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SINGULAR CHARACTERISTICS OF NONLINEAR NORMAL MODES IN A TWO DEGREES OF FREEDOM ASYMMETRIC SYSTEMS WITH CUBIC NONLINEARITIES
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作者 徐鉴 陆启韶 黄克累 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2001年第8期972-982,共11页
Nonlinear normal modes in a two degrees of freedom asymmetric system with cubic nonlinearities as singularity occurs in the system are studied, based on the invariant space in nonlinear normal modes and perturbation t... Nonlinear normal modes in a two degrees of freedom asymmetric system with cubic nonlinearities as singularity occurs in the system are studied, based on the invariant space in nonlinear normal modes and perturbation technique. Emphasis is placed on singular characteristics as the linear coupling between subsystems degenerated. For nonresonances, it is analytically presented that a single-mode motion and localization of vibrations occur in the system, and the degree of localization relates not only to the coupling stiffness between oscillators, but also to the asymmetric parameter. The parametric threshold value of localization is analytically given. For 1 : 1 resonance, there exist bifurcations of normal modes with nonlinearly coupling stiffness and asymmetric parameter varying. The bifurcating set on the parameter and bifurcating curves of normal modes are obtained. 展开更多
关键词 asymmetric system nonlinear normal mode localization of vibration bifurcation of normal mode nonlinear dynamics
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Self-Synchronous Principle and Design of Vibrating Machines in Asymmetric System
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作者 陈飞 李艾民 《International Journal of Mining Science and Technology》 SCIE EI 1999年第1期72-74,79,共4页
Self-Synchronous principle of vibrating machines in asymmetric system is studied, and a design method is put forward. Based on Hamilton’s principle, a stable difference of phase angle is obtained,and this design meth... Self-Synchronous principle of vibrating machines in asymmetric system is studied, and a design method is put forward. Based on Hamilton’s principle, a stable difference of phase angle is obtained,and this design method is proved correct. 展开更多
关键词 asymmetric system self-synchronous vibrating MACHINE DESIGN
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Effects of asymmetric coupling and boundary on the dynamic behaviors of a random nearest neighbor coupled system
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作者 徐玲 姜磊 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期309-322,共14页
This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically... This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically coupled system in an unconfined space, which are then validated through numerical simulations. Simulation results show that asymmetric coupling has a significant impact on synchronization conditions. Moreover, it is observed that irrespective of whether the system is confined, an increase in coupling asymmetry leads to a hastened synchronization pace. Additionally, the study examines the effects of boundaries on the system's collective behaviors via numerical experiments. The presence of boundaries ensures the system's stability and synchronization, and reducing these boundaries can expedite the synchronization process and amplify its effects. Finally, the study reveals that the system's output amplitude exhibits stochastic resonance as the confined boundary size increases. 展开更多
关键词 asymmetric coupled confined space SYNCHRONIZATION stochastic resonance stability
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Decentralized Optimal Control and Stabilization of Interconnected Systems With Asymmetric Information
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作者 Na Wang Xiao Liang +1 位作者 Hongdan Li Xiao Lu 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第3期698-707,共10页
The paper addresses the decentralized optimal control and stabilization problems for interconnected systems subject to asymmetric information.Compared with previous work,a closed-loop optimal solution to the control p... The paper addresses the decentralized optimal control and stabilization problems for interconnected systems subject to asymmetric information.Compared with previous work,a closed-loop optimal solution to the control problem and sufficient and necessary conditions for the stabilization problem of the interconnected systems are given for the first time.The main challenge lies in three aspects:Firstly,the asymmetric information results in coupling between control and estimation and failure of the separation principle.Secondly,two extra unknown variables are generated by asymmetric information(different information filtration)when solving forward-backward stochastic difference equations.Thirdly,the existence of additive noise makes the study of mean-square boundedness an obstacle.The adopted technique is proving and assuming the linear form of controllers and establishing the equivalence between the two systems with and without additive noise.A dual-motor parallel drive system is presented to demonstrate the validity of the proposed algorithm. 展开更多
关键词 asymmetric information decentralized control forwardbackward stochastic difference equations interconnected system stalibization
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Asymmetric Drying and Wetting Trends in Eastern and Western China 被引量:1
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作者 Wen WU Fei JI +1 位作者 Shujuan HU Yongli HE 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第2期221-232,共12页
As an important factor that directly affects agricultural production, the social economy, and policy implementation,observed changes in dry/wet conditions have become a matter of widespread concern. However, previous ... As an important factor that directly affects agricultural production, the social economy, and policy implementation,observed changes in dry/wet conditions have become a matter of widespread concern. However, previous research has mainly focused on the long-term linear changes of dry/wet conditions, while the detection and evolution of the non-linear trends related to dry/wet changes have received less attention. The non-linear trends of the annual aridity index, obtained by the Ensemble Empirical Mode Decomposition(EEMD) method, reveal that changes in dry/wet conditions in China are asymmetric and can be characterized by contrasting features in both time and space in China. Spatially, most areas in western China have experienced transitions from drying to wetting, while opposite changes have occurred in most areas of eastern China. Temporally, the transitions occurred earlier in western China compared to eastern China. Research into the asymmetric spatial characteristics of dry/wet conditions compensates for the inadequacies of previous studies, which focused solely on temporal evolution;at the same time, it remedies the inadequacies of traditional research on linear trends over centennial timescales. Analyzing the non-linear trend also provides for a more comprehensive understanding of the drying/wetting changes in China. 展开更多
关键词 aridity index EEMD dry/wet conditions asymmetric evolution
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Event-Triggered Asymmetric Bipartite Consensus Tracking for Nonlinear Multi-Agent Systems Based on Model-Free Adaptive Control
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作者 Jiaqi Liang Xuhui Bu +1 位作者 Lizhi Cui Zhongsheng Hou 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2023年第3期662-672,共11页
In this paper,an asymmetric bipartite consensus problem for the nonlinear multi-agent systems with cooperative and antagonistic interactions is studied under the event-triggered mechanism.For the agents described by a... In this paper,an asymmetric bipartite consensus problem for the nonlinear multi-agent systems with cooperative and antagonistic interactions is studied under the event-triggered mechanism.For the agents described by a structurally balanced signed digraph,the asymmetric bipartite consensus objective is firstly defined,assigning the agents'output to different signs and module values.Considering with the completely unknown dynamics of the agents,a novel event-triggered model-free adaptive bipartite control protocol is designed based on the agents'triggered outputs and an equivalent compact form data model.By utilizing the Lyapunov analysis method,the threshold of the triggering condition is obtained.Subsequently,the asymptotic convergence of the tracking error is deduced and a sufficient condition is obtained based on the contraction mapping principle.Finally,the simulation example further demonstrates the effectiveness of the protocol. 展开更多
关键词 asymmetric bipartite consensus tracking eventtriggered model-free adaptive control(MFAC) nonlinear systems signed digraph
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Asymmetric Consortium Blockchain and Homomorphically Polynomial-Based PIR for Secured Smart Parking Systems
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作者 T.Haritha A.Anitha 《Computers, Materials & Continua》 SCIE EI 2023年第5期3923-3939,共17页
In crowded cities,searching for the availability of parking lots is a herculean task as it results in the wastage of drivers’time,increases air pollution,and traffic congestion.Smart parking systems facilitate the dr... In crowded cities,searching for the availability of parking lots is a herculean task as it results in the wastage of drivers’time,increases air pollution,and traffic congestion.Smart parking systems facilitate the drivers to determine the information about the parking lot in real time and book them depending on the requirement.But the existing smart parking systems necessitate the drivers to reveal their sensitive information that includes their mobile number,personal identity,and desired destination.This disclosure of sensitive information makes the existing centralized smart parking systems more vulnerable to service providers’security breaches,single points of failure,and bottlenecks.In this paper,an Improved Asymmetric Consortium Blockchain and Homomorphically Computing Univariate Polynomial-based private information retrieval(IACB-HCUPPIR)scheme is proposed to ensure parking lots’availability with transparency security in a privacy-preserving smart parking system.In specific,an improved Asymmetric Consortium Blockchain is used for achieving secure transactions between different parties interacting in the smart parking environment.It further adopted the method of Homomorphically Computing Univariate Polynomial-based private information retrieval(HCUPPIR)scheme for preserving the location privacy of drivers.The results of IACB-HCUPPIR confirmed better results in terms of minimized computation and communication overload with throughput,latency,and response time with maximized drivers’privacy preservation.Moreover,the proposed fully homomorphic algorithm(FHE)was compared against partial-homomorphic encryption(PHE)and technique without encryption and found that the proposed model has quick communication in allocating the parking slots starting with 24.3 s,whereas PHE starts allocating from 24.7 s and the technique without encryption starts at 27.4 s.Thus,we ensure the proposed model performs well in allocating parking slots with less time and high security with privacy preservation. 展开更多
关键词 Smart parking asymmetric consortium blockchain privacy preservation homomorphic encryption private information retrieval
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Enhanced and asymmetric signatures of hybridization at climatic margins: Evidence from closely related dioecious fig species
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作者 Jian-Feng Huang Clive T.Darwell Yan-Qiong Peng 《Plant Diversity》 SCIE CAS CSCD 2024年第2期181-193,共13页
Hybridization plays a significant role in biological evolution. However, it is not clear whether ecological contingency differentially influences likelihood of hybridization, particularly at ecological margins where p... Hybridization plays a significant role in biological evolution. However, it is not clear whether ecological contingency differentially influences likelihood of hybridization, particularly at ecological margins where parental species may exhibit reduced fitnesses. Moreover, it is unknown whether future ecosystem change will increase the prevalence of hybridization. Ficus heterostyla and F. squamosa are closely related species co-distributed from southern Thailand to southwest China where hybridization, yielding viable seeds, has been documented. As a robust test of ecological factors driving hybridization, we investigated spatial hybridization signatures based on nuclear microsatellites from extensive population sampling across a widespread contact range. Both species showed high population differentiation and strong patterns of isolation by distance. Admixture estimates exposed asymmetric interspecific gene flow.Signatures of hybridization increase significantly towards higher latitude zones, peaking at the northern climatic margins. Geographic variation in reproductive phenology combined with ecologically challenging marginal habitats may promote this phenomenon. Our work is a first systematic evaluation of such patterns in a comprehensive, latitudinally-based clinal context, and indicates that tendency to hybridize appears strongly influenced by environmental conditions. Moreover, that future climate change scenarios will likely alter and possibly augment cases of hybridization at ecosystem scales. 展开更多
关键词 HYBRIDIZATION Heterospecific visitation FIG Pollinator wasp asymmetric gene flow
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Dynamics and vibration reduction performance of asymmetric tristable nonlinear energy sink
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作者 Hongyan CHEN Youcheng ZENG +2 位作者 Hu DING Siukai LAI Liqun CHEN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第3期389-406,共18页
With its complex nonlinear dynamic behavior,the tristable system has shown excellent performance in areas such as energy harvesting and vibration suppression,and has attracted a lot of attention.In this paper,an asymm... With its complex nonlinear dynamic behavior,the tristable system has shown excellent performance in areas such as energy harvesting and vibration suppression,and has attracted a lot of attention.In this paper,an asymmetric tristable design is proposed to improve the vibration suppression efficiency of nonlinear energy sinks(NESs)for the first time.The proposed asymmetric tristable NES(ATNES)is composed of a pair of oblique springs and a vertical spring.Then,the three stable states,symmetric and asymmetric,can be achieved by the adjustment of the distance and stiffness asymmetry of the oblique springs.The governing equations of a linear oscillator(LO)coupled with the ATNES are derived.The approximate analytical solution to the coupled system is obtained by the harmonic balance method(HBM)and verified numerically.The vibration suppression efficiency of three types of ATNES is compared.The results show that the asymmetric design can improve the efficiency of vibration reduction through comparing the chaotic motion of the NES oscillator between asymmetric steady states.In addition,compared with the symmetrical tristable NES(TNES),the ATNES can effectively control smaller structural vibrations.In other words,the ATNES can effectively solve the threshold problem of TNES failure to weak excitation.Therefore,this paper reveals the vibration reduction mechanism of the ATNES,and provides a pathway to expand the effective excitation amplitude range of the NES. 展开更多
关键词 asymmetric nonlinear energy sink(NES) tristable vibration control po-tential barrier
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Dynamics of information diffusion and disease transmission in time-varying multiplex networks with asymmetric activity levels
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作者 谢笑笑 霍良安 +1 位作者 董雅芳 程英英 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期690-699,共10页
While the interaction between information and disease in static networks has been extensively investigated,many studies have ignored the characteristics of network evolution.In this study,we construct a new two-layer ... While the interaction between information and disease in static networks has been extensively investigated,many studies have ignored the characteristics of network evolution.In this study,we construct a new two-layer coupling model to explore the interactions between information and disease.The upper layer describes the diffusion of disease-related information,and the lower layer represents the disease transmission.We then use power-law distributions to examine the influence of asymmetric activity levels on dynamic propagation,revealing a mapping relationship characterizing the interconnected propagation of information and diseases among partial nodes within the network.Subsequently,we derive the disease outbreak threshold by using the microscopic Markov-chain approach(MMCA).Finally,we perform extensive Monte Carlo(MC)numerical simulations to verify the accuracy of our theoretical results.Our findings indicate that the activity levels of individuals in the disease transmission layer have a more significant influence on disease transmission compared with the individual activity levels in the information diffusion layer.Moreover,reducing the damping factor can delay disease outbreaks and suppress disease transmission,while improving individual quarantine measures can contribute positively to disease control.This study provides valuable insights into policymakers for developing outbreak prevention and control strategies. 展开更多
关键词 information diffusion disease transmission asymmetric activity levels quarantine strength
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Activation Redistribution Based Hybrid Asymmetric Quantization Method of Neural Networks
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作者 Lu Wei Zhong Ma Chaojie Yang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期981-1000,共20页
The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedd... The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedded devices.In order to reduce the complexity and overhead of deploying neural networks on Integeronly hardware,most current quantization methods use a symmetric quantization mapping strategy to quantize a floating-point neural network into an integer network.However,although symmetric quantization has the advantage of easier implementation,it is sub-optimal for cases where the range could be skewed and not symmetric.This often comes at the cost of lower accuracy.This paper proposed an activation redistribution-based hybrid asymmetric quantizationmethod for neural networks.The proposedmethod takes data distribution into consideration and can resolve the contradiction between the quantization accuracy and the ease of implementation,balance the trade-off between clipping range and quantization resolution,and thus improve the accuracy of the quantized neural network.The experimental results indicate that the accuracy of the proposed method is 2.02%and 5.52%higher than the traditional symmetric quantization method for classification and detection tasks,respectively.The proposed method paves the way for computationally intensive neural network models to be deployed on devices with limited computing resources.Codes will be available on https://github.com/ycjcy/Hybrid-Asymmetric-Quantization. 展开更多
关键词 QUANTIZATION neural network hybrid asymmetric ACCURACY
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Coexistence behavior of asymmetric attractors in hyperbolic-type memristive Hopfield neural network and its application in image encryption
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作者 李晓霞 何倩倩 +2 位作者 余天意 才壮 徐桂芝 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期302-315,共14页
The neuron model has been widely employed in neural-morphic computing systems and chaotic circuits.This study aims to develop a novel circuit simulation of a three-neuron Hopfield neural network(HNN)with coupled hyper... The neuron model has been widely employed in neural-morphic computing systems and chaotic circuits.This study aims to develop a novel circuit simulation of a three-neuron Hopfield neural network(HNN)with coupled hyperbolic memristors through the modification of a single coupling connection weight.The bistable mode of the hyperbolic memristive HNN(mHNN),characterized by the coexistence of asymmetric chaos and periodic attractors,is effectively demonstrated through the utilization of conventional nonlinear analysis techniques.These techniques include bifurcation diagrams,two-parameter maximum Lyapunov exponent plots,local attractor basins,and phase trajectory diagrams.Moreover,an encryption technique for color images is devised by leveraging the mHNN model and asymmetric structural attractors.This method demonstrates significant benefits in correlation,information entropy,and resistance to differential attacks,providing strong evidence for its effectiveness in encryption.Additionally,an improved modular circuit design method is employed to create the analog equivalent circuit of the memristive HNN.The correctness of the circuit design is confirmed through Multisim simulations,which align with numerical simulations conducted in Matlab. 展开更多
关键词 hyperbolic-type memristor Hopfield neural network(HNN) asymmetric attractors image encryption
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Asymmetric Electrolytes Design for Aqueous Multivalent Metal Ion Batteries
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作者 Xiaochen Yang Xinyu Wang +2 位作者 Yue Xiang Longtao Ma Wei Huang 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期227-253,共27页
With the rapid development of portable electronics and electric road vehicles,high-energy-density batteries have been becoming front-burner issues.Traditionally,homogeneous electrolyte cannot simultaneously meet diame... With the rapid development of portable electronics and electric road vehicles,high-energy-density batteries have been becoming front-burner issues.Traditionally,homogeneous electrolyte cannot simultaneously meet diametrically opposed demands of high-potential cathode and low-potential anode,which are essential for high-voltage batteries.Meanwhile,homogeneous electrolyte is difficult to achieve bi-or multi-functions to meet different requirements of electrodes.In comparison,the asymmetric electrolyte with bi-or multi-layer disparate components can satisfy distinct requirements by playing different roles of each electrolyte layer and meanwhile compensates weakness of individual electrolyte.Consequently,the asymmetric electrolyte can not only suppress by-product sedimentation and continuous electrolyte decomposition at the anode while preserving active substances at the cathode for high-voltage batteries with long cyclic lifespan.In this review,we comprehensively divide asymmetric electrolytes into three categories:decoupled liquid-state electrolytes,bi-phase solid/liquid electrolytes and decoupled asymmetric solid-state electrolytes.The design principles,reaction mechanism and mutual compatibility are also studied,respectively.Finally,we provide a comprehensive vision for the simplification of structure to reduce costs and increase device energy density,and the optimization of solvation structure at anolyte/catholyte interface to realize fast ion transport kinetics. 展开更多
关键词 asymmetric electrolyte Aqueous multivalent metal ion batteries Electrochemical stability windows Electrolyte interface
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Acoustic Bilayer Gradient Metasurfaces for Perfect and Asymmetric Beam Splitting
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作者 权家琪 孙宝印 +2 位作者 伏洋洋 高雷 徐亚东 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第1期39-50,共12页
We experimentally and theoretically present a paradigm for the accurate bilayer design of gradient metasurfaces for wave beam manipulation,producing an extremely asymmetric splitting effect by simply tailoring the int... We experimentally and theoretically present a paradigm for the accurate bilayer design of gradient metasurfaces for wave beam manipulation,producing an extremely asymmetric splitting effect by simply tailoring the interlayer size.This concept arises from anomalous diffraction in phase gradient metasurfaces and the precise combination of the phase gradient in bilayer metasurfaces.Ensured by different diffraction routes in momentum space for incident beams from opposite directions,extremely asymmetric acoustic beam splitting can be generated in a robust way,as demonstrated in experiments through a designed bilayer system.Our work provides a novel approach and feasible platform for designing tunable devices to control wave propagation. 展开更多
关键词 SURFACES SPLITTING asymmetric
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Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells
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作者 Shufang Li Huilan Guan +4 位作者 Can Zhu Chaoyuan Sun Qingya Wei Jun Yuan Yingping Zou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1713-1719,共7页
Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology... Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology of blend film,thereby improving charge mobility and reducing energy loss within the corresponding film.Notably,the PM6:BP4F-UU device exhibited a higher open-circuit voltage(V_(oc))of 0.878 V compared to the PM6:BP4F-HU device with a V_(oc)of 0.863 V.Further,a new wide bandgap SMA named BTP-TA was designed and synthesized as the third component to the PM6:BP4F-UU host binary devices,which showed an ideal complementary absorption spectrum in PM6:BP4F-UU system.In addition,BTP-TA can achieve efficient intermolecular energy transfer to BP4F-UU by fluorescence resonance energy transfer(FRET)pathway,due to the good overlap between the photoluminescence(PL)spectrum of BTP-TA and the absorption region of BP4F-UU.Consequently,ternary devices with 15wt%BTP-TA exhibits broader photon utilization,optimal blend morphology,and reduced charge recombination compared to the corresponding binary devices.Consequently,PM6:BP4F-UU:BTP-TA ternary device achieved an optimal power conversion efficiency(PCE)of 17.83%with simultaneously increased V_(oc)of 0.905 V,short-circuit current density(J_(sc))of 26.14 mA/cm^(2),and fill factor(FF)of 75.38%. 展开更多
关键词 asymmetric hexacyclic acceptor outside chain wide bandgap acceptor ternary organic solar cells
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Asymmetric orbital hybridization in Zn-doped antiperovskite Cu_(1-x)Zn_(x)NMn_(3)enables highly efficient electrocatalytic hydrogen production
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作者 Yuxiang Yan Yuxin Cao +9 位作者 Zhichao Wang Ka Wang Hengdong Ren Shaoqi Zhang Yi Wang Jian Chen Yong Zhou Lizhe Liu Jun Dai Xinglong Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期304-312,I0008,共10页
Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(HER)catalysts is a key factor for developing energy conversion technologies.Currently,antiperovskite nitride CuNMn_(3)has gar... Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(HER)catalysts is a key factor for developing energy conversion technologies.Currently,antiperovskite nitride CuNMn_(3)has garnered significant interest due to its remarkable properties such as negative/zero thermal expansion and magnetocaloric effects.However,when utilized as hydrogen evolution catalysts,it encounters large challenge resulting from excessively strong/weak interactions with adsorbed H on Mn/Cu active sites,which leads to low HER activity.In this study,we introduce an asymmetric orbital hybridization strategy in Zn-doped Cu_(1-x)Zn_(x)NMn_(3)by leveraging the localization of Zn electronic states to reconfigure the electronic structures of Cu and Mn,thereby reducing the energy barrier for water dissociation and optimizing Cu and Mn active sites for hydrogen adsorption and H_(2)production.Electrochemical evaluations reveal that Cu_(0.85)Zn_(0.15)NMn_(3)with x=0.15 demonstrates exceptional electrocatalytic activity in alkaline electrolytes.A low overpotential of 52 mV at 10 mA cm^(-2)and outstanding stability over a 150-h test period are achieved,surpassing commercial Pt/C.This research offers a novel strategy for enhancing HER performance by modulating asymmetric hybridization of electron orbitals between multiple metal atoms within a material structure. 展开更多
关键词 Cu_(1-x)ZnxNMn_(3) asymmetric orbital hybridization Hydrogen adsorption Hydrogen production
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Operationally Simple Enantioselective Silane Reduction of Ketones by the [Ir(OMe)(cod)]2/Azolium Catalytic System
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作者 Satoshi Sakaguchi Chika Nagao +1 位作者 Ryo Ichihara Shogo Matsuo 《International Journal of Organic Chemistry》 2024年第1期1-19,共19页
An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal ... An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal catalyst precursor. This reaction was driven by chiral hydroxyamide-functionalized azolium salt 2. The catalytic ESR reaction could be performed under benchtop conditions at room temperature. Treatment of 2 with 3 in THF yielded the monodentate IrCl(NHC)(cod) (NHC = N-heterocyclic carbene) complex 4 in 93% yield, herein the anionic methoxy ligand of 3 serves as an internal base that deprotonates the azolium ring of 2. The well-defined Ir complex 4 catalyzed the ESR reaction of propiophenone (6) with (EtO)<sub>2</sub>MeSiH using the pre-mixing reaction procedure. Based on this success, the catalytic ESR reaction was designed and implemented using an in situ-generated NHC/Ir catalyst derived from 2 and 3. Thus, a wide variety of aryl ketones could be reduced to the corresponding optically active alcohols in moderate to excellent stereoselectivities at room temperature without temperature control. Since the high catalytic activity of 3 was observed, we next evaluated several other transition metal catalyst precursors for the catalytic ESR reaction under the influence of 2. This evaluation revealed that Ir(acac)(cod) (acac = acetylacetonate) (28) and [IrCl(cod)]<sub>2</sub> (5) can be successfully used as metal catalyst precursors in the ESR reaction. 展开更多
关键词 asymmetric Catalysis Enantioselective Reduction Hydrosilylation Reaction N-Heterocyclic Carbene IRIDIUM
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Constraints on Asymmetric Dark Matter in Quintessence Model
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作者 Sujuan Qiu Hoernisa Iminniyaz 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第2期599-608,共10页
The modified cosmology like quintessence model with kination phase predicted the Hubble expansion rate of the universe before Big Bang Nucleosynthesis is different from the standard cosmological scenario. The modified... The modified cosmology like quintessence model with kination phase predicted the Hubble expansion rate of the universe before Big Bang Nucleosynthesis is different from the standard cosmological scenario. The modified expansion rate leaves its imprint on the relic density of asymmetric dark matter. In this work, we review the calculation of relic density of asymmetric WIMP dark matter in the standard cosmological scenario and quintessence model with kination phase. Then we use the Planck data to find constraints on the annihilation cross section and the mass of the asymmetric dark matter in those models. 展开更多
关键词 asymmetric Dark Matter Standard Model Quintessence Model
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The evolution of cooperation in asymmetric systems 被引量:12
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作者 WANG RuiWu1 & SHI Lei2 1 State Key Laboratory of Genetic Resources and Evolution,Kunming Institute of Zoology,Chinese Academy of Science,Kunming 650223,China 2 Statistics and Mathematics College,Yunnan University of Finance and Economics,Kunming 650221,China 《Science China(Life Sciences)》 SCIE CAS 2010年第1期139-149,共11页
Explaining the "Tragedy of the Commons" of the evolution of cooperation remains one of the greatest problems for both biology and social science.Asymmetrical interaction,which is one of the most important ch... Explaining the "Tragedy of the Commons" of the evolution of cooperation remains one of the greatest problems for both biology and social science.Asymmetrical interaction,which is one of the most important characteristics of cooperative systems,has not been sufficiently considered in the existing models of the evolution of cooperation.Considering the inequality in the number and payoff between the cooperative actors and recipients in cooperation systems,discriminative density-dependent interference competition will occur in limited dispersal systems.Our model and simulation show that the local but not the global stability of a cooperative interaction can be maintained if the utilization of common resource remains unsaturated,which can be achieved by density-dependent restraint or competition among the cooperative actors.More intense density dependent interference competition among the cooperative actors and the ready availability of the common resource,with a higher intrinsic contribution ratio of a cooperative actor to the recipient,will increase the probability of cooperation.The cooperation between the recipient and the cooperative actors can be transformed into conflict and,it oscillates chaotically with variations of the affecting factors under different environmental or ecological conditions.The higher initial relatedness(i.e.similar to kin or reciprocity relatedness),which is equivalent to intrinsic contribution ratio of a cooperative actor to the recipient,can be selected for by penalizing less cooperative or cheating actors but rewarding cooperative individuals in asymmetric systems.The initial relatedness is a pivot but not the aim of evolution of cooperation.This explains well the direct conflict observed in almost all cooperative systems. 展开更多
关键词 cooperation ALTRUISM density dependent TRAGEDY of the COMMONS OSCILLATION CHAOS asymmetric interaction interference COMPETITION
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Zone inhomogeneity with the random asymmetric simple exclusion process in a one-lane system 被引量:4
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作者 肖松 蔡九菊 刘飞 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第11期4613-4621,共9页
In this paper we use theoretical analysis and extensive simulations to study zone inhomogeneity with the random asymmetric simple exclusion process (ASEP). In the inhomogeneous zone, the hopping probability is less ... In this paper we use theoretical analysis and extensive simulations to study zone inhomogeneity with the random asymmetric simple exclusion process (ASEP). In the inhomogeneous zone, the hopping probability is less than 1. Two typical lattice geometries are investigated here. In case A, the lattice includes two equal segments. The hopping probability in the left segment is equal to 1, and in the right segment it is equal to p, which is less than 1. In case B, there are three equal segments in the system; the hopping probabilities in the left and right segments are equal to 1, and in the middle segment it is equal to p, which is less than 1. Through theoretical analysis, we can discover the effect on these systems when p is changed. 展开更多
关键词 zoned inhomogeneity asymmetric simple exclusion process one-lane system computer simulation
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