This paper investigates the thermal energy effect on electron auto-localization. The polaron characteristics (self-action potential and effective mass) are observed to be expressed via the renormalized electron-phonon...This paper investigates the thermal energy effect on electron auto-localization. The polaron characteristics (self-action potential and effective mass) are observed to be expressed via the renormalized electron-phonon coupling constant tailored by the thermal energy. Low temperatures are observed to favour auto-localization of the carrier while high temperatures favour polaron undressing and subsequent quenching of the quantum behaviour thereby rendering the system classical. The critical (transition) temperature <em>τ<sub>c</sub></em> expressed via the critical coupling constant <span style="white-space:nowrap;">ϒ</span><em><sub>C</sub></em> is found to be the separating boundary between the quantum and the classical phases. Therefore, the polaron undergoes phase transition (from self-tapped to quasi free states) when the temperature of the medium is enhanced.展开更多
A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanopartiele. A critical size of the cluster regarding in...A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanopartiele. A critical size of the cluster regarding in formation of an electron＇s autolocalized state, dependencies of energy and radius of a polaron on a cluster＇s size are obtained by a variational method. It has been found that binding energy of the electron in the cluster depends on a eluster＇s radius but a radius of electron＇s auto-localization does not depend on the cluster＇s radius and it equals to the polaron radius in a corresponding infinity crystal. A bound state of the electron in a cluster is possible only if the duster＇s radius is more than the polaron radius.展开更多
文摘This paper investigates the thermal energy effect on electron auto-localization. The polaron characteristics (self-action potential and effective mass) are observed to be expressed via the renormalized electron-phonon coupling constant tailored by the thermal energy. Low temperatures are observed to favour auto-localization of the carrier while high temperatures favour polaron undressing and subsequent quenching of the quantum behaviour thereby rendering the system classical. The critical (transition) temperature <em>τ<sub>c</sub></em> expressed via the critical coupling constant <span style="white-space:nowrap;">ϒ</span><em><sub>C</sub></em> is found to be the separating boundary between the quantum and the classical phases. Therefore, the polaron undergoes phase transition (from self-tapped to quasi free states) when the temperature of the medium is enhanced.
文摘A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanopartiele. A critical size of the cluster regarding in formation of an electron＇s autolocalized state, dependencies of energy and radius of a polaron on a cluster＇s size are obtained by a variational method. It has been found that binding energy of the electron in the cluster depends on a eluster＇s radius but a radius of electron＇s auto-localization does not depend on the cluster＇s radius and it equals to the polaron radius in a corresponding infinity crystal. A bound state of the electron in a cluster is possible only if the duster＇s radius is more than the polaron radius.
