Evaluation of Atmosphere–Land Interactions in an LES from the Perspective of Heterogeneity Propagation

Atmosphere–land interactions simulated by an LES model are evaluated from the perspective of heterogeneity propagation by comparison with airborne measurements. It is found that the footprints of surface heterogeneity, though as 2D patterns can be dissipated quickly due to turbulent mixing, as 1D projections can persist and propagate to the top of the atmospheric boundary layer. Direct comparison and length scale analysis show that the simulated heterogeneity patterns are comparable to the observation. The results highlight the model＇s capability in simulating the complex effects of surface heterogeneity on atmosphere–land interactions.

Role of land-atmosphere coupling in persistent extreme climate events in eastern China in summer 2022

2022年暖季,中国东部地区遭受持续性高温,少雨和土壤干旱的复合极端事件.特征分析指出,在研究时段内,中国东部地区的气温,降水和土壤湿度呈现明显的季节内变化和南北差异。由1940-2022年的气候态可知,长江流域和东南地区的土壤含水充足,蒸散主要受限于陆面有效能量.然而,潜在机制研究指出,2022年土壤湿度对蒸散的限制作用在上述区域异常偏强,土壤湿度与气候要素之间的强反馈可能在2022年复合极端事件的演变和持续中发挥了关键作用。

A comparative study of the land-atmosphere energy and water exchanges over the Tibetan Plateau and the Yangtze River Region

正确认识不同区域能量和水分循环特征是研究局地地气相互作用及准确预测区域天气,气候变化的关键.为了研究属于干旱/半干旱气候的青藏高原(TP)和湿润/半湿润气候的长江流域(YRR)之间地表能量和水分交换的异同,本文对比分析了两个区域8个不同地表类型(包括高山荒漠,高山草地,(平原)城市和(平原)草地等)观测站点的地表辐射和能量通量数据.结果显示:(1)TP由于高原大气层稀薄且空气洁净,年平均入射短波辐射为251.3W m^(-2),是YRR的1.7倍.加之高原地表反照率高导致反射辐射(59.6 W m^(-2))是YRR的2.87倍.入射及出射的长波辐射为231.5和338.0 W m^(-2),分别为YRR的0.64和0.83.而两个区域的净辐射差异不大;(2)草地站更多的潜热释放使得地表总加热效率高于城市和高山荒漠,TP和YRR的草地站的年平均潜热分别为35.0和38.8 W m^(-2),而植被稀疏且土壤干燥的高山荒漠地区感热最大,年平均感热为42.1 W m^(-2);其次是城市下垫面,其年平均感热为37.7 W m^(-2).研究结果揭示了不同气候背景下典型下垫面地气相互作用特征,为地气相互作用过程深入分析奠定了基础.

Using a Modified Soil-Plant-Atmosphere Scheme(MSPAS)to Simulate the Interaction between Land Surface Processes and Atmospheric Boundary Layer in Semi-Arid Regions

This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.

Seeing through the magnetite:Reassessing Eoarchean atmosphere composition from Isua(Greenland) ≥3.7 Ga banded iron formations

Estimates of early atmosphere compositions from metamorphosed banded iron formations(BIFs)including the well-studied ≥3.7 BIFs of the Isua supracrustal belt(Greenland)are dependent on knowledge of primary versus secondary Fe-mineralogical assemblages.Using new observations from locally well preserved domains,we interpret that a previously assumed primary redox indicator mineral,magnetite,is secondary after sedimentary Fe-clays(probably greenalite)±carbonates.Within ~3.7 Ga Isua BIF,pre-tectonic nodules of quartz+Fe-rich amphibole±calcite reside in a finegrained(≤100 μm)quartz+magnetite matrix.We interpret the Isua nodule amphibole as the metamorphosed equivalent of primary Fe-rich clays,armoured from diagenetic oxidative reactions by early silica concretion.Additionally,in another low strain lacunae,~3.76 Ga BIF layering is not solid magnetite but instead fine-grained magnetite+quartz aggregates.These magnetite+quartz aggregates are interpreted as the metamorphosed equivalent of Fe-clay-rich layers that were oxidised during diagenesis,because they were not armoured by early silicification.In almost all Isua BIF exposures,this evidence has been destroyed by strong ductile deformation.The Fe-clays likely formed by abiotic reactions between aqueous Fe^(2+)and silica.These clays along with silica±carbonate were deposited below an oceanic Fe-chemocline as the sedimentary precursors of BIF.Breakdown of the clays on the sea floor may have been by anaerobic oxidation of Fe^(2+),a mechanism compatible with iron isotopic data previously published on these rocks.The new determinations of the primary redoxsensitive Fe-mineralogy of BIF significantly revise estimates of early Earth atmospheric oxygen and CO_2 content,with formation of protolith Fe-rich clays and carbonates compatible with an anoxic Eoarchean atmosphere with much higher CO_2 levels than previously estimated for Isua and in the present-day atmosphere.

Corrosion behavior of copper in extremely harsh marine atmosphere in Nansha Islands,China

The corrosion behavior of pure copper exposed to the atmosphere of Nansha Islands for 21 months was studied by mass loss method,composition analysis,morphology observation and electrochemical measurements.The results showed that the average corrosion rate of copper exposed for one year was approximately 7.85μm/a,implying that Nansha Islands was classified as a corrosion category of CX.The structure and properties of the corrosion product layer generated on the front and back sides of the exposed sample differed significantly.The inner corrosion product layer(Cu2O)on the front side was relatively thick and dense,whereas the outer product layer(Cu2Cl(OH)3)was extremely thin.However,the outer product layer on the back side was thicker than the inner layer.Electrochemical measurements indicated that the protection afforded by the corrosion product layer on the front side was improved gradually,while that on the back side was deteriorated.

Corrosion and pitting behavior of pure aluminum 1060 exposed to Nansha Islands tropical marine atmosphere

The corrosion and pitting behavior of pure aluminum 1060 exposed to Nansha Islands marine atmosphere for 34 months was investigated based on mass loss measurement,scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),X-ray photoelectron spectroscopy(XPS),and electrochemical impedance spectroscopy(EIS).The results indicated that serious pitting corrosion occurred on the surfaces of pure aluminum.The corrosion rate after exposure for 13 months was approximately 1.28 g/(m^(2)·a).The XPS results showed that the corrosion products were Al_(2)O_(3),Al(OH)_(3),and AlCl_(3).Moreover,the corrosion product layer was more protective than the native oxide film,and the protectiveness first increased and then decreased.Finally,the shape of the pits was evaluated using statistical analysis.

Regional Features and Seasonality of Land–Atmosphere Coupling over Eastern China

Land-atmosphere coupling is a key process of the climate system, and various coupling mechanisms have been proposed before based on observational and numerical analyses. The impact of soil moisture（SM） on evapotranspiration（ET） and further surface temperature（ST） is an important aspect of such coupling. Using ERA-Interim data and CLM4.0 offline simulation results, this study further explores the relationships between SM/ST and ET to better understand the complex nature of the land-atmosphere coupling（i.e., spatial and seasonal variations） in eastern China, a typical monsoon area. It is found that two diagnostics of land-atmosphere coupling（i.e., SM-ET correlation and ST-ET correlation） are highly dependent on the climatology of SM and ST. By combining the SM-ET and ST-ET relationships, two ＂hot spots＂ of land-atmosphere coupling over eastern China are identified： Southwest China and North China. In Southwest China, ST is relatively high throughout the year, but SM is lowest in spring, resulting in a strong coupling in spring. However, in North China, SM is relatively low throughout the year, but ST is highest in summer, which leads to the strongest coupling in summer. Our results emphasize the dependence of land-atmosphere coupling on the seasonal evolution of climatic conditions and have implications for future studies related to land surface feedbacks.

Characteristics Variation of Atmospheric CO_(2)and CH_(4)in Yongxing Island,South China Sea

Using the observation data in Yongxing Island,South China Sea(SCS)from December 2013 to November 2018,the multiple time scales variation of atmospheric CO_(2)and CH_(4)were analyzed to understand their temporal variation characteristics and controlling factors.The regional-averaged background mole fractions of CO_(2)and CH_(4)both show a single-period sinusoidal variation with a lower value at noon and a higher value in the wee hours.In the seasonal scale,they exhibited a significant seasonal difference with higher values in winter and lower values in summer.In the annual scale,CO_(2)and CH_(4)both show an increasing trend,with an annual growth rate of approximately 3.2 ppm and 12 ppb,respectively.The annual growth rate at this site was higher than the global average.The change in atmospheric CO_(2)and CH_(4)in Yongxing Island was probably caused by the higher emission of the surrounding areas and the airflows driven by monsoon.Hopefully,the long-term and high-resolution greenhouse gases(GHGs)dataset will aid relevent researchers and decision-makers in performing more in-depth studies for GHG sources in order to derive effective strategies.

An Updated Coupled Model for Land-Atmosphere Interaction.Part I:Simulations of Physical Processes

A new two-way land-atmosphere interaction model （R42_AVIM） is fulfilled by coupling the spectral atmospheric model （SAMIL_R42L9） developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences （LASG/IAP/CAS） with the land surface model, Atmosphere-Vegetation-Interaction-Model （AVIM）. In this coupled model, physical and biological components of AVIM are both included. Climate base state and land surface physical fluxes simulated by R42_AVIM are analyzed and compared with the results of R42_SSIB [which is coupled by SAMIL_R42L9 and Simplified Simple Biosphere （SSIB） models]. The results show the performance of the new model is closer to the observations. It can basically guarantee that the land surface energy budget is balanced, and can simulate June-July-August （JJA） and December-January- February （DJF） land surface air temperature, sensible heat flux, latent heat flux, precipitation, sea level pressure and other variables reasonably well. Compared with R42_SSIB, there are obvious improvements in the JJA simulations of surface air temperature and surface fluxes. Thus, this land-atmosphere coupled model will offer a good experiment platform for land-atmosphere interaction research.

Simulating the Escaping Atmosphere of GJ 436 b with Two-fluid Magnetohydrodynamic Models

Observations of transmission spectra reveal that hot Jupiters and Neptunes are likely to possess escaping atmospheres driven by stellar radiation.Numerous models predict that magnetic fields may exert significant influences on the atmospheres of hot planets.Generally,the escaping atmospheres are not entirely ionized,and magnetic fields only directly affect the escape of ionized components within them.Considering the chemical reactions between ionized components and neutral atoms,as well as collision processes,magnetic fields indirectly impact the escape of neutral atoms,thereby influencing the detection signals of planetary atmospheres in transmission spectra.In order to simulate this process,we developed a magnetohydrodynamic multi-fluid model based on MHD code PLUTO.As an initial exploration,we investigated the impact of magnetic fields on the decoupling of H^(+)and H in the escaping atmosphere of the hot Neptune GJ436b.Due to the strong resonant interactions between H and H^(+),the coupling between them is tight even if the magnetic field is strong.Of course,alternatively,our work also suggests that merging H and H^(+)into a single flow can be a reasonable assumption in MHD simulations of escaping atmospheres.However,our simulation results indicate that under the influence of magnetic fields,there are noticeable regional differences in the decoupling of H^(+)and H.With the increase of magnetic field strength,the degree of decoupling also increases.For heavier particles such as O,the decoupling between O and H^(+)is more pronounced.Our findings provide important insights for future studies on the decoupling processes of heavy atoms in the escaping atmospheres of hot Jupiters and hot Neptunes under the influence of magnetic fields.

Impact of Exercise Atmosphere on Adolescents’Exercise Behavior:Chain Mediating Effect of Exercise Identity and Exercise Habit

Appropriate physical exercise has a positive impact on adolescents’physical and mental health,but there is a serious lack of physical exercise among Chinese adolescents.How to shape their exercise behavior(EB)has become an important task in promoting their development.A questionnaire survey was conducted using stratified cluster random sampling on three middle schools by class in Zhejiang Province,China to investigate the impact of exercise atmosphere(EA)on adolescents’exercise behavior and the mediating role of exercise identity(EI)and exercise habit(EH).806 adolescents were investigated by the Exercise Atmosphere Scale(EAS),Exercise-Identity Scale(EIS),Self-Report Habit Index(SRHI),and Physical Activity Rating Scale(PARS-3).The results show that:There is a significant positive correlation between each two of exercise atmosphere,exercise identity,exercise habit,and exercise behavior(p<0.05).Exercise atmosphere could not only directly affect adolescents’physical exercise behavior but can also indirectly affect their physical exercise behavior through the mediating effect of exercise identity and exercise habit,involving three mediating pathways,namely,the mediating path through exercise identity,the mediating pathway through exercise habit and the chain mediating pathway through exercise identity and exercise habit.The direct effect of exercise atmosphere on exercise behavior was 0.459(p<0.01),accounting for 62.62% of the total effect of 0.733,and its indirect effect was 0.274,accounting for 37.28% of the total effect.To a certain extent,the mediating effect model reveals the mechanism of exercise atmosphere affecting exercise behavior and has a certain reference value for promoting adolescents’exercise behavior.We should start by creating an exercise atmosphere,cultivating exercise identity,and enhancing exercise habits to help teenagers form active physical exercise behaviors.

Study of the reaction mechanism for preparing powdered activated coke with SO_(2)adsorption capability via one-step rapid activation method under flue gas atmosphere

In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is summarized.Results indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this stage.This stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of particles.This stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as material.Besides,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third stage.Mastering the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.

Investigating the Creation of Cultural Atmospheres in Physical Bookstores Within the Context of Scene-Based Consumption:A Perspective Based on the Ways of Seeing

In an era of scene-based consumption,the essence of operating a bookstore lies in accepting and enabling the bookstore to play its role as a cultural medium for browsing and appreciating books,which in turn fosters the development of a distinctive bookstore culture.This new type of consumption context has led to an evolution in the book-reading culture in physical bookstores that is characterized by a shift from a paradigm of passive reading to one where the emphasis is on interactive viewing.This transition has laid the foundation for the creation of cultural atmospheres in bookstores,and it highlights the visual interactions that now exist between readers and books as well as with other related cultural industries.The dominant and fundamental logic behind this process is symbiosis,experience,aesthetics,immersion,and creativity.However,when a form of culture that focuses on consumption-oriented browsing begins to overshadow knowledge acquisition during the process of book reading,the cultural essence of bookstores is likely to be diminished.Therefore,the cultural essence within the scene-based consumption context should be enhanced by creating innovative viewing activities that showcase the cultural and emotional implications inherent in the scene itself,and thus help to align the identity of the bookstore with its in-situ cultural space.

Analysis of quality-related proteins in golden pompano(Trachinotus ovatus)fillets with modified atmosphere packaging under superchilling storage

Here,we aimed to study the changes in proteome of golden pompano fillets during post-mortem storage.Tandem mass tags(TMT)-labeled quantitative proteomic strategy was applied to investigate the relationships between protein changes and quality characteristics of modified atmosphere packaging(MAP)fillets during superchilling(-3°C)storage.Scanning electron microscopy was used to show that the muscle histology microstructure of fillets was damaged to varying degrees,and low-field nuclear magnetic resonance was used to find that the immobilized water and free water in the muscle of fillets changed significantly.Total sulfhydryl content,TCA-soluble peptides and Ca2+-ATPase activity also showed that the fillet protein had a deterioration by oxidation and denaturation.The Fresh(FS),MAP,and air packaging(AP)groups were set.Total of 150 proteins were identified as differential abundant proteins(DAPs)in MAP/FS,while 209 DAPs were in AP/FS group.The KEGG pathway analysis indicated that most DAPs were involved in binding proteins and protein turnover.Correlation analysis found that 52 DAPs were correlated with quality traits.Among them,8 highly correlated DAPs are expected to be used as potential quality markers for protein oxidation and water-holding capacity.These results provide a further understanding of the muscle deterioration mechanism of packaging golden pompano fillets during superchilling.

High temperature oxidation of inoculated high Si/SiMo ductile cast irons in air and combustion atmospheres

The present work aims to investigate the effect of heating temperature(400,600 and 800°C)and inoculating elements(Ca,Ca-Ba,Ca-RE)on oxidation behavior of ductile irons containing 5.25%Si and 4.8%Si-2.3%Mo in dry air and combustion gas containing water vapour(natural gas burning).The oxidation is influenced by the gas atmosphere type,the iron alloying system,and the inoculating elements depending on the heating temperature.The weight gain increases from 0.001%-0.1%(400°C)to 0.05%-0.70%(600°C)and up to 0.10%-2.15%(800°C).No particular effects of the considered influencing factors are found when heating at 400°C,while at 600°C,mainly the oxidation gas atmosphere type shows a visible influence.At the highest heating temperature of 800°C,a limited increase of the weight gain is found for dry air atmosphere(up to 0.25%),but it drastically increases for combustion atmospheres(0.65%-2.15%).The water vapour presence in the combustion atmosphere is an important oxidising factor at 600-800°C.The alloying system appears to influence the oxidation behavior mainly at a heating temperature of 800°C in the combustion atmosphere,as evidenced by the lower weight gain in 5.25%silicon cast iron.Positive effects of inoculating elements increase with the heating temperature,with Ca and Ba-FeSi inoculation generally showing better performance.Irons inoculated with CaRE-FeSi exhibit a higher degree of oxidation.These results are in good relationship with the previous reported data:Ca-Ba-inoculation system appears to be better than simple Ca for improving the graphite parameters,while RE-bearing inoculant negatively affects the compactness degree of graphite particles in high-Si ductile irons.As the lower compactness degree is typical for graphite nodules in high-Si ductile irons,which negatively affects the oxidation resistance,it is necessary to employ specific metallurgical treatments to improve nodule quality.Inoculation,in particular,is a potential method to achieve this improvement.

Land Response to Atmosphere at Different Resolutions in the Common Land Model over East Asia

Towards a better understanding of hydrological interactions between the land surface and atmosphere, land surface mod- els are routinely used to simulate hydro-meteorological fluxes. However, there is a lack of observations available for model forcing, to estimate the hydro-meteorological fluxes in East Asia. In this study, Common Land Model （CLM） was used in offline-mode during the summer monsoon period of 2006 in East Asia, with different forcings from Asiaflux, Korea Land Data Assimilation System （KLDAS）, and Global Land Data Assimilation System （GLDAS）, at point and regional scales, separately. The CLM results were compared with observations from Asiaflux sites. The estimated net radiation showed good agreement, with r = 0.99 for the point scale and 0.85 for the regional scale. The estimated sensible and latent heat fluxes using Asiaflux and KLDAS data indicated reasonable agreement, with r = 0.70. The estimated soil moisture and soil temperature showed similar patterns to observations, although the estimated water fluxes using KLDAS showed larger discrepancies than those of Asiaflux because of scale mismatch. The spatial distribution of hydro-meteorological fluxes according to KLDAS for East Asia were compared to the CLM results with GLDAS, and the GLDAS provided online. The spatial distributions of CLM with KLDAS were analogous to CLM with GLDAS, and the standalone GLDAS data. The results indicate that KLDAS is a good potential source of high spatial resolution forcing data. Therefore, the KLDAS is a promising alternative product, capable of compensating for the lack of observations and low resolution grid data for East Asia.

An Updated Coupled Model for Land-Atmosphere Interaction.Part II:Simulations of Biological Processes

In Part I, the authors succeeded in coupling the spectral atmospheric model （SAMIL_R42L9） developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences （LASG/IAP/CAS） with the land surface model, Atmosphere-Vegetation-Interaction-Model （AVIM） and analyzed the climate basic state and land surface physical fluxes simulated by R42_AVIM. In this Part Ⅱ, we further evaluate the simulated results of the biological processes, including leaf area index （LAI）, biomass and net primary productivity （NPP） etc. Results indicate that R42_AVIM can simulate the global distribution of LAI and has good consistency with the monthly mean LAI provided by Max Planck Institute for Meteorology. The simulated biomass corresponds reasonably to the vegetation classifications. In addition, the simulated annual mean NPP has a consistent distribution with the data provided by IGBP and MODIS, and compares well with the work in literature. This land-atmosphere coupled model will offer a new experiment tool for the research on the two-way interaction between climate and biosphere, and the global terrestrial ecosystem carbon cycle.

Using a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to Study the Sensitivity of Land Surface and Boundary Layer Processes to Soil and Vegetation Conditions

A series of sensitivity tests are performed to test the stability and sensibility of the Modified Soil-Plant-Atmosphere Scheme (MSPAS), which was wholly introduced in a previous paper. The numerical simulation results from the experiments show good agreement with physical reality. Besides, some of the results are illuminating. Together with the first paper, it is concluded that MSPAS is a simple but effective model, and it is practically valuable in the research work of desertification control and reforestation in China.

Assessing the corrosion protection property of coatings loaded with corrosion inhibitors using the real-time atmospheric corrosion monitoring technique

The atmospheric corrosion monitoring(ACM)technique has been widely employed to track the real-time corrosion behavior of metal materials.However,limited studies have applied ACM to the corrosion protection properties of organic coatings.This study compared a bare epoxy coating with one containing zinc phosphate corrosion inhibitors,both applied on ACM sensors,to observe their corrosion protection properties over time.Coatings with artificial damage via scratches were exposed to immersion and alternating dry and wet environments,which allowed for monitoring galvanic corrosion currents in real-time.Throughout the corrosion tests,the ACM currents of the zinc phosphate/epoxy coating were considerably lower than those of the blank epoxy coating.The trend in ACM current variations closely matched the results obtained from regular electrochemical tests and surface analysis.This alignment highlights the potential of the ACM technique in evaluating the corrosion protection capabilities of organic coatings.Compared with the blank epoxy coating,the zinc phosphate/epoxy coating showed much-decreased ACM current values that confirmed the effective inhibition of zinc phosphate against steel corrosion beneath the damaged coating.