A calculation method for the isothermal nucleation incubation time of pro-eutectoid ferrite formed from deformed austenite has been developed by introducing Feder's incubation time expression into the decompositio...A calculation method for the isothermal nucleation incubation time of pro-eutectoid ferrite formed from deformed austenite has been developed by introducing Feder's incubation time expression into the decomposition of deformed austenite.The effects of austenite deformation stored energy and austenite grain boundary energy change on the incubation time have been theoretically calculated and the rule of calculated results is consistent with that of experiments,this confirms that austenite deformation stored energy and the change of austenite grain boundary energy are the natural effect of austenite deformation on ferrite nucleation.展开更多
Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V(C, N) is o...Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V(C, N) is observed. The combination of thermomeehanical processes with adequate amounts of non-metallic inclusions formed in low-car- bon steels could effectively refine the grain size and the microstructure. Ferrite nucleated on the single MnS or V(C, N) inclusions and complex MnS+V(C,N) inclusion. The proper addition of elements S and V could effectively promote the formation of ferrite and further refinement of ferrite grains.展开更多
Isothermal transformation (TTT) behavior of the low carbon steels with two Si contents (0.50 wt pct and 1.35 wt pct) was investigated with and without the prior deformation. The results show that Si and the prior ...Isothermal transformation (TTT) behavior of the low carbon steels with two Si contents (0.50 wt pct and 1.35 wt pct) was investigated with and without the prior deformation. The results show that Si and the prior deformation of the austenite have significant effects on the transformation of the ferrite and bainite. The addition of Si refines the ferrite grains, accelerates the polygonal ferrite transformation and the formation of M/A constituents, leading to the improvement of the strength. The ferrite grains formed under the prior deformation of the austenite become more homogeneous and refined. However, the influence of deformation on the tensile strength of both steels is dependent on the isothermal temperatures. Thermodynamic calculation indicates that Si and prior deformation reduce the incubation time of both ferrite and bainite transformation, but the effect is weakened by the decrease of the isothermal temperatures.展开更多
The volume fraction of proeutectoid ferrite transformed from deformed austenite fv as a func- tion of isothermal time t has been investigated in 0.037% Nb microalloyed steel.The results show that lnln(1-fv)^(-1) vs In...The volume fraction of proeutectoid ferrite transformed from deformed austenite fv as a func- tion of isothermal time t has been investigated in 0.037% Nb microalloyed steel.The results show that lnln(1-fv)^(-1) vs Int relation does not follow the Avrami equation strictly and con- sists of two straight lines.By comparing the differences between the results and Cahn's theory, the authors' idea has been expounded.展开更多
The influence of prior austenite deformed at different temperature on the subsequent continuous cooling bainitic transformation has been investigated in an C-Ma-Cr-Ni-Mo plastic die steel. The results show that the pr...The influence of prior austenite deformed at different temperature on the subsequent continuous cooling bainitic transformation has been investigated in an C-Ma-Cr-Ni-Mo plastic die steel. The results show that the prior deformation in low temperature region of austenite retards significantly the bainitic transformation. For the same continuous cooling schedule, as austenite deformed at lower temperature, the quantity of the classical sheaf-like bainite becomes less. The present results show that severe deformation leads to mechanical stabilization of austenite and causes the difficulty of bainitic ferrite propagation into the austenite.展开更多
On the basis of transformation thermodynamics and kinetics theories,an algorithm for predicting ferrite grain size after continuous cooling transformation from deformed austenite to ferrite is suggested.The calculated...On the basis of transformation thermodynamics and kinetics theories,an algorithm for predicting ferrite grain size after continuous cooling transformation from deformed austenite to ferrite is suggested.The calculated results of computer simulation with the algorithm are in so good agreement with the measured ones in controlled rolling and controlled cooling experiments that the theoretical algorithm is feasible.展开更多
Based on the rigid-plastic finite element method(FEM), the shear stress field of deformation region for high manganese austenite steel during hot asymmetrical rolling process was analyzed. The influences of rolling ...Based on the rigid-plastic finite element method(FEM), the shear stress field of deformation region for high manganese austenite steel during hot asymmetrical rolling process was analyzed. The influences of rolling parameters, such as the velocity ratio of upper to lower rolls, the initial temperature of workpiece and the reduction rate, on the shear deformation of three nodes in the upper, center and lower layers were discussed. As the rolling parameters change, distinct shear deformation appears in the upper and lower layers, but the shear deformation in the center layer appears only when the velocity ratio is more than 1.00, and the absolute value of the shear stress in this layer is changed with rolling parameters. A mathematical model which reflected the change of the maximal absolute shear stress for the center layer was established, by which the maximal absolute shear stress for the center layer can be easily calculated and the appropriate rolling technology can be designed.展开更多
The austenitic heat resistant-steels have been considered as important candidate materials for advanced supercritical boilers, nuclear reactors, super heaters and chemical reactors, due to their favorable combination ...The austenitic heat resistant-steels have been considered as important candidate materials for advanced supercritical boilers, nuclear reactors, super heaters and chemical reactors, due to their favorable combination of high strength, corrosion resistance, perfect mechanical properties, workability and low cost.Since the precipitation behavior of the steels during long-term service at elevated temperature would lead to the deterioration of mechanical properties, it is essential to clarify the evolution of secondary phases in the microstructure of the steels. Here, a summary of recent progress in the precipitation behavior and the coarsening mechanism of various precipitates during aging in austenitic steels is made. Various secondary phases are formed under service conditions, like MX carbonitrides, M_(23)C_6 carbides, Z phase, sigma phase and Laves phase. It is found that the coarsening rate of M_(23)C_6 carbides is much higher than that of MX carbonitrides. In order to understand the thermal deformation mechanism, a constitutive equation can be established, and thus obtained processing maps are beneficial to optimizing thermal processing parameters, leading to improved thermal processing properties of steels.展开更多
The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing...The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.展开更多
A combined process of hot-deformation plus two-step quenching and partitioning (HDQP) treatment was applied to a low carbon 20Si2CrNi3MoV steel, and transmission electron microscopy (TEM), scanning electron micros...A combined process of hot-deformation plus two-step quenching and partitioning (HDQP) treatment was applied to a low carbon 20Si2CrNi3MoV steel, and transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), Vickers hardness and tension test were used to characterize the microstructure and mechanical properties. More stable retained austen ite due to fine microstructures and typical curved micromorphology is obtained, and the newly-treated steel obtains more retained austenite because of the effect of hot deformation. The retained austenite fraction increases and then decreases with the increasing quenching temperature from 200 to 350 ℃. The maximum retained austenite fraction (18.3 % ) and elongation (15 % ) are obtained to enhance the ductility.展开更多
文摘A calculation method for the isothermal nucleation incubation time of pro-eutectoid ferrite formed from deformed austenite has been developed by introducing Feder's incubation time expression into the decomposition of deformed austenite.The effects of austenite deformation stored energy and austenite grain boundary energy change on the incubation time have been theoretically calculated and the rule of calculated results is consistent with that of experiments,this confirms that austenite deformation stored energy and the change of austenite grain boundary energy are the natural effect of austenite deformation on ferrite nucleation.
基金Item Supported by National Natural Science Foundation of China (50871059)Specialized Research Foundation for Doctoral Program of Higher Education (20070003006)
文摘Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V(C, N) is observed. The combination of thermomeehanical processes with adequate amounts of non-metallic inclusions formed in low-car- bon steels could effectively refine the grain size and the microstructure. Ferrite nucleated on the single MnS or V(C, N) inclusions and complex MnS+V(C,N) inclusion. The proper addition of elements S and V could effectively promote the formation of ferrite and further refinement of ferrite grains.
基金the Baoshan Iron and Steel Group for the financial support
文摘Isothermal transformation (TTT) behavior of the low carbon steels with two Si contents (0.50 wt pct and 1.35 wt pct) was investigated with and without the prior deformation. The results show that Si and the prior deformation of the austenite have significant effects on the transformation of the ferrite and bainite. The addition of Si refines the ferrite grains, accelerates the polygonal ferrite transformation and the formation of M/A constituents, leading to the improvement of the strength. The ferrite grains formed under the prior deformation of the austenite become more homogeneous and refined. However, the influence of deformation on the tensile strength of both steels is dependent on the isothermal temperatures. Thermodynamic calculation indicates that Si and prior deformation reduce the incubation time of both ferrite and bainite transformation, but the effect is weakened by the decrease of the isothermal temperatures.
文摘The volume fraction of proeutectoid ferrite transformed from deformed austenite fv as a func- tion of isothermal time t has been investigated in 0.037% Nb microalloyed steel.The results show that lnln(1-fv)^(-1) vs Int relation does not follow the Avrami equation strictly and con- sists of two straight lines.By comparing the differences between the results and Cahn's theory, the authors' idea has been expounded.
文摘The influence of prior austenite deformed at different temperature on the subsequent continuous cooling bainitic transformation has been investigated in an C-Ma-Cr-Ni-Mo plastic die steel. The results show that the prior deformation in low temperature region of austenite retards significantly the bainitic transformation. For the same continuous cooling schedule, as austenite deformed at lower temperature, the quantity of the classical sheaf-like bainite becomes less. The present results show that severe deformation leads to mechanical stabilization of austenite and causes the difficulty of bainitic ferrite propagation into the austenite.
文摘On the basis of transformation thermodynamics and kinetics theories,an algorithm for predicting ferrite grain size after continuous cooling transformation from deformed austenite to ferrite is suggested.The calculated results of computer simulation with the algorithm are in so good agreement with the measured ones in controlled rolling and controlled cooling experiments that the theoretical algorithm is feasible.
基金Item Sponsored by National Natural Science Foundation of China(51274062)
文摘Based on the rigid-plastic finite element method(FEM), the shear stress field of deformation region for high manganese austenite steel during hot asymmetrical rolling process was analyzed. The influences of rolling parameters, such as the velocity ratio of upper to lower rolls, the initial temperature of workpiece and the reduction rate, on the shear deformation of three nodes in the upper, center and lower layers were discussed. As the rolling parameters change, distinct shear deformation appears in the upper and lower layers, but the shear deformation in the center layer appears only when the velocity ratio is more than 1.00, and the absolute value of the shear stress in this layer is changed with rolling parameters. A mathematical model which reflected the change of the maximal absolute shear stress for the center layer was established, by which the maximal absolute shear stress for the center layer can be easily calculated and the appropriate rolling technology can be designed.
基金the China National Funds for Distinguished Young Scientists(Grant No.51325401)the National Natural Science Foundation of China(Grant No.51474156 and U1660201)the National High Technology Research and Development Program of China(Grant No.2015AA042504)for grant and financial support
文摘The austenitic heat resistant-steels have been considered as important candidate materials for advanced supercritical boilers, nuclear reactors, super heaters and chemical reactors, due to their favorable combination of high strength, corrosion resistance, perfect mechanical properties, workability and low cost.Since the precipitation behavior of the steels during long-term service at elevated temperature would lead to the deterioration of mechanical properties, it is essential to clarify the evolution of secondary phases in the microstructure of the steels. Here, a summary of recent progress in the precipitation behavior and the coarsening mechanism of various precipitates during aging in austenitic steels is made. Various secondary phases are formed under service conditions, like MX carbonitrides, M_(23)C_6 carbides, Z phase, sigma phase and Laves phase. It is found that the coarsening rate of M_(23)C_6 carbides is much higher than that of MX carbonitrides. In order to understand the thermal deformation mechanism, a constitutive equation can be established, and thus obtained processing maps are beneficial to optimizing thermal processing parameters, leading to improved thermal processing properties of steels.
基金financial support of the National Key Research and Development Program of China(No.2017YFB0304401)National Natural Science Foundation of China(Nos.U1564203,51571141 and 51201105)the support provided by Shanghai Key Laboratory of Materials Laser Processing and Modification,Shanghai Jiao Tong University
文摘The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.
基金supported by the National Key Research and Development Plan(Nos.2017YFB0304401 and 2016YFB0101605)the Major State Basic Research Development Program of China(973Program)(No.2010CB630803)
文摘A combined process of hot-deformation plus two-step quenching and partitioning (HDQP) treatment was applied to a low carbon 20Si2CrNi3MoV steel, and transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), Vickers hardness and tension test were used to characterize the microstructure and mechanical properties. More stable retained austen ite due to fine microstructures and typical curved micromorphology is obtained, and the newly-treated steel obtains more retained austenite because of the effect of hot deformation. The retained austenite fraction increases and then decreases with the increasing quenching temperature from 200 to 350 ℃. The maximum retained austenite fraction (18.3 % ) and elongation (15 % ) are obtained to enhance the ductility.