Kinetic-boosted CO_(2) electroreduction to formate via synergistic electric-thermal field on hierarchical bismuth with amorphous layer

Electrocatalytic converting CO_(2) into chemical products has emerged as a promising approach to achieving carbon neutrality.Herein,we report a bismuth-based catalyst with high curvature terminal and amorphous layer which fabricated via two-step electrodeposition achieves stable formate output in a wide voltage window of 600 mV.The Faraday efficiency(FE) of formate reached up to 99.4% at-0.8 V vs.RHE and it remained constant for more than 92 h at-15 mA cm^(-2).More intriguingly,FE formate of95.4% can be realized at a current density of industrial grade(-667.7 mA cm^(-2)) in flow cell.The special structure promoted CO_(2) adsorption and reduced its activation energy and enhanced the electric-thermal field and K^(+) enrichment which accelerated the reaction kinetics.In situ spectroscopy and theoretical calculation further confirmed that the introduction of amorphous structure is beneficial to adsorpting CO_(2)and stabling*OCHO intermediate.This work provides special insights to fabricate efficient electrocatalysts by means of structural and crystal engineering and makes efforts to realize the industrialization of bismuth-based catalysts.

Values of macular ganglion cell-inner plexiform layer and 10-2 visual field measurements in detecting and evaluating glaucoma

AIM:To assess the performance of macular ganglion cell-inner plexiform layer thickness(mGCIPLT)and 10-2 visual field(VF)parameters in detecting early glaucoma and evaluating the severity of advanced glaucoma.METHODS:Totally 127 eyes from 89 participants(36 eyes of 19 healthy participants,45 eyes of 31 early glaucoma patients and 46 eyes of 39 advanced glaucoma patients)were included.The relationships between the optical coherence tomography(OCT)-derived parameters and VF sensitivity were determined.Patients with early glaucoma were divided into eyes with or without central 10°of the VF damages(CVFDs),and the diagnostic performances of OCT-derived parameters were assessed.RESULTS:In early glaucoma,the mGCIPLT was significantly correlated with 10-2 VF pattern standard deviation(PSD;with average mGCIPLT:β=-0.046,95%CI,-0.067 to-0.024,P<0.001).In advanced glaucoma,the mGCIPLT was related to the 24-2 VF mean deviation(MD;with average mGCIPLT:β=0.397,95%CI,0.199 to 0.595,P<0.001),10-2 VF MD(with average mGCIPLT:β=0.762,95%CI,0.485 to 1.038,P<0.001)and 24-2 VF PSD(with average mGCIPLT:β=0.244,95%CI,0.124 to 0.364,P<0.001).Except for the minimum and superotemporal mGCIPLT,the decrease of mGCIPLT in early glaucomatous eyes with CVFDs was more severe than that of early glaucomatous eyes without CVFDs.The area under the curve(AUC)of the average mGCIPLT(AUC=0.949,95%CI,0.868 to 0.982)was greater than that of the average circumpapillary retinal nerve fiber layer thickness(cpRNFLT;AUC=0.827,95%CI,0.674 to 0.918)and rim area(AUC=0.799,95%CI,0.610 to 0.907)in early glaucomatous eyes with CVFDs versus normal eyes.CONCLUSION:The 10-2 VF and mGCIPLT parameters are complementary to 24-2 VF,cpRNFLT and ONH parameters,especially in detecting early glaucoma with CVFDs and evaluating the severity of advanced glaucoma in group level.

Layered injection technology for chemical flooding of Class-Ⅲ oil reservoirs in the Daqing Oil Fields complex,Songliao Basin,Northeast China

The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the total geological reserves of the oilfield.Therefore,they have considerable potential for future oil production.The current layered injection technologies fail to achieve effective control over the low single-layer injection rates since they can only produce low throttle differential pressure under low injection rates(5-20 m^(3)/d).In this study,a symmetrically-structured double-offset-hole injection allocator and a novel throttling component were developed.Their spatial layout was constructed and mechanical parameters were optimized using finite element analysis,which allows for expanding the flow rate range at low injection rates.According to experimental results,the throttle differential pressure increased from 0.2 MPa to 0.8 MPa at an injection rate of 5 m^(3)/d,and the range of the single-layer flow rates expanded from 20-70 m^(3)/d to 5-70 m3/d.The field test results show that the effective production of oil layers with medium and low permeability was achieved and that the ratio of producing oil layer thickness to the total reservoir thickness increased by 9.7%on average.Therefore,this study provides valuable technical support for the effective chemical-flooding-based development of Class-Ⅲ oil reservoirs.

Stress corrosion cracking behavior of buried oil and gas pipeline steel under the coexistence of magnetic field and sulfate-reducing bacteria

Magnetic field and microorganisms are important factors influencing the stress corrosion cracking(SCC)of buried oil and gas pipelines. Once SCC occurs in buried pipelines, it will cause serious hazards to the soil environment. The SCC behavior of X80 pipeline steel under the magnetic field and sulfate-reducing bacteria(SRB) environment was investigated by immersion tests, electrochemical tests, and slow strain rate tensile(SSRT) tests. The results showed that the corrosion and SCC sensitivity of X80 steel decreased with increasing the magnetic field strength in the sterile environment. The SCC sensitivity was higher in the biotic environment inoculated with SRB, but it also decreased with increasing magnetic field strength, which was due to the magnetic field reduces microbial activity and promotes the formation of dense film layer. This work provided theoretical guidance on the prevention of SCC in pipeline steel under magnetic field and SRB coexistence.

Simulation of Corrosion-Induced Cracking of Reinforced Concrete Based on Fracture Phase Field Method

Accurate simulation of the cracking process caused by rust expansion of reinforced concrete(RC)structures plays an intuitive role in revealing the corrosion-induced failure mechanism.Considering the quasi-brittle fracture of concrete,the fracture phase field driven by the compressive-shear term is constructed and added to the traditional brittle fracture phase field model.The rationality of the proposed model is verified by a mixed fracture example under a shear displacement load.Then,the extended fracture phase model is applied to simulate the corrosion-induced cracking process of RC.The cracking patterns caused by non-uniform corrosion expansion are discussed for RC specimens with homogeneous macroscopically or heterogeneous with different polygonal aggregate distributions at the mesoscopic scale.Then,the effects of the protective layer on the crack propagation trajectory and cracking resistance are investigated,illustrating that the cracking angle and cracking resistance increase with the increase of the protective layer thickness,consistent with the experimental observation.Finally,the corrosion-induced cracking process of concrete specimens with large and small spacing rebars is simulated,and the interaction of multiple corrosion cracking is easily influenced by the reinforcement spacing,which increases with the decrease of the steel bar interval.These conclusions play an important role in the design of engineering anti-corrosion measures.The fracture phase field model can provide strong support for the life assessment of RC structures.

Effects of direct current electric field on corrosion behaviour of copper, Cl- ion migration behaviour and dendrites growth under thin electrolyte layer

Effect of direct current electric field （DCEF） on corrosion behaviour of copper printed circuit board （PCB-Cu）, Cl-ion migration behaviour, dendrites growth under thin electrolyte layer was investigated using potentiodynamic polarization and scanning electron microscopy （SEM） with energy dispersive spectrometer （EDS）. Results indicate that DCEF decreases the corrosion of PCB-Cu;Cl-ions directionally migrate from the negative pole to the positive pole, and enrich on the surface of the positive pole, which causes serious localized corrosion; dendrites grow on the surface of the negative pole, and the rate and scale of dendrite growth become faster and greater with the increase of external voltage and exposure time, respectively.

A Laboratory Modeling of the Velocity Field in the Convective Boundary Layer with the Particle Image Velocimetry Technique

Based on the research of the convective boundary layer (CBL) temperature field in a convective tank, this paper studies the characteristics of the CBL velocity field in the convective tank. Aluminium powder (400 orders) is used as a tracer particle in the application of the particle image velocimetry (PIV) technique. The experiment demonstrates: the velocity distribution in the mixed layer clearly possesses the characteristics of CBL thermals; the velocity distribution in the top zone of the mixed layer shows entrainment layer characteristics; the vertical distribution of turbulent characteristic variables is reasonable, which is similar to field observations and other tank results; the error analysis demonstrates the validity of aluminium powder, which implies the reliability of the results.

Breakdown voltage model and structure realization of a thin silicon layer with linear variable doping on a silicon on insulator high voltage device with multiple step field plates

Based on the theoretical and experimental investigation of a thin silicon layer（TSL） with linear variable doping（LVD） and further research on the TSL LVD with a multiple step field plate（MSFP）,a breakdown voltage（BV） model is proposed and experimentally verified in this paper.With the two-dimensional Poisson equation of the silicon on insulator（SOI） device,the lateral electric field in drift region of the thin silicon layer is assumed to be constant.For the SOI device with LVD in the thin silicon layer,the dependence of the BV on impurity concentration under the drain is investigated by an enhanced dielectric layer field（ENDIF）,from which the reduced surface field（RESURF） condition is deduced.The drain in the centre of the device has a good self-isolation effect,but the problem of the high voltage interconnection（HVI） line will become serious.The two step field plates including the source field plate and gate field plate can be adopted to shield the HVI adverse effect on the device.Based on this model,the TSL LVD SOI n-channel lateral double-diffused MOSFET（nLDMOS） with MSFP is realized.The experimental breakdown voltage（BV） and specific on-resistance（R on,sp） of the TSL LVD SOI device are 694 V and 21.3 ·mm 2 with a drift region length of 60 μm,buried oxide layer of 3 μm,and silicon layer of 0.15 μm,respectively.

Development of mean-field electrical double layer theory

In order to understand the electric interfacial behavior, mean field based electric double layer （EDL） theory has been continuously developed over the past 150 years. In this article, we briefly review the development of the EDL model, from the dimensionless Gouy-Chapman model to the symmetric Bikerman-Freise model, and finally toward size-asymmetric mean field theory models. We provide the general derivations within the framework of Helmholtz free energy of the lattice- gas model, and it can be seen that the above-mentioned models are consistent in the sense that the interconversi0n among them can be achieved by reducing the basic assumptions.

Experimental studies on flow visualization and velocity field of compression ramp with different incoming boundary layers

Experimental studies which focus on flow visualization and the velocity field of a supersonic laminar/turbulent flow over a compression ramp were carried out in a Mach 3.0 wind tunnel. Fine flow structures and velocity field structures were obtained via NPLS （nanoparticle-tracer planar laser scattering） and PIV （particle image velocimetry） techniques, time- averaged flow structures were researched, and spatiotemporal evolutions of transient flow structures were analyzed. The flow visualization results indicated that when the ramp angles were 25~, a typical separation occurred in the laminar flow, some typical flow structures such as shock induced by the boundary layer, separation shock, reversed flow and reattachment shock were visible clearly. While a certain extent separation occurred in turbulent flow, the separation region was much smaller. When the ramp angles were 28~, laminar flow separated further, and the separation region expanded evidently, flow structures in the separation region were complex. While a typical separation occurred in turbulent flow, reversed flow structures were significant, flow structures in the separation region were relatively simple. The experimental results of velocity field were corresponding to flow visualization, and the velocity field structures of both compression ramp flows agreed with the flow structures well. There were three layered structures in the U component velocity, and the V component velocity appeared like an oblique ＂v＂. Some differences between these two compression ramp flows can be observed in the velocity profiles of the shear layer and the shearing intensity.

Non-Gaussian Lagrangian Stochastic Model for Wind Field Simulation in the Surface Layer

Wind field simulation in the surface layer is often used to manage natural resources in terms of air quality,gene flow(through pollen drift),and plant disease transmission(spore dispersion).Although Lagrangian stochastic(LS)models describe stochastic wind behaviors,such models assume that wind velocities follow Gaussian distributions.However,measured surface-layer wind velocities show a strong skewness and kurtosis.This paper presents an improved model,a non-Gaussian LS model,which incorporates controllable non-Gaussian random variables to simulate the targeted non-Gaussian velocity distribution with more accurate skewness and kurtosis.Wind velocity statistics generated by the non-Gaussian model are evaluated by using the field data from the Cooperative Atmospheric Surface Exchange Study,October 1999 experimental dataset and comparing the data with statistics from the original Gaussian model.Results show that the non-Gaussian model improves the wind trajectory simulation by stably producing precise skewness and kurtosis in simulated wind velocities without sacrificing other features of the traditional Gaussian LS model,such as the accuracy in the mean and variance of simulated velocities.This improvement also leads to better accuracy in friction velocity(i.e.,a coupling of three-dimensional velocities).The model can also accommodate various non-Gaussian wind fields and a wide range of skewness–kurtosis combinations.Moreover,improved skewness and kurtosis in the simulated velocity will result in a significantly different dispersion for wind/particle simulations.Thus,the non-Gaussian model is worth applying to wind field simulation in the surface layer.

Three-Dimensional Modelling of a Multi-Layer Sandstone Reservoir： the Sebei Gas Field, China

Multi-layer sandstone reservoirs occur globally and are currently in international production. The 3D characteristics of these reservoirs are too complicated to be accurately delineated by general structural-facies-reservoir modelling. In view of the special geological features, such as the vertical architecture of sandstone and mudstone interbeds, the lateral stable sedimentation and the strong heterogeneity of reservoir poroperm and fluid distribution, we developed a new three-stage and six-phase procedure for 3D characterization of multi-layer sandstone reservoirs. The procedure comprises two-phase structural modelling, two-phase facies modelling and modelling of two types of reservoir properties. Using this procedure, we established models of the formation structure, sand body structure and microfacies, reservoir facies and properties including porosity, permeability and gas saturation and provided a 3D fine-scale, systematic characterization of the Sebei multi-layer sandstone gas field, China. This new procedure, validated by the Sebei gas field, can be applied to characterize similar multi-layer sandstone reservoirs.

A high mobility C_(60) field-effect transistor with an ultrathin pentacene passivation layer and bathophenanthroline/metal bilayer electrodes

C60 field-effect transistor （OFET） with a mobility as high as 5.17 cm2/V.s is fabricated. In our experiment, an ultrathin pentacene passivation layer on poly-（methyl methacrylate） （PMMA） insulator and a bathophenanthroline （Bphen）/Ag bilayer electrode are prepared. The OFET shows a significant enhancement of electron mobility compared with the corresponding device with a single PMMA insultor and an Ag electrode. By analysing the C60 film with atomic force microscopy and X-ray diffraction techniques, it is shown that the pentacene passivation layer can contribute to C60 film growth with the large grain size and significantly improve crystallinity. Moreover, the Bphen buffer layer can reduce the electron contact barrier from Ag electrodes to C60 film efficiently.

A novel LDMOS with a junction field plate and a partial N-buried layer

A novel lateral double-diffused metal–oxide semiconductor（LDMOS） with a high breakdown voltage（BV） and low specific on-resistance（Ron.sp） is proposed and investigated by simulation. It features a junction field plate（JFP） over the drift region and a partial N-buried layer（PNB） in the P-substrate. The JFP not only smoothes the surface electric field（E-field）, but also brings in charge compensation between the JFP and the N-drift region, which increases the doping concentration of the N-drift region. The PNB reshapes the equipotential contours, and thus reduces the E-field peak on the drain side and increases that on the source side. Moreover, the PNB extends the depletion width in the substrate by introducing an additional vertical diode, resulting in a significant improvement on the vertical BV. Compared with the conventional LDMOS with the same dimensional parameters, the novel LDMOS has an increase in BV value by 67.4%,and a reduction in Ron.sp by 45.7% simultaneously.

Kelvin-Helmholtz Instability in a Fluid Layer Bounded Above by a Porous Layer and Below by a Rigid Surface in Presence of Magnetic Field

We study the stability of an interface between two fluids of different densities flowing parallel to each other in the presence of a transverse magnetic field. A simple theory based on fully developed flow approximations is used to de-rive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The magnetic field is found to be stabilizing and the influence of the various parameters of the problem on the interface stability is thoroughly analyzed. These are favorable to control the surface instabilities in many practical applications discussed in this paper.

Influence of Schottky drain contacts on the strained AlGaN barrier layer of AlGaN/AlN/GaN heterostructure field-effect transistors

Rectangular Schottky drain AlGaN/AlN/GaN heterostructure field-effect transistors （HFETs） with different gate contact areas and conventional AlGaN/AlN/GaN HFETs as control were both fabricated with same size. It was found there is a significant difference between Schottky drain AlGaN/AlN/GaN HFETs and the control group both in drain series resistance and in two-dimensional electron gas （2DEG） electron mobility in the gate–drain channel. We attribute this to the different influence of Ohmic drain contacts and Schottky drain contacts on the strained AlGaN barrier layer. For conventional AlGaN/AlN/GaN HFETs, annealing drain Ohmic contacts gives rise to a strain variation in the AlGaN barrier layer between the gate contacts and the drain contacts, and results in strong polarization Coulomb field scattering in this region. In Schottky drain AlGaN/AlN/GaN HFETs, the strain in the AlGaN barrier layer is distributed more regularly.

Electrical properties and electrical field in depletion layer for CZT crystals

Current—voltage (I—V) and capacitance—voltage (C—V) characteristics of Au/p-CZT contacts with different surface treatments on cadmium zinc telluride (CZT) wafer’s surface were measured with Agilent 4339B high resistance meter and Agilent 4294A precision impedance analyzer, respectively. The Schottky barrier height was 0.85±0.05, 0.96±0.05 eV for non-passivated and passivated CZT crystals by I—V measurement. By C—V measurement, the Schottky barrier height was 1.39±0.05, 1.51±0.05 eV for non-passivated and passivated CZT crystals. The results show that the passivation treatment can increase the barrier height of the Au/p-CZT contact and decrease the leakage current. The main reason is that the higher barrier height of Au/p-CZT contacts can decrease the possibility for electrons to pass through the native TeO2 film. Most of the applied voltage appears on the depleted layer and there is only a negligible voltage drops across the nearly undepleted region. Furthermore, the electric field in the depleted layer is not uniform and can be calculated by the depletion approximation. The maximum electric field of CZT crystals is Em1=133 V/cm at x=0 for non-passivated CZT crystal and Em2=55 V/cm for passivated CZT crystal, respectively.

Anisotropy of Critical Fields in MgB_2: Two-Band Ginzburg-Landau Theory for Layered Superconductors

The temperature dependence of the anisotropy parameter of upper critical field γHe2 （T） = Hc2^‖ （T） /Hc2^⊥ （T） and London penetration depth γλ （T） = λ‖（T）/λ⊥ （T） are calculated using two-band Ginzburg-Landau theory for layered superconductors. It is shown that, with decreasing temperature the anisotropy parameter γHc2 （T） is increased, while the London penetration depth anisotropy γλ（T） reveals an opposite behavior. Results of our calculations are in agreement with experimental data for single crystal MgB2 and with other calculations..Results of an analysis of magnetic field Hc1 in a single vortex between superconducting layers are also presented.

Effect of Magnetic Field on Kelvin-Helmholtz Instability in a Couple-Stress Fluid Layer Bounded Above by a Porous Layer and Below by a Rigid Surface

Kelvin-Helmholtz instability (KHI) appears in stratified two-fluid flow at surface. When the relative velocity is higher than the critical relative velocity, the growth of waves occurs. It is found that magnetic field has a stabilization effect whereas the buoyancy force has a destabilization effect on the KHI in the presence of sharp inter-face. The RT instability increases with wave number and flow shear, and acts much like a KHI when destabilizing effect of sheared flow dominates. It is shown that both of ablation velocity and magnetic field have stabilization effect on RT instability in the presence of continued interface. In this paper, we study the effect of magnetic field on Kelvin-Helmholtz instability (KHI) in a Couple-stress fluid layer above by a porous layer and below by a rigid surface. A simple theory based on fully developed flow approximations is used to derive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition at the rigid surface. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The stabilization effect of magnetic field takes place for whole waveband and becomes more significant for the short wavelength. The growth rate decreases as the density scale length increases. The stabilization effect of magnetic field is more significant for the short density scale length.

Numerical Solution of MHD Boundary Layer Flow of Non-Newtonian Casson Fluid on a Moving Wedge with Heat and Mass Transfer and Induced Magnetic Field

The paper investigates the numerical solution of the magnetohydrodynamics (MHD) boundary layer flow of non-Newtonian Casson fluid on a moving wedge with heat and mass transfer. The effects of thermal diffusion and diffusion thermo with induced magnetic field are taken in consideration. The governing partial differential equations are transformed into nonlinear ordinary differential equations by applying the similarity transformation and solved numerically by using finite difference method (FDM). The effects of various governing parameters, on the velocity, temperature and concentration are displayed through graphs and discussed numerically. In order to verify the accuracy of the present results, we have compared these results with the analytical solutions by using the differential transform method (DTM). It is observed that this approximate numerical solution is in good agreement with the analytical solution. Furthermore, comparisons of the present results with previously published work show that the present results have high accuracy.