The surface of nodular cast iron (NCI) with a ferrite substrate was rapidly remelted and solidified by plasma transferred arc (PTA) to induce a chilled structure with high hardness and favorable wear resistance. T...The surface of nodular cast iron (NCI) with a ferrite substrate was rapidly remelted and solidified by plasma transferred arc (PTA) to induce a chilled structure with high hardness and favorable wear resistance. The effect of scanning speed on the microstructure, micro-hardness distribution, and wear properties of PTA-remelted specimens was systematically investigated. Microstructural characterization in-dicated that the PTA remelting treatment could dissolve most graphite nodules and that the crystallized primary austenite dendrites were transformed into cementite, martensite, an interdendritic network of ledeburite eutectic, and certain residual austenite during rapid solidifica-tion. The dimensions of the remelted zone and its dendrites increase with decreased scanning speed. The microhardness of the remelted zone varied in the range of 650 HV0.2 to 820 HV0.2, which is approximately 2.3-3.1 times higher than the hardness of the substrate. The wear re-sistance of NCI was also significantly improved after the PTA remelting treatment.展开更多
The effects of rare earths with different contents on anti-degradation of Y base heavy rare earths-magnesium and cerium base light rare earths-magnesium nodular cast iron were studied. Curves of the relationship betwe...The effects of rare earths with different contents on anti-degradation of Y base heavy rare earths-magnesium and cerium base light rare earths-magnesium nodular cast iron were studied. Curves of the relationship between the spheroidization grade of liguid iron treated by different nodulizers and holding time were obtained. The results show that the more the remains of the rare earth, the longer the anti-degradation time, the liquid iron was treated either by Y-Mg-Si or by Ce-Mg-Si nodulizer. When the rare earth remains are above certain quantity, the spheroidization grade starts to decline. When liquid iron treated by either Y-Mg-Si or Ce-Mg-Si nodulizer with proper remains of rare earths about 0.04% 0.06%(mass fraction), the anti-degradation is the best, and the remains of Mg being about 0.04% -0.07% (mass fraction). Rare earths-Mg nodulizer with moderate RE remains is better than that of Mg-Si nodulizer in anti-degradation property. However, Y-Mg-Si nodulizer with moderate remins of Re is better than Ce-Mg-Si nodulizer. Sometimes Ce-Mg- Si nodulizer can be used for the production of heavy section nodular cast iron.展开更多
The centrifugal casting of compound HSS/nodular cast iron roll collar was studied,and the factors affecting transition zone quality were analyzed.The pouring temperature and interval in pouring are the main factors af...The centrifugal casting of compound HSS/nodular cast iron roll collar was studied,and the factors affecting transition zone quality were analyzed.The pouring temperature and interval in pouring are the main factors affecting transition zone quality.By controlling process parameter and flux adding during casting,high quality roll collar was obtained.The cause,why in the casting of HSS part,segregation appears easily,was analyzed and the countermeasure eliminating segregation was put forward,the measure eliminating heat treatment crackling was also put forward.展开更多
Size distribution and precipitation of VC particles in ferritic nodular cast iron have been examined by techniques of ultrasonic screening,small angle X-ray scattering and chemical dissolution.The VC particles are siz...Size distribution and precipitation of VC particles in ferritic nodular cast iron have been examined by techniques of ultrasonic screening,small angle X-ray scattering and chemical dissolution.The VC particles are sized over a wide range.The superfine ones, dispersed in the ferritic matrix,are the majority.A saturated dispersion with ultrafine VC particles may be approached as the V content increasing in the iron.Thi5 seems to play an important role in the precipitation strengthening for ferritic nodular cast iron.展开更多
The morphology,size and composition of intermetallic compound at the interface of Al 1050 and nodular cast iron were studied by electron microprobe analysis(EMPA)and scan electron microscopy(SEM),respectively.The bond...The morphology,size and composition of intermetallic compound at the interface of Al 1050 and nodular cast iron were studied by electron microprobe analysis(EMPA)and scan electron microscopy(SEM),respectively.The bond strength of the interface was measured by the tensile tests and the morphology of the fracture surface was observed by SEM.The observation of the interface reveals that there are two distinct morphologies:no intermetallic compound exists in the central area at the interface;while numbers of intermetallic compounds(FexAly)are formed in the peripheral area due to the overfull heat input.The tensile tests indicate that the distribution of strength in radial direction at the interface is inhomogeneous,and the central area of the interface performs greater bond strength than the peripheral area,which proves directly that the FexAly intermetallic compounds have a negative effect on the integration of interface.The morphology on the fracture surface shows that the facture in the central area at the interface has characteristic of the ductile micro-void facture.So it is important to restrain the form of the intermetallic compound to increase the bond strength of the Al 1050 and nodular cast iron by optimizing welding parameters and the geometry of components.展开更多
The graphite phase has been extracted from the nodular cast iron to measure the concentration of trace element in it. The impurity phase was removed from the extracted matter by dissolving it with HCl and HCl+H<sub...The graphite phase has been extracted from the nodular cast iron to measure the concentration of trace element in it. The impurity phase was removed from the extracted matter by dissolving it with HCl and HCl+H<sub>2</sub>O<sub>2</sub> to get the pure graphite phase. PIXE measurements were performed with thick targets of the pure graphite phase. Differences in the trace element concentrations between the graphite phase and the matrix have been observed. The effect of Ti and As in graphite phase on the nodularization rate and the mechanical properties have been studied.展开更多
The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Mea...The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Measurements of ultimate tensile strength, 0.2% proof strength, elongation and unnotched Charpy impact energy are presented as a function of alloy amounts within 0.25 to 0.75 wt pct range. Hardness is measured on the broken tensile specimens. The small additions of Mo, Cu, Ni and Cr changed the as-cast mechanical properties owing to the different as-cast matrix microstructures. The ferrite matrix of Mo and Ni alloyed cast iron exhibits low strength and hardness as well as high elongation and impact energy. The increase in Mo and Ni contents developed some fractions of pearlite structures near the austenite eutectic cell boundaries, which caused the elongation and impact energy to drop in a small range. Adding Cu and Cr elements rapidly changed the ferrite matrix into pearlite matrix, so strength and hardness were significantly increased. As more Mo and Cr were added, the size and fraction of primary carbides in the eutectic cell boundaries increased through the segregation of these elements into the intercellular boundaries.展开更多
This paper gives a brief introduction to the four research methods for the study on thermal conductivity of cast irons,including experimental measurement,statistical analysis,effective medium theory and numerical simu...This paper gives a brief introduction to the four research methods for the study on thermal conductivity of cast irons,including experimental measurement,statistical analysis,effective medium theory and numerical simulation.Recent studies on the thermal conductivity of various cast irons are reviewed through the influence of alloying elements,structural constituents,and temperature.The addition of alloying elements is the main reason that restricts the thermal conductivity of cast irons,especially spheroidal graphite cast iron.The connectivity of graphite has a significant effect on the thermal conductivity of flake and compacted graphite cast irons,semiquantitative and quantitative analysis of this factor is a key and difficult point in the study of thermal conductivity of cast irons.The thermal conductivities of different types of cast irons show varying degrees of dependence on temperature.This phenomenon is the combination of graphite and matrix,rather than just depending on graphite morphology.The study of the relationship between individual phase and temperature is the focus of future research.These summaries and discussions may provide reference and guidance for the future research and development of high thermal conductivity cast irons.展开更多
A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experiment...A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experimental castings have the following dimensions 180 mm x 180 mm x 190 mm.The achieved as-cast Charpy impact strengths were as follows:17 J (RT),16 J (-20℃) and 11 J (-40℃).The foundry process,the chemical composition and the microstructure of this experimental casting are compared to the ones of various examples in order to show the detrimental effects of residual elements,microshrinkage and microcarbide on the impact properties.Finally,quality index empirical models (based on casting chemical compositions) are used to analyse the impact tests results.This paper illustrates that an adequate nodule count can contribute to reducing the detrimental effects of the residual elements and microsegregation.展开更多
EN-GJS-450-10 ductile cast iron was produced with and without vibration to evaluate microstructural features. To investigate the effect of vibration, a reference, and two different castings having amplitudes of 0.9 mm...EN-GJS-450-10 ductile cast iron was produced with and without vibration to evaluate microstructural features. To investigate the effect of vibration, a reference, and two different castings having amplitudes of 0.9 mm and 1.8 mm were cast with a fixed vibration frequency of 50 Hz. The nodule count (density), form (type), size distribution, nodularity, and the fraction of graphite, percentages of both ferrite and pearlite phases, length of ferrite shell, and pore, were evaluated via optical microscopy using an image analysis software. It is observed that the microstructure of the cast iron is more uniform by vibrational casting than that by non-vibrational casting. Additionally, mechanical vibration enhances nodule count and nodularity, also, more ferritic matrix could be obtained after the application of vibration. Nodule count and nodularity of vibrational casting with 1.8 mm amplitude increased from 226 nodule per mm2 and 80% to 311 nodule per mm2 and 86.5% of non-vibrational casting. Percentages of ferrite and graphite area dramatically improved from 24% and 16.5% for non-vibrational casting to 57% and 22.3% for vibrational casting with 1.8 mm amplitude, whereas the percentages of pearlite and pores decreased significantly from 56.1% and 5% to 20% and 1%, respectively.展开更多
The development of computer picture processing technique in metallography analysis is dealed with and a picture processing procedure fit to metallography analysis is developed. The image processing of nodular cast iro...The development of computer picture processing technique in metallography analysis is dealed with and a picture processing procedure fit to metallography analysis is developed. The image processing of nodular cast iron is carried out with this system展开更多
The dependence of nodularization of graphite upon Ce content in RE bearing nodular cast iron,prepared by directional solidification,has been investigated by electrolytic extraction-radioisotope assay analysis of Ce in...The dependence of nodularization of graphite upon Ce content in RE bearing nodular cast iron,prepared by directional solidification,has been investigated by electrolytic extraction-radioisotope assay analysis of Ce in each phase of the iron together with measurement of nodulized graphite.Results show that the Ce occurs mainly as alloyed form. In the graphite phase,the Ce content is believed to be characterization of nodularization.The graphite would completely nodulized only the Ce is over a certain content in graphite phase.展开更多
According to the principle of damage mechanics,the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular c...According to the principle of damage mechanics,the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular cast iron occurs when the applied stress is more than a certain extent,and the damage variable increases with stress. The evolutional law of damage variable as a function of stress was obtained.The damage threshold of nodular cast iron increases with nodularity,but it is below the yield strength,which provides reference significance to the design of machinery structure and the choice of materials.The critical damage variable is not related to the nodularity,which is about 0. 060-0. 068.展开更多
基金financially supported by the Key Project of China National Erzhong Group Co.(No.2012zx04010-081)
文摘The surface of nodular cast iron (NCI) with a ferrite substrate was rapidly remelted and solidified by plasma transferred arc (PTA) to induce a chilled structure with high hardness and favorable wear resistance. The effect of scanning speed on the microstructure, micro-hardness distribution, and wear properties of PTA-remelted specimens was systematically investigated. Microstructural characterization in-dicated that the PTA remelting treatment could dissolve most graphite nodules and that the crystallized primary austenite dendrites were transformed into cementite, martensite, an interdendritic network of ledeburite eutectic, and certain residual austenite during rapid solidifica-tion. The dimensions of the remelted zone and its dendrites increase with decreased scanning speed. The microhardness of the remelted zone varied in the range of 650 HV0.2 to 820 HV0.2, which is approximately 2.3-3.1 times higher than the hardness of the substrate. The wear re-sistance of NCI was also significantly improved after the PTA remelting treatment.
文摘The effects of rare earths with different contents on anti-degradation of Y base heavy rare earths-magnesium and cerium base light rare earths-magnesium nodular cast iron were studied. Curves of the relationship between the spheroidization grade of liguid iron treated by different nodulizers and holding time were obtained. The results show that the more the remains of the rare earth, the longer the anti-degradation time, the liquid iron was treated either by Y-Mg-Si or by Ce-Mg-Si nodulizer. When the rare earth remains are above certain quantity, the spheroidization grade starts to decline. When liquid iron treated by either Y-Mg-Si or Ce-Mg-Si nodulizer with proper remains of rare earths about 0.04% 0.06%(mass fraction), the anti-degradation is the best, and the remains of Mg being about 0.04% -0.07% (mass fraction). Rare earths-Mg nodulizer with moderate RE remains is better than that of Mg-Si nodulizer in anti-degradation property. However, Y-Mg-Si nodulizer with moderate remins of Re is better than Ce-Mg-Si nodulizer. Sometimes Ce-Mg- Si nodulizer can be used for the production of heavy section nodular cast iron.
文摘The centrifugal casting of compound HSS/nodular cast iron roll collar was studied,and the factors affecting transition zone quality were analyzed.The pouring temperature and interval in pouring are the main factors affecting transition zone quality.By controlling process parameter and flux adding during casting,high quality roll collar was obtained.The cause,why in the casting of HSS part,segregation appears easily,was analyzed and the countermeasure eliminating segregation was put forward,the measure eliminating heat treatment crackling was also put forward.
文摘Size distribution and precipitation of VC particles in ferritic nodular cast iron have been examined by techniques of ultrasonic screening,small angle X-ray scattering and chemical dissolution.The VC particles are sized over a wide range.The superfine ones, dispersed in the ferritic matrix,are the majority.A saturated dispersion with ultrafine VC particles may be approached as the V content increasing in the iron.Thi5 seems to play an important role in the precipitation strengthening for ferritic nodular cast iron.
基金Project supported by the985Program of Jilin University,China
文摘The morphology,size and composition of intermetallic compound at the interface of Al 1050 and nodular cast iron were studied by electron microprobe analysis(EMPA)and scan electron microscopy(SEM),respectively.The bond strength of the interface was measured by the tensile tests and the morphology of the fracture surface was observed by SEM.The observation of the interface reveals that there are two distinct morphologies:no intermetallic compound exists in the central area at the interface;while numbers of intermetallic compounds(FexAly)are formed in the peripheral area due to the overfull heat input.The tensile tests indicate that the distribution of strength in radial direction at the interface is inhomogeneous,and the central area of the interface performs greater bond strength than the peripheral area,which proves directly that the FexAly intermetallic compounds have a negative effect on the integration of interface.The morphology on the fracture surface shows that the facture in the central area at the interface has characteristic of the ductile micro-void facture.So it is important to restrain the form of the intermetallic compound to increase the bond strength of the Al 1050 and nodular cast iron by optimizing welding parameters and the geometry of components.
文摘The graphite phase has been extracted from the nodular cast iron to measure the concentration of trace element in it. The impurity phase was removed from the extracted matter by dissolving it with HCl and HCl+H<sub>2</sub>O<sub>2</sub> to get the pure graphite phase. PIXE measurements were performed with thick targets of the pure graphite phase. Differences in the trace element concentrations between the graphite phase and the matrix have been observed. The effect of Ti and As in graphite phase on the nodularization rate and the mechanical properties have been studied.
文摘The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Measurements of ultimate tensile strength, 0.2% proof strength, elongation and unnotched Charpy impact energy are presented as a function of alloy amounts within 0.25 to 0.75 wt pct range. Hardness is measured on the broken tensile specimens. The small additions of Mo, Cu, Ni and Cr changed the as-cast mechanical properties owing to the different as-cast matrix microstructures. The ferrite matrix of Mo and Ni alloyed cast iron exhibits low strength and hardness as well as high elongation and impact energy. The increase in Mo and Ni contents developed some fractions of pearlite structures near the austenite eutectic cell boundaries, which caused the elongation and impact energy to drop in a small range. Adding Cu and Cr elements rapidly changed the ferrite matrix into pearlite matrix, so strength and hardness were significantly increased. As more Mo and Cr were added, the size and fraction of primary carbides in the eutectic cell boundaries increased through the segregation of these elements into the intercellular boundaries.
基金financial support by the National Natural Science Foundationof China(Grant No.51371104)。
文摘This paper gives a brief introduction to the four research methods for the study on thermal conductivity of cast irons,including experimental measurement,statistical analysis,effective medium theory and numerical simulation.Recent studies on the thermal conductivity of various cast irons are reviewed through the influence of alloying elements,structural constituents,and temperature.The addition of alloying elements is the main reason that restricts the thermal conductivity of cast irons,especially spheroidal graphite cast iron.The connectivity of graphite has a significant effect on the thermal conductivity of flake and compacted graphite cast irons,semiquantitative and quantitative analysis of this factor is a key and difficult point in the study of thermal conductivity of cast irons.The thermal conductivities of different types of cast irons show varying degrees of dependence on temperature.This phenomenon is the combination of graphite and matrix,rather than just depending on graphite morphology.The study of the relationship between individual phase and temperature is the focus of future research.These summaries and discussions may provide reference and guidance for the future research and development of high thermal conductivity cast irons.
文摘A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experimental castings have the following dimensions 180 mm x 180 mm x 190 mm.The achieved as-cast Charpy impact strengths were as follows:17 J (RT),16 J (-20℃) and 11 J (-40℃).The foundry process,the chemical composition and the microstructure of this experimental casting are compared to the ones of various examples in order to show the detrimental effects of residual elements,microshrinkage and microcarbide on the impact properties.Finally,quality index empirical models (based on casting chemical compositions) are used to analyse the impact tests results.This paper illustrates that an adequate nodule count can contribute to reducing the detrimental effects of the residual elements and microsegregation.
文摘EN-GJS-450-10 ductile cast iron was produced with and without vibration to evaluate microstructural features. To investigate the effect of vibration, a reference, and two different castings having amplitudes of 0.9 mm and 1.8 mm were cast with a fixed vibration frequency of 50 Hz. The nodule count (density), form (type), size distribution, nodularity, and the fraction of graphite, percentages of both ferrite and pearlite phases, length of ferrite shell, and pore, were evaluated via optical microscopy using an image analysis software. It is observed that the microstructure of the cast iron is more uniform by vibrational casting than that by non-vibrational casting. Additionally, mechanical vibration enhances nodule count and nodularity, also, more ferritic matrix could be obtained after the application of vibration. Nodule count and nodularity of vibrational casting with 1.8 mm amplitude increased from 226 nodule per mm2 and 80% to 311 nodule per mm2 and 86.5% of non-vibrational casting. Percentages of ferrite and graphite area dramatically improved from 24% and 16.5% for non-vibrational casting to 57% and 22.3% for vibrational casting with 1.8 mm amplitude, whereas the percentages of pearlite and pores decreased significantly from 56.1% and 5% to 20% and 1%, respectively.
文摘The development of computer picture processing technique in metallography analysis is dealed with and a picture processing procedure fit to metallography analysis is developed. The image processing of nodular cast iron is carried out with this system
文摘The dependence of nodularization of graphite upon Ce content in RE bearing nodular cast iron,prepared by directional solidification,has been investigated by electrolytic extraction-radioisotope assay analysis of Ce in each phase of the iron together with measurement of nodulized graphite.Results show that the Ce occurs mainly as alloyed form. In the graphite phase,the Ce content is believed to be characterization of nodularization.The graphite would completely nodulized only the Ce is over a certain content in graphite phase.
基金the Education Committee of Hebei for the financial support ( B2003102 )
文摘According to the principle of damage mechanics,the damage characteristics of ferrite nodular cast iron under uniaxial stress were studied by measuring electric resistance. The results show that the damage in nodular cast iron occurs when the applied stress is more than a certain extent,and the damage variable increases with stress. The evolutional law of damage variable as a function of stress was obtained.The damage threshold of nodular cast iron increases with nodularity,but it is below the yield strength,which provides reference significance to the design of machinery structure and the choice of materials.The critical damage variable is not related to the nodularity,which is about 0. 060-0. 068.