HYDROGEN ATTACK ON AUSTENITIC STEEL 304 UNDER HIGH TEMPERATURE AND HIGH PRESSURE

The hydrogen attack of austenitic stainless steel 304 exposed to hydrogen under the pressure of 5 MPa at 733 K for 2×10~4 h in service was detected.The microstructure has been studied by SEM and TEM.Hydrogen was determined with molten samples which had tempered at.573,673,773,873,and 973 K for 6 h.The results showed that hydrogen attack in this steel was due to methane bubbles which resulted in occuring of Cr_(23)C_6.Thermodynamic analysis of hydrogen attack for stainless steel 304 was discussed.

The Enrichment of Chloride Anion in the Occluded Cell and Its Effect on Stress Corrosion Crack of 304 Stainless Steel in Low Chloride Concentration Solution

The enrichment of chloride anion within the occluded cell （OC） for Type 304 austenitic stainless steel in low chloride concentration solution has been investigated by means of a simulated OC. The influence of the enrichment of chloride anion on stress corrosion crack （SCC） of Type 304 stainless steel has been studied. It was observed that the amount of chloride anion migration was proportional to the charge flowing through the anode. Owning to the effects of enrichment of chloride anion, low chloride concentration solution could induce SCC for Type 304 stainless steel.

Softening interstage annealing of austenitic stainless steel sheets for stamping processes

To study the mechanics of work-hardening and annealing-softening, a series of experiments were conducted on samples of 304 austenitic stainless steel sheets. In addition, transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, and tensile testing were carried out to study changes and mechanisms of the stainless steel structures and properties during work-hardening and annealing-softening. The results indicate that annealing at low temperatures （100-500 ~C） can only remove partial residual stresses in the sample and the softening via annealing is not obvious. Bright annealing and rapid cooling in a protective atmosphere can completely soften the cold-worked material. In addition, the low-temperature sample without a protective atmosphere only has a little oxidation on the surface, but at higher temperature the oxidized layer is very thick. Thus, high-temperature annealing should include bright annealing.

Influence of Strain Rate on Tensile Characteristics of SUS304 Metastable Austenitic Stainless Steel

The microstructure characteristics and plastic deformation behavior of SUS304 metastable austenitic stainless steel sheets have been investigated during tensile process at different strain rates at room temperature. The yield stress continuously increases with strain rates due to low fraction of martensite transformed from austenite at 0.2% plastic stain. While the ultimate tensile stress （UTS） and elongation gradually decreases and then slightly increases with increase in strain rate from 0.0005 s-1 to 0.i s-1, which is attributed to the variation of the martensite fraction that is affected seriously by adiabatic heating. A higher temperature increase in the tensile specimens restricts the martensitic transformation at high strain rate. The strain rate of 0.1 s-1 is considered as a transition deformation rate from quasi-static state to plastic forming, where the transformed martensitic content is very small in a higher strain rate range. Anomalous stress peaks in the later half stage of deformation occur at a very low strain rate （i.e., 0.0005 s-1） result from X-shaped strain localization repeatedly sweeping over the specimen. With increasing strain rates, the variation of dimple number density follows similar trend as that of UTS and ductility because martensite fraction mostly influences void nucleation and growth.

Effect of martensitic transformation on nano/ultrafine-grained structure in 304 austenitic stainless steel

304 austenitic stainless steel was cold rolled in the range of 20%-80%reductions and then annealed at 700-900°C for 60 sto obtain nano/ultrafine-grained（NG/UFG）structure.Transmission electron microscopy,electron backscatter diffraction and X-ray diffraction were used to characterize the resulting microstructures.The results showed that with the increase of cold reduction,the content of martensite was increased.The steel performed work hardening during cold-working owing to the occurrence of strain induced martensite which nucleated in single shear bands.Further rolling broke up the lath-type martensite into dislocation-cell type martensite because of the formation of slip bands.Samples annealed at 800-960°C for 60 swere of NG/UFG structure with different percentage of nanocrystalline（60-100 nm）and ultrafine（100-500 nm）grains,submicron size（500-1000 nm）grains and micron size（〉1000 nm）grains.The value of the Gibbs free energy exhibited that the reversion mechanism of the reversion process was shear controlled by the annealing temperature.For a certain annealing time during the reversion process,austenite nucleated first on dislocation-cell type martensite and the grains grew up subsequently and eventually to be micrometer/submicrometer grains,while the nucleation of austenite on lath-type martensite occurred later resulting in nanocrystalline/ultrafine grains.The existence of the NG/UFG structure led to a higher strength and toughness during tensile test.