The fly ashes(Class F and C)have been successfully used as the main substrates in the hydrothermal syntheses of Na-A,Na-P1,Na-X and sodalite zeolites.Both ashes and their derivatives after milling with magnetic field ...The fly ashes(Class F and C)have been successfully used as the main substrates in the hydrothermal syntheses of Na-A,Na-P1,Na-X and sodalite zeolites.Both ashes and their derivatives after milling with magnetic field grinder were used.The paper investigates the effect of fly ash fraction size on the syntheses efficiency and physicochemical properties of the obtained zeolites.The starting material and obtained zeolites were subjected to physicochemical characteristics using X-ray diffraction,X-ray fluorescence,particle size analysis,and scanning electron microscopy methods.The paper showed a significant effect of the used fly ash fractions on the quantity,purity,quality and level of crystallinity of the zeolites phase obtained.The application of the grinding process prior to the syntheses of zeolites,with a relatively small financial outlay,significantly increases their application potential.Obtained zeolites are a promising material in the context of their use,inter alia,in environmental protection.展开更多
The geological behaviors of wet outflow deposition fly ash were investigated, including the feature of in-situ single and even bridge cone penetration test (CPT) curves, the change of the penetration parameters and va...The geological behaviors of wet outflow deposition fly ash were investigated, including the feature of in-situ single and even bridge cone penetration test (CPT) curves, the change of the penetration parameters and vane strength with the increase of depth and the difference of the penetration resistance on and down the water level. Drilling, CPT and vane shear test were carried out in silty clay, fine sand, and fly ash of the ash-dam. The CPT curves of the fly ash do not show a critical depth. The cone resistance (qc) of the fly ash is smaller than that of silty clay or sand; the friction resistance is smaller than that of filling silty clay, similar to that of deposition silty clay or more than that of fine sand; the friction ratio is smaller than that of filling silty clay, or more than that of deposition silty clay or much more than that of fine sand. The specific penetration resistance (ps) is similar to that of filling silty clay, or more than that of deposition silty clay. There is a clear interface effect between the deposition fly ash and the clay. Interface effect of ps-h curve at the groundwater table is clear, and ps of the fly ash reduces significantly under the table. The vane strength of the fly ash increases as the depth increases. The deposition fly ash with wet outflow is similar to silt in the geological behavior.展开更多
Recently, a large amount of circulating fluidized bed boiler ash (CFBA) and desulfurization gypsum (DSG) has been produced, and it is essential to develop technology to utilize them. These materials have CaO and SO<...Recently, a large amount of circulating fluidized bed boiler ash (CFBA) and desulfurization gypsum (DSG) has been produced, and it is essential to develop technology to utilize them. These materials have CaO and SO</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">are</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> considered to be a stimulant for blast furnace slag (BFS). This study presents an experimental investigation of the compressive strength and heavy metal ions immobilization properties of cement-free materials comprising CFBA, BFS, and DSG. The feasibility of manufacturing foamed concrete using these materials was examined, and field test of foamed concrete was conducted. Experimentally, the flow, compressive strength, and heavy metal ions concentration were evaluated via inductively coupled plasma atomic emission spectroscopy (ICP</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">-</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">AES) of the paste and foamed concrete. The experimental investigation revealed the self-healing hardening ability of fluidized bed boiler ash. In addition, the compressive strength was increased with the increasing replacement rates of BFS and DSG in the CFBA paste, and the compressive strength of 14.6</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> - </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">17.2 MPa was recorded over 28 days of curing. From the result obtained, the feasibility of manufacturing foamed concrete with a foam volume </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">of </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">120 L, incorporating the aforementioned materials, is confirmed. It was also found that after 28 days of age, a 7.9-MPa compressive strength of the foamed concrete was attained, and heavy metal ions elution in this foamed concrete was also significantly reduced. Therefore, CFBA, BFS, and DSG could be used as a binder for the foamed concrete.展开更多
基金financed by The National Center for Research and Development contract No GEKON2/O2/266818/1/2015.
文摘The fly ashes(Class F and C)have been successfully used as the main substrates in the hydrothermal syntheses of Na-A,Na-P1,Na-X and sodalite zeolites.Both ashes and their derivatives after milling with magnetic field grinder were used.The paper investigates the effect of fly ash fraction size on the syntheses efficiency and physicochemical properties of the obtained zeolites.The starting material and obtained zeolites were subjected to physicochemical characteristics using X-ray diffraction,X-ray fluorescence,particle size analysis,and scanning electron microscopy methods.The paper showed a significant effect of the used fly ash fractions on the quantity,purity,quality and level of crystallinity of the zeolites phase obtained.The application of the grinding process prior to the syntheses of zeolites,with a relatively small financial outlay,significantly increases their application potential.Obtained zeolites are a promising material in the context of their use,inter alia,in environmental protection.
基金Project(05JJ30105) supported by the Hunan Provincial Natural Science Foundation, ChinaProject(20070420818) supported by the China Postdoctoral Science Foundation
文摘The geological behaviors of wet outflow deposition fly ash were investigated, including the feature of in-situ single and even bridge cone penetration test (CPT) curves, the change of the penetration parameters and vane strength with the increase of depth and the difference of the penetration resistance on and down the water level. Drilling, CPT and vane shear test were carried out in silty clay, fine sand, and fly ash of the ash-dam. The CPT curves of the fly ash do not show a critical depth. The cone resistance (qc) of the fly ash is smaller than that of silty clay or sand; the friction resistance is smaller than that of filling silty clay, similar to that of deposition silty clay or more than that of fine sand; the friction ratio is smaller than that of filling silty clay, or more than that of deposition silty clay or much more than that of fine sand. The specific penetration resistance (ps) is similar to that of filling silty clay, or more than that of deposition silty clay. There is a clear interface effect between the deposition fly ash and the clay. Interface effect of ps-h curve at the groundwater table is clear, and ps of the fly ash reduces significantly under the table. The vane strength of the fly ash increases as the depth increases. The deposition fly ash with wet outflow is similar to silt in the geological behavior.
文摘Recently, a large amount of circulating fluidized bed boiler ash (CFBA) and desulfurization gypsum (DSG) has been produced, and it is essential to develop technology to utilize them. These materials have CaO and SO</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">are</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> considered to be a stimulant for blast furnace slag (BFS). This study presents an experimental investigation of the compressive strength and heavy metal ions immobilization properties of cement-free materials comprising CFBA, BFS, and DSG. The feasibility of manufacturing foamed concrete using these materials was examined, and field test of foamed concrete was conducted. Experimentally, the flow, compressive strength, and heavy metal ions concentration were evaluated via inductively coupled plasma atomic emission spectroscopy (ICP</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">-</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">AES) of the paste and foamed concrete. The experimental investigation revealed the self-healing hardening ability of fluidized bed boiler ash. In addition, the compressive strength was increased with the increasing replacement rates of BFS and DSG in the CFBA paste, and the compressive strength of 14.6</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> - </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">17.2 MPa was recorded over 28 days of curing. From the result obtained, the feasibility of manufacturing foamed concrete with a foam volume </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">of </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">120 L, incorporating the aforementioned materials, is confirmed. It was also found that after 28 days of age, a 7.9-MPa compressive strength of the foamed concrete was attained, and heavy metal ions elution in this foamed concrete was also significantly reduced. Therefore, CFBA, BFS, and DSG could be used as a binder for the foamed concrete.