in helium)in a homemade gas‐phase electrochemical electrolyzer,using a low‐cost copper(Cu)or nanoscale copper(nano‐Cu)catalyst.Mixed with steam,the gas‐phase CO_(2) was directly delivered onto the gas‐solid interface with the Cu catalyst and reduced to CO,without the need/constraint of being adsorbed by aqueous solution or alkaline electrolytes.By tuning the catalyst and experi‐mental parameters,the conversion efficiency of CO_(2) reached as high as~95%.Furthermore,we demonstrated the direct electroreduction of 0.04%CO_(2) from real air sample with an optimized conversion efficiency of~79%,suggesting a promising perspective of the electroreduction ap‐proach toward direct CO_(2) conversion.展开更多
Steam-reforming is an effective approach for upgrading methane and hydrocarbon of coke-oven gas into CO and HE, but the kinetic behavior needs more study. We investigated the conversion of methane in coke-oven gas by ...Steam-reforming is an effective approach for upgrading methane and hydrocarbon of coke-oven gas into CO and HE, but the kinetic behavior needs more study. We investigated the conversion of methane in coke-oven gas by steam reforming process in an electric tubular flow at 14 kPa with temperature varying from .500 ℃ to 9.50 ℃, and developed a kenetic model for, ignoring the effects of adsorption and diffusion. The optimal dynamic conditions for methane conversion 14 kPa are as follows: the ratio of the amount of water to the amount of methane is from 1.1 to 1.3; the reaction temperature is from 1 223 K to 1 273 K. The methane conversion rate is larger than 95% when the ratio of the amount of water to the amount of methane is 1.2 at a temperature above 1 223 K with the residence time up to 0.75 s.展开更多
We propose a Rate-Distortion (RD) optimized strategy for frame-dropping and scheduling of multi-user conversa- tional and streaming videos. We consider a scenario where conversational and streaming videos share the fo...We propose a Rate-Distortion (RD) optimized strategy for frame-dropping and scheduling of multi-user conversa- tional and streaming videos. We consider a scenario where conversational and streaming videos share the forwarding resources at a network node. Two buffers are setup on the node to temporarily store the packets for these two types of video applications. For streaming video, a big buffer is used as the associated delay constraint of the application is moderate and a very small buffer is used for conversational video to ensure that the forwarding delay of every packet is limited. A scheduler is located behind these two buffers that dynamically assigns transmission slots on the outgoing link to the two buffers. Rate-distortion side information is used to perform RD-optimized frame dropping in case of node overload. Sharing the data rate on the outgoing link between the con- versational and the streaming videos is done either based on the fullness of the two associated buffers or on the mean incoming rates of the respective videos. Simulation results showed that our proposed RD-optimized frame dropping and scheduling ap- proach provides significant improvements in performance over the popular priority-based random dropping (PRD) technique.展开更多
Laser-assisted simulation technique has played a crucial role in the investigation of dose rate effects of silicon-based devices and integrated circuits,due to its exceptional advantages in terms of flexibility,safety...Laser-assisted simulation technique has played a crucial role in the investigation of dose rate effects of silicon-based devices and integrated circuits,due to its exceptional advantages in terms of flexibility,safety,convenience,and precision.In recent years,wide band gap materials,known for their strong bonding and high ionization energy,have gained increasing attention from researchers and hold significant promise for extensive applications in specialized environments.Consequently,there is a growing need for comprehensive research on the dose rate effects of wide band gap materials.In response to this need,the use of laser-assisted simulation technology has emerged as a promising approach,offering an effective means to assess the efficacy of investigating these materials and devices.This paper focused on investigating the feasibility of laser-assisted simulation to study the dose rate effects of wide band gap semiconductor devices.Theoretical conversion factors for laser-assisted simulation of dose rate effects of GaN-based and SiC-based devices were been provided.Moreover,to validate the accuracy of the conversion factors,pulsed laser and dose rate experiments were conducted on GaN-based and SiC-based PIN diodes.The results demonstrate that pulsed laser radiation andγ-ray radiation can produce highly similar photocurrent responses in GaN-based and SiC-based PIN diodes,with correlation coefficients of 0.98 and 0.974,respectively.This finding reaffirms the effectiveness of laser-assisted simulation technology,making it a valuable complement in studying the dose rate effects of wide band gap semiconductor devices.展开更多
文摘Purpose: Perforated peptic ulcer is an emergency condition. Laparoscopic ulcer repair is a feasible and safe procedure. The aim of this study was to research the efficacy of laparoscopic repair of peptic ulcer and to discuss the causes of conversion from laparoscopy to laparotomy. Methods: We collected 34 patients with perforated peptic ulcer underwent laparoscopic surgery from October 2003 to October 2008. Thirty four patients with perforated peptic ulcer underwent laparoscopic intervention and 6 cases were converted to laparotomy. The demographics, laboratory data, perioperative data, morbidity and mortality were compared. Results: In demographics of two groups, there were no significant differences in sex, age, location, and mean duration of symptoms of acute abdominal pain. However, there were significant differences in median size of perforation, mean duration of history of peptic ulcer related pain, and the experiences of surgeon. There were no significant differences in the laboratory data and perioperative data of two groups. In morbidity?and mortality of two groups, there were no significant differences in leakage, wound infection, intra-abdominal abscess, ileus, urinary tract infection, pneumonia, and mortality, but there was significant difference in overall morbidity in two groups. Conclusions: Laparoscopic repair of perforated peptic ulcer is safe and could be used in routine clinical practice. However, patients with larger perforations (>10 mm), longer duration of history peptic ulcer related pain (>2 years), and learning curve of surgeon could be associated with conversion rate. It is associated with higher morbidity in patients with conversion from laparoscopy to laparotomy.
基金the financial support of the Scientific Research Projects Coordination Unit of Istanbul University (Project number: 17344 and 31088)
文摘Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and pseudomorphic conversion to SrC2 O4·H2O occurs. In the second step, SrC2 O4·H2O reacts with H2C2O4 to form H[Sr(C2 O4)1.5(H2O)]. Sr(HC2 O4)(C2 O4)0.5·H2 O crystallizes during cooling of the reaction mixture to room temperature if the solution reaches the saturation concentration of (H[Sr(C2O4)1.5(H2O)]. The aims of this study are the derivation of reaction rate equations and the determination of the kinetic parameters such as pre-exponential factor, apparent activation energy and order of H2C2O4 concentration for each reaction step.Fractional conversions of SrSO4 were calculated using the quantitative amounts of dissolved S and Sr. It was determined that the reaction rate increased at the initial time of reaction by increasing the temperature using solutions with approximately same H2C2O4 concentrations. The reaction extends very slowly after a certain time in solutions with low H2C2O4 concentration and ends by the formation of a protective layer of SrC2O4-H2O around the surfaces of solid particles. Fractional conversion of SrSO4 is increased by increasing concentration of H2C2O4 at constant temperature. Kinetic model equations were derived using shrinking core model for each step.
文摘Sampling rate conversion finds great use in the area of multirate signal processing, communications system, speech processing system, etc. In this paper, we describe a structure of 72 MHz/54 MHz sampling rate conversion system which is applied to HDTV system. First, we discuss the theoretical model of a 4/3 conversion scheme and then design the hardware structure implemented in parallel and illustrate the subsystem structure in detail. Finally, the phase diagrams are presented to show the relations between the clocks.
文摘The conversion rates of SO2 to SO42- and NO2 to HNO3+NO3- are estimated from the field-data obtained in Beijing in summer, 1988. The results show that the conversion rate of NO2 is about four times as much as that of SO2; The conversion rates have a diurnal variation in a day. On the average, the rate of SO2 is estimated to be 4.7% h-1 during the daytime and 3.4% h-1 during the nighttime. Similarly, the rate of NO2 is estimated to be 17.2% h-1 and 12% h-1 respectively.
基金Under the auspices of the National Natural Science Foundation of China(No.40075026)
文摘Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal and seasonal variations, with maximum readings at noon or afternoon, similar to 80x10(6)OH/cm(3) in summer and similar to 20x10(6)-40x10(6)OH/cm(3) in fall. On the basis of measured data, the reaction rates related to the photochemical process of HO(x) (OH+HO(2)) were derived and characteristics of atmospheric chemical processes in the city were analyzed. The results showed that conversion rates of atmospheric OH and HO(2) in the summer of Beijing City were about 700x10(6) molecule/(cm(3) . s) and 600x10(6)molecule/(cm(3) . s), respectively. And the net production of OH in the air of the city mainly originated from the photolysis of the gaseous HNO(2), and the main sink of OH were the photochemical reactions with VOCs, NO(2), HCHO and CO. It was different from the clean area.
文摘This paper concerns the influence of temperature and local concentration of oxygen on the conversion efficiency of carbon into CO, CO2, CH4, C3H8, C2H4, C2H2, C2H6, C6H6, during the thermal degradation of plastic bags and millet stalks. The experimental device used is the tubular kiln, coupled to an analyzer Fourier Transform Infrared (FTIR) and a Non Dispersive Infrared analyzer (NDIR). Temperatures are considered between 800 and 1000°C. Local concentrations of oxygen during thermal degradation are 0%, 10% and 21%. On the one hand results obtained on the influence of temperature show that for each type of thermal degradation and whatever the temperature of the combustion, the rate of conversion of carbon remains substantially the same. In the case of plastic bags, the rate of carbon converted during pyrolysis is about 90% of carbon converted during reductive combustion. On the other hand, with millet stalks, the carbon converted represents only 60% of the rate of carbon converted during combustion to 10% oxygen. 1 to 2% of carbon not analyzed is in the form of aromatic compounds that are found most often in the soot and/or tar from this combustion system. Moreover, whatever the temperature, the overall efficiency of carbon conversion increases linearly with the local concentration of oxygen. During the thermal degradation of plastic bags, we see that the reducer environment has fostered the conversion of 7% of carbon more while the presence of oxygen in double proportion promotes the conversion of 27% carbon. Regarding the influence of the local content of oxygen, it is clear that for plastic bags, the reactions of oxidation of CO into CO2 tend to be favored for the benefit of those of hydrocarbons into CO. The formation of CO and CO2 by oxidation of light hydrocarbons is primarily from gaseous compounds CH4 and C2H4. At 950°C, we have also acetylene (C2H2) which is involved in the production of carbon oxides. At 1000°C, benzene (C6H6) heavily involved in the formation of CO and CO2. However, with millet stalks, more the local content of oxygen increases, more combustion is better, that is to say that the oxidation reactions producing CO2 are faster than the oxidation reactions of hydrocarbons into CO. The rate of carbon converted into CO and CO2 is higher for millet stalks than for plastic bags, due to this oxygen levels higher in millet stalks than in plastic bags. Similarly, for the millet stalks, from pyrolysis to combustion (at 10 and 21% oxygen), there is practically no hydrocarbon emitted.
基金Collaborative Innovation Task of Science and Technology Innovation Project of Chinese Academy of Agricultural Sciences—Integration and Demonstration of Green and Efficient Agricultural Technology Innovation in Danjiangkou Water Conservation Area(CAAS-XTCX2016015)Major Scientific and Technological Projects in Guangxi(GUIKE AA17204077)+2 种基金Special Project of Guangxi Science and Technology Base and Talent(GUIKE AD18126012)First-class Discipline(Geography)Construction Project in GuangxiSpecial Funds for"Guangxi Bagui Scholars".
文摘This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for wheat by data mining method based on data of"3414 fertilizer field trials"of wheat by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of wheat for plot was that,Y N≈a+b×optimum nitrogen application amount+c×optimum fertilizer amount of K+d×rainfall in growth season,Y P≈a+b×optimum fertilizer amount of K+c×rainfall in growth season,Y K≈a+b×temperature in growth season+c×rainfall in growth season-d×optimum yield-e×optimum nitrogen application amount,respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships.No significant relationships:13,of which 8 were soil nutrients,the results showed that soil nutrients had little effect on nutrient conversion rate and fertilizer utilization ratio;consistent significant relationships:4,they were all nitrogen and phosphorus,explaining the importance of nitrogen and phosphorus;contrary significant relationships:6,they were all nitrogen and phosphorus,illustrating that phosphorus and nitrogen had inhibitory effect;complementary significant relationships:31,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the measuring index of fertilizer efficiency in one season,while the nutrient conversion rate was the measuring index of fertilizer efficiency in more seasons.It showed that the fertilizer utilization rate was significantly correlated,or the nutrient conversion rate was significantly correlated.
基金Major Scientific and Technological Projects in Guangxi(GUIKE AA17204077)Special Project of Guangxi Science and Technology Base and Talent(GUIKE AD18126012)+2 种基金First-class Discipline(Geography)Construction Project in GuangxiSpecial Funds for"Guangxi Bagui Scholars"Collaborative Innovation Task of Science and Technology Innovation Project of Chinese Academy of Agricultural Sciences—Integration and Demonstration of Green and Efficient Agricultural Technology Innovation in Danjiangkou Water Conservation Area(CAAS-XTCX2016015).
文摘This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for rice by data mining method based on data of"3414 fertilizer field trials"of rice by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of rice for plot was that,Y N≈a+b×optimum yield+c×optimum fertilizer amount of K,Y P≈a+b×optimum yield,Y K≈a respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships:①no significant relationships:25,of which 14 were soil nutrients and 9 were environmental factors,the results showed that soil nutrients and environmental factors had little effect on nutrient yield ratio and fertilizer utilization ratio;②consistent significant relationships:2,one was that yield ratio and utilization ratio of N were positively correlated with the optimum production,explaining the importance of N for production,the other was that yield ratio and utilization ratio of P had a significantly positive correlation with conversion rate and utilization ratio of N,illustrating that nitrogen and phosphorus had mutual promotion;③contrary significant relationships:5,these showed as negative correlations of fertilizer utilization ratio and positive correlation of nutrient conversion ratio;④complementary significant relationships:22,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the index of fertilizer efficiency in one season,while the nutrient conversion rate was the index of fertilizer efficiency in more seasons,which showed that the fertilizer utilization rate was significantly correlated,or the nutrient conversion rate was significantly correlated.
基金Collaborative Innovation Task of Science and Technology Innovation Project of Chinese Academy of Agricultural Sciences—Integration and Demonstration of Green and Efficient Agricultural Technology Innovation in Danjiangkou Water Conservation Area(CAAS-XTCX2016015)Major Scientific and Technological Projects in Guangxi(GUIKE AA17204077)+2 种基金Special Project of Guangxi Science and Technology Base and Talent(GUIKE AD18126012)First-class Discipline(Geography)Construction Project in GuangxiSpecial Funds for"Guangxi Bagui Scholars".
文摘This paper studied the relationships between utilization ratios and conversion rates of nitrogen,phosphorus and potassium for maize by data mining method based on data of"3414 fertilizer field trials"of maize by published papers from national soil testing and recommendation since 2005.The results and conclusions were as follows:①the conceptual model of fertilizer utilization ratio of maize for plot was that,Y N≈a+b×optimum yield,Y P≈a+b×optimum yield-c×optimum nitrogen application amount-d×optimum potassium application amount,Y K≈a-b×optimum nitrogen application amount-c×temperature in growth season-d×rainfall in growth season,respectively.②Fertilizer utilization ratio and nutrient conversion rate had 4 kinds of relationships.No significant relationships:22,of which 16 were soil nutrients and 5 were environmental factors,the results showed that soil nutrients and environmental factors had little effect on nutrient conversion rate and fertilizer utilization ratio;consistent significant relationships:14,illustrating that conversion rate and utilization ratio of maize were consistent in most cases,and it was because that maize was planted for a long term,and its fertilizer absorption law was basically stable;contrary significant relationships:0,illustrating that there was no reverse relationship between conversion rate and utilization ratio of maize;complementary significant relationships:18,the cause of the complementary phenomenon was that the fertilizer utilization ratio was the measuring index of fertilizer efficiency in one season,while the nutrient conversion rate was the measuring index of fertilizer efficiency in more seasons.It showed that the fertilizer utilization ratio was significantly correlated,or the nutrient conversion rate was significantly correlated.
基金Supported by the National Natural Science Foundation of China(No.82072022 and No.81771956,MZ)the Guang-Dong Basic and Applied Basic Research Foundation(No.2021A1515010403,NL).
文摘The high mortality rate in hepatocellular carcinoma(HCC)is partially due to the fact that a significant number of patients are diagnosed at an intermediate or advanced stage,with surgical treatment options unavailable.Conversion therapy,which involves both locoregional and systemic treatments,has the potential to downstage tumors in selected patients with initially unresectable HCC,thereby making surgical treatment a possibility and potentially increasing long-term survival.To optimize the conversion rate,it is necessary to maximize successful conversions and clearly define the target population for conversion treatment through a collaborative effort.In this review article,we summarize the clinical experience and evidence for conversion therapy in patients with‘potentially resectable’HCC from four perspectives:1)defining the target population for conversion therapy,2)selecting the appropriate conversion strategy,placing emphasis on the utilization of combination therapy that exhibits a significant objective response rate,3)determining the timing and urgency of surgical resection,4)promoting the adoption of a multidisciplinary team model.The authors are optimistic that with the continuous progress in treatment and a deeper understanding of HCC,the success rate of HCC conversion therapy will increase,and the overall survival of HCC patients will be prolonged.
文摘On the basis of continuous tests and batch tests, conversion regular patterns of acetate, propionate and butyrate in activated sludge at different heights of the UASB reactor were conducted. Results indicated that the conversion capacity of the microbe is decided by the substrate characteristic when sole VFA is used as the only substrate. But when mixed substrates are used,the conversion regulations would have changed accordingly. Relationships of different substrates vary according to their locations. In the whole reactor, propionate's conversion is restrained by acetate and butyrate of high concentration. On the top and at the bottom of the reactor, conversion of acetate, but butyrate, is restrained by propionate. And in the midst, acetate's conversion is accelerated by propionate while that of butyrate is restrained. It is proved, based on the analysis of specific conversion rate, that the space distribution of the microbe is the main factor that affects substrates' conversion. The ethanol type fermentation of the acidogenic phase is the optimal acid type fermentation for the two phase anaerobic process.
基金Supported by the Knowledge Innovation Program of Chinese Academy of Sciences(No.KZCX2-EW-201)the Basic Research Program of Science and Technology Projects of Qingdao(No.11-1-4-95-jch)
文摘Using 19-year satellite altimetric data, variations in the eddy kinetic energy, energy exchanges and interaction between the eddy fi eld and mean fl ow are discussed for the Kuroshio south of Japan. In the seasonal cycle, the eddy kinetic energy level is a minimum in December/January and a maximum in April/May. In addition to seasonal variations, the eddy kinetic energy undergoes interannual changes. The energy transfers mainly from the mean fl ow to the eddy fi eld in the Kuroshio south of Japan, and dominant energy exchanges mainly occur along the Kuroshio path south of Japan in each year from 1993 to 2011. In addition, there is often barotropic instability south of Honshu. Regarding interactions between the eddy fi eld and mean fl ow, cyclonic and anticyclonic accelerations are also found along the Kuroshio path and they fl ank each other. There is cyclonic acceleration always imposed on southeast of Kyushu, and anticyclonic acceleration dominates south of Honshu from 2001 to mid-2005. Reynolds stress is used to explain the dynamic process of energy exchange. Furthermore, lag-correlation and linear regression analysis show that variability of the energy conversion rate and Reynolds stress involve responses to eddy acceleration at two time scales. The enhanced eddy acceleration induces large Reynolds stress, and enhanced Reynolds stress or barotropic instability further enforces energy transfer from the mean fl ow to the eddy fi eld.
基金supported by the National Natural Science Foundation of China(Nos.U1908225,U1702253)Fundamental Research Funds for the Central Universities of China(Nos.N182515007,N170908001,N2025004)。
文摘In order to achieve high-efficiency alkali conversion and impurity removal of high titanium slag under the condition of low alkali concentration,a new way of oxygen-rich alkali conversion in KOH solution was proposed.The conversion law of element occurrence state and the influence of the conversion conditions on the titanium conversion rate and removal rate of silicon and aluminum were studied.The results showed that the KOH solution converted the titanium oxide in high titanium slag into whisker-like potassium titanate.Silicon and aluminum elements were dissolved into the solution.Under the following conditions,KOH concentration of 6 mol/L,conversion temperature of 260℃,initial oxygen partial pressure of 2 MPa,liquid−solid ratio of 35 mL/g,conversion time of 4 h,and high titanium slag particle size of 48−74μm,the conversion rate of titanium was 97.0%,and the removal rates of silicon and aluminum were 90.2%and 76.2%,respectively.Oxygen-rich alkali conversion product was converted to rutile with a TiO_(2) grade of 99.1%by acid hydrolysis conversion.
文摘The electrochemical conversion of carbon dioxide(CO_(2))has been attracting increasingly research interest in the past decade,with the ultimate goal of utilizing electricity from renewable energy to realize carbon neutrality,as well as economic and energy benefits.Nonetheless,the capture and concentrating of CO_(2) cost a substantial portion of energy,while almost all the reported researches showed CO_(2) electroreduction under high concentrations of(typically pure)CO_(2) reactants,and only very few recent studies have investigated the capability of applying low CO_(2) concentrations(such as~10%in flue gases).In this work,we first demonstrated the electroreduction of 0.03%CO_(2)(in helium)in a homemade gas‐phase electrochemical electrolyzer,using a low‐cost copper(Cu)or nanoscale copper(nano‐Cu)catalyst.Mixed with steam,the gas‐phase CO_(2) was directly delivered onto the gas‐solid interface with the Cu catalyst and reduced to CO,without the need/constraint of being adsorbed by aqueous solution or alkaline electrolytes.By tuning the catalyst and experi‐mental parameters,the conversion efficiency of CO_(2) reached as high as~95%.Furthermore,we demonstrated the direct electroreduction of 0.04%CO_(2) from real air sample with an optimized conversion efficiency of~79%,suggesting a promising perspective of the electroreduction ap‐proach toward direct CO_(2) conversion.
基金the Postdoctoral Foundation of China under the grant No. 2910001
文摘Steam-reforming is an effective approach for upgrading methane and hydrocarbon of coke-oven gas into CO and HE, but the kinetic behavior needs more study. We investigated the conversion of methane in coke-oven gas by steam reforming process in an electric tubular flow at 14 kPa with temperature varying from .500 ℃ to 9.50 ℃, and developed a kenetic model for, ignoring the effects of adsorption and diffusion. The optimal dynamic conditions for methane conversion 14 kPa are as follows: the ratio of the amount of water to the amount of methane is from 1.1 to 1.3; the reaction temperature is from 1 223 K to 1 273 K. The methane conversion rate is larger than 95% when the ratio of the amount of water to the amount of methane is 1.2 at a temperature above 1 223 K with the residence time up to 0.75 s.
基金Project (No. STE1093/1-1) supported by the German ResearchFoundation, Germany
文摘We propose a Rate-Distortion (RD) optimized strategy for frame-dropping and scheduling of multi-user conversa- tional and streaming videos. We consider a scenario where conversational and streaming videos share the forwarding resources at a network node. Two buffers are setup on the node to temporarily store the packets for these two types of video applications. For streaming video, a big buffer is used as the associated delay constraint of the application is moderate and a very small buffer is used for conversational video to ensure that the forwarding delay of every packet is limited. A scheduler is located behind these two buffers that dynamically assigns transmission slots on the outgoing link to the two buffers. Rate-distortion side information is used to perform RD-optimized frame dropping in case of node overload. Sharing the data rate on the outgoing link between the con- versational and the streaming videos is done either based on the fullness of the two associated buffers or on the mean incoming rates of the respective videos. Simulation results showed that our proposed RD-optimized frame dropping and scheduling ap- proach provides significant improvements in performance over the popular priority-based random dropping (PRD) technique.
基金National Natural Science Foundation of China(12205028)Natural Science Foundation of Sichuan Province(2022NSFSC1235)Young and Middle-aged Backbone Teacher Foundation of Chengdu University of Technology(10912-JXGG2022-08363)。
文摘Laser-assisted simulation technique has played a crucial role in the investigation of dose rate effects of silicon-based devices and integrated circuits,due to its exceptional advantages in terms of flexibility,safety,convenience,and precision.In recent years,wide band gap materials,known for their strong bonding and high ionization energy,have gained increasing attention from researchers and hold significant promise for extensive applications in specialized environments.Consequently,there is a growing need for comprehensive research on the dose rate effects of wide band gap materials.In response to this need,the use of laser-assisted simulation technology has emerged as a promising approach,offering an effective means to assess the efficacy of investigating these materials and devices.This paper focused on investigating the feasibility of laser-assisted simulation to study the dose rate effects of wide band gap semiconductor devices.Theoretical conversion factors for laser-assisted simulation of dose rate effects of GaN-based and SiC-based devices were been provided.Moreover,to validate the accuracy of the conversion factors,pulsed laser and dose rate experiments were conducted on GaN-based and SiC-based PIN diodes.The results demonstrate that pulsed laser radiation andγ-ray radiation can produce highly similar photocurrent responses in GaN-based and SiC-based PIN diodes,with correlation coefficients of 0.98 and 0.974,respectively.This finding reaffirms the effectiveness of laser-assisted simulation technology,making it a valuable complement in studying the dose rate effects of wide band gap semiconductor devices.