Monte Carlo simulation of asymmetrical growth of cube-shaped nanoparticles

We simulated the asymmetrical growth of cube-shaped nanoparticles by applying the Monte Carlo method.The influence of the specific mechanisms on the crystal growth of nanoparticles has been phenomenologically described by efficient growth possibilities along different directions（or crystal faces）.The roles of the thermodynamic and kinetic factors have been evaluated in three phenomenological models.The simulation results would benefit the understanding about the cause and manner of the asymmetrical growth of nanoparticles.

Progresses and Prospects of Asymmetrically Coordinated Single Atom Catalysts for Lithium-Sulfur Batteries

Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides(LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.Accordingly,the introduction of catalysts into LSBs is one of the effective strategy to solve the issues of the sluggished LiPS conversion.Because of their nearly 100%atom utilization and high electrocatalytic activity,single-atom catalysts(SACs)have been widely used as reaction mediators for LSBs’reactions.Excitingly,the SACs with asymmetric coordination structures have exhibited intriguing electronic structures and superior catalytic activities when compared to the traditional M-N_(4)active sites.In this review,we systematically describe the recent advancements in the installation of asymmetrically coordinated single-atom structure as reactions catalysts in LSBs,including asymmetrically nitrogen coordinated SACs,heteroatom coordinated SACs,support effective asymmetrically coordinated SACs,and bimetallic coordinated SACs.Particularly noteworthy is the discussion of the catalytic conversion mechanism of LiPSs spanning asymmetrically coordinated SACs.Finally,a perspective on the future developments of asymmetrically coordinated SACs in LSB applications is provided.

Bose–Einstein distribution temperature features of quasiparticles around magnetopolaron in Gaussian quantum wells of alkali halogen ions

We have applied strong coupling unitary transformation method combined with Bose–Einstein statistical law to investigate magnetopolaron energy level temperature effects in halogen ion crystal quantum wells.The obtained results showed that under magnetic field effect,magnetopolaron quasiparticle was formed through the interaction of electrons and surrounding phonons.At the same time,magnetopolaron was influenced by phonon temperature statistical law and important energy level shifts down and binding energy increases.This revealed that lattice temperature and magnetic field could easily affect magnetopolaron and the above results could play key roles in exploring thermoelectric conversion and conductivity of crystal materials.

Model-free Speed Control of Single-phase Flux Switching Motor with an Asymmetrical Rotor

This paper proposes and implements a model-free open-loop iterative learning control(ILC)strategy to realize the speed control of the single-phase flux switching motor(FSM)with an asymmetrical rotor.Base on the proposed winding control method,the asymmetrical rotor enables the motor to generate continuous positive torque for positive rotation,and relatively small resistance torque for negative rotation.An initial iteration coefficient and variable iteration coefficient optimized scheme was proposed based on the characteristics of the hardware circuit,thereby forming the model-free strategy.A series of prototype experiments was carried out.Experimental results verify the effectiveness and practicability of the proposed ILC strategy.

Numerical Exploration of Asymmetrical Impact Dynamics: Unveiling Nonlinearities in Collision Problems and Resilience of Reinforced Concrete Structures

This study provides a comprehensive analysis of collision and impact problems’ numerical solutions, focusing ongeometric, contact, and material nonlinearities, all essential in solving large deformation problems during a collision.The initial discussion revolves around the stress and strain of large deformation during a collision, followedby explanations of the fundamental finite element solution method for addressing such issues. The hourglassmode’s control methods, such as single-point reduced integration and contact-collision algorithms are detailedand implemented within the finite element framework. The paper further investigates the dynamic responseand failure modes of Reinforced Concrete (RC) members under asymmetrical impact using a 3D discrete modelin ABAQUS that treats steel bars and concrete connections as bond slips. The model’s validity was confirmedthrough comparisons with the node-sharing algorithm and system energy relations. Experimental parameterswere varied, including the rigid hammer’s mass and initial velocity, concrete strength, and longitudinal and stirrupreinforcement ratios. Findings indicated that increased hammer mass and velocity escalated RC member damage,while increased reinforcement ratios improved impact resistance. Contrarily, increased concrete strength did notsignificantly reduce lateral displacement when considering strain rate effects. The study also explores materialnonlinearity, examining different materials’ responses to collision-induced forces and stresses, demonstratedthrough an elastic rod impact case study. The paper proposes a damage criterion based on the residual axialload-bearing capacity for assessing damage under the asymmetrical impact, showing a correlation betweendamage degree hammer mass and initial velocity. The results, validated through comparison with theoreticaland analytical solutions, verify the ABAQUS program’s accuracy and reliability in analyzing impact problems,offering valuable insights into collision and impact problems’ nonlinearities and practical strategies for enhancingRC structures’ resilience under dynamic stress.

Interfacial microstructure evolution for coordinated deformation of Mg/Al composite plates by asymmetrical rolling with differential temperature rolls

In this work,Mg/Al composite plates with different thickness ratios were prepared by the asymmetrical rolling process with differential temperature rolls and isothermal symmetrical rolling.Microstructural evolution and mechanical properties of matrix and composite materials with different thicknesses were analyzed.Influence of thickness ratios on the coordinated deformability of heterogeneous metals and interface toughness under the action of temperature gradient and shear force was investigated.Results show that the relative deformation rates of matrix and composite materials converge gradually under the influence of work hardening of Mg/Al layer.The Mg layer is mainly DRXed grains and texture intensity gradually weakens with increasing thickness ratio.The Al layer is mostly dominated by subgrains and deformed grains,which have a strong correlation with thickness ratio.Strength and plasticity of composites first increase and then decrease with increasing thickness ratio.Fracture of composite plate occurs in intermetallic compounds(IMCs).Thickness of IMCs has a strong positive correlation with thickness ratio.When the thickness ratio of AZ31B/Al6061 for 5,the relative thickness of IMCs is the largest and the relative bonding strength is the smallest.When the thickness ratio of AZ31B/Al6061 for 3,there is no element aggregation in IMCs,and the comprehensive mechanical properties of composite plate are comparatively better.

Comparative Study of the Reliability and Complexity of Symmetrical and Asymmetrical Cryptosystems for the Protection of Academic Data in the Democratic Republic of Congo

In the digital age, the data exchanged within a company is a wealth of knowledge. The survival, growth and influence of a company in the short, medium and long term depend on it. Indeed, it is the lifeblood of any modern company. A companys operational and historical data contains strategic and operational knowledge of ever-increasing added value. The emergence of a new paradigm: big data. Today, the value of the data scattered throughout this mother of knowledge is calculated in billions of dollars, depending on its size, scope and area of intervention. With the rise of computer networks and distributed systems, the threats to these sensitive resources have steadily increased, jeopardizing the existence of the company itself by drying up production and losing the interest of customers and suppliers. These threats range from sabotage to bankruptcy. For several decades now, most companies have been using encryption algorithms to protect and secure their information systems against the threats and dangers posed by the inherent vulnerabilities of their infrastructure and the current economic climate. This vulnerability requires companies to make the right choice of algorithms to implement in their management systems. For this reason, the present work aims to carry out a comparative study of the reliability and effectiveness of symmetrical and asymmetrical cryptosystems, in order to identify one or more suitable for securing academic data in the DRC. The analysis of the robustness of commonly used symmetric and asymmetric cryptosystems will be the subject of simulations in this article.

Formation mechanism and organizational controlling of ultra-fine-grain copper processed by asymmetrical accumulative rolling-bond and annealing

The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond （AARB） and annealing, the ultra-fine-grained （UFG） copper with grain size of 200 nm was obtained, and the microstructures and properties were studied. The results show that there are large sub-structures and also texture component C for the UFG copper obtained by six passes AARB, possessing high strength and microhardness in company with poor elongation and conductivity. Thereafter, the UFG copper was annealed at 220 °C for 35 min, in which the sub-structures disappear, the grain boundaries are composed of big angle grain boundaries, and the textures are composed of a variety of texture components and parts of twins. Compared with the UFG copper obtained by six passes AARB, the tensile strength and yield strength for the UFG copper obtained by six passes AARB and annealing at 220 °C for 35 min are decreased slightly, the elongation and conductivity are improved obviously.

Influence of symmetric and asymmetric rolling on texture evolution of work-hardened AA 5xxx aluminium alloy

The textures and microstructures of hot-and cold-rolled sheets of an AA 5454 aluminium alloy were studied,with special attention paid to comparing the texture development for the symmetric and asymmetric cold rolling.Scanning electron microscopy with electron-backscatter diffraction was used to monitor the development of the microstructure in the differently deformed and additionally annealed samples.Details of the formations and transformations of individual texture components occurring during the rolling processes were observed and discussed.The average grain sizes,textures and mechanical properties were correlated and explained for the symmetric and asymmetric cold-rolled samples.The asymmetric rolling is beneficial in terms of deep drawability because it reduces the planar anisotropy of the annealed material due to the decrease of the Cube,Goss,rotated-Cube and η-fibre texture components and at the same time strengthens X1-and X2-fibre texture components which are shear texture components and improve deep drawability.During the asymmetric cold rolling,the temperature increases due to friction,triggering recrystallisation processes and leading to larger grains.It is also confirmed that asymmetric cold rolling uses less rolling force and consequently less energy to produce a final material with better formability,particularly earing.

Chiral inorganic nanocatalysts for electrochemical and enzyme⁃mimicked biosensing

In recent years,chiral inorganic nanomaterials have become promising candidates for applications in sensing,catalysis,biomedicine,and photonics.Plasmonic nanomaterials with an intrinsic chiral structure exhibit intriguing geometry‑dependent optical chirality,which benefits the combination of plasmonic characteristics with chirality.Recent advances in the biomolecule‑directed geometric control of intrinsically chiral plasmonic nanomaterials have further provided great opportunities for their widespread applications in many emerging technological areas.In this review,we present the recent progress in biosensing using chiral inorganic nanomaterials,with a particular focus on electrochemical and enzyme‑mimicking catalytic approaches.This paper commences with a review of the basic tenets underlying chiral nanocatalysts,incorporating the chiral ligand‑induced mechanism and the architectures of intrinsically chiral nanostructures.Additionally,it methodically expounds upon the applications of chiral nanocatalysts in the realms of electrochemical biosensing and enzyme‑mimicking catalytic biosensing respectively.Conclusively,it proffers a prospective view of the hurdles and prospects that accompany the deployment of chiral nanoprobes for nascent biosensing applications.By rational design of the chiral nanoprobes,it is envisioned that biosensing with increasing sensitivity and resolution toward the single‑molecule level can be achieved,which will substantially promote sensing applications in many emerging interdisciplinary areas.

Multiple Plasmonic Resonances and Cascade Effect in Asymmetrical Ag Nanowire Homotrimer

Plasmonic Ag nanowire homotrimer with asymmetrical radii and separations, which exhibits characteristics of multiple plamonic resonances and different electric field distributions, is systematically investigated by means of 2D finite element method. It was found that the dark and bright modes appear in asymmetrical nanowire homotrimer. In addition, when the dark modes appear between the smaller radii of the nanowires, the cascade effect results in enhanced electric field between the smaller radii nanowires. As a result of the appearance of the bright modes between the smaller radii of the nanowires, the restriction of the cascade effect generates enhanced electric field between the bigger nanowires.

Stability analyses of the mass abrasive projectile high-speed penetrating into concrete target. Part Ⅱ: Structural stability analyses

The initial oblique and attacking angles as well as the asymmetrical nose abrasion may lead to bending or even fracture of a projectile,and the penetration efficiency decreases distinctly.The structural stability of a high-speed projectile non-normally penetrating into concrete and the parametric influences involved are analyzed with the mass abrasion taken into account.By considering the symmetrical or asymmetrical nose abrasion as well as the initial oblique and attacking angles,both the axial and the transverse drag forces acting on the projectile are derived.Based on the ideal elastic-plastic yield criterion,an approach is proposed for predicting the limit striking velocity（LSV）that is the highest velocity at which no yielding failure has occurred and the projectile can still maintain its integral structural stability.Furthermore,some particular penetration scenarios are separately discussed in detail.Based on the engineering model for the mass loss and nose-blunting of ogive-nose projectiles established in Part I of this study,the above approach is validated by several high-speed penetration tests.The analysis on parametric influences indicates that the LSV is reduced with an increase in the asymmetrical nose abrasion,thelength-diameter-ratio,and the concrete strength,as well as the oblique and attacking angles.Also,the LSV raises with an increase in the initial caliber-radius-head（CRH）and the dimensionless cartridge thickness of a projectile.

SEMI-ACTIVE CONTROL OF VEHICLE SUSPENSION WITH MAGNETO-RHEOLOGICAL DAMPERS PARTⅡ——EVALUATION OF SUSPENSION PERFORMANCE

The design and analysis of an intelligent vehicle suspension with MR dampers should address hybrid semi-active control goals, such as rejection of current-switching discontinuity and MR-damper hysteresis, asymmetric damping from the symmetric MR-damper design, robustness on the vehicle operation parameter uncertainties and consideration of essential multiple suspension goals. Following the proposed skyhook-based asymmetric semi-active controller （Part I ） for achieving the above goals, herein, a set of suspension performance measures and three kinds of varying amplitude harmonic, rounded pulse and really measured random excitations are systematically defined, and the sensitivity of quarter-vehicle MR-suspension performance to variations in operating conditions is thoroughly analyzed. The results illustrate that the proposed skyhook-based semi-active MR-suspension in the asymmetric mode yields relatively superior dynamic responses to meet the multiple suspension performances of ride, rattle space, road-holding and dynamic tire force transmitted to the pavement, and has desirable robustness on variations in operating conditions of vehicle load and speed and the road roughness.

Asymmetrical traumatic bilateral hip dislocations with hemodynamic instability and an unstable pelvic ring: Case report and review of literature

Simultaneous anterior and posterior traumatic dislocations of both hips are very rare. Only 33 cases have been previously reported in the English language literature. Although they were all due to high-energy injuries, they were hemodynamically stable and had a stable pelvic ring. We report a unique case of asymmetrical hip dislocations with an unstable pelvic ring and hemodynamic instability. A 40-year-old man was injured in a high-energy motor vehicle accident. He was hemodynamically unstable when he presented in the emergency department. Radiolographs showed asymmetrical dislocations of both hips with an unstable pelvic ring. Under general anesthesia, he had closed reduction of the dislocations of both hips, followed by temporary stabilization with an external fixator. Transcatheter arterial embolization was performed to stop active pelvic bleeding. Delayed open reduction and internal fixation was performed 12 d later with anterior and posterior plates. The patient recovered well with an uneventful post-operative course. Asymmetrical bilateral hip dislocations with pelvic ring instability caused by trauma, as presented in this case, is very rare and potentially life threatening. Prompt treatment can give a good outcome.

Recrystallized microstructural evolution of UFG copper prepared by asymmetrical accumulative rolling-bonding process

Copper sheet with grain size of 30-60μm was processed by plastic deformation of asymmetrical accumulative rolling-bonding(AARB)with the strain of 3.2.The effects of annealing temperature and time on microstructural evolution were studied by means of electron backscattered diffraction(EBSD).EBSD grain mapping,recrystallization pole figure and grain boundary misorientation angle distribution graph were constructed,and the characteristics were assessed by microstructure,grain size,grain boundary misorientation and texture.The results show that ultra fine grains(UFG)are obtained after annealing at 250℃ for 30?40 min.When the annealing is controlled at 250℃for 40 min,the recrystallization is finished,a large number of small grains appear and most grain boundaries consist of low-angle boundaries.The character of texture is rolling texture after the recrystallization treatment,but the strength of the texture is faint.While second recrystallization happens,{110}<1ī2>+{112}<11ī> texture component disappears and turns into{122}<212>cube twin texture component.

Automatic Scallion Seedling Feeding Mechanism with an Asymmetrical High-order Transmission Gear Train

The current automatic scallion-transplanting machine is a complicated mechanism composed of two linkage mechanisms and two band carriers.It delivers seedlings ine ciently because of the movement limitations of the linkage mechanism.This paper proposes a new high-order non-circular gear train for an automatic scallion-seedling feeding mechanism.The proposed gear train has an asymmetrical transmission ratio;i.e.,its transmission ratio varies.This allows the mechanism’s execution component to move in a long displacement and rotate in a large rotation angle.The long displacement enables the execution component to reach the designed working position,and the large rotation angle allows it to feed a scallion in the required pose.A mathematical model for calculating the asymmetrical transmission ratio was established according to the closure requirements and the full-cycle motion of the driven gear pitch curve.Then,the parameter-design model of the new seedling-feeding mechanism was established,based on precise pose points and trajectory-shape control points.Moreover,an aided-design program was developed to obtain the parameter-solution domain of the scallion-seedling feeding mechanism.The mechanism parameters,which met the seedling-feeding function,were optimized to determine the transmission ratio,using a program and a kinematic simulation.Finally,a prototype of the mechanism was produced,and a seedling-feeding experiment was carried out.One-thousand seedlings were tested at a rate of 100 seedlings per minute,and the statistical success rate was 93.4%.Thus,the automatic scallion-seedling feeding mechanism significantly improves the e ciency of automatically transplanting scallions.

Average Cycle Period in Asymmetrical Flashing Ratchet

The directed motion of a Brownian particle in a Bashing potential with various transition probabilities and waiting times in one of two states is studied. An expression for the average cycle period is proposed and the steady current J of the particle is calculated via Langevin simulation. The results show that the optimal cycle period (Tm), which takes the maximum of J, is shifted to a small value when the transition probability A from the potential on to the potential off decreases, the maximal current appears in the case of the average waiting time in the potential on being longer than in the potential off, and the direction of current depends on the ratio of the average times waiting in two states.

ASYMMETRICAL STRUCTURES OF THE TEMPERATURE AND HUMIDITY OF TROPICAL CYCLONES

Based on NCEP/CFSR 0.5° reanalysis data and the best track data from the Japan Tokyo Typhoon Center,composite and comparative analyses demonstrate the asymmetrical structures of the temperature and humidity in tropical cyclones over the Western North Pacific and the South China Sea from 1979 to 2010.The results are shown as follows.(1) With intensifying tropical cyclones,the flow field tends to become gradually more axisymmetric;however,the asymmetry of the specific humidity in the outer regions is more obvious.(2) In general,tropical cyclones have a non-uniform,vertical, "double warm-core" structure.The "warm-cores" in the lower level of weak tropical cyclones and in the higher level of strong tropical cyclones are the stronger of the two.(3) The distribution area of a "warm-core" is enhanced with cyclone intensification and tends to become more axisymmetric.At 200 hPa,the "warm-core" of a weak cyclone has a weak anticyclone in the center,whereas that of a strong cyclone has a weak cyclone in the center.(4)The "wet-core" of a tropical cyclone is primarily located in the lower level(700-850 hPa).With the cyclone's intensification,the intensity of the "wet-core" increases and the scope of the 0.8 g kg^(-1) specific humidity anomaly tends to expand to higher levels.(5) With the cyclone's deepening,the pseudo-equivalent potential temperature at different levels in different regions increases.In addition,the largest warming rates at each intensity level in the different regions occur in the core area,followed in turn by the envelope and outer areas.

Asymmetrical Quantum Encryption Protocol Based on Quantum Search Algorithm

Quantum cryptography and quantum search algorithm are considered as two important research topics in quantum information science.An asymmetrical quantum encryption protocol based on the properties of quantum one-way function and quantum search algorithm is proposed.Depending on the no-cloning theorem and trapdoor one-way functions of the publickey,the eavesdropper cannot extract any private-information from the public-keys and the ciphertext.Introducing key-generation randomized logarithm to improve security of our proposed protocol,i.e.,one privatekey corresponds to an exponential number of public-keys.Using unitary operations and the single photon measurement,secret messages can be directly sent from the sender to the receiver.The security of the proposed protocol is proved that it is informationtheoretically secure.Furthermore,compared the symmetrical Quantum key distribution,the proposed protocol is not only efficient to reduce additional communication,but also easier to carry out in practice,because no entangled photons and complex operations are required.

Analytic Solution of an Asymmetrical Crack in a Strip

We present the analytic solution of an asymmetrical crack in a strip from which the stress intensity factors are determined.The results have important application in earthquake source physics and provide information concerning the instability of faults and the detection of earthquake precursors.