A novel decarboxylative fluorination process has been developed for the synthesis of ortho-hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho-hydroxy/amino group plays an important role in the...A novel decarboxylative fluorination process has been developed for the synthesis of ortho-hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho-hydroxy/amino group plays an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions.展开更多
基金We are grateful for the financial support from the National Natural Science Foundation of China （24172219, 21532009, 21761142010 and 21790330）, the National Basic Research Program of China （973-2015CB856600）, the strategic Priority Research Program （XDB20000000）, the Key Research Program of Froniter Science （QYZDJSSW-SLH055）, CAS, and the Science Technology Commission of the Shanghai Municipality （17XD140500 and 17JC1401200）. This research was partially supported by CAS Interdisciplinary Innovation Team.
文摘A novel decarboxylative fluorination process has been developed for the synthesis of ortho-hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho-hydroxy/amino group plays an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions.
