The ^10Be/^7Be ratio is a sensitive tracer for the study of atmospheric transport, particularly with regard to stratosphere-troposphere exchange. Measurements with high accuracy and efficiency are crucial to ^7Be and ...The ^10Be/^7Be ratio is a sensitive tracer for the study of atmospheric transport, particularly with regard to stratosphere-troposphere exchange. Measurements with high accuracy and efficiency are crucial to ^7Be and ^10Be tracer studies. This article describes sample preparation procedures and analytical benchmarks for ^7Be and ^10Be measurements at the Xi＇an Accelerator Mass Spectrometry（Xi＇an-AMS） laboratory for the study of rainwater samples. We describe a sample preparation procedure to fabricate beryllium oxide（Be O） AMS targets that includes co-precipitation, anion exchange column separation and purification. We then provide details for the AMS measurement of ^7Be and ^10Be following the sequence BeO^-→Be^2＋→Be^4＋ in the Xi＇an- AMS. The ^10Be/^7Be ratio of rainwater collected in Xi＇an is shown to be about 1.3 at the time of rainfall. The virtue of the method described here is that both ^7Be and ^10Be are measured in the same sample, and it is suitable for routine analysis of large numbers of rainwater samples by AMS.展开更多
基金Supported by National Natural Science Foundation of China(11205161)CAS Key Technology Talent Program
文摘The ^10Be/^7Be ratio is a sensitive tracer for the study of atmospheric transport, particularly with regard to stratosphere-troposphere exchange. Measurements with high accuracy and efficiency are crucial to ^7Be and ^10Be tracer studies. This article describes sample preparation procedures and analytical benchmarks for ^7Be and ^10Be measurements at the Xi＇an Accelerator Mass Spectrometry（Xi＇an-AMS） laboratory for the study of rainwater samples. We describe a sample preparation procedure to fabricate beryllium oxide（Be O） AMS targets that includes co-precipitation, anion exchange column separation and purification. We then provide details for the AMS measurement of ^7Be and ^10Be following the sequence BeO^-→Be^2＋→Be^4＋ in the Xi＇an- AMS. The ^10Be/^7Be ratio of rainwater collected in Xi＇an is shown to be about 1.3 at the time of rainfall. The virtue of the method described here is that both ^7Be and ^10Be are measured in the same sample, and it is suitable for routine analysis of large numbers of rainwater samples by AMS.
