In order to understand the biological community characteristics of different surface treatments of ＇artificial reef templates ,which had been placed on the offshore, Yuanzhou island, Daya Bay. Sampling survey was tak...In order to understand the biological community characteristics of different surface treatments of ＇artificial reef templates ,which had been placed on the offshore, Yuanzhou island, Daya Bay. Sampling survey was taken in August of 2014. The results showed that 39 species of fouling organisms were collected and iden- tiffed, Ostrea nigromarginata has attached the absolute position of the dominant species ; Through the concrete block surface treatment has a better biofouling effect, and red brick, granite plates and no-surface-treated concrete template attached biomass and abundance of organisms were very low ; Biomass and abundance indices and ecological indices do not show a certain degree of regularity.展开更多
Metal binding of organic ligands can definitely affect its environmental behavior in waters,while information on the binding heterogeneity with different organic ligands is still lacked till now.In this study,the bind...Metal binding of organic ligands can definitely affect its environmental behavior in waters,while information on the binding heterogeneity with different organic ligands is still lacked till now.In this study,the binding of zinc with organic matters associated with cyanobacterial blooms,including dissolved organic matters（DOM） and attached organic matters（AOM）,were studied by using fluorescence quenching titration combined with two-dimensional correlation spectroscopy（2D-COS）.Metal-induced fluorescent quenching was obviously observed both for DOM and AOM,indicating the formation of metal-ligand complexes.Compared with the one-dimensional spectra,2D-COS revealed the sequences of metal-ligand interaction with the following orders：276 nm 〉 232 ran for DOM and232 nm 〉 276 nm for AOM.Furthermore,the modified Stern-Volmer model showed that the binding constant（logKM） of 276 nm in DOM was higher than that of 232 nm（4.93 vs.4.51）,while AOM was characterized with a high binding affinity for 232 nm（log KM：4.83）.The ranks of log KM values were consistent with the sequential orders derived from 2D-COS results both for the two samples.Fluorescence quenching titration combined with 2D-COS was an effective method to characterize the metal-ligand interaction.展开更多
基金Supported by Fund on the National Key Technology R&D Program of the Ministry of Science and Technology of China(2012BAD18B022012BAD18B01-2)+1 种基金The National Public Welfare Industry(Agriculture)Special Program(201003068)The Special Project for the Social Common Wealth Research of the National Science Research Institute(2015TS05)
文摘In order to understand the biological community characteristics of different surface treatments of ＇artificial reef templates ,which had been placed on the offshore, Yuanzhou island, Daya Bay. Sampling survey was taken in August of 2014. The results showed that 39 species of fouling organisms were collected and iden- tiffed, Ostrea nigromarginata has attached the absolute position of the dominant species ; Through the concrete block surface treatment has a better biofouling effect, and red brick, granite plates and no-surface-treated concrete template attached biomass and abundance of organisms were very low ; Biomass and abundance indices and ecological indices do not show a certain degree of regularity.
基金funded by the National Natural Science Foundation of China(Nos.51479187,51209192)the China Postdoctoral Science Foundation(Nos.2014T70505+1 种基金2013M 540438)the PAPD,and the State Key Laboratory of Pollution Control and Resource Reuse Foundation(No.PCRRF13011)
文摘Metal binding of organic ligands can definitely affect its environmental behavior in waters,while information on the binding heterogeneity with different organic ligands is still lacked till now.In this study,the binding of zinc with organic matters associated with cyanobacterial blooms,including dissolved organic matters（DOM） and attached organic matters（AOM）,were studied by using fluorescence quenching titration combined with two-dimensional correlation spectroscopy（2D-COS）.Metal-induced fluorescent quenching was obviously observed both for DOM and AOM,indicating the formation of metal-ligand complexes.Compared with the one-dimensional spectra,2D-COS revealed the sequences of metal-ligand interaction with the following orders：276 nm 〉 232 ran for DOM and232 nm 〉 276 nm for AOM.Furthermore,the modified Stern-Volmer model showed that the binding constant（logKM） of 276 nm in DOM was higher than that of 232 nm（4.93 vs.4.51）,while AOM was characterized with a high binding affinity for 232 nm（log KM：4.83）.The ranks of log KM values were consistent with the sequential orders derived from 2D-COS results both for the two samples.Fluorescence quenching titration combined with 2D-COS was an effective method to characterize the metal-ligand interaction.
